CN1537818A - Preparation method of brick used for bottom of tin bath - Google Patents
Preparation method of brick used for bottom of tin bath Download PDFInfo
- Publication number
- CN1537818A CN1537818A CNA200310105307XA CN200310105307A CN1537818A CN 1537818 A CN1537818 A CN 1537818A CN A200310105307X A CNA200310105307X A CN A200310105307XA CN 200310105307 A CN200310105307 A CN 200310105307A CN 1537818 A CN1537818 A CN 1537818A
- Authority
- CN
- China
- Prior art keywords
- preparation
- tin bath
- molten tin
- batching
- bottom brick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000011449 brick Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 17
- 238000000462 isostatic pressing Methods 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 11
- 239000004927 clay Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000012423 maintenance Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000011236 particulate material Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000001354 calcination Methods 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 5
- 229910052863 mullite Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
A process for preparing the brick used for the bottom of tin bath includes such steps as proportionally mixing raw materials, shaping by isostatic pressing and calcining. Its advantages are high productivity, high quality, strength and density, and high resistance to corrosion.
Description
Technical field
The present invention relates to a kind of preparation method of bottom brick of molten tin bath, be the refractory products production technical field.
Background technology
Bottom brick of molten tin bath is applied in the float glass, and the quality quality of bottom brick of molten tin bath directly affects the ordinary production operation of float glass.What the production of existing bottom brick of molten tin bath was adopted basically is injection forming, vibratory compaction and vacuum pressure injection forming, wherein the vacuum pressure injection forming belongs to a kind of preferably, the bottom brick of molten tin bath quality product of producing is better, density is higher, intensity is bigger, void content is lower, has obtained applying to a certain degree, still, because the injection forming water content is big, cause product to burn till and shrink greatly, cause the product crackle easily, again, half product stripping, maintenance and drying treatment technical difficulty are big, grasp not easy to operate causes product percent of pass on the low side, and because water content is big, cause the demoulding, maintenance, the time of operations such as drying is elongated greatly, time of drying just needs 60 days, and the production cycle is long, and production efficiency is low.
Summary of the invention
The object of the present invention is to provide a kind of novel method of producing bottom brick of molten tin bath, easy and simple to handle, control is with short production cycle easily, the production efficiency height, and the bottom brick of molten tin bath quality product of producing is better, qualification rate is high.
The preparation method of bottom brick of molten tin bath of the present invention comprises batching, moulding and burns till that its technical essential is that molding mode has adopted isostatic pressing method.
Isostatic pressing, the product quality of acquisition is even, the density height, intensity is big, no bubble and gross blow hole, resistance to fouling is strong, steady quality, long service life.Equal pressing forming technology is applied in other technical field, and effect obtains confirming.
Among the preparation method of the present invention:
The moulding batching adopts the dry-press process batching, and water content is no more than 4% of batching, and the forming pressure of isostatic pressing is 50～300MPa.The demoulding at once of product after the moulding is dried and can be gone into klining in 3 days.
Bottom brick of molten tin bath after the moulding need be handled through 1 day maintenance, promptly places naturally dry 1 day under the normal temperature.
The firing temperature of bottom brick of molten tin bath is 1250 ℃～1500 ℃, looks batching and technical requirements difference and determines.
The batching chemistry weight percentage composition of the bottom brick of molten tin bath that wearing quality is good is: Al
2O
339～42%, SiO
261～58%, surplus is the conventional impurity of refractory materials, as ferric oxide, titanium oxide, calcium oxide etc.
The batching mineral weight percent of preferred bottom brick of molten tin bath consists of: Ke's More grog 80～90%, plastic clay 10～20%.The main effect of plastic clay is a processability, and therefore, the used plastic clay of fire resisting material field can use basically.
