CN1544552A - Tunnel fireproof paint based on nano-surface-treatment technology and method for making same - Google Patents
Tunnel fireproof paint based on nano-surface-treatment technology and method for making same Download PDFInfo
- Publication number
- CN1544552A CN1544552A CNA2003101155251A CN200310115525A CN1544552A CN 1544552 A CN1544552 A CN 1544552A CN A2003101155251 A CNA2003101155251 A CN A2003101155251A CN 200310115525 A CN200310115525 A CN 200310115525A CN 1544552 A CN1544552 A CN 1544552A
- Authority
- CN
- China
- Prior art keywords
- nano
- fire
- coating
- tunnels
- proportioning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a tunnel fire-resisting paint including fire-resisting paint and nano paint having surface functional properties modification, wherein the fire-resisting paint comprises silicate, phosphate adhesive, polymer emulsion, skeletal material, fortifying fiber and combustion inhibitor, while the nano paint having surface functional properties modification comprises non-flammable composite polymer base-material, composite nano material, nano material surface modifier, fire-retardant elasticizer, solvent gasoline and flowing deformation agent.
Description
(1) technical field
The present invention relates to a kind of fire-proof coating for tunnels and manufacturing process thereof.
(2) background technology
Fire-proof coating for tunnels is a kind of frie retardant coating that uses in the specific occasion.Under the situation of presence of fire, it plays and delays Steel Concrete agent structure temperature rise in the tunnel, prevents that reinforcing bar destroys the effect that loses supporting capacity and cause the tunnel to collapse in explosion, the lining.Environment relative closure in the while tunnel, the tail gas loss difficulty of vehicular emission, to cause severe contamination and acid corrosion to the tunnel inwall, and some the fire-retardant compositions in the fire-proof coating for tunnels are basic oxide or oxyhydroxide, under the effect of long-term acid corrosion, may cause the fire-proof coating for tunnels degradation.
In recent years, the fire safety problem in tunnel has caused that international community pays close attention to widely.G.L.Tan (G.L.Tan, Tunnelling and Underground Space Technology, 2002, (17): 179-180) fire scene temperature of tunnel fire hazard and the destructiveness of fire are described, have proposed the necessity of tunnel fire proofing protection; (Varley N such as Varley N, Fire protection of concrete linings in tunnels, Concrete, 1999:27-30) itemized the fire scene temperature of European main tunnel fire hazard, the intensification and the structural instability process of tunnel masonry when tunnel fire hazard takes place have been inquired into, propose new tunnel fire proofing standard, emphasized the necessity of brushing fire-proof coating for tunnels; (Matsuo such as Matsuo, Yukihisa etc.[P] JP 10 310477) to have proposed with sepiolite, wollastonite, fortifying fibre, high-alumina cement, unformed silica be the main frie retardant coating of forming, this coating has good heat insulating ability and anti-burst, can be applicable to skin, tunnel etc.; (Zhao-fen Jin such as Zhao-fenJin, Yutaka Asako, etc.Heat and Mass Transfer.2000, (43): 4395-4404) inquired into of the influence of the water content of some fire retardant to the coating fire resistance, adopt a kind of new method to delay the release of fire retardant internal crystallization water, to improve its fire resistance, think that the fire resistance of fire retardant strengthens along with the increase of its body intercrystalline water-content, and CaCl has been adsorbed in utilization
2Polymer gel and the fire retardant blended way water content of controlling fire-resistant composition, obtained good effect; Passut (Passut, Johann.[P] DE 19725761) development can be used for the frie retardant coating of metal and concrete surface, consist of wilkinite, pure aluminium silicate, wollastonite, Magnesium Silicate q-agent, glass microballon and some protruded packings, binding agent is one or more in water glass, portland cement, gypsum, the phosphoric acid salt.Qin Wenqing (Qin Wenqing, fire science and technology, 2002 (3): 54-56) having proposed a kind of is main binding agent with silicate, with aluminium hydroxide, expanded vermiculite, Magnesium Trisilicate etc. is stopping composition, sodium tetraborate is the fire-proof coating for tunnels of fire proofing additive, when coat-thickness 10mm, fire endurance 120min; What old and well-known family (what old and well-known family; decorating and renovating material; 2002 (9): 30-31) at the characteristics of tunnel masonry non-refractory, developed a kind of hydraulicity fire-proof coating for tunnels of the humidity environment based on inorganic coagulation material, this coating can be applied to steel construction and concrete flameproof protection simultaneously.During coat-thickness 16mm, the concrete fire endurance is greater than 2.0h; When coat-thickness was 21mm, concrete fire endurance was greater than 3.0h.
Nano material has surface effects, small-size effect, quantum size effect and macro quanta tunnel effect, can show special selection (absorption) property, photoelectrocatalysis (conversion) characteristic etc.Therefore,, can improve the physical strength, sticking power, non-corrosibility of coating, physicochemical property such as fast light and weather-proof significantly, also can give coating some other critical functions simultaneously the reasonable utilization of nano material in coating.Sohn etc. (Sohn, Byeong Hyeok, etc.[P] KR20010022244) utilize nano-TiO
2Photocatalysis, through surface treatment, interior wall coating is carried out modification, make it to have stronger purify air, the function of bactericidal, the obnoxious flavour that the indoor decoration finishing is brought also has stronger capacity of decomposition; (Mclean such as Mclean, LarryJames, etc.[P] US20010961632) nano coating is applied to the traditional coating surface, utilize nanoparticle ultraviolet scattering process to be improved the resistance to deterioration of coating, utilize the photocatalysis performance of nano material simultaneously, the free radical of production strong oxidizing property under illumination decomposes organic sediment, obtains self-cleaning function; Mehnert etc. (Mehnert Reiner, etc.[P] JP2002371243) are in conjunction with microcapsulary and nanotechnology, make the organosilicon microcapsule that are surrounded by nanoparticle and make an addition in the coating, and coating has good wear resistance; Bock etc. (Bock Manfred Dr, etc.[P] JP11349868) by introducing nano-TiO
2Particulate has improved conventional mechanical properties such as ADHESION OF PAINTS power, anti-impact force, snappiness, and certain self-cleaning function has been arranged; (Qiu Xinglin, Xu Anwu, nano level TiO such as Qiu Xinglin
2The development of light catalytic purifying atmosphere environmental protection coating material, Chinese coating, 2000,4:30～33) adopt polysiloxane, dichloride in anatase type level TiO
2, filler and solvent, make photochemical catalysis atmosphere environmental protection coating material; Zhang Yulin etc. (Zhang Yulin, Feng Hui etc., decorating and renovating material, 2002,3:18～21) are with nano-TiO
2Be applied in the building coating, improved water-repellancy, contamination resistance, the ageing resistance of coating, utilize nano-TiO simultaneously
2Photolytic activity, active adsorption and decompose airborne obnoxious flavour reduces the VOC value and also has the antibacterial and mouldproof effect; Liang Li rue etc. (Liang Li rues, Xia Zhengbin etc., chemical building material, 2002,2:19～21) replace color stuffing with nano titanium oxide as the part of coating, utilize the absorption characteristic of nano-powder material to UV-light, significantly improved the weathering resistance of emulsion paint; Chen Zhonghua (Chen Zhonghua, coatings industry, 2002,9:1～3) adds nano-TiO on the basis of traditional exterior wall latex paint
2And SiO
2On particle, take the method for surface modification and ultrasonic dispersing, nanoparticle is effectively disperseed in coating system, improve the over-all properties of coating; (Liu Yanquan, Ma Junhua etc., decorating and renovating material, 2003, (4): 55～56) on the basis of existing exterior wall latex paint, adopt nano material, significantly improved the water resistance of coating, and had certain self-cleaning function such as Liu Yanquan to its modification.
