CN1545577A - 用于消防服外套的织物 - Google Patents

用于消防服外套的织物 Download PDF

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CN1545577A
CN1545577A CNA028163419A CN02816341A CN1545577A CN 1545577 A CN1545577 A CN 1545577A CN A028163419 A CNA028163419 A CN A028163419A CN 02816341 A CN02816341 A CN 02816341A CN 1545577 A CN1545577 A CN 1545577A
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查尔斯·A·托马斯
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克利夫顿·A·佩里
O
理查德·O·塔克
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Abstract

本发明涉及一种织物(10)。该织物特别适合用作由短纤纱(12)和复丝纱线(14)构成的外套织物。所述短纤纱(12)包括第一短纤维和第二短纤维,所述第一短纤维是从由PBI、PBO、或者三聚氰胺甲醛构成的组中选择的一种聚合物,所述第二短纤维是芳族聚酰胺长丝。

Description

用于消防服外套的织物
技术领域
本发明涉及一种用作消防服外套织物的织物。
背景技术
消防服的外套织物必须是防火、防热、防磨损、防撕裂和防潮气、耐用和轻质的。所述外套织物提供了用于消防服的第一保护层。
U.S.专利Nos.5,095,549;5,136,723;5,701,606;5,983,409;5,996,122;和6,038,700在众多事项中公开了具有由PBI/芳族聚酰胺纤维制成的外套织物的消防服。
U.S.专利No.5,299,602公开了一种机织的用于消防服的外套织物,其中经纱是复丝芳族聚酸胺纱线,而纬纱或者是复丝纱线或者是芳族聚酰胺短纤纱。
U.S.专利No.5,628,065公开了一种由PBI和芳族聚酰胺纤维的混合物制成的针织物的消防服风帽。
U.S.专利Nos.6,065,153和6,192,520公开了一种用于消防服的机织外套织物。这种织物具有平纹、斜纹或者防破裂(rip stop)组织,并且纱线是PBI和芳族聚酰胺纤维的混合物。所述织物具有5.5至8OSY范围内的重量,优选是7.5OSY。
一种流行的外套织物是短纤纱的机织织物,所述纱线由PBI和芳族聚酰胺短纤维构成。这种织物在市场上已知为“PBI GOLD”。在美国,所述织物通常通过下述的方式制成:1)由16/2c.c.的由40%重量的PBI和60%重量的对-芳族聚酰胺构成的短纤纱制成的7.5OSY防破裂组织;或者2)一个标称7.0OSY(实际上为7.3至7.4OSY)防破裂组织,其由40%重量的PBI和60%重量的对-芳族聚酰胺构成的21/2c.c.短纤纱制成。
在国际上,所述织物为6.0至6.5OSY防破裂组织的形式,所述组织由40%重量的PBI和60%重量的对-芳族聚酰胺构成的24-25/2c.c.短纤纱制成,或者所述织物为斜纹组织的形式,该组织由40%重量的PBI和60%重量的对-芳族聚酰胺构成的35/2c.c.短纤纱制成。
另一种用作外套织物的织物在市场上的商品名为“Millenia”,由GA,Union City的Southern Mills,Inc.制造。所述Millenia织物利用由40%PBO和60%对-芳族聚酰胺构成的短纤纱制成。
同时“PBI GOLD”已经证明是极好的外套织物,仍然需要改进这些织物。期望具有一种更轻质的织物,所述织物具有更好的抗撕裂和抗磨损性能。
发明内容
本发明涉及一种织物。所述织物优选用作消防服的外套织物。所述织物是短纤纱和复丝纱线的机织织物。所述短纤纱包括第一短纤维和第二短纤维,所述第一短纤维是选自由PBI或者PBO或者三聚氰胺甲醛树脂构成的组中的一种聚合物;所述第二短纤维是芳族聚酰胺聚合物。所述复丝纱线包括一种芳族聚酰胺长丝。
附图说明
为了表示本发明,在所述附图中表示了本发明的一种形式,然而,应当理解,本发明不局限于图示的精确设置和手段。
图1是根据本发明制造的织物的俯视图;
图2是根据本发明制造的织物的放大的俯视图;
具体实施方式
参照附图,其中类似的标号表示类似的元件。在图1中表示了根据本发明制造的织物10。优选的,所述织物10为金色,具有通过黑色复丝纱线14形成的“方格”图案。所述织物10优选用短纤纱12和复丝纱线14织造。织物组织选自这样一组,该组由平纹、斜纹、防破裂和牛津组织构成。织物重量可以在6至8OSY的范围内,优选为7OSY。短纤纱与复丝纱的重量比的范围应当为85∶15至92∶8,优选为90∶10。复丝纱可以插入在所述短纤纱中,包括在经纱和纬纱中,其插入比率为1∶5至1∶20,优选为1∶9。优选地,所述织物用抗水/潮气整理处理,这是已知的。
所述短纤纱12是第一短纤维和第二短纤维的一种混合物。第一短纤维是由从PBI、PBO、或者三聚氰胺甲醛树脂或者其结合构成的组中选择的一种聚合物制成。所述第二短纤维是由芳族聚酰胺或者其混合物制成的纤维。示例的短纤纱包括,但是不局限于,PBI和芳族聚酰胺短纤维、PBO和芳族聚酰胺短纤维、三聚氰胺甲醛树脂和芳族聚酰胺短纤维和PBI、PBO、三聚氰胺甲醛树脂和芳族聚酰胺短纤维的混合物。所述短纤纱优选包括45%重量的第一短纤维和55%重量的芳族聚酰胺短纤维。所述短纤纱可以在32/2至16/2c.c.的尺寸范围内,优选地,为24/2c.c.。
PBI短纤维可以在商业上从NC Charlotte的Celanese AcetateLLC获得。PBO短纤维可以从日本Osaka的Toyobo Co.,Ltd以商品名ZYLON从商业上获得。三聚氰胺甲醛树脂纤维可以从NewJersey,Mount Olive的BASF Corporation以商品名BASOFIL从商业上获得。
芳族聚酰胺短纤维可以或者是间-芳族聚酰胺或者是对-芳族聚酰胺;其中优选为对-芳族聚酰胺。这种芳族聚酰胺纤维可以从日本Osaka的Teijin Co.以商品名TWARON、CONEX、TECHNORA;从德国Wilmington的Dupont以商品名NOMEX或者KELVAR;或者从奥地利Lenzing的Lenzing AG的P84或者从新泽西Cranbury的Rhodia Inc.以商品名KERMEL从商业上获得。
复丝纱线由芳族聚酰胺长丝制成。芳族聚酰胺可以或者是间-芳族聚酰胺或者是对-芳族聚酰胺;其中优选为对-芳族聚酰胺。这种芳族聚酰胺纤维可以从日本Osaka的Teijin Co.以商品名TECHNORA、TWARON、CONEX;从德国Wilmington的Dupont以商品名NOMEX或者KELVAR;或者从奥地利Lenzing的Lenzing AG的P84或者从新泽西Cranbury的Rhodia Inc.以商品名KERMEL从商业上获得。复丝纱线的尺寸范围为200至1500旦尼尔,优选为400旦尼尔。复丝纱线可以是无捻纱线、加捻纱线或者拉伸断裂纱线(stretch broken yarn)。
与PBI GOLD织物相比,本发明具有优良的抗撕裂和抗磨损性能,并且具有较低的重量。结果如表1所示。
织物A为6.0OSY织物;短纤纱是27/2c.c.,具有45%重量的PBI和55%重量的Technora短纤维;复丝纱线是无捻纱线,其在经纱和纬纱中每第10根纱线处插入。
织物B为6.9OSY织物;短纤纱是24/2c.c.,具有45%重量的PBI和55%重量的Twaron微旦尼尔(microdenier)短纤维;复丝是加捻纱线,其在经纱和纬纱中每第9根纱线处插入。
                                   表1
    性能特性        测试方法   PBIGold   发明A   发明B
重量(OSY)   7.5   6.0   6.8-7.0
梯形撕裂(Trap Tear)(1bs.) ASTM D5733(梯形1方法)   40×35   75×75   63×63
劳动磨损(Tabor abrasion) ASTM D-3844(500wt.具有H18的摩擦轮) 225 180 293
热保护性能,TPP(复合) NFPA1971(2000版6.10节)   40   40   40
在UV后的梯形撕裂 AATCC 16E(用于在1.1rad下Xenon arc曝光的标准方法)
60hr   28.4×18.7   44.6×38.5
180hr   27.8×12.3   25.7×18.9
300hr   15.2×10.6   21.2×16.1
阳光后梯形撕裂 ASTM D5733(梯形1方法)
1周   30.8×20.8   64.9×62.7
2周   24.3×17.0   45.5×40.1
3周   20.0×14.6   39.0×34.2
4周   18.8×13.1   34.0×33.9
5周   16.6×13.5   29.7×30.1
6周   14.8×10.5   26.6×23.6
本发明可以以其它形式实施,而不脱离其精神和实质贡献,因此,应当参照所附权利要求书,而不是参照前述说明;所述权利要求书表示了本发明的范围。

