CN104229926A - Composite material applied to water molecule cluster cutting reaction and preparation method of composite material - Google Patents
Composite material applied to water molecule cluster cutting reaction and preparation method of composite material Download PDFInfo
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- CN104229926A CN104229926A CN201410440088.9A CN201410440088A CN104229926A CN 104229926 A CN104229926 A CN 104229926A CN 201410440088 A CN201410440088 A CN 201410440088A CN 104229926 A CN104229926 A CN 104229926A
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Abstract
The invention relates to a composite material applied to a water molecule cluster cutting reaction and a preparation method of the composite material. The method comprises the following steps: (1) weighing raw materials comprising iron tourmaline powder, tourmaline powder, diatomite, montmorillonite, attapulgite clay, cerous nitrate and lanthanum nitrate; (2) uniformly mixing the cerous nitrate and the lanthanum nitrate, and dissolving the mixture with water for spraying, thereby preparing a mixed spraying solution; (3) uniformly mixing the iron tourmaline powder, the tourmaline powder, the diatomite, the montmorillonite and the attapulgite clay, regulating the spraying humidity of the mixed spraying solution, and preparing spheres from the uniformly mixed powder under the action of the mixed spraying solution; and (4) sintering the spheres, and cooling, thereby obtaining the final material. The composite material can be applied to the water molecule cluster cutting reaction to prepare small molecule cluster water and also has excellent bactericidal performance, and harmful substances in water can be effectively removed.
Description
Technical field
The invention belongs to material technology, water-treatment technology field, be specifically related to a kind ofly be applied to matrix material of water molecule cluster cleavage reaction and preparation method thereof.
Background technology
Water is made up of with the structure of triangular form 2 hydrogen 1 oxygen, 3 atoms, is connect with covalent linkage therebetween.Because its bond angle is about 105 degree, so the charge-site of water molecules is not overlapping.The relatively large aobvious negativity of cloud density on Sauerstoffatom, two hydrogen atoms then aobvious positive polarity, makes water become strong polar molecule.Under van der Waals interaction, between water molecules, can hydrogen bond be formed, have the trend attracting each other into bulk.Such water molecules just can pass through hydrogen bond, interacts with multiple water molecules, is formed " water bunch (Water Cluster) ".In recent years, the paper of more and more many water cluster structures is delivered at famous " science " and " nature " magazine.Under certain condition, water can be formed structurizing five rings, or clustered water.Five rings water is actually unstable.Clustered water is relatively stable.Structurizing small water molecule bunch also can form structurized macromole bunch (H2O) n under certain condition.
In most cases, particularly when long inactivity, water can form the cluster of nearly tens water moleculess.These macromolecular mass are random, a unbodied chain ball of string.Its dissolving power, seepage force are all very low, are not easily absorbed by animal and plant and people, become " one, stagnant water ".The molecular clustering of these amorphous structures through certain physical chemistry process, can become less molecular clustering.
The characterizing method of water molecule cluster size mainly adopts nuclear magnetic resonance method.The test process of nuclear magnetic resonance method measures after water sample directly being put into nuclear magnetic tube sealing, and avoid the interference of outside moisture, good test effect, process is simple.NMR spectral line has certain width and results from uncertainty principle, and namely the width of spectral line and sample were inversely proportional in the life-span of this state.Want to continue in a certain time interval NMR signal to be detected, must relaxation process be there is.Therefore the width of Nmr Lines and the relaxation time of sample are inversely proportional to.For liquid water, nuclear magnetic resonance spectrum live width is mainly subject to the impact of transverse relaxation process.Transverse relaxation process is spin-spin relaxation, reflection nuclear-magnetism apart between interaction, the cluster of water is larger, and oxygen core or the spin states between proton and adjacent core exchange faster, and sample time required for state that restores balance is shorter, and spectral line is wider.Therefore, can characterize the average relative size of liquid water cluster with the width of NMR spectral line, the wider cluster of spectral line is larger, and vice versa.When utilizing nuclear magnetic resonance method to study the structure of liquid water, should select
17o core is measured;
17o NMR half-breadth is high can the mean size of reflecting liquid water cluster preferably, and spectral line is wider, and liquid water cluster is larger, and spectral line is narrower, and liquid water cluster is less.
Research finds: tourmalinite is a kind of cyclosilicate crystalline mineral elementary composition by Na, Ca, Mg, B and Fe etc., l9 century is just found it and has piezoelectricity and pyroelectric effect along c-axis.Tourmalinite has pyroelectricity and piezoelectricity, the change of the tourmalinite interior molecules moment of dipole caused by the subtle change of temperature or pressure at normal temperatures can be energized into high level molecule, when its downward transition, unnecessary energy just can discharge with the form of ir radiation.Although far infrared rays is invisible light, possess all characteristics that visible ray has, it has stronger seepage force and radial force, has significant temperature control effect and resonance effect, is easily subsequently absorbed in the material and is converted into the interior energy of material.Therefore the change of envrionment temperature and pressure is the power of tourmalinite outwardly radiated electromagnetic wave, this process nature is a kind of energy exchange between tourmalinite and environment.
Tourmalinite surface is the outer boundary of condensed matter, when it and other medium contact, is just called as interface.In block, be set to null with antibonding(molecular)orbital because bonding orbital is full of by electron institute, mineral crystal is in stable state.But be in the atom on surface because original in block with the adjacent atom " losss " of its Cheng Jian, its net plane is blocked suddenly in other words, can produce excessive electric density, or claims surface to hang key.Outstanding key causes mineral surface high-energy state, requires that Surface Layer Atomic Structure is recombinated.The object of surface rearrangement is that the bonding orbital that requirement negatively charged ion produces can by complete filling in the restructuring of surface, and cationic antibonding(molecular)orbital can be put sky completely in restructuring.Therefore the atom of condensed matter surface (or outer boundary) is due to the existence of its outstanding key in surface, has absorption foreign ion or molecule to reduce the tendency of its surface free energy.When mineral contact with water, its surface can produce hydroxylating owing to having the electric field action being similar to electric dipole, can make water molecules that slight electrolysis occurs, form H when the tourmaline particles contact aqueous solution
+and OH
-, wherein H
+and H
2o molecule combines and forms H
3o
+bioactive molecule, bioactive molecule has extremely strong interfacial activity, can attract the impurity in water, dirt, plays the effect of purified water source.OH
-and H
2o molecule combines and forms H
3o
2 -the H that negative ion electrolysis water molecules is formed
+and OH
-neutralization reaction occurs, and too much discharges with the form of hydrogen.
Hydrogen ion obtains the electronics that between tourmalinite electrode, weak current provides and forms hydrogen; Hydroxide ion is combined with water molecules or other macromole and forms negative ion group,
H2O→OH－+H+(1)
2H++2e→H2↑(2)
OH－+nH2O→OH－(H2O)n(3)
Research finds to produce a large amount of " aquation hydroxyl ion H through modification and the tourmaline capable after activating
3o
2 -", and be referred to as " alkalion ".The negative ion of the generation of common tourmalinite is 300-600/cm2, and the negative ion after activation can reach 2000/more than cm2.In the dynamic hydrogen bond complex system of water clusters, mainly form hydrogen bond by electron hole track.When a large amount of negative ion exists, because negative ion has sufficient electron hole and unsaturated polarity lattice vacancy, form electric microfield, its OH ˙ robs electronic capability and is far longer than H
2hydrogen bond in O.Because water is a kind of polar molecule, the major cause that intermolecular hydrogen bonding is formed is exactly that the eelctric dipole existed between water molecules interacts, extra electric field can change the dynamic hydrogen bond network system of water cluster, by weakening or cutting off the hydrogen bond between water molecules, large water molecule cluster hydrogen bond rupture can be made, realize the object of cutting water clusters.
In addition between water molecules, the bond energy of hydrogen bond is 29 ~ 42kJ/mol, is equivalent to the photon energy of infrared region 2.7 ~ 4.1Lm, and the far infrared rays therefore through modification and the tourmalinite radiation after activating also has enough energy to interrupt the hydrogen bond in water.When the infrared ray action of tourmalinite radiation is in water, ultrared wavelength is corresponding with the absorbing wavelength of water, produces resonance absorption, meets the principle that the radiation peak band of ir radiation material is consistent with the absorption peak band of infra-red absorbent substance.Thus severed segment hydrogen bond, hydrogen bond action weakens, and makes water molecule cluster diminish and be activated.
Summary of the invention
The object of this invention is to provide and be a kind ofly applied to matrix material of water molecule cluster cleavage reaction and preparation method thereof, apply this material when carrying out water treatment, macromolecular mass water can be made to resolve into small-micelle water, realize reactivating of water; This material also has good bactericidal property simultaneously, effectively can remove the objectionable impurities in water.
The matrix material being applied to water molecule cluster cleavage reaction of the present invention, its preparation method comprises the following steps:
1) raw material is taken, each component and massfraction are respectively: the 800-1200 order iron tourmaline powder of 12-21%, the 100-400 order iron tourmaline powder of 10-16%, the 100-150nm tourmaline powder of 2-4%, the diatomite of 22-28%, the polynite of 15-20%, the attapulgite clay of 22-28%, the cerous nitrate of 0.1-0.2%, and the lanthanum nitrate of 0.1-0.2%;
2) by cerous nitrate and lanthanum nitrate mixing, and dissolve into spray-water, make mixing spray liquid;
3) by iron tourmaline powder, tourmaline powder, diatomite, polynite and attapulgite clay mixing, regulate the spray humidity of described mixing spray liquid, the powder of mixing is made spheroid under the effect of described mixing spray liquid;
4) sintering processes is carried out to described spheroid, after cooling, obtain final material.
Preferably, step 3) the spray humidity of described mixing spray liquid is 10-20%.
Preferably, step 3) granularity of described spheroid is 3-5mm.
Preferably, step 3) adopt disk machine to prepare described spheroid, its rotating speed is 130-230 rev/min.
Preferably, in described disk machine, appropriate ball core is added shaping to accelerate spheroid.
Preferably, step 4) the control temperature rise rate that adopts when sintering is 2-4 DEG C/min, sintering temperature is 700-1000 DEG C, and the time is 2-4 hour.
Preferably, step 4) adopt retort furnace to carry out described sintering,
Preferably, described iron tourmaline powder is Xinjiang iron tourmaline powder.
Adopt aforesaid method prepare the matrix material being applied to water molecule cluster cleavage reaction, also can be described as ion-sieve material, it forms the great soil group nonmetallic mineral material that tourmalinite that mainly content is 24-41% (massfraction) and content are 59-76% (massfraction), and other are rare earth material.
Apply above-mentioned matrix material when carrying out water treatment, great amount of hydroxy group negative ion can be discharged, because hydroxyl group anion has sufficient electron hole and unsaturated polarity lattice vacancy, form electric microfield reaction tank, its OH ˙ robs electronic capability and is far longer than hydrogen bond in H2O, thus the dynamic hydrogen bond network system of water cluster can be changed, by weakening or cutting off the hydrogen bond between water molecules, macromolecular mass water is made to resolve into the small-micelle water only containing several water molecules, realize reactivating of water, realize the object of cutting water clusters.Matrix material particle diameter is less, and the electric field action on surface is stronger, larger to the weakening effect of hydrogen bond.This matrix material has higher infrared emissing ability in the infrared signature absorption region of water, meets the principle that the radiation peak band of ir radiation material is consistent with the absorption peak band of infra-red absorbent substance.The far infrared rays of composite material radiation has enough energy to interrupt the hydrogen bond in water.Ultrared wavelength is corresponding with the absorbing wavelength of water, produces resonance absorption, thus severed segment hydrogen bond, hydrogen bond action weakens, so the surface tension of water reduces, makes water molecule cluster diminish and be activated.This micromolecular water is to recovery cell function, strengthen cell viability, improve body immunity, promote HUMAN HEALTH, delay senility and can play important effect, and have auxiliary improvement result to the disease such as hypertension, hyperglycemia, hyperlipidemia and obesity, gout, gastro-duodenal ulcer, constipation, endocrine regulation.
This matrix material also has good bactericidal property simultaneously, and effectively can remove the objectionable impurities in water.Specifically, applying this material, to carry out the performance perameter of water treatment as follows:
Bactericidal property: to Candida albicans, staphylococcus aureus, colibacillary killing rate for being not less than 40%;
Make water small molecules: the water after process is used
17within O nuclear magnetic resonance analyser records half fabric width 80Hz;
Make water negative ionization: under the prerequisite that the water after process declines at each metal ion species, (nonmetal) negative ion significantly improves, and specific conductivity raises more than 20%;
Dispel residual chlorine more than 30% in water; Dispel nitrate in water, nitrite more than 30%; Dispel ammonia nitrogen more than 30% in water.
Accompanying drawing explanation
Fig. 1 is that Application and preparation of the present invention is in the flow chart of steps of the matrix material of water molecule cluster cleavage reaction.
Fig. 2 A and Fig. 2 B is scanning electron microscope (SEM) Photomicrograph being applied to the matrix material of water molecule cluster cleavage reaction prepared in embodiment, and wherein Fig. 2 A is the SEM photo of 10000 times, and wherein Fig. 2 B is the SEM photo of 40000 times.
Fig. 3 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation in embodiment 1.
Fig. 4 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation in embodiment 2.
Fig. 5 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation in embodiment 3.
Embodiment
Below by specific embodiments and the drawings, the present invention is described in detail.
Embodiment 1:
The matrix material being applied to water molecule cluster cleavage reaction of the present embodiment, its preparation process as shown in Figure 1, is described as follows:
1) take raw material, each component and massfraction are respectively:
1000 order Xinjiang iron tourmaline powder (do and inhale iron process) 16%, 300 order Xinjiang iron tourmaline powder 13% (do and inhale iron process), granularity is the tourmaline powder 3% of 100-150nm, diatomite 24%, polynite 18%, attapulgite clay 26%.The cerous nitrate of 0.14% and the lanthanum nitrate of 0.12%.
2) by the cerous nitrate of 0.14% and 0.12% lanthanum nitrate (catalyzed reaction agent, play a part modification and activate tourmalinite), after mixing, dissolve into spray-water, prepare for subsequent use.
3) by other component mixing beyond cerous nitrate and lanthanum nitrate, the powder of mixing is injected disk machine, add appropriate ball core (add a small amount of ball core spheroid can be accelerated shaping) simultaneously, regulation and control spray humidity about 15% and rotating speed 180 revs/min, shake the spheroid making 3-5mm, after drying in the shade, in retort furnace, temperature control fires sintering 4 hours, controlling temperature rise rate is 3 DEG C/min, top temperature sets 750 DEG C, be incubated 2 hours after reaching top temperature, naturally cooling, obtains the ion(ic)sieve spheroid of 3-5mm.Fig. 2 is the scanning electron microscope Photomicrograph of this matrix material of preparation, and as can be seen from this figure, substantially do not reunite between material granule, all dispersed with simple particle form, granule boundary is clear, favorable dispersity.Fig. 3 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation, and wherein T represents tourmalinite, and now tourmaline crystal structure does not change but lattice expands.
The material of above-mentioned preparation may be used for carrying out water treatment, is especially applied to water molecule cluster cleavage reaction to prepare micromolecular water.The detection method that the present embodiment is concrete adopted is:
A) sterilization detects: inoculation culture slant strains, scrapes inclined-plane lawn in diluting soln, is mixed with 10
6the bacteria suspension of about cfu/ml, the compound material ball getting 20 grams of above-mentioned preparations puts into sterile purified water, adds 1 milliliter of bacteria suspension, jolting one hour on shaking table.Then take out and carry out 10 times of dilutions containing bacterium mixed solution, then take out 0.5 milliliter of mixed solution to slat chain conveyor.Microbial culture 48 hours, fungus culture 72 hours.Blank is not containing the colony number that ion(ic)sieve pottery ball is cultivated as stated above:
Antibiotic rate=[(blank colony number-sample colony number)/blank colony number] х 100%
B) micromolecular water detects, and uses
17after O nuclear magnetic resonance analyser measurement processing, half of water is secondary wide.Half pair of more untreated water is wide.
C) each metal ion species in water sample after check processing, then measure the specific conductivity of water sample.When metal ion species each in water sample declines or do not have to rise, the raising of its specific conductivity is exactly the raising of nonmetallic ion, i.e. the degree of negative ionization.Contrast untreated electrical conductivity of water.
D) residual chlorine of water sample after measurement processing, compares with former water.
E) NO3-N and NO2-N of water sample after measurement processing, compares with former water.
F) the ammonia nitrogen value of water sample after measurement processing, compares with former water.
The Specifeca tion speeification adopting above-mentioned detection method finally to obtain is as follows:
Bactericidal property: to Candida albicans, staphylococcus aureus, colibacillary killing rate for being not less than 40%.
Make water small molecules: the water after process is used
17within O nuclear magnetic resonance analyser records half fabric width 80Hz.
Make water negative ionization: under the prerequisite that the water after process declines at each metal ion species, (nonmetal) negative ion significantly improves, and specific conductivity raises more than 20%.
Dispel residual chlorine more than 30% in water
Dispel nitrate in water, nitrite more than 30%.
Dispel ammonia nitrogen more than 30% in water.
Embodiment 2:
The matrix material being applied to water molecule cluster cleavage reaction of the present embodiment, its preparation process is:
1) take raw material, each component and massfraction are respectively:
800 order Xinjiang iron tourmaline powder (do and inhale iron process) 21%, 100 order Xinjiang iron tourmaline powder 10%, 100-150nm tourmaline powders 2%, diatomite 22%, polynite 17%, attapulgite clay 28%.The cerous nitrate of 0.2% and the lanthanum nitrate of 0.2%.
2) by the cerous nitrate of 0.2% and 0.2% lanthanum nitrate (catalyzed reaction agent, play a part modification and activate tourmalinite), after mixing, dissolve into spray-water, prepare for subsequent use.
3) by other component mixing beyond cerous nitrate and lanthanum nitrate, the powder of mixing is injected disk machine, add appropriate ball core (add a small amount of ball core spheroid can be accelerated shaping) simultaneously, regulation and control spray humidity about 10% and rotating speed 130 revs/min, shake the spheroid making 3-5mm, after drying in the shade, in retort furnace, temperature control fires sintering 4 hours, controlling temperature rise rate is 2 DEG C/min, top temperature sets 850 DEG C, be incubated 4 hours after reaching top temperature, naturally cooling, obtains the ion(ic)sieve spheroid of 3-5mm.Fig. 4 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation, and wherein T represents tourmalinite, and M represents mullite, S represents boraxal, H represents ferric oxide, and surperficial sintered layer appears in 850 DEG C of samples, starts to be decomposed to form new thing phase mullite, boraxal and rhombohedral iron ore.
Material prepared by application aforesaid method carries out water treatment, and detection method is with embodiment 1, and its Specifeca tion speeification is:
Bactericidal property: to Candida albicans, staphylococcus aureus, colibacillary killing rate for being not less than 40%.
Make water small molecules: the water after process is used
17within O nuclear magnetic resonance analyser records half fabric width 80Hz.
Make water negative ionization: under the prerequisite that the water after process declines at each metal ion species, (nonmetal) negative ion significantly improves, and specific conductivity raises more than 25%.
Dispel residual chlorine more than 35% in water
Dispel nitrate in water, nitrite more than 30%.
Dispel ammonia nitrogen more than 35% in water.
Embodiment 3:
The matrix material being applied to water molecule cluster cleavage reaction of the present embodiment, its preparation process is:
1) take raw material, each component and massfraction are respectively:
1200 order Xinjiang iron tourmaline powder (do and inhale iron process) 12%, 400 order Xinjiang iron tourmaline powder 16%, 100-150nm tourmaline powders 4%, diatomite 28%, polynite 18%, attapulgite clay 22%.The cerous nitrate of 0.1% and the lanthanum nitrate of 0.1%.
2) by the cerous nitrate of 0.2% and 0.2% lanthanum nitrate (catalyzed reaction agent, play a part modification and activate tourmalinite), after mixing, dissolve into spray-water, prepare for subsequent use.
3) by other component mixing beyond cerous nitrate and lanthanum nitrate, the powder of mixing is injected disk machine, add appropriate ball core (add a small amount of ball core spheroid can be accelerated shaping) simultaneously, regulation and control spray humidity about 20% and rotating speed 230 revs/min, shake the spheroid making 3-5mm, after drying in the shade, in retort furnace, temperature control fires sintering 4 hours, controlling temperature rise rate is 4 DEG C/min, top temperature sets 950 DEG C, be incubated 3 hours after reaching top temperature, naturally cooling, obtains the ion(ic)sieve spheroid of 3-5mm.Fig. 5 is the XRD figure spectrum being applied to the matrix material of water molecule cluster cleavage reaction of preparation, and wherein T represents tourmalinite, and M represents mullite, A represents aluminium borate, H represents ferric oxide, and surperficial sintered layer appears in 950 DEG C of samples, starts to be decomposed to form new thing phase mullite, aluminium borate and rhombohedral iron ore.
Material prepared by application aforesaid method carries out water treatment, and detection method is with embodiment 1, and its Specifeca tion speeification is:
Bactericidal property: to Candida albicans, staphylococcus aureus, colibacillary killing rate for being not less than 40%.
Make water small molecules: within the water 17O nuclear magnetic resonance analyser after process records half fabric width 80Hz.
Make water negative ionization: under the prerequisite that the water after process declines at each metal ion species, (nonmetal) negative ion significantly improves, and specific conductivity raises more than 15%.
Dispel residual chlorine more than 20% in water
Dispel nitrate in water, nitrite more than 20%.
Dispel ammonia nitrogen more than 20% in water.
Above embodiment is only in order to illustrate technical scheme of the present invention but not to be limited; those of ordinary skill in the art can modify to technical scheme of the present invention or equivalent replacement; and not departing from the spirit and scope of the present invention, protection scope of the present invention should be as the criterion with described in claim.
Claims (9)
1. be applied to a preparation method for the matrix material of water molecule cluster cleavage reaction, its step comprises:
1) raw material is taken, each component and massfraction are respectively: the 800-1200 order iron tourmaline powder of 12-21%, the 100-400 order iron tourmaline powder of 10-16%, the 100-150nm tourmaline powder of 2-4%, the diatomite of 22-28%, the polynite of 15-20%, the attapulgite clay of 22-28%, the cerous nitrate of 0.1-0.2%, and the lanthanum nitrate of 0.1-0.2%;
2) by cerous nitrate and lanthanum nitrate mixing, and dissolve into spray-water, make mixing spray liquid;
3) by iron tourmaline powder, tourmaline powder, diatomite, polynite and attapulgite clay mixing, regulate the spray humidity of described mixing spray liquid, the powder of mixing is made spheroid under the effect of described mixing spray liquid;
4) sintering processes is carried out to described spheroid, after cooling, obtain final material.
2. the method for claim 1, is characterized in that: step 3) the spray humidity of described mixing spray liquid is 10-20%.
3. the method for claim 1, is characterized in that: step 3) granularity of described spheroid is 3-5mm.
4. the method for claim 1, is characterized in that: step 3) adopt disk machine to prepare described spheroid, its rotating speed is 130-230 rev/min.
5. method as claimed in claim 4, is characterized in that: in described disk machine, add appropriate ball core shaping to accelerate spheroid.
6. the method for claim 1, is characterized in that, step 4) carry out described sintering time adopt temperature rise rate be 2-4 DEG C/min, sintering temperature is 700-1000 DEG C, and the time is 2-4 hour.
7. method as claimed in claim 6, is characterized in that, step 4) adopt retort furnace to carry out described sintering.
8. the method for claim 1, is characterized in that, step 1) described iron tourmaline powder is Xinjiang iron tourmaline powder.
9. the matrix material being applied to water molecule cluster cleavage reaction that according to any one of claim 1 to 8 prepared by method.
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| CN104525051A (en) * | 2014-12-25 | 2015-04-22 | 中国科学院深圳先进技术研究院 | Water molecular cluster hydrogen bond activation reactor and method for activating water molecular cluster hydrogen bonds |
| CN108002512A (en) * | 2018-01-04 | 2018-05-08 | 清华大学 | A kind of ammonia removal device and method using cladded type piezoelectric CPM as main stuffing |
| CN108203166A (en) * | 2016-12-19 | 2018-06-26 | 深圳市国沅生态环保科技有限公司 | A kind of suspending type water correction device |
| CN109928478A (en) * | 2019-03-19 | 2019-06-25 | 固安天天一泉环保科技有限公司 | A kind of water purification PH adjusts filtrate and preparation method thereof |
| CN117658612A (en) * | 2023-12-05 | 2024-03-08 | 宜兴市海王陶瓷研究所 | Super-induction functional material and preparation method and application thereof |
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| JPH09225456A (en) * | 1996-02-21 | 1997-09-02 | Kakouzuru Kk | Refining material for water-tank water and refining method |
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| CN104525051A (en) * | 2014-12-25 | 2015-04-22 | 中国科学院深圳先进技术研究院 | Water molecular cluster hydrogen bond activation reactor and method for activating water molecular cluster hydrogen bonds |
| CN108203166A (en) * | 2016-12-19 | 2018-06-26 | 深圳市国沅生态环保科技有限公司 | A kind of suspending type water correction device |
| CN108002512A (en) * | 2018-01-04 | 2018-05-08 | 清华大学 | A kind of ammonia removal device and method using cladded type piezoelectric CPM as main stuffing |
| CN109928478A (en) * | 2019-03-19 | 2019-06-25 | 固安天天一泉环保科技有限公司 | A kind of water purification PH adjusts filtrate and preparation method thereof |
| CN117658612A (en) * | 2023-12-05 | 2024-03-08 | 宜兴市海王陶瓷研究所 | Super-induction functional material and preparation method and application thereof |
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