The fire-proof coating for tunnels of above-mentioned report mainly is made of inorganic materials, and its binding material has water glass, cement, white cement, high-alumina cement, phosphoric acid salt etc.; Filler aggregate has perlite, expanded vermiculite, microvoid Calucium Silicate powder, silicon bath soil, powder coal ash glass-microballons, sepiolite powder, talcum powder etc.; Strongthener has glass fibre, steel fiber, polypropylene fiber etc.; Fire retardant has oxide compound of the aluminium that contains crystal water, magnesium, boron, zinc etc.Nano paint mainly is to add nano-TiO in emulsion paint
2, SiO
2Or contain the organosilicon microcapsule of nanoparticle, or with nano-TiO
2Be applied in the epoxypaint, only utilize nanoparticle that ultraviolet scattering process is improved the resistance to deterioration of coating, or utilize the photocatalysis performance of nanoparticle, decompose organic sediment and obtain self-cleaning function, improve the physical and chemical performance of coating.The covering with paint of exterior wall in present nano paint is mainly used in.
(3) summary of the invention
The object of the present invention is to provide a kind ofly to be suitable for that the tunnel uses, coating surface has the fire-proof coating for tunnels and the manufacture method thereof based on the Nanosurface treatment technology of effects such as good fire-retardant, temperature intercept, antifouling, enhancing.
The said fire-proof coating for tunnels based on the Nanosurface treatment technology of the present invention comprises nano paint two portions of frie retardant coating and tool function of surface sex modification.Wherein, the composition of frie retardant coating and proportioning are (relative weight umber): cement of high index 25.0～27.0, aluminium triphosphate 6.2～7.5, water glass 6.5～8.8, polymer emulsion 5～10, pearlstone 7.5～12.5, powder coal ash glass-microballons 5.0～10.0, mica powder 2.5～3.7, kaolin 3.7～8.7, aluminum silicate fiber 3.7～6.2, aluminium hydroxide 18.0～25.0, magnesium hydroxide 16.7～25.0; Said polymer emulsion is polyacrylic acid emulsion or aqueous polyvinyl acetate emulsion or benzene emulsion, and the solid content of emulsion is 42%～52%.
The composition and the proportioning of the nano paint of tool function of surface sex modification is (relative weight umber): uninflammability composition polymer base-material 40～60, composite nano materials 0.8～3.0, nano-material surface properties-correcting agent 0.002～0.02, flame-retardant plasticizer 1～2, industrial naptha 45～55, rheological agent 0.5～1.0; Said uninflammability composition polymer base-material is a modified aminoresin: the hybrid resin of chlorinated rubber=4: 1; Said composite nano materials is a nano-silicon nitride: carbon nanotube: the mixture of nano titanium oxide=2: 1: 1; Said nano-material surface properties-correcting agent is aminosilane, and its structural formula is H
2N (CH
2)
2NH (CH
2)
3Si (OMe)
3Said flame-retardant plasticizer is a tributyl phosphate; Said rheological agent is organobentonite (U.S. NL chemical company Bentone38).
The manufacturing process of the said frie retardant coating of the present invention is as follows:
1) A component: it is even by proportioning cement of high index, aluminium triphosphate, water glass, pearlstone, powder coal ash glass-microballons, mica powder, kaolin, aluminum silicate fiber, aluminium hydroxide, magnesium hydroxide to be added stirrer for mixing successively, packing.
2) B component: polymer emulsion is pressed the proportioning independent packaging.After during use the A component being soaked into less water, add the B component and fully stir, disperse to get final product.
The manufacturing process of the said nano paint of the present invention is as follows:
1) composite nano materials is placed the encloses container of being with high speed dispersion, high-pressure atomization, reliever by proportioning, again nano-material surface properties-correcting agent is dissolved in the industrial naptha, enter in the encloses container by the high-pressure atomization device in batches, behind the high speed dispersion 60min, leave standstill, decompression extracts industrial naptha, gets the composite nano materials of modification;
2) by proportioning industrial naptha, rheological agent are added in the high speed dispersor high speed dispersion 20～30 minutes;
3) add composition polymer base-material and softening agent in batches, after treating abundant dissolving, disperseing, material be transferred in the ultrasonic disperser:
4) slowly add the composite nano materials of modification, ultra-sonic oscillation are after 120～180 minutes, discharging, packing.
During use, in the tunnel, cover with paint, lacquer, colour wash, etc. one deck frie retardant coating earlier, after waiting to do, again the nano paint of tool function of surface sex modification is covered with paint, lacquer, colour wash, etc. on frie retardant coating.
The present invention is in the preparation process of fire-proof coating for tunnels, adopted nanotechnology, surface effects, small-size effect, quantum size effect and the macro quanta tunnel effect of nanoparticle have particularly been utilized, as the fusing point of nanoparticle, sintering temperature, crystallization temperature than low (2000 ℃ of the conventional silicon nitride sintering temperatures of conventional powder, 400～500 ℃ of nano-silicon nitride sintering temperatures, nano-TiO
2Present tangible densification 500 ℃ of heating, reach conventional TiO
2Hardness during 900 ℃ of sintering); CNT (carbon nano-tube) and TiO under special construction of CNT (carbon nano-tube) (tensile strength is higher 100 times than steel, have flexible, huge energy storage character etc.) and the high temperature
2Reaction generates character such as titanium carbide, has obtained the nano paint of the fire-proof coating for tunnels function of surface sex modification that has the following advantages.When 1) meeting high temperature, composite nano materials is sintering, changes in crystal structure and energy-storage function progressively, consumes big energy, has delayed the temperature rise of fire-proof coating for tunnels, has further stoped the temperature rise of tunnel Steel Concrete masonry; When 2) nano material was distributed in the polymer coating film, because nanoparticle is very big to the ratio interface of fluoropolymer resin, bonding force was strong, and particularly the length-to-diameter ratio of CNT (carbon nano-tube) super large plays enhancing, toughening effect to coating, significantly improves the physical and mechanical properties of coating; 3) nano coating can produce powerful and persistent interface interaction power with the fire-proof coating for tunnels surface, improves cohesive strength; 4) nano material is under certain energy, and generation unbound electron-hole is right, makes airborne oxygen activation, produce free radical, when organic pollutants such as vehicle exhaust are adsorbed in its surface, will combine with unbound electron or hole, redox reaction takes place, and reaches and reduces the purpose of polluting; 5) environment relative closure in the tunnel, the tail gas loss difficulty of vehicular emission, nano coating has stoped acidic substance such as vehicle exhaust, and (the fire-retardant composition of some in the fire-proof coating for tunnels is basic oxide or oxyhydroxide to the pollution of fire-proof coating for tunnels and corrosion, under long-term acid gas effect, may cause degradation), improved erosion resistance, the weathering resistance of fire-proof coating for tunnels.(4) embodiment
The invention will be further described below by embodiment.
Embodiment 1: the preparation of fire-proof coating for tunnels.With cement of high index 26.0Kg, aluminium triphosphate 6.8kg, water glass 6.5Kg, pearlstone 9.5Kg, powder coal ash glass-microballons 7.5Kg, mica powder 2.8Kg, kaolin 4.5Kg, aluminum silicate fiber 4.3Kg, it is even that aluminium hydroxide 19.6Kg, magnesium hydroxide 18.5Kg add stirrer for mixing successively, adds less water and soak into, add acrylate polymer emulsion 8.6Kg again, stir.The fire performance of fire-proof coating for tunnels: coat-thickness 10mm, fire endurance 180min; Surface drying time: 3.0h; Cohesive strength: 0.48Mpa; Density: 495Kg/m
3Thermal conductivity: 0.114W/ (mk).
The preparation of the nano paint of fire-proof coating for tunnels function of surface sex modification: successively industrial naptha 500g, organobentonite 6g are added in the high speed dispersor, after the high speed dispersion 25 minutes, add modified aminoresin 379Kg, chlorinated rubber 95g, tributyl phosphate 10g in batches, after treating abundant dissolving, dispersion, material is transferred in the ultrasonic disperser, slowly add through the amino silane modified nano-silicon nitride 5g of 0.05g, carbon nanotube 2.5g, nano titanium oxide 2.5g, after the ultra-sonic oscillation 150 minutes, discharging, packing.
Embodiment 2 (embodiment 1 is pressed in the preparation of frie retardant coating).
The manufacturing of the nano paint of tool function of surface sex modification: successively industrial naptha 500g, organobentonite 8g are added in the high speed dispersor, after the high speed dispersion 30 minutes, add modified aminoresin 376g, chlorinated rubber 94g, tributyl phosphate 10g in batches, after treating abundant dissolving, dispersion, material is transferred in the ultrasonic disperser, slowly add through the amino silane modified nano-silicon nitride 6g of 0.16g, carbon nanotube 3g, nano titanium oxide 3g, after the ultra-sonic oscillation 165 minutes, discharging, packing.