Claims (16)

1.一种织物,其包括:短纤纱的机织材料,所述短纤纱包括第一短纤维和第二短纤维,所述第一短纤维是从由PBI、PBO、或者三聚氰胺甲醛构成的组中选择的一种聚合物,所述第二短纤维是芳族聚酰胺聚合物,复丝纱包括一种芳族聚酰胺长丝。
2.根据权利要求1所述的织物,其特征在于,所述短纤纱与复丝纱线的重量比的范围为85∶15至92∶8。
3.根据权利要求2所述的织物,其特征在于,所述重量比为90∶10。
4.根据权利要求1所述的织物,其特征在于,所述机织织物重量为6至8OSY。
5.根据权利要求1所述的织物,其特征在于,所述机织织物具有从由平纹、斜纹、防破裂或者牛津组织构成的组中选择的一种组织。
6.根据权利要求1所述的织物,其特征在于,所述短纤纱的范围为32/2至16/2c.c。
7.根据权利要求1所述的织物,其特征在于,所述复丝纱线的范围为200至1500旦尼尔。
8.根据权利要求1所述的织物,其特征在于,所述复丝纱线以1∶5至1∶20的比率插入在短纤纱中。
9.一种织物,其包括:一种短纤纱的机织材料,所述短纤纱是短纤纱的混合物,从由PBI、PBO、三聚氰胺甲醛或者其组合物构成的组中选择的一种聚合物制成的第一短纤维,由芳族聚酰胺制成的第二短纤维,和一种复丝纱线,所述复丝纱线包括芳族聚酰胺长丝,所述复丝纱线被插入所述机织材料中,既插入经纱中又插入纬纱中,所述复丝纱线与短纤纱的比率为1∶5至1∶20。
10.根据权利要求9所述的织物,其特征在于,所述短纤纱是PBI和芳族聚酰胺短纤维的混合物。
11.根据权利要求9所述的织物,其特征在于,所述短纤纱是PBO和芳族聚酰胺短纤维的混合物。
12.根据权利要求9所述的织物,其特征在于,所述短纤纱是PBI、PBO和芳族聚酰胺短纤维的混合物。
13.根据权利要求9所述的织物,其特征在于,所述短纤纱的范围为32/2至16/2c.c。
14.根据权利要求9所述的织物,其特征在于,所述复丝纱线的范围为200至1500旦尼尔。
15.根据权利要求9所述的织物,其特征在于,所述机织织物的重量为6至8OSY。
16.根据权利要求15所述的织物,其特征在于,所述机织织物具有从由平纹、斜纹、防破裂或者牛津组织构成的组中选择的一种组织。
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