CN1513798A - Curing agent for providing soil and building garbage - Google Patents

Curing agent for providing soil and building garbage Download PDF

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Publication number
CN1513798A
CN1513798A CNA031311474A CN03131147A CN1513798A CN 1513798 A CN1513798 A CN 1513798A CN A031311474 A CNA031311474 A CN A031311474A CN 03131147 A CN03131147 A CN 03131147A CN 1513798 A CN1513798 A CN 1513798A
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CN
China
Prior art keywords
plain
solidifying agent
excite
agent
lime
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA031311474A
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Chinese (zh)
Inventor
米忠路
蒋建华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Guoye Aotesaite Curing Agent Research & Development Centre
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Beijing Guoye Aotesaite Curing Agent Research & Development Centre
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Filing date
Publication date
Application filed by Beijing Guoye Aotesaite Curing Agent Research & Development Centre filed Critical Beijing Guoye Aotesaite Curing Agent Research & Development Centre
Priority to CNA031311474A priority Critical patent/CN1513798A/en
Publication of CN1513798A publication Critical patent/CN1513798A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A solidifying agent used for soil and building garbage to make the brick by die presisng and natural curing or for treating the bed of road or railway is disclosed. Its advantages are high effect and low cost.

Description

The solidifying agent of a kind of soil and building waste is provided
Technical field the present invention relates to that a kind of soil and building waste solidified material of being used for---special Saite solidifying agent difficult to understand the invention belongs to building material field.
The handled soil of background technology the present invention is mainly used in the more unmanageable or engineering that has higher requirements such as water conservancy imperviousing preventing flushing brush, flabbiness ground strengthened processing, road and rail subgrade strengthening.The handled building waste of the present invention is meant because the city layout adjustment, urban planning construction, development of real estate, dilapidated house are pulled down and removed a building for reconstruction in the process, waste and old concrete, grit, brick and tile, lime and a spot of pottery that forms, glass, soil etc. do not comprise metal, timber, pitch and organic domestic waste etc.
Along with the rapid growth of economic construction, environment protection and Sustainable development further worsen, and environmental requirement improves day by day.This protrusion phenomenon in building materials field, the one, a large amount of stackings of urban architecture rubbish form the new pollution in city; The 2nd, solid clay brick destroys and ploughs, the mass consumption energy.Though the new wall materials layer goes out not group on the market, as structural clay tile, haydite holllow building block, concrete hollow block, autoclave aerated concrete building block and all kinds of wallboards etc., but aspect bearing wall material, still there is not suitable material to substitute solid clay brick.Mentougou District, Beijing utilizes shale and coal gangue to produce the sintering solid clay brick at present, but still obviously has the defective of environmental protection aspect.
" naturally-cured powdered coal ash brick " patent of invention of patent " 89102223.6 " discloses a kind of flyash that utilizes and has made non-burning brick technological method, it uses flyash and sand, silicate cement and alkaline earth metal halide, through stirring, extrusion forming, hardening treatment become flyash brick.Hydraulic cinder brick, the piece of patent " CN1117030A " have then utilized solid waste, replace Tu Yuan as lime-ash, slag, slag etc., manufacture experimently out to contain cindery hydraulicity solidifying agent.
Above patent differs from one another, but still comes with some shortcomings when solidify material, and as 1, when solidifying silt or containing the thinner powder of particle, intensity there is no obvious raising.2, lime-ash or flyash brick all need to add a large amount of sands, have obviously increased cost.3, the main purpose of patent is how to digest lime-ash and flyash, is applied in the problem that the materials for wall aspect also exists intensity and weather resistance.4, the storage of lime-ash or flyash is not enough to provide the quantity-produced amount, and utilization ratio is not high.
Patent 1125702 provides a kind of lime firming agent for soil, utilizes unslaked lime, anhydrite, sodium sulfate and Tai-Ace S 150 combined grinding to specific surface area 300~500m 2/ kg.Patent 1131131 provides a kind of cement-like soil firming agent, utilizes Portland clinker, anhydrite, glycerol combined grinding to specific surface area 300~500m 2/ kg.Patent 1107500 provides a kind of soil modifier of stable soil making roadbed, has utilized alkyl benzene sulphonate (ABS), polysiloxane phosphoric acid, polyacrylic acid, lipid acid, polyvinyl alcohol to make emulsion.More than three kinds of patents characteristics are respectively arranged, but still have some shortcomings during curing soil, three kinds of solidifying agent all can't be handled the loam inferior in the engineerings such as the mud, collapsible loess, saline soil of high liquid plastic limit high organic.
Summary of the invention the purpose of this invention is to provide a kind of can solidification treatment building waste pellet extrusion forming standard solid brick, and maintenance reaches national building material industry standard " non-sintered common clay brick " every index request (JC422-91) under normal temperature condition.Its purposes can be as various building blocks of functions such as load-bearing and non-bearing wall body material, pavement brick, slope protecting components.
Another object of the present invention is the solidifying agent that provided can also be handled the various complexity that run in highway, railway, water conservancy, soft foundation treatment project a soil.The solidifying agent Stabilized Soil is as road basement material, and its performance can satisfy the rules requirement of national building material industry standard CJJ/J80-98.
High-performance special Saite solidifying agent difficult to understand is a kind of powdery solid, add the special inorganic materials that excites element to obtain and be main cement based organic polymer composite, this well behaved solidify material for general low in liquid limit clay, river sand, saprolite and contain organic higher mud etc. very significant stable curing effect is all arranged.Can be used for road and rail roadbed, water conservancy channel, lakebed and solidify in antiseepage antiscour, the soft foundation treatment project, compare, have that intensity height, barrier performance are good, antiscour, pollution are little, short construction period, the low characteristics of comprehensive cost with traditional technology.High-performance special Saite solidifying agent difficult to understand is as soil-stabilising material, can handle the engineering special soil that stable material such as cement and lime can't be handled, and as mud, powder fine earth etc., its intensity is compared with the cement of volume and wanted high by 50%~200%.
The exploitation that utilizes building waste to prepare unburned solid standard square curing technology, have save coal-fired, save mineral wealth, improve environment, advantage such as reduce cost.Its principle is summarized as follows:
The cement of coming of new, brick and tile are used on buildings or the structures, and after the use several years, owing to multiple reason, buildings or structures must be scrapped, remove, so become building waste.As building waste itself, by classification analysis, can be clear that there is difference in they on chemical ingredients and mineralogical composition, different chemically reactives is arranged, if it is simply passed through fragmentation, grinding mixes again as aggregate, economically may not be worthwhile.Chemical analysis and X-ray diffraction analysis show, in the waste and old concrete of 20 years usage periods, still have unhydrated C 2S reaches the not Ca of carbonization (OH) 2, and the aggregate material that can use according to the analysis correct decision waste and old concrete of mineralogical composition: useless common brick and blue bricks mineralogical composition behind life-time service are quite similar, the SiO that reacts during sintering 2The a large amount of existence, and a large amount of not carbonizations, the oxide compound of aquation are arranged behind the sintering, these oxide compounds can continue to bring into play cementation through after the special excitation.And building waste after levigate owing to following reason also has certain glued active: (1) is newly broken, levigate waste residue surface has higher surface energy; (2) contain a certain amount of not aquation composition in new broken, the levigate waste residue: (3) are newly broken, some have the material of lateral reactivity in the levigate waste residue, under the effect of exciting agent, show certain hydration reaction activity.Therefore essential earlier with its activation before utilizing this part material again.
The building waste pellet need be through broken, screening, and the particle diameter and the ratio of the broken back of control building waste pellet.Building waste pellet grating of the present invention is: 20~2mm accounts for 40%~60%, accounts for 60%~40% below the 2mm.
Solidifying agent of the present invention divides main solidifying agent and excites plain two parts.
Whole raw materials of solidifying agent are: Portland clinker, lime, anhydrite, Ammonium Persulfate 98.5, Na 2SO 4, NaNO 2, CaCl 2, trolamine, water-soluble melamino-formaldehyde resin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium polyacrylate, aqueous epoxy resins, titanate coupling agent, silicate coupling agent, tween 80, ethylene glycol monobutyl ether, quadrol, ethanol and industrial residue comprise slag, Water Quenching Slag, flyash and fireclay silica flour.
More than all raw materials on market, all can buy, Portland clinker, lime and anhydrite meet the cement industry standard, industrial residue all meets corresponding country and industry standard.
The solidifying agent weight percent is as follows:
Portland clinker 10%~50%
Industrial residue 10%~70%
Lime 8%~20%
Anhydrite 8%~20%
Excite plain A 0.4%~3%
Excite plain B 0.1%~2%
Excite plain A weight percent as follows:
Na 2SO 4 20%~40%
NaNO 2 5%~10%
CaCl 2 1%~5%
Ca(NO 2) 2 5%~10%
Ammonium Persulfate 98.5 5%~10%
Trolamine 5%~20%
Quadrol 2%~7%
Water-soluble melamino-formaldehyde resin sulfonate 10%~30%
Naphthalenesulfonate formaldehyde condensation compound 10%~30%
Excite plain B weight percent as follows:
Sodium polyacrylate 5%~10%
Aqueous epoxy resins 30%~60%
Titanate coupling agent 2%~5%
Tween 80 0.1%~3%
Ethanol 30%~50%
Ethylene glycol monobutyl ether 0.1%~1%
Solidifying agent requires fineness: its specific surface area is not less than 380~500m 2/ kg.
Should and excite that plain A is levigate respectively to be mixed in proportion then to requiring fineness with solidifying agent, or it is levigate to requiring fineness to be mixed in proportion the back, packing becomes solidifying agent AS.This solidifying agent can be directly used in the curing of building waste.To excite plain B to be configured to emulsion by material rate, sealing is preserved.During use, measure in proportion with water and admix in the solidified earth mixed material of solidifying agent AS adding.
Embodiment 1
Take by weighing Portland clinker 360g, grain slag 320, lime 80g, anhydrite 170g.
Take by weighing 9gNa 2SO 4, 1gCaCl 2, 2g Ammonium Persulfate 98.5,5g trolamine, 3 quadrols, the water-soluble melamino-formaldehyde resin sulfonate of 10g.
It is mixed to be excite plain A.
With above two groups respectively or combined grinding to 400m 2/ kg becomes solidifying agent AS.
Take by weighing the 10g sodium polyacrylate, 50g aqueous epoxy resins, 2g titanate coupling agent, 2g tween 80,35g ethanol, 1g ethylene glycol monobutyl ether.Excite plain B
Embodiment 2
Take by weighing Portland clinker 400g, grain slag 340, lime 100g, anhydrite 150g.
Take by weighing 10gNa 2SO 4, 2g NaNO 2, 2g Ammonium Persulfate 98.5,5g trolamine, 1g quadrol, the water-soluble melamino-formaldehyde resin sulfonate of 5g, 5g naphthalenesulfonate formaldehyde condensation compound.It is mixed to be excite plain A.
With above two groups respectively or combined grinding to 400m 2/ kg becomes solidifying agent AS.Take by weighing the 10g sodium polyacrylate, 43g aqueous epoxy resins, 4g titanate coupling agent, 2g tween 80,40g ethanol, 1g ethylene glycol monobutyl ether.
Embodiment 3
Take by weighing building waste coarse aggregate (20~2mm) 1200g, fine aggregate (2mm is following) 1800g, solidifying agent (AS) 300g, abundant mix, extrusion forming is made into 240 * 115 * 53mm standard square, the test of materials for wall testing standard is pressed in natural curing, and its 28 days intensity can reach 8~11Mpa.
Embodiment 4
Take by weighing building waste coarse aggregate (20~2mm) 1800g, fine aggregate (2mm is following) 1200g, solidifying agent (AS) 450g, abundant mix, extrusion forming is made into 240 * 115 * 53mm standard square, the test of materials for wall testing standard is pressed in natural curing, and its 28 days intensity can reach 12~16Mpa.
Embodiment 5
Carry out compaction test, definite maximum dry density and optimum moisture content to desiring the solidified soil property earlier.Take by weighing clay 3000g, sieve removes the above extraordinarily thick particle of 10mm, mixes solidifying agent (AS) 240g, and mix is even; Measure water by optimum moisture content+2%, take by weighing 2.4g and excite plain B to add in the load weighted water, mix is even in the back adding solidified earth that stirs.Calculate suitable weighing by maximum dry density, make the test specimen of Φ 50 * 50mm, normal curing, its 28 days intensity can reach 1~5Mpa.

Claims (7)

1, a kind of cement based organic polymer composite curing agent that is used for curing soil and building waste is characterized in that: by Portland clinker, lime, anhydrite, industrial residue, excite plain A or excite plain B to form.
2, solidifying agent as claimed in claim 1 excites plain A, it is characterized in that: by Ammonium Persulfate 98.5, Na 2SO 4, NaNO 2, CaCl 2, 1~4 kind of composition in trolamine, water-soluble melamino-formaldehyde resin sulfonate, naphthalenesulfonate formaldehyde condensation compound and the quadrol.
3, solidifying agent as claimed in claim 1 excites plain B, it is characterized in that: be made up of sodium polyacrylate, aqueous epoxy resins, titanate coupling agent, silicate coupling agent, tween 80, ethylene glycol monobutyl ether, ethanol.
4, its industrial residue of solidifying agent as claimed in claim 1 is meant in slag, Water Quenching Slag, flyash and the fireclay silica flour one or more.
5, as the described solidifying agent of claim 1-4, it is characterized in that: its weight percent is:
Portland clinker 10%~50%
Industrial residue 10%~70%
Lime 8%~20%
Anhydrite 8%~20%
Excite plain A 0.4%~3%
Excite plain B 0.1%~2%
6, excite plain A as the described solidifying agent of claim 1-4, it is characterized in that: its weight percent is:
Na 2SO 4 20%~40%
NaNO 2 5%~10%
CaCl 2 1%~5%
Ca(NO 2) 2 5%~10%
Ammonium Persulfate 98.5 5%~10%
Trolamine 5%~20%
Quadrol 2%~7%
Water-soluble melamino-formaldehyde resin sulfonate 10%~30%
Naphthalenesulfonate formaldehyde condensation compound 10%~30%
7, excite plain B as the described solidifying agent of claim 1-4, it is characterized in that: its weight percent is:
Sodium polyacrylate 5%~10%
Aqueous epoxy resins 30%~60%
Titanate coupling agent 2%~5%
Tween 80 0.1%~3%
Ethanol 30%~50%
Ethylene glycol monobutyl ether 0.1%~1%
CNA031311474A 2003-05-14 2003-05-14 Curing agent for providing soil and building garbage Pending CN1513798A (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100408500C (en) * 2007-04-25 2008-08-06 刘文伟 Clay solidification intensifier for express highway pavement foundation and uses thereof
CN101215141B (en) * 2008-01-02 2010-06-16 邓亚光 Soft soil curing agent
CN103485328A (en) * 2013-09-23 2014-01-01 河海大学 Method for performing ecological reinforcement on soil slope surface by utilizing composite curing agent
CN103833298A (en) * 2014-01-17 2014-06-04 淄博环亿资源综合利用有限公司 Slope protection material and preparation method thereof
CN103833311A (en) * 2014-01-18 2014-06-04 中建四局第六建筑工程有限公司 Novel soil curing agent using desulfurized gypsum
CN103911160A (en) * 2014-04-22 2014-07-09 江苏工大伟业新材料有限公司 High-titanium slag soft soil stabilizer
CN103951364A (en) * 2014-04-02 2014-07-30 郝志峰 Rock soil curing agent and preparation method thereof
CN105154098A (en) * 2015-08-28 2015-12-16 黄梁艳 Soil stabilizer
CN105367010A (en) * 2015-10-30 2016-03-02 郑卫忠 Hardening agent for road and roadbed hardening method
CN105442409A (en) * 2015-12-31 2016-03-30 中城建第五工程局集团有限公司 Waterborne epoxy stabilized soil, application thereof and stabilized soil road surface
CN105670641A (en) * 2016-02-11 2016-06-15 孙华平 Soil curing agent for water conservancy dam and preparation method of soil curing agent
CN106929029A (en) * 2017-03-08 2017-07-07 原生泰科技发展(北京)有限公司 A kind of new loam wall special-purpose soil curing agent and preparation method thereof
CN107021716A (en) * 2017-05-12 2017-08-08 上海理工大学 A kind of macromolecular mud curing agent and preparation method thereof
CN107352821A (en) * 2017-08-02 2017-11-17 李军宏 A kind of method that building waste recycles
CN107793108A (en) * 2017-10-24 2018-03-13 四川昊龙高科轨道交通新材料科技股份有限公司 A kind of builder's road soil consolidation material
CN109626892A (en) * 2019-01-28 2019-04-16 武汉市市政建设集团有限公司 A kind of pellet class curing agent and the high-strength low-shrinkage anti-crack road surface base material using its preparation
CN111978963A (en) * 2020-08-26 2020-11-24 安徽茵际源新材料科技有限公司 Soil solidifying composition, preparation method and application thereof
CN117602871A (en) * 2024-01-22 2024-02-27 中建八局西南建设工程有限公司 Novel fast-curing residue-soil-based regenerated composite material and preparation method thereof

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100408500C (en) * 2007-04-25 2008-08-06 刘文伟 Clay solidification intensifier for express highway pavement foundation and uses thereof
CN101215141B (en) * 2008-01-02 2010-06-16 邓亚光 Soft soil curing agent
CN103485328B (en) * 2013-09-23 2015-04-08 河海大学 Method for performing ecological reinforcement on soil slope surface by utilizing composite curing agent
CN103485328A (en) * 2013-09-23 2014-01-01 河海大学 Method for performing ecological reinforcement on soil slope surface by utilizing composite curing agent
CN103833298A (en) * 2014-01-17 2014-06-04 淄博环亿资源综合利用有限公司 Slope protection material and preparation method thereof
CN103833298B (en) * 2014-01-17 2016-04-06 淄博环亿资源综合利用有限公司 Slop protection material and preparation method thereof
CN103833311A (en) * 2014-01-18 2014-06-04 中建四局第六建筑工程有限公司 Novel soil curing agent using desulfurized gypsum
CN103951364A (en) * 2014-04-02 2014-07-30 郝志峰 Rock soil curing agent and preparation method thereof
CN103911160B (en) * 2014-04-22 2017-02-15 江苏工大伟业新材料有限公司 High-titanium slag soft soil stabilizer
CN103911160A (en) * 2014-04-22 2014-07-09 江苏工大伟业新材料有限公司 High-titanium slag soft soil stabilizer
CN105154098A (en) * 2015-08-28 2015-12-16 黄梁艳 Soil stabilizer
CN105367010A (en) * 2015-10-30 2016-03-02 郑卫忠 Hardening agent for road and roadbed hardening method
CN105442409A (en) * 2015-12-31 2016-03-30 中城建第五工程局集团有限公司 Waterborne epoxy stabilized soil, application thereof and stabilized soil road surface
CN105670641A (en) * 2016-02-11 2016-06-15 孙华平 Soil curing agent for water conservancy dam and preparation method of soil curing agent
CN106929029A (en) * 2017-03-08 2017-07-07 原生泰科技发展(北京)有限公司 A kind of new loam wall special-purpose soil curing agent and preparation method thereof
CN106929029B (en) * 2017-03-08 2019-11-08 原生泰科技发展(北京)有限公司 A kind of novel loam wall special-purpose soil curing agent and preparation method thereof
CN107021716A (en) * 2017-05-12 2017-08-08 上海理工大学 A kind of macromolecular mud curing agent and preparation method thereof
CN107352821A (en) * 2017-08-02 2017-11-17 李军宏 A kind of method that building waste recycles
CN107793108A (en) * 2017-10-24 2018-03-13 四川昊龙高科轨道交通新材料科技股份有限公司 A kind of builder's road soil consolidation material
CN109626892A (en) * 2019-01-28 2019-04-16 武汉市市政建设集团有限公司 A kind of pellet class curing agent and the high-strength low-shrinkage anti-crack road surface base material using its preparation
CN109626892B (en) * 2019-01-28 2021-08-03 武汉市市政建设集团有限公司 Granular curing agent and high-strength low-shrinkage crack-resistant pavement base material prepared from same
CN111978963A (en) * 2020-08-26 2020-11-24 安徽茵际源新材料科技有限公司 Soil solidifying composition, preparation method and application thereof
CN117602871A (en) * 2024-01-22 2024-02-27 中建八局西南建设工程有限公司 Novel fast-curing residue-soil-based regenerated composite material and preparation method thereof
CN117602871B (en) * 2024-01-22 2024-04-09 中建八局西南建设工程有限公司 Novel fast-curing residue-soil-based regenerated composite material and preparation method thereof

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