Embodiment 3 (expanding test, embodiment 1 is pressed in the preparation of frie retardant coating, the prescription of embodiment 2 is pressed in the manufacturing of the nano paint of tool function of surface sex modification):
The manufacturing of the nano paint of tool function of surface sex modification: successively industrial naptha 50Kg, organobentonite 0.8Kg are added in the high speed dispersor, after the high speed dispersion 30 minutes, add modified aminoresin 37.6Kg, chlorinated rubber 9.4Kg, tributyl phosphate 1.0Kg in batches, after treating abundant dissolving, dispersion, material is transferred in the ultrasonic disperser, slowly add through the amino silane modified nano-silicon nitride 0.6Kg of 16g, carbon nanotube 0.3Kg, nano titanium oxide 0.3Kg, after the ultra-sonic oscillation 165 minutes, discharging, packing.
Claims (5)
1. based on the fire-proof coating for tunnels of Nanosurface treatment technology, it is characterized in that said fire-proof coating for tunnels is made up of nano paint two portions of frie retardant coating and tool function of surface sex modification, wherein, the composition of frie retardant coating and proportioning are (relative weight umber): cement of high index 25.0～27.0, aluminium triphosphate 6.2～7.5, water glass 6.5～8.8, polymer emulsion 5～10, pearlstone 7.5～12.5, powder coal ash glass-microballons 5.0～10.0, mica powder 2.5～3.7, kaolin 3.7～8.7, aluminum silicate fiber 3.7～6.2, aluminium hydroxide 18.0～25.0, magnesium hydroxide 16.7～25.0; Said polymer emulsion is polyacrylic acid emulsion or aqueous polyvinyl acetate emulsion or benzene emulsion;
The composition of the nano paint of tool function of surface sex modification with by the proportioning of relative weight umber be: uninflammability composition polymer base-material 40～60, composite nano materials 0.8～3.0, nano-material surface properties-correcting agent 0.002～0.02, flame-retardant plasticizer 1～2, industrial naptha 45～55, rheological agent 0.5～1.0; Said uninflammability composition polymer base-material is the hybrid resin of modified aminoresin and chlorinated rubber; Said composite nano materials is nano-silicon nitride and carbon nanotube, nano titanium oxide; Said nano-material surface properties-correcting agent is aminosilane, and its structural formula is H
2N (CH
2)
2NH (CH
2)
3Si (OMe)
3Said flame-retardant plasticizer is a tributyl phosphate; Said rheological agent is an organobentonite.
2. the fire-proof coating for tunnels based on the Nanosurface treatment technology as claimed in claim 1 is characterized in that modified aminoresin in the uninflammability polymer base material: chlorinated rubber=4: 1.
3. the fire-proof coating for tunnels based on the Nanosurface treatment technology as claimed in claim 1 is characterized in that nano-silicon nitride in the composite nano materials: carbon nanotube: nano titanium oxide=2: 1: 1.
4. the fire-proof coating for tunnels based on the Nanosurface treatment technology as claimed in claim 1, the solid content that it is characterized in that polymer emulsion is 42%～52%.
5. based on the manufacturing process of the fire-proof coating for tunnels of Nanosurface treatment technology, it is characterized in that the manufacturing process of said frie retardant coating is as follows:
1) A component: it is even by proportioning cement of high index, aluminium triphosphate, water glass, pearlstone, powder coal ash glass-microballons, mica powder, kaolin, aluminum silicate fiber, aluminium hydroxide, magnesium hydroxide to be added stirrer for mixing successively, packing;
2) B component: polymer emulsion by the proportioning independent packaging, after during use the A component being soaked into less water, is added the B component and fully stirs, disperses to get final product;
The manufacturing process of the nano paint of said tool function of surface sex modification is as follows:
1) composite nano materials is placed the encloses container of being with high speed dispersion, high-pressure atomization, reliever by proportioning, again nano-material surface properties-correcting agent is dissolved in the industrial naptha, enter in the encloses container by the high-pressure atomization device in batches, behind the high speed dispersion 60min, leave standstill, decompression extracts industrial naptha, gets the composite nano materials of modification;
2) by proportioning industrial naptha, rheological agent are added in the high speed dispersor high speed dispersion 20～30 minutes;
3) add composition polymer base-material and softening agent in batches, after treating abundant dissolving, disperseing, material is transferred in the ultrasonic disperser;
4) slowly add the composite nano materials of modification, ultra-sonic oscillation are after 120～180 minutes, discharging, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101155251A CN100462412C (en) | 2003-11-28 | 2003-11-28 | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101155251A CN100462412C (en) | 2003-11-28 | 2003-11-28 | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1544552A true CN1544552A (en) | 2004-11-10 |
| CN100462412C CN100462412C (en) | 2009-02-18 |
Family
ID=34337334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003101155251A Expired - Fee Related CN100462412C (en) | 2003-11-28 | 2003-11-28 | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100462412C (en) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100378185C (en) * | 2006-03-29 | 2008-04-02 | 江苏京安消防设备制造有限公司 | Expansion type fire fighting glue |
| WO2008081173A1 (en) * | 2006-12-29 | 2008-07-10 | World Minerals, Inc. | Polymer compositions comprising fluoro elastomers and expanded perlite |
| CN100509967C (en) * | 2006-08-29 | 2009-07-08 | 泰州五行涂料有限公司 | Fire-retardant coatings for tunnel, and preparation method thereof |
| CN101117510B (en) * | 2007-09-14 | 2010-06-02 | 东北林业大学 | Modified amino resin expansion type aqueous flame-proof paint |
| CN101973750A (en) * | 2010-10-21 | 2011-02-16 | 童金荣 | Inorganic heat-insulating material and preparation method thereof |
| CN102134882A (en) * | 2010-01-21 | 2011-07-27 | 安徽省建筑科学研究设计院 | Method for improving fireproof performance of extruded polystyrene board in outer-wall external thermal insulation system |
| CN102329549A (en) * | 2011-06-24 | 2012-01-25 | 湖南新纪元消防工程有限公司 | Water-borne inflation type refractory coating and preparation method thereof |
| CN102358692A (en) * | 2011-08-04 | 2012-02-22 | 长江水利委员会长江科学院 | Inorganic insulation coating for large dam surface, and preparation method thereof |
| CN101659824B (en) * | 2008-08-28 | 2012-07-18 | 上海富臣化工有限公司 | Nano flame retardant emulsion paint and method for preparing same |
| CN102626673A (en) * | 2012-05-09 | 2012-08-08 | 齐齐哈尔科诺科技有限公司 | Method for changing relative dielectric constant of fiber capture medium |
| CN102876145A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | High-stability composite coating |
| CN103043976A (en) * | 2013-01-18 | 2013-04-17 | 宝鸡市铁军化工防腐安装有限责任公司 | Thin fire-resistant/flame-retardant paint for tunnel and preparation method thereof |
| CN103242689A (en) * | 2013-06-04 | 2013-08-14 | 沈宇杰 | Flame-retardant interior wall coating |
| CN103572850A (en) * | 2013-11-19 | 2014-02-12 | 济南大学 | Anti-radiation type expanded perlite compound insulation board and manufacturing method thereof |
| CN103773170A (en) * | 2014-02-20 | 2014-05-07 | 铜陵祥云消防科技有限责任公司 | Fireproof coating with black mica powder |
| CN104877545A (en) * | 2015-05-14 | 2015-09-02 | 江苏有能新能源有限公司 | Fireproof container for shore power sources |
| CN105295457A (en) * | 2015-10-30 | 2016-02-03 | 三棵树涂料股份有限公司 | Preparation method of carbon nano-tube loaded titanium dioxide top facing coating material |
| CN106461333A (en) * | 2014-03-21 | 2017-02-22 | 维苏威坩埚公司 | Blast furnace hearth repair material |
| CN109456630A (en) * | 2018-11-20 | 2019-03-12 | 南通蛇类治疗研究所 | The nano flame retardant fireproof coating of specific function |
| CN109762379A (en) * | 2018-12-14 | 2019-05-17 | 重庆清徽节能环保科技有限公司 | It is a kind of anti-to be layered the vcehicular tunnel fireproof coating that falls off and application |
| CN115043605A (en) * | 2022-07-25 | 2022-09-13 | 浙江长兴钰峰新型材料科技有限公司 | Anti-corrosion coating steel fiber for concrete and preparation process thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1106851A (en) * | 1994-11-07 | 1995-08-16 | 刘小兵 | Compound insulation and fire-proof paint |
-
2003
- 2003-11-28 CN CNB2003101155251A patent/CN100462412C/en not_active Expired - Fee Related
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100378185C (en) * | 2006-03-29 | 2008-04-02 | 江苏京安消防设备制造有限公司 | Expansion type fire fighting glue |
| CN100509967C (en) * | 2006-08-29 | 2009-07-08 | 泰州五行涂料有限公司 | Fire-retardant coatings for tunnel, and preparation method thereof |
| US8357747B2 (en) | 2006-12-29 | 2013-01-22 | Imerys Filtration Minerals, Inc. | Polymer compositions comprising fluoro elastomers and expanded perlite |
| WO2008081173A1 (en) * | 2006-12-29 | 2008-07-10 | World Minerals, Inc. | Polymer compositions comprising fluoro elastomers and expanded perlite |
| CN101117510B (en) * | 2007-09-14 | 2010-06-02 | 东北林业大学 | Modified amino resin expansion type aqueous flame-proof paint |
| CN101659824B (en) * | 2008-08-28 | 2012-07-18 | 上海富臣化工有限公司 | Nano flame retardant emulsion paint and method for preparing same |
| CN102134882A (en) * | 2010-01-21 | 2011-07-27 | 安徽省建筑科学研究设计院 | Method for improving fireproof performance of extruded polystyrene board in outer-wall external thermal insulation system |
| CN101973750A (en) * | 2010-10-21 | 2011-02-16 | 童金荣 | Inorganic heat-insulating material and preparation method thereof |
| CN101973750B (en) * | 2010-10-21 | 2013-09-11 | 童金荣 | Inorganic heat-insulating material and preparation method thereof |
| CN102329549A (en) * | 2011-06-24 | 2012-01-25 | 湖南新纪元消防工程有限公司 | Water-borne inflation type refractory coating and preparation method thereof |
| CN102358692A (en) * | 2011-08-04 | 2012-02-22 | 长江水利委员会长江科学院 | Inorganic insulation coating for large dam surface, and preparation method thereof |
| CN102626673A (en) * | 2012-05-09 | 2012-08-08 | 齐齐哈尔科诺科技有限公司 | Method for changing relative dielectric constant of fiber capture medium |
| CN102626673B (en) * | 2012-05-09 | 2014-04-09 | 齐齐哈尔科诺科技有限公司 | Method for changing relative dielectric constant of fiber capture medium |
| CN102876145A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | High-stability composite coating |
| CN103043976A (en) * | 2013-01-18 | 2013-04-17 | 宝鸡市铁军化工防腐安装有限责任公司 | Thin fire-resistant/flame-retardant paint for tunnel and preparation method thereof |
| CN103043976B (en) * | 2013-01-18 | 2015-05-27 | 宝鸡市铁军化工防腐安装有限责任公司 | Thin fire-resistant/flame-retardant paint for tunnel and preparation method thereof |
| CN103242689B (en) * | 2013-06-04 | 2015-05-20 | 沈宇杰 | Flame-retardant interior wall coating |
| CN103242689A (en) * | 2013-06-04 | 2013-08-14 | 沈宇杰 | Flame-retardant interior wall coating |
| CN103572850A (en) * | 2013-11-19 | 2014-02-12 | 济南大学 | Anti-radiation type expanded perlite compound insulation board and manufacturing method thereof |
| CN103773170A (en) * | 2014-02-20 | 2014-05-07 | 铜陵祥云消防科技有限责任公司 | Fireproof coating with black mica powder |
| CN103773170B (en) * | 2014-02-20 | 2016-02-17 | 铜陵祥云消防科技有限责任公司 | A kind of frie retardant coating adding biotite powder |
| CN106461333A (en) * | 2014-03-21 | 2017-02-22 | 维苏威坩埚公司 | Blast furnace hearth repair material |
| US10295261B2 (en) | 2014-03-21 | 2019-05-21 | Vesuvius U S A Corporation | Refractory lining repair material |
| CN104877545A (en) * | 2015-05-14 | 2015-09-02 | 江苏有能新能源有限公司 | Fireproof container for shore power sources |
| CN105295457A (en) * | 2015-10-30 | 2016-02-03 | 三棵树涂料股份有限公司 | Preparation method of carbon nano-tube loaded titanium dioxide top facing coating material |
| CN105295457B (en) * | 2015-10-30 | 2017-12-15 | 三棵树涂料股份有限公司 | A kind of preparation method of titanium dioxide loaded on carbon nano tube overlay coating |
| CN109456630A (en) * | 2018-11-20 | 2019-03-12 | 南通蛇类治疗研究所 | The nano flame retardant fireproof coating of specific function |
| CN109762379A (en) * | 2018-12-14 | 2019-05-17 | 重庆清徽节能环保科技有限公司 | It is a kind of anti-to be layered the vcehicular tunnel fireproof coating that falls off and application |
| CN115043605A (en) * | 2022-07-25 | 2022-09-13 | 浙江长兴钰峰新型材料科技有限公司 | Anti-corrosion coating steel fiber for concrete and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100462412C (en) | 2009-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100462412C (en) | Tunnel fireproof paint based on nano-surface-treatment technology and method for making same | |
| US11261380B2 (en) | Aerogel compositions for high temperature applications | |
| Wang et al. | Facile preparation of slag or fly ash geopolymer composite coatings with flame resistance | |
| CN1323118C (en) | Fire-proof paint modifier of tunnel based on polymer/clay intercalation modifying technology and production thereof | |
| KR101405322B1 (en) | Inorganic ceramic paint for curing at room temperature and painting method using the same | |
| CN108192389A (en) | A kind of preparation method of nano ceramics fireproof coating | |
| CN112521756B (en) | High-mechanical-strength ceramizable organic silicon material and preparation method thereof | |
| CN102585570A (en) | Water-soluble non-combustible ceramic anti-radiation coating and preparation method thereof | |
| Wang et al. | Benign design of intumescent flame retardant coating incorporated various carbon sources | |
| KR20080070485A (en) | Method for coating agent composite having retardent flame | |
| CN101274987A (en) | Calcium hydroxide-based halogen-free flame-proof plastic masterbatch and preparation for special resin therefor | |
| RU2523818C1 (en) | Fire-resistant thermal-protective coating and method for production thereof | |
| CN1793271A (en) | Single component mildew-proof flame retarded organic silicon sealing agent for machinery and preparation process thereof | |
| CN107722652A (en) | A kind of pitch smoke inhibition modifying agent, suppression cigarette modified pitch and preparation method thereof | |
| CN102218883B (en) | Wood plastic plate coated by silicone flame retardant coating | |
| CN109456630A (en) | The nano flame retardant fireproof coating of specific function | |
| CN113234324B (en) | Flame-retardant ceramizable organic silicon material and preparation method thereof | |
| CN110240867B (en) | Two-component compound synergistic inorganic fireproof adhesive and preparation method thereof | |
| KR101225500B1 (en) | Room temperature curing type water-soluable inorganic painting composition having excellent water-resistance and method for preparing the same | |
| CN107722683A (en) | A kind of survival capsule fire resistant coating and its production and use | |
| CN1152094C (en) | Waterproof and fireproof water soluble inorganic paint | |
| Abdullayev et al. | Halloysite tubule nanoreactors in industrial and agricultural applications | |
| CN1869155A (en) | Aluminium series fire retardant-tetrahydroxy aluminium oxalate micro crystal and its production method | |
| JP2004250310A (en) | Fiber powder-containing inorganic adhesive composition | |
| KR100492622B1 (en) | Compositions for Heat resistant and Fire resistant Construction Panel Material using Clay Minerals and its Manufacture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090218 Termination date: 20121128 |