Wherein Ke's More grog belongs to mullite refractory grog series, be also referred to as " low aluminum-containing mullite ", basic identical with the preparation method of mullite grog, by kaolin and potassium felspar sand, also can add an amount of plastic clay, carry out the synthetic calcining of high temperature about 1600 ℃ again and make.Its aluminum content is low, contains 1～2% K
2O, raw material will be handled through wet ball grinding, below the particle diameter to 5 micron.Ke's More mineral crystalline phase is mullite, glassy phase, does not have high quartzy phase, thereby has the low coefficient of expansion, compares with the mullite of identical aluminium content, also has lower thermal conductivity, can satisfy the application performance of bottom brick of molten tin bath.
Wherein, the particle weight grating of Ke's More grog is advisable by following grasp in the batching.
Slightly: the particulate material 20～35% of 5mm＜particle diameter d≤1mm
In: the material 20～35% of particle diameter d＜1mm
Carefully: the powder 35～50% of particle diameter d＜0.074mm.
Preparation method of the present invention does not describe part in detail with the conventional preparation method of refractory materials with wait the conventional forming method of static pressure basic identical, repeats no more.
The preparation method of bottom brick of molten tin bath of the present invention, easy and simple to handle, grasp control easily, overcome slip casting to all multifactor restrictions such as raw material, temperature and humidities, moulding water content is low, and is with short production cycle, the whole production cycle can be 20 days, production efficiency height, product percent of pass height, and the bottom brick of molten tin bath good product quality of producing, quality is even, the density height, intensity is big, no bubble and gross blow hole, and resistance to fouling is strong, steady quality, long service life.The inventive method can be made large-sized bottom brick of molten tin bath, and length can reach 1.5m, the wide 800mm that reaches, Gao Keda 500mm.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
The preparation method of bottom brick of molten tin bath of the present invention, the ingredients by weight percentage composition is:
Ke's More grog 86%, Guangdong smolmitza 14%.
Wherein, the particle weight grating of Ke's More grog (Zi Bowang village alum clay mineral products) is advisable by following grasp in the batching.
Slightly: the particulate material 32% of 5mm＜particle diameter d≤1mm
In: the material 26% of particle diameter d＜1mm
Carefully: the powder 42% of particle diameter d＜0.074mm.
Batch mixes is even, add the moulding moisture of batching 3.5%, standby;
Batching is packed in the forming mould, implement isostatic pressing, forming pressure is 150MPa;
Demoulding oven dry: the normal temperature natural condition are placed maintenance 1 day; 120 ℃ of 2 days time of drying.
1480 ℃～1500 ℃ of firing temperatures.
The detection technique index is:
Al
2O
3?41.2％、SiO
2?56.8％。
Hydrogen diffusion index 80mmH
2O
Thermal conductivity 1.10w/mk
1000 ℃ 0.58% of thermal expansivity
Test raw materials used: Ke's More grog and plastic clay have the commercially available prod, can directly buy.Ke's More grog that we use always is that the Wang Cun of Zibo City bauxite or three rivers, Inner Mongol produce.The chemical weight percentage composition of the raw material that we select for use sees Table 1.
Other embodiment situation sees Table 2.
The chemical weight percentage composition table of table 1, Ke's More grog, plastic clay
| Al 2O 3 | ?SiO 2 | ?Fe 2O 3 | ?TiO 2 | ?CaO | ?MgO | ?K 2O | Loss on ignition | |
| The Guangdong smolmitza | 28.8 | ?54.2 | ?0.9 | ?1.5 | ?0.3 | ?0.5 | ?/ | ?12.4 |
| Ke's More grog | 42 | ?54 | ?0.18 | ?0.20 | ?0.2 | ?0.15 | ?1.5 |
Table 2, other embodiment parameter situation.</entry></row></tbody></tgroup></table></tables>
Claims (7)
1, a kind of preparation method of bottom brick of molten tin bath comprises batching, moulding and burns till, and it is characterized in that its molding mode is an isostatic pressing method.
2, preparation method according to claim 1 is characterized in that the moulding batching is the dry-press process batching, and the forming pressure of isostatic pressing is 50～300MPa.
3, preparation method according to claim 1 is characterized in that the bottom brick of molten tin bath after the moulding need be handled through 1 day maintenance.
4, preparation method according to claim 1, the firing temperature that it is characterized in that bottom brick of molten tin bath is 1250 ℃～1500 ℃.
5,, it is characterized in that the batching chemistry weight percentage composition of bottom brick of molten tin bath is: Al according to claim 1,2,3 or 4 described preparation methods
2O
339～42%, SiO
261～58%, surplus is conventional impurity.
6, preparation method according to claim 5 is characterized in that the batching mineral weight percent of bottom brick of molten tin bath consists of: Ke's More grog 80～90%, plastic clay 10～20%.
7, preparation method according to claim 6, the particle weight grating of Ke's More grog is in it is characterized in that preparing burden:
The particulate material 20～35% of 5mm＜particle diameter d≤1mm
The material 20～35% of particle diameter d＜1mm
The powder 35～50% of particle diameter d＜0.074mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105307 CN1218892C (en) | 2003-10-09 | 2003-10-09 | Preparation method of brick used for bottom of tin bath |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105307 CN1218892C (en) | 2003-10-09 | 2003-10-09 | Preparation method of brick used for bottom of tin bath |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1537818A true CN1537818A (en) | 2004-10-20 |
| CN1218892C CN1218892C (en) | 2005-09-14 |
Family
ID=34333699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310105307 Expired - Lifetime CN1218892C (en) | 2003-10-09 | 2003-10-09 | Preparation method of brick used for bottom of tin bath |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1218892C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927557B (en) * | 2006-09-27 | 2011-06-15 | 淄博工陶耐火材料有限公司 | Manufacture method of tin slot bottom brick |
| CN102557688A (en) * | 2012-01-06 | 2012-07-11 | 淄博工陶耐火材料有限公司 | Preparation method for isostatic pressure calcium-aluminum-silicon tin bath bottom brick |
| CN111440003A (en) * | 2020-04-07 | 2020-07-24 | 山东淄博沈淄耐火材料有限公司 | Bottom brick special for high-temperature section of tin bath of novel float glass kiln and preparation method thereof |
| CN116751068A (en) * | 2023-08-18 | 2023-09-15 | 山东淄博沈淄耐火材料有限公司 | Method for preparing isostatic pressing forming calcium-tin aluminate bottom bricks |
-
2003
- 2003-10-09 CN CN 200310105307 patent/CN1218892C/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927557B (en) * | 2006-09-27 | 2011-06-15 | 淄博工陶耐火材料有限公司 | Manufacture method of tin slot bottom brick |
| CN102557688A (en) * | 2012-01-06 | 2012-07-11 | 淄博工陶耐火材料有限公司 | Preparation method for isostatic pressure calcium-aluminum-silicon tin bath bottom brick |
| CN102557688B (en) * | 2012-01-06 | 2013-08-14 | 淄博工陶耐火材料有限公司 | Preparation method for isostatic pressure calcium-aluminum-silicon tin bath bottom brick |
| CN111440003A (en) * | 2020-04-07 | 2020-07-24 | 山东淄博沈淄耐火材料有限公司 | Bottom brick special for high-temperature section of tin bath of novel float glass kiln and preparation method thereof |
| CN116751068A (en) * | 2023-08-18 | 2023-09-15 | 山东淄博沈淄耐火材料有限公司 | Method for preparing isostatic pressing forming calcium-tin aluminate bottom bricks |
| CN116751068B (en) * | 2023-08-18 | 2023-10-31 | 山东淄博沈淄耐火材料有限公司 | Method for preparing isostatic pressing forming calcium-tin aluminate bottom bricks |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1218892C (en) | 2005-09-14 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 255200 Shandong Province, Zibo city Boshan District Five Road No. 60 Patentee after: Zibo Gongtao New Materials Group Co.,Ltd. Address before: 255200 Shandong Province, Zibo city Boshan District Five Road No. 60 Patentee before: ZIBO GT INDUSTRIAL CERAMICS Co.,Ltd. |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050914 |