CN1511808A - Composite material thermal insulation plate - Google Patents

Composite material thermal insulation plate Download PDF

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Publication number
CN1511808A
CN1511808A CNA021591512A CN02159151A CN1511808A CN 1511808 A CN1511808 A CN 1511808A CN A021591512 A CNA021591512 A CN A021591512A CN 02159151 A CN02159151 A CN 02159151A CN 1511808 A CN1511808 A CN 1511808A
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Prior art keywords
warming plate
matrix material
flyash
sepiolite
foam powder
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CNA021591512A
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Chinese (zh)
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CN1278997C (en
Inventor
杨飞华
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BEIJING ACADEMY OF ARCHITECTURAL MATERIAL SCIENCES
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BEIJING ACADEMY OF ARCHITECTURAL MATERIAL SCIENCES
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Publication of CN1511808A publication Critical patent/CN1511808A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Building Environments (AREA)

Abstract

The thermal insulating plate of composite material is produced with waste foamed phenolic plastic powder as basic heat insulating material, flyash as stuffing, expanded perlite as aggregate, mineral wool, glass wool, sepiolite and palygorskite as reinforcing material, neutral water glass or silica sol as inorganic adhesive and guar gum, methylcellulose or CMC as organic adhesive, and through high speed dispersion, stirring, mixing, molding, forming and drying. The thermal insulating plate has low heat conducting coefficient, is non-inflammable, smell-less, non-toxic, long in service life and wide in application range. The production process adopts industrial waste as main components and produces no waste, and used plate may be reused, so that the present invention is significant in environment protection.

Description

The matrix material warming plate
Affiliated technical field
The present invention relates to the technical field of buildings, boiler tubing usefulness heat-insulation and heat-preservation material, specifically, relate to a kind of technical field of utilizing trade waste to produce the matrix material warming plate.
Background technology
Lagging material mean do not readily conduct heat, to material or composite body that hot-fluid has remarkable resistance, be a kind of functional materials that is used to reduce structure and environment heat exchange.The heat-insulating property quality of material is that the size by the thermal conductivity of material decides.Thermal conductivity is littler, and insulation, heat-proof quality are better.The characteristics of lagging material are lightweight, loose, porous, and some is fibrous, insulation, good heat-insulation effect.Usually the heat preserving and insulating material of indication is meant density<350kg/m 3, thermal conductivity<0.12W/ (m.K) material.Heat preserving and insulating material is porous material normally, and structural basic characteristics are to have high voidage.Pore size in the material is generally in the 3-5mm scope.Pore can be divided into sealed porosity and be communicated with two types at pore, generally has the heat-proof quality of a large amount of sealed porosity materials than having the much better of a large amount of connection pores.The structure of heat preserving and insulating material can be divided into filamentary structure vesicular structure, granular texture or laminate structure basically.Have hole in the material of vesicular structure and be generally and be similar to the spheric closed pores, and the hole of the material internal of filamentary structure, granular texture and laminate structure normally is interconnected.
At present, though the insulation form of building energy conservation heat insulation has only three kinds of roof heat insulation, external wall outer insulation and exterior wall internal insulations, the kind of building energy-saving heat-insulating material is more.The common buildings heat insulating energy saving material mainly generally is divided into four big class, i.e. inanimate matter lagging material, organic lagging material, organic-inorganic composite lagging material and metal species lagging materials by material.Physical aspect by energy-saving and heat-insulating material can be divided into fibrous heat insulator, the granular lagging material of micropore, air bubble-shaped lagging material and stratiform lagging material.Can be divided into normal temperature lagging material (use temperature is lower than 100 ℃), middle temperature lagging material (use temperature is 100-800 ℃), soak material (use temperature is more than 800 ℃) by use temperature.Divide by energy-saving heat preserving mechanism, energy-saving and heat-insulating material is divided into porous light type lagging material and high photothermal reflectance type lagging material again.Be divided into from structure: homogeneous single structure energy-saving and heat-insulating material and compound complex structure lagging material.Divide from material shape, can be divided into again: three kinds of section bar class, dry mash class and slurry class lagging materials.From the generating mode of material, can be divided into: synthetic lagging material and natural lagging material.
Organic lagging material mainly comprises shaving board, cork, fiberboard, urethane foam, polystyrene foamed plastics, polymerization phenolic resin foam, urea-formaldehyde foamed plastics, rubber and plastic foam materials, polyvinyl chloride foam etc.Such material is widely used by force according to its unique low heat conductivity, lightweight, hydrophobic nature.Yet because the inflammableness of such material, particularly the burning smoke coefficient is big, and toxicity is big, environment is had significantly and directly be subjected to great restriction with potential serious contaminative on Application Areas and application level.
The inanimate matter energy-saving and heat-insulating material, such material comprises again: 1, loose fiber and goods thereof.As asbestos, slag wool, rock wool, glass fibre cotton and goods.2, loose powder shape lagging material is as pearlstone, expanded vermiculite and lightweight Calucium Silicate powder.3, mixed type: such material mainly is the compound silicate insulating paint that loose fiber and porous prilled mixing of materials are made.Compare with organic energy-saving and heat-insulating material, the inanimate matter energy-saving and heat-insulating material is prevented fires, flame retardant resistance is strong, mostly is incombustible substance, and nontoxicity, and safety coefficient height, its thermal conductivity are generally between 0.045-0.070w/ (m.k).
Organic-inorganic matter compound insulating material is meant that the minimum quantity of a certain phase in two phase materials is not less than the novel material of 25% compound homogeneous, as GRC plate, polyphenyl class composite silicate thermal insulation mortar etc.More in addition organic-inorganic phase structure combined type.The light steel and color plate roofing thermal-insulating board of the cement polystyrene board of sandwich style, haydite styrofoam, sandwich type for example.The organic-inorganic composite energy-saving and heat-insulating material has overcome the low strength of inanimate matter, organic inflammableness.
The lagging material of Shi Yonging has cement polystyrene board, perlite heat-insulating mortar, broken air-entrained concrete building block, composition silicate series insulating material, interior exterior wall polyphenyl plate heat preserving material etc. in the market, and product category is abundanter.Though outer heat preservation technology is advocated energetically and promoted in recent years, because the restriction of the operating technique level and the level of the productive forces, outer heat preservation technology difficulty of construction is big, cost is high, and its application still is in the exploratory stage; Inside thermal conservation material gypsum insulation plate, thermal insulation mortar still are leading product, and the production technique of manufacturer is very different, and market is relatively more chaotic, thereby have influenced the raising of overall application level.
Heat-insulation and heat-preservation material development in recent years is very fast, is that the thermal isolation technique of material is promoted the use of more with polystyrene, rock wool, glass wool, multicellular glass, microporous calcium silicate.Make lagging material with polystyrene, though its thermal and insulating performance is good, its highest Applicable temperature is 40 ℃, when temperature Gao Shihui makes contraction, decomposition, cracking; Multicellular glass, its cost of microporous calcium silicate lagging material are too high.In addition, cement and polystyrene warming plate bed thickness, surface layer are easy to cracking, and the polystyrene foamed plastics inflammableness is strong, and burning smoke has severe toxicity, is not preferably the covil construction interior finish material; The wet construction of energy-saving heat preserving cream, seasoning cycle are longer, influence job schedule.
Summary of the invention
The objective of the invention is to environmental protection, recovery and reuse of waste and high-efficiency insulated mutually combining, three waste prodss of useless phenolic foamed plastics, waste polyurethane foam plastics and flyash one class that will pollute environment are recycled, provide that a kind of cost is low, heat insulation and preservation effect good, do not fire, not hollowing, do not ftracture, absorb sound, the matrix material warming plate of protection against the tide, high, the no asbestos of intensity, reproducible utilization.
Matrix material warming plate raw material of the present invention is to be heat-insulation base material with the useless phenol formaldehyde foam powder (or waste polyurethane foam powder) of industrial waste, flyash is filler, pearlstone is an aggregate, mineral wool, glass wool, sepiolite, polygorskite is a strongthener, neutral water glass or silicon sol are mineral binder bond, guar gum flour, methylcellulose gum or carboxymethyl cellulose are organic binder bond, by with polygorskite, mineral wool adds water carry out high speed dispersion after, adding sepiolite stirs, add neutral water glass or silicon sol and methylcellulose gum afterwards again, carboxymethyl cellulose or guar gum flour mix, and add useless phenol formaldehyde foam powder then, flyash and perlite remix, last injection molding, shaping and drying is made matrix material warming plate of the present invention.
Matrix material warming plate feed composition of the present invention is prepared by following proportioning (weight %):
Useless phenol formaldehyde foam powder (or waste polyurethane foam powder) 10-30%;
Flyash 2-8%;
Perlite 5-30%;
Sepiolite 5-15%;
Polygorskite 5-10%;
Mineral wool 2-10%;
Neutral water glass or silicon sol 2.0-5.0%;
Guar gum flour, methylcellulose gum or carboxymethyl cellulose 0.15-1.5%;
Water 35-50%.
The feed composition proportioning prepares (see figure 1) by the technological process of production after determining.
1-adds water with polygorskite, mineral wool; The 2-high speed dispersion; 3-adds sepiolite; 4--stirs; 5-adds neutral water glass or silicon sol; 6-methylate Mierocrystalline cellulose, carboxymethyl cellulose or guar gum flour; 7-mixes; 8-adds useless phenol formaldehyde foam powder or waste polyurethane foam powder; 9-adds perlite, flyash; The 10-secondary mixes; 11-moulding, drying; 12-detects; 13 packings.
Example 1:
Matrix material warming plate feed composition is prepared by following proportioning (weight %):
Useless phenol formaldehyde foam powder-15%; Flyash-7%; Perlite-15%; Sepiolite-10%; Polygorskite-5%; Mineral wool-10%; Water glass-2.75%; Methylcellulose gum-0.25%; Water-35%.
Example 2:
Waste polyurethane foam powder-20%; Flyash-5%; Perlite-15%; Sepiolite-5%; Polygorskite-5%; Mineral wool-8%; Silicon sol-1.5%; Carboxymethyl cellulose-0.5%; Water-40%.
The performance index of the matrix material warming plate of preparation of raw material of the present invention are as follows:
Thermal conductivity:<0.062W/ (m.k); Use temperature :-100 ℃-500 ℃; Density is little:<250kg/m 3Ultimate compression strength: 〉=0.20Mpa; Cohesive strength: 〉=0.05Mpa; Tensile strength: 〉=0.10Mpa; Asbestos content: 0; Hydrophobic rate: 〉=80%.
The matrix material warming plate is on the basis of heat insulating paste product; in conjunction with current environment protection, Mineral resources are rationally utilized and the prerequisite of recovery and reuse of waste policy under; a kind ofly have lightweight, porous, a high-strength heat preservation plