CN1528214A - Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry - Google Patents
Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry Download PDFInfo
- Publication number
- CN1528214A CN1528214A CNA200310106082XA CN200310106082A CN1528214A CN 1528214 A CN1528214 A CN 1528214A CN A200310106082X A CNA200310106082X A CN A200310106082XA CN 200310106082 A CN200310106082 A CN 200310106082A CN 1528214 A CN1528214 A CN 1528214A
- Authority
- CN
- China
- Prior art keywords
- attapulgite
- filter
- additive
- cigarette
- tobacco
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The present invention relates to application of attapulgite in tobacco industry. It can be used as additive for tobacco shred, and its added quantity is 0.01-0.5 wt% of weight of tabacco shred in the tobacco shred, it also can be used as additive for filter tip, when it is used as additive for filter tip, firstly, the attapulgite powder glyceride tracetate suspension liquor whose weight ratio is 0.1-10% can be prepared, then the suspension lqiuor can be sprayed on the cellulose acetate fibre bundle by means of filter tip machine so as to obtain qualified filter rod for cigarette. Its invention can reduce tar content and nicotine content in the cigarette.
Description
Technical field
Attapulgite is made tobacco shred additive and/or filter tip additive in tobacco industry, relate to attapulgite and use and the production of cigarettes technical field.
Background technology
The world today, smoking further gets more and more people's extensive concerning with the relation of health.The formed flue gas of cigarette burning is a kind of aerosol, and tar accounts for the 6-8% of flue gas total amount, and it is the granule phase substance that many materials mix in the flue gas, contains many harmful substances, as the condensed-nuclei aromatics class, and phenols, the inferior pin of N-amine, some heterocyclic compound.They mostly are short cancer and carcinogenic substance, main lung cancer caused and other organ cancer.Gas phase accounts for 92% of flue gas total amount, and mainly containing harmful substances in the gas phase has: CO, NO, HCN, methacrylaldehyde etc.Adopting multiple channel to reduce tar content and reach wherein harmful substance, is a big problem of tobacco business research.
China rose on January 1st, 1997 in " cigarette " serial new national standard of implementation, tar content class in the cigarette smoke and corresponding tar content have been made clear and definite regulation:＜12mg/ propped up to low, 12-＜16mg/ is low in propping up and being, during 16-＜19mg/ props up and is, 19-＜23mg/ props up and is that middle height, 〉=23mg/ prop up and is height.By 2005, be higher than the inaccurate listing of cigarette that 15mg/ props up.
Make the smoker feel that the cigarette taste is flat but reduce tar content simply, can't satisfy psychological need.Therefore, in reducing tar, in the harmful components, also to improve eating of cigarette, fragrance.
Attapulgite is an a kind of layer of chain structure clay ore, owing to its special architectural feature has extremely strong selection adsorption capacity.Attapulgite is palygorskite or Palygorskite again, in Soviet Union Ural, and the attapulgus area of Georgia, USA, this kind ore is found in the not grand area of France's mole.1976, Chinese scholar Xu Jiquan took into account the crystal structure characteristic of these mineral simultaneously according to the sound of concavo-convex fort, is translated into " attapulgite ", passed at home in recent years and used.The beginning of the eighties in last century, verify Soviet Union's concavo-convex mine belt reserves in Anhui and reach nearly 2,000,000,000 tons, be the unique attapulgite clay mineral resources of verifying of China with long-term exploitation value.Attapulgite characterization of adsorption and development and use are carried out big quantity research, mainly concentrated on building materials, light, agricultural, animal husbandry, weaving, oil exploration, the processing of food grease, environmental protection, chemical industry, cosmetics, plastic, rubber, pharmacy, industry such as metallurgy.The application of attapulgite in tobacco product do not appear in the newspapers as yet.
Summary of the invention
The purpose of this invention is to provide attapulgite and in tobacco industry, be used as tobacco shred additive and/or filter tip additive.Make the filter tip additive and help to reduce tar and harmful components in the flue gas; Make tobacco shred additive and under the situation that does not increase tar content substantially, can improve nicotine content, improve the eating of cigarette, fragrance.
The crystal shape of attapulgite is bar-shaped, fibrous, needle-like, long 0.5-5 micron, and wide 0.05-0.15 micron is 2: 1 type clay minerals, promptly two-layer silicon-oxy tetrahedron, the layer of aluminum oxygen octahedra, its molecular formula is Mg
5Si
8O
20(OH)
2(OH
2)
44H
2O.The attapulgite clay aggregate is the earthy block configuration, and color is canescence, steel gray, little Huang or light green, greasy luster, light specific gravity, the formula of rubbing hardness 2-3 level is viscosity and plasticity when moist, dry contraction is little, and do not produce be full of cracks, water imbibition is strong, can reach more than 150%.Because inner duct is many, specific area is big, can reach 350m
2/ gram, most cation, hydrone and a certain size organic molecule all can directly be inhaled in the duct, and its stable electrochemical property should not be flocculated by electrolyte.
Attapulgite has higher safety and sanitation through Jiangsu Province State Scientific and Technological Commission tissue characterization, is widely used in industries such as medicine, food.The present invention inquires into attapulgite as additive, adds cigarette shreds and filter stick, makes the technology of finished cigarettes.
Attapulgite preparation technology flow process: mining, ore dressing---batching, preliminary treatment---abrasive dust---stone roller mud---oven dry bakes---classification, granulation---surface treatment, activation and modification---selected and deep processing---homogenizing thermalization control---storage and metering packing.
Technical solution of the present invention: use attapulgite as tobacco shred additive and/or filter tip additive.Make tobacco shred additive: the attapulgite that in pipe tobacco, adds pipe tobacco weight ratio 0.01-0.5%; The filter tip additive: get the attapulgite powder it evenly is suspended in the triacetyl glycerine, being made into weight ratio is the attapulgite powder suspension of 0.1-10%, suspension is chewed on the machine in filter spray on acetate silk, makes qualified cigarette filter rod.Attapulgite powder addition (weight ratio) is 3% attapulgite triacetyl glycerine suspension, and on the spray tow, filter effect is better, and the fineness of used attapulgite powder is a 500-1200 order optimum.
Add the preparation technology of attapulgite in the pipe tobacco: 0.25g methylcellulose (CMC) is added in the 50ml ethanol, vibration is stirred, again the 2.5g attapulgite is added, and then adding 100ml ethanol dilution and constantly stirring, make it to become even suspension, with atomizer it is formed vaporific spray then and be added in the 5kg pipe tobacco, place 8 hours (envionmental humidity is 65 ± 5%) ethanol volatilization, roll-forming on cigarette machine then.
As the filter tip additive, control triacetyl glycerine content is about 0.05g/ and props up, and adsorbent attapulgite content was that 0.5-2.5mg/ props up during controlled filter was chewed.
Filter chew add behind the attapulgite as shown in table 1 to the filtration adsorption effect of the tar in the flue gas, nicotine, carbon monoxide.
The filtration adsorption effect that the various filters of table 1 are chewed the tar in the flue gas, nicotine, carbon monoxide compares
| TPM (mg/ props up) | Tar (mg/ props up) | Tar rate of change % | Nicotine (mg/ props up) | Nicotine rate of change % | Tar/nicotine ratio | CO (mg/ props up) | CO rate of change % | |
| 1% attapulgite | 19.13 | ?13.9 | ?4.79 | ?1.12 | ?1.75 | ?12.4∶1 | ?17.5 | ?-0.57 |
| 3% attapulgite | 18.01 | ?13.2 | ?9.59 | ?1.14 | ?0 | ?11.6∶1 | ?16.3 | ?6.32 |
| 5% attapulgite | 18.40 | ?14.0 | ?4.11 | ?1.18 | ?-3.50 | ?11.9∶1 | ?16.9 | ?2.87 |
| Former state is chewed in filter | 19.98 | ?14.6 | ?0 | ?1.14 | ?0 | ?12.8∶1 | ?17.4 | ?0 |
| The active carbon filter is chewed | 17.16 | ?13.2 | ?9.59 | ?1.08 | ?5.26 | ?12.2∶1 | ?17.2 | ?1.1 |
Filter chew add behind the attapulgite as shown in table 2 to the adsorption effect of harmful components in the tar.
The adsorption effect to harmful components in the tar is chewed in the various filters of table 2
| BaP % | Benzofluoranthrene % | ?％ | Pyrene % | Fluoranthene % | Anthracene % | Luxuriant and rich with fragrance % | Benzanthracene % | |
| Filter is chewed the former state cigarette and is propped up | 0.2201 | ?0.2427 | ?0.1901 | ?0.1681 | ?0.8142 | ?0.2298 | ?0.8882 | ?0.0055 |
| 3% attapulgite cigarette props up | 0.1718 | ?0.1949 | ?0.0351 | ?0.0695 | ?0.2623 | ?0.0588 | ?0.1939 | ?0.0217 |
| The active carbon filter is chewed cigarette and is propped up | 0.4477 | ?0.3140 | ?0.1042 | ?0.0667 | ?0.6909 | ?0.2132 | ?0.7040 | ?0.0098 |
Add attapulgite in the pipe tobacco to tarry matters in smoke, the influence of nicotine:
Add attapulgite and the comparison that contrasts coke tar in cigarette, nicotine in table 3 pipe tobacco
| TPM (mg/ props up) | Tar (mg/ props up) | Nicotine (mg/ props up) | CO (mg/ props up) | |
| Pipe tobacco former state cigarette props up | ????21.04 | ????15.4 | ????1.38 | ????16.5 |
| Pipe tobacco adds the attapulgite cigarette and props up | ????21.14 | ????16.1 | ????1.66 | ????15.9 |
| The increase and decrease amount | ????0.10 | ????0.70 | ????0.28 | ????-0.6 |
| Gradient (%) | ????0.48 | ????4.54 | ????20.3 | ????--3.64 |
Add attapulgite cigarette shreds tar than the high 0.7mg of control group, increment rate 4.54%, but its nicotine is than the high 0.28mg of control group, increment rate 20.3%.It is lower to solve the low-coke tar cigarette nicotine content, jealous flat problem.
Add the influence of attapulgite in the pipe tobacco to harmful components in the tar:
Table 4 component separating resulting (absolute magnitude)
| TPM (mg/ props up) | Saturated hydrocarbons (mg/ props up) | Aromatic hydrocarbons (mg/ props up) | Nonhydrocarbon (mg/ props up) | Asphalitine (mg/ props up) | Post stays nonhydrocarbon (mg/ props up) | |
| Pipe tobacco former state cigarette props up | ????21.04 | ????0.41 | ????0.49 | ????3.31 | ????7.51 | ????9.32 |
| Pipe tobacco adds the attapulgite cigarette and props up | ????21.14 | ????0.65 | ????0.47 | ????3.81 | ????8.91 | ????7.30 |
| The increase and decrease amount | ????0.10 | ????0.24 | ????-0.02 | ????0.50 | ????1.40 | ????-2.02 |
| Gradient (%) | ????0.48 | ????58.54 | ????-4.08 | ????15.1 | ????18.64 | ????-21.67 |
Being found out by table, although two kinds of cigarette TPMs are more or less the same, only is 0.48%, each component relative quantity of extract, absolute magnitude generation basic change.Add the attapulgite cigarette in the pipe tobacco and prop up the saturated hydrocarbons material than former state cigarette Zhi Zengjia 0.24mg, amplification 58.54%; Aromatic hydrocarbon substance decline 0.02mg, the range of decrease 4.08%; Nonhydrocarbon increases 0.50mg, amplification 15.1%; Asphalitine increases 1.40mg, amplification 18.64%; Post stays nonhydrocarbon to reduce 2.02mg, the range of decrease 21.67%.Prove further that thus attapulgite has certain adsorption capacity to aromatic hydrocarbon substance, but to saturated hydrocarbons, low molecule heterocycle heteroatomic compound (nonhydrocarbon), macromolecule heterocyclic compound (asphalitine) absorption seldom, and may participate in the cigarette high-temp combustion at attapulgite and impel some component generation saturated hydrocarbons and low molecule heteroatomic compound and macromolecule heterocyclic compound in the pipe tobacco, because in this class material as ester class, Polyphenols, volatilization wet goods material cigarette jealous played bigger effect, thus also further proof interpolation attapulgite to the mechanism of action of the jealous improvement of cigarette.
Table 5 aromatic hydrocarbons chromatography result
| BaP % | Benzofluoranthrene % | ???? ????％ | Pyrene % | Fluoranthene % | Anthracene % | Luxuriant and rich with fragrance % | Benzanthracene % | |
| Pipe tobacco former state cigarette props up | 0.2201 | ?0.2427 | ?0.1901 | ?0.1681 | ?0.8143 | ?0.2298 | ?0.8882 | ?0.0055 |
| Pipe tobacco adds the attapulgite cigarette and props up | 0.1301 | ?0.2172 | ?0.0327 | ?0.1116 | ?0.5356 | ?0.1752 | ?0.6091 | ?0.0024 |
| The increase and decrease amount | -0.09 | ?-0.0255 | ?-0.1574 | ?-0.0565 | ?-0.2787 | ?-0.0546 | ?-0.2791 | ?-0.0031 |
| Gradient (%) | -40.89 | ?-10.51 | ?-82.80 | ?-33.61 | ?-34.23 | ?-23.76 | ?-31.42 | ?-56.36 |
Assay shows that attapulgite has stronger adsorption capacity to strong carcinogen in the aromatic hydrocarbons.
Beneficial effect of the present invention: the attapulgite mining deposits is abundanter, develops, studies its application in tobacco industry and have broad prospects.
In actual production technology, only need existing equipment is done slightly to change and adjust, can realize the interpolation of attapulgite in pipe tobacco.Concerning the additive effect of pipe tobacco, it adds, and cost is lower with respect to other additive, and adding technology is simple, and additive effect is remarkable, can be production of cigarettes and brings gratifying economic benefit and social benefit, and great promotional value is arranged.
Add 0.5 ‰ attapulgite cigarette and control group contrast in the pipe tobacco, nicotine increases 0.28mg/ and props up; Amplification 20.3%, tar aggregate level do not have to change substantially.By gas chromatographic analysis,, remarkable to harmful components effect in the reduction tar though it can not reduce tar content in cigarette.Adopt the Latin equation method of smokeing panel test, please provincial expert judging panel smoke panel test, after pipe tobacco adds attapulgite, the cigarette inherence effect of smokeing panel test is greatly improved, cigarette is risen to from category-B be that category-A, the inherence index of smokeing panel test obtains very big improvement, hamony significantly improves, assorted gas and excitant have obtained elimination, and pleasant impression is improved.
In actual production technology, physics added attapulgite during filter was chewed, and it is with low cost, and is low for equipment requirements, need not transform and buy new equipment substantially.Filter chew add tar falls behind the attapulgite, to fall the CO effect obvious, tar reduces 1.4mg/ and props up, CO reduces 1.1mg/ and props up; Reduction to carcinogen BaP, benzofluoranthrene is also all very remarkable, and average specific control sample reduction amplitude is respectively 21.9% and 19.7%.The nicotine amount remains unchanged substantially, when reducing tar, has kept that cigarette is originally eaten, fragrance.
The specific embodiment
Embodiment 1
Cigarette adds attapulgite in chewing with filter
Get 900 purpose attapulgite powder it evenly is suspended in the triacetyl glycerine, be made into 1%, 3%, 5% suspension respectively.The attapulgite suspension of 1%, 3%, 5% (w/w) is chewed on the machine spray on acetate silk in filter, make qualified filter rod sample, control and contain adsorbent in every rod and be about that 0.5mg/ props up, 1.5mg/ props up, 2.5mg/ props up, triacetyl glycerine content is about 0.05g/ and props up, consider adsorption capacity, it is too big or too little that the factors such as joint of cost of material and actual production equipment, attapulgite particle diameter can not be selected.
Embodiment 2
Add attapulgite in the pipe tobacco
Earlier 0.25g CMC is added in the 50ml ethanol, vibration is stirred, again the 2.5g attapulgite is added, and then adding 100ml ethanol dilution and constantly stirring, make it to become even suspension, with atomizer it is formed vaporific spray then and be added in the 5kg pipe tobacco, place 8 hours (envionmental humidity is 65 ± 5%) ethanol volatilization, roll-forming on cigarette machine then.
Claims (5)
1. the application process of an attapulgite in tobacco industry is characterized in that chewing additive with attapulgite as tobacco shred additive and/or filter; Make tobacco shred additive: the attapulgite that in pipe tobacco, adds pipe tobacco weight ratio 0.01-0.5%; Make the filter tip additive: get the attapulgite powder it evenly is suspended in the triacetyl glycerine, being made into weight ratio is the attapulgite powder suspension of 0.1-10%, suspension is chewed on the machine in filter spray on acetate silk, makes qualified cigarette filter rod.
2. application process according to claim 1, it is characterized in that adding in the pipe tobacco preparation technology of attapulgite: earlier 0.25g CMC is added in the 50ml ethanol, vibration is stirred, again the 2.5g attapulgite is added, and then add dilution of 100ml ethanol and continuous the stirring, make it to become even suspension, with atomizer it being formed vaporific spray then is added in the 5kg pipe tobacco, placed 8 hours, with ethanol volatilization, roll-forming on cigarette machine then.
3. application process according to claim 1 is characterized in that attapulgite chews additive as filter, is made into the attapulgite triacetyl glycerine suspension of weight ratio 3%, and on the spray tow, filter effect is better.
4. application process according to claim 1 is characterized in that it is the 500-1200 order that the used attapulgite powder of additive is chewed in filter.
5. application process according to claim 1 is characterized in that chewing additive control triacetyl glycerine content as filter is about 0.05g/ and props up, and adsorbent attapulgite content was that 0.5-2.5mg/ props up during the control filter was chewed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106082 CN1228003C (en) | 2003-10-14 | 2003-10-14 | Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310106082 CN1228003C (en) | 2003-10-14 | 2003-10-14 | Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1528214A true CN1528214A (en) | 2004-09-15 |
| CN1228003C CN1228003C (en) | 2005-11-23 |
Family
ID=34304419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310106082 Expired - Fee Related CN1228003C (en) | 2003-10-14 | 2003-10-14 | Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1228003C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102247012A (en) * | 2011-07-02 | 2011-11-23 | 云南瑞升烟草技术（集团）有限公司 | Application of acetate fiber paper added with adsorptive filling material in paper filter rod |
| CN102499457A (en) * | 2011-10-27 | 2012-06-20 | 庄信修 | Method for reducing benzene-contained compounds in smoke of cigarettes and application thereof |
| CN108968134A (en) * | 2018-06-08 | 2018-12-11 | 李华 | A kind of composition for substituting conventional cigarette and helping to give up smoking |
| CN109757768A (en) * | 2019-02-15 | 2019-05-17 | 滁州卷烟材料厂 | A kind of cigarette filter tip rod and its preparation process |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103190701B (en) * | 2013-04-01 | 2014-04-02 | 云南恩典科技产业发展有限公司 | Method for preparing cigarette filter with controllable adsorption performance |
-
2003
- 2003-10-14 CN CN 200310106082 patent/CN1228003C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102247012A (en) * | 2011-07-02 | 2011-11-23 | 云南瑞升烟草技术（集团）有限公司 | Application of acetate fiber paper added with adsorptive filling material in paper filter rod |
| CN102499457A (en) * | 2011-10-27 | 2012-06-20 | 庄信修 | Method for reducing benzene-contained compounds in smoke of cigarettes and application thereof |
| CN108968134A (en) * | 2018-06-08 | 2018-12-11 | 李华 | A kind of composition for substituting conventional cigarette and helping to give up smoking |
| CN108968134B (en) * | 2018-06-08 | 2022-02-25 | 李华 | A composition for replacing conventional cigarette and helping quit smoking |
| CN109757768A (en) * | 2019-02-15 | 2019-05-17 | 滁州卷烟材料厂 | A kind of cigarette filter tip rod and its preparation process |
| CN109757768B (en) * | 2019-02-15 | 2021-05-04 | 滁州卷烟材料厂 | Cigarette filter tip and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1228003C (en) | 2005-11-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1843670B1 (en) | Filter cigarette | |
| CN101061889A (en) | Cigarette harmless to human body and the method of producing the same | |
| CN102038284B (en) | Tobacco addition and application thereof | |
| CN102524950B (en) | Health-care cigarette containing agilawood | |
| CN101077223A (en) | Surface modification mesopore molecular screen for cigarette filter tip rod and preparation method thereof | |
| CN102783712A (en) | Filter stick flavor enhancing tea particle and preparation method thereof | |
| CN1228003C (en) | Attapulgus stone as cut tobacco additive and/or filter tip in to bacco industry | |
| CN101485493A (en) | Mint type cigarette | |
| CN101912161B (en) | Mint tobacco filter stick and preparation method thereof | |
| DE3532618C2 (en) | ||
| CN101487203A (en) | Preparation of peppermint type cigarette tissue | |
| CN111802702B (en) | Flavor slow-release material, heating rod, cigarette holder rod, preparation method of flavor slow-release material and cigarette holder rod, and application of flavor slow-release material and cigarette holder rod in heating of non-combustible tobacco products | |
| CN1923066A (en) | Composite additive for raising cigarette smoke moisture and its use | |
| CN201657766U (en) | Filter stick with corrugated functional coating forming paper | |
| CN101049186A (en) | Cigarette holder stick of adsorbing and reducing tar in high efficiency | |
| CN1356072A (en) | Tip filter of cigarette for reducing harmful component in smoke fume | |
| CN101897478B (en) | Filter stick for cigarettes and preparation method thereof | |
| CN1265744C (en) | Method for producing diacetate fiber tows of chitosan modified cigarette | |
| DE2919556A1 (en) | TOBACCO MIXTURE, CIGARETTES, CIGARS AND PIPE TOBACCO PRODUCED THEREOF AND METHOD FOR TREATING TOBACCO | |
| CN1214887A (en) | Tobacco modifying agent and making method thereof | |
| CN1656952A (en) | Composite cigarette filter tip capable of effectively reducing cigarette smoke gaseous phase free radical and its preparation method | |
| CN1286052A (en) | Easily ignited fragrant cigarettes containing tar reduced selectively and its production method | |
| CN101912160B (en) | Harm reduction filter stick for cigarette and preparation method thereof | |
| CN1931038A (en) | Additive for lowering tar and free radical content in cigarette smoke and its adding method | |
| CN104705783A (en) | Filter tip additive material capable of improving sensory characteristics of smoke and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |