CN1514049A - Composite elastic filament material and its processing method - Google Patents

Composite elastic filament material and its processing method Download PDF

Info

Publication number
CN1514049A
CN1514049A CNA021377855A CN02137785A CN1514049A CN 1514049 A CN1514049 A CN 1514049A CN A021377855 A CNA021377855 A CN A021377855A CN 02137785 A CN02137785 A CN 02137785A CN 1514049 A CN1514049 A CN 1514049A
Authority
CN
China
Prior art keywords
silk material
polypropylene
tourmaline
submicron
silk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA021377855A
Other languages
Chinese (zh)
Other versions
CN1205363C (en
Inventor
张明华
杨菁
丁永良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fishery Machinery and Instrument Research Institute of CAFS
Original Assignee
Fishery Machinery and Instrument Research Institute of CAFS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fishery Machinery and Instrument Research Institute of CAFS filed Critical Fishery Machinery and Instrument Research Institute of CAFS
Priority to CNB021377855A priority Critical patent/CN1205363C/en
Publication of CN1514049A publication Critical patent/CN1514049A/en
Application granted granted Critical
Publication of CN1205363C publication Critical patent/CN1205363C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Landscapes

  • Biological Treatment Of Waste Water (AREA)
  • Artificial Filaments (AREA)
  • Filtering Materials (AREA)

Abstract

A composite elastic filament material used as the biofiller in biomembrane method for treating sewage is prepared from the mother polypropylene particles containing the superfine tourmalinite particles and polypropylene particles through preparing filament, napping, and embossing.

Description

Composite elastic silk material and process thereof
Technical field
The present invention relates to be used in the environmental protection biologic packing material of biomembrance process sewage disposal, refer to constitute the composite elastic silk material and the manufacturing technique method thereof of biologic packing material especially.
Background technology
Biomembrance process purifies water becomes one of important method of sewage disposal, and the silk material performance of using as the biologic packing material of biofilm carrier directly affects the effect of this method.In the biologic packing material of many rigid classes, soft class and medium-soft class formation form, tow shape stereo-elastic biologic packing material is because of hard and soft preferably combination property and characteristics simple and reasonable for structure, maintenance easy to operate are arranged, and is more apparent superior and practical.Its anti-waterpower and organic loading impact property are good, and the material life-span is long, and the adhesion conglomeration has preferable anti-dirt blocking ability and air water flow-disturbing performance.But the silk material smooth surface that this tow shape stereo-elastic biologic packing material uses, specific area is little, and biofilm is slower; Make raw material with simple material polypropylene, active low, these shortcomings have restricted its further developing in water treatment field to some extent.The process of this silk material is that polypropylene agglomerate according to a conventional method through extruder spray silk-coiling-stretching-traction-cut-out-oven dry, is made smooth silk material.
Summary of the invention
The present invention overcomes the shortcoming that above-mentioned biologic packing material elastic yarn material exists, and improves water and biomembranous activity, and a kind of be applied in the composite elastic silk material and the manufacturing technique method thereof that contain active material new in the water treatment of environmental protection, municipal administration, aquaculture are provided.
The present invention proposes a kind of with pp material with to contain the polypropylene agglomerate of tourmaline compound, through tow shape and curling shape elastic yarn material technological method for processing, make silk material with active function; Simultaneously this silk material is made biologic packing material, be applied to water treatment field such as environmental protection, municipal administration, aquaculture.Tourmaline is a kind of mineral crystal with environment-friendly function, its radiation-curable far infrared, release anion, generation bioelectricity, and contain trace element and several mineral materials.By the effect of infrared activated hydrone, the macromolecular mass of water is diminished, thereby promote the penetrability of water, dissolving power and energy make it easier turnover cell membrane, transport nutriment and promote metabolism.The comprehensive function of above all effects can improve biomembranous activity and purifying water effect in addition.
The process that production contains the composite elastic silk material of active material is, polypropylene agglomerate contains 20~35% tourmaline submicron-sized particulates, tourmaline submicron-sized particulate diameter 0.3~1 μ m, polypropylene particles and polypropylene agglomerate be by weight 10: 1~1.5 evenly mix after,, reel, stretch through extruder spray silk with the common process method; Increase plucking and double-sided embossing two procedures afterwards, that is, adopt serrated knife,, carry out the routine traction afterwards, cut off, dry then through the roller mill double-sided embossing with the monofilament plucking; Make elastomeric monofilaments, filament diameter 0.2-0.5mm.The monofilament overall appearance that adopts this explained hereafter is a linear, and its technological process is as follows: raw material mixing-spray silk-coiling-stretching-plucking-double-sided embossing-traction-cut-out-oven dry.
After the double-sided embossing operation, available machinery is expected crimping by stretching with silk, is placed under 155~160 ℃ the temperature to dry by the fire typing in 2~3 hours, and the silk material is spring-like, cuts off.The monofilament overall appearance that adopts this explained hereafter is that helical coil is curved, and its technological process is as follows: raw material mixing-spray silk-coiling-stretching-plucking-double-sided embossing-crimping by stretching-drying and shaping-cut-out.
The invention allows for the application of above-mentioned silk material in water treatment.The elastic yarn material that above-mentioned process is made is evenly distributed to be radiation-like and to intert and be bonded on the axial cord, makes the tow shape elastic biological filler with active function, adopts to hang or the mode of stacking is installed and is applied to water treatment field; Be particularly useful for dripping the utilization of formula filtering ponds.Adopt suspension or the mode of stacking that the biologic packing material with active function is installed in the trickling filter, because of silk material tool elasticity preferably, under the water droplet percussion, significantly vibration is continuously arranged, the part water droplet is rebounded upward, in trickling filter, play water distribution effect again, and the water droplet that falls more is tending towards homogenising, prolonged the time that in filler, stops, simultaneously owing to the friction between the water, impact can produce effective stimulation to this active material of tourmaline, external energy (comprising the electric charge increment) is provided, has increased the effect of air water exchange.
The present invention makes raw material because employing contains active function material tourmaline submicron-sized particulate, in production technology, increase plucking and double-sided embossing two procedures, make above-mentioned two kinds of monofilament radial section peripheries producing be the convex-concave polygon, monofilament surface is lousiness shape branch simultaneously, use such monofilament to make biologic packing material, not only strengthened its activity, and biofilm is rapid, specific area also increases substantially.Use this filler sewage to be carried out biomembrane and handle its NH as carrier 3 +-N, clearances such as COD all improve about 40% than conventional fillers.
The specific embodiment
Embodiment 1:
Production contains the process of the composite elastic silk material of active material, polypropylene agglomerate contains 20~35% tourmaline submicron-sized particulates, tourmaline submicron-sized particulate diameter 0.7 μ m, polypropylene particles is a double centner, after 10 kilograms polypropylene agglomerate evenly mixes, under 250 ℃ of temperature, spray silk through conventional process extruder, reel, stretch; Adopt serrated knife with the monofilament plucking then, through the roller mill double-sided embossing, draw afterwards, cut off, dry; Make elastomeric monofilaments, filament diameter 0.4mm.The monofilament overall appearance that adopts this explained hereafter is a linear, and silk material radial section periphery is the convex-concave polygon, and silk material surface is lousiness shape branch simultaneously.
Embodiment 2:
Production contains the process of the composite elastic silk material of active material, polypropylene agglomerate contains 30% tourmaline submicron-sized particulate, tourmaline submicron-sized particulate diameter 0.3 μ m, 80 kilograms of polypropylene particles, after 12 kilograms polypropylene agglomerate evenly mixes, under 250 ℃ of temperature, spray silk through conventional process extruder, reel, stretch; Adopt serrated knife with the monofilament plucking then, through the roller mill double-sided embossing, after the double-sided embossing operation, with machinery silk is expected crimping by stretching, be placed under 155~160 ℃ the temperature and dry by the fire typing in 2~3 hours, the silk material is spring-like, cut-out.Filament diameter 0.5mm.The monofilament overall appearance that adopts this explained hereafter is that helical coil is curved, and silk material radial section periphery is the convex-concave polygon, and silk material surface is lousiness shape branch simultaneously.
The elastic yarn material that above-mentioned process is made is three-dimensional evenly distributed to be radiation-like and to intert and be bonded on the axial cord, makes the tow shape elastic biological filler with active function, adopts to hang or the mode of stacking is installed and is applied to water treatment field; Be particularly useful for dripping the utilization of formula filtering ponds.

Claims (6)

1, a kind of process of producing composite elastic silk material, it is characterized in that, polypropylene agglomerate contains 20~35% tourmaline submicron-sized particulates, tourmaline submicron-sized particulate diameter 0.3~1 μ m, polypropylene particles and polypropylene agglomerate be by weight 10: 1~1.5 evenly mix after, through extruder spray silk, reel, stretch; Adopt serrated knife that silk is expected plucking then,, draw afterwards, cut off, dry again through the roller mill double-sided embossing; Make the elastomeric monofilaments of diameter 0.2-0.5mm.
2, according to the process of the composite elastic silk material of the described production of claim 1, it is characterized in that, after the double-sided embossing operation, with machinery silk is expected crimping by stretching, be placed under 155~160 ℃ the temperature and dry by the fire typing in 2~3 hours, the silk material is spring-like, cut-out.0.2-0.5mm
3, according to the process of the composite elastic silk material of claim 1 or 2 described productions, it is characterized in that polypropylene agglomerate contains 30% tourmaline submicron-sized particulate, tourmaline submicron-sized particulate diameter 0.3 μ m; Polypropylene particles and polypropylene agglomerate are 10: 1 or 10: 1.5 by weight.
4, the composite elastic silk material of producing according to the described process of claim 1 is characterized in that including polypropylene particles and polypropylene agglomerate, and polypropylene agglomerate contains 20~35% tourmaline submicron-sized particulates, tourmaline submicron-sized particulate diameter 0.3~1 μ m; Polypropylene particles and polypropylene agglomerate weight ratio are 10: 1~1.5; Silk material radial section periphery is the convex-concave polygon, and silk material surface is lousiness shape branch simultaneously; Silk material overall appearance is a linear; Elastomeric monofilaments diameter 0.2-0.5mm.
5, the composite elastic silk material of producing according to the described process of claim 2 is characterized in that including polypropylene particles and polypropylene agglomerate, and polypropylene agglomerate contains 20~35% tourmaline submicron-sized particulates, tourmaline submicron-sized particulate diameter 0.3~1 μ m; Polypropylene particles and polypropylene agglomerate weight ratio are 10: 1~1.5; Silk material radial section periphery is the convex-concave polygon, and silk material surface is lousiness shape branch simultaneously; Silk material overall appearance is that helical coil is curved.
6, the evenly distributed radiation-like that is of the elastic yarn material that above-mentioned process is made is interted and to be bonded on the axial cord, makes the tow shape elastic biological filler with active function, adopts to hang or the mode of stacking is installed and is applied to water treatment field; Be particularly useful for dripping the utilization of formula filtering ponds.
CNB021377855A 2002-11-01 2002-11-01 Composite elastic filament material and its processing method Expired - Fee Related CN1205363C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB021377855A CN1205363C (en) 2002-11-01 2002-11-01 Composite elastic filament material and its processing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB021377855A CN1205363C (en) 2002-11-01 2002-11-01 Composite elastic filament material and its processing method

Publications (2)

Publication Number Publication Date
CN1514049A true CN1514049A (en) 2004-07-21
CN1205363C CN1205363C (en) 2005-06-08

Family

ID=34231700

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB021377855A Expired - Fee Related CN1205363C (en) 2002-11-01 2002-11-01 Composite elastic filament material and its processing method

Country Status (1)

Country Link
CN (1) CN1205363C (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100351438C (en) * 2005-03-09 2007-11-28 丁宏广 Monofilament capable of emitting negative ion, its preparing method and use
CN100453715C (en) * 2004-10-27 2009-01-21 上海依福瑞实业有限公司 Functionalized polypropylene fibre and its preparation method
CN102776587A (en) * 2011-05-09 2012-11-14 宜兴市填料厂 Elastic silk filler molding complete device
CN103203179A (en) * 2013-03-19 2013-07-17 王映璋 Preparation method for multiple micropore negative ion far-infrared electric field biological affinity packing
CN112978903A (en) * 2021-04-07 2021-06-18 吉林建筑大学 Rolling type biological filler

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100453715C (en) * 2004-10-27 2009-01-21 上海依福瑞实业有限公司 Functionalized polypropylene fibre and its preparation method
CN100351438C (en) * 2005-03-09 2007-11-28 丁宏广 Monofilament capable of emitting negative ion, its preparing method and use
CN102776587A (en) * 2011-05-09 2012-11-14 宜兴市填料厂 Elastic silk filler molding complete device
CN103203179A (en) * 2013-03-19 2013-07-17 王映璋 Preparation method for multiple micropore negative ion far-infrared electric field biological affinity packing
CN103203179B (en) * 2013-03-19 2016-04-20 王映璋 A kind of preparation method of many micropores negative ion far-infrared electric field biocompatible filler
CN112978903A (en) * 2021-04-07 2021-06-18 吉林建筑大学 Rolling type biological filler

Also Published As

Publication number Publication date
CN1205363C (en) 2005-06-08

Similar Documents

Publication Publication Date Title
CN102660813B (en) Biological activated carbon fibe, ecological carbon fiber composite comprising same and preparation method thereof
KR100815459B1 (en) Method for producing textiles and masterbatch contained of powdered ore
CN102491498B (en) Ecological carbon-fiber composite, preparation method thereof and sewage treatment reactor containing ecological carbon-fiber composite
CN101889534B (en) Cultivation medium
KR101759483B1 (en) Synthetic resin with antibiotic and deodorant functional material and manufacture method thereof
CN104069879A (en) Preparation method for titanium dioxide/hydroxyapatite composite photocatalyst
CN1205363C (en) Composite elastic filament material and its processing method
CN108950852B (en) Warp knitted spacer fabric with partial hollows
CN109529780A (en) A kind of magnetic porous adsorbent and preparation method thereof
CN103755041B (en) Fiber-based ecological nest for water purification of polluted water body
CN104787873A (en) Artificial root system packing unit, biological carrier and biological membrane bioreactor module
CN203048667U (en) Novel denitrifying nitrogen removal device
CN104229926A (en) Composite material applied to water molecule cluster cutting reaction and preparation method of composite material
CN100391866C (en) Wastewater treating apparatus
CN204345372U (en) A kind of novel intelligent air purifying lamp
CN105950498B (en) The production method and its biological denitrification method of Paracoccus denitrificans
CN110357248A (en) A kind of water treatment filler and preparation method thereof
Han et al. A convenient ultraviolet irradiation technique for synthesis of antibacterial Ag-Pal nanocomposite
CN110484528B (en) Method for treating oily sewage by utilizing immobilized bacteria and algae combination
CN109748398A (en) A kind of production technology and bio-carrier of the bio-carrier that making Nano surface quantum biological can be implanted into
CN107986557A (en) A kind of synchronous coupled biological treatment process for removing agricultural runoff nitrogen phosphorus
CN2577575Y (en) Composite elastic wire biological filling
CN112320949A (en) Nitrification-denitrification coupling biological membrane system for slowly releasing organic carbon source
CN1321902C (en) Water treatment materials and production thereof
CN101328057A (en) Modified active surface treating negative ion far infrared multifunctional additive and manufacturing process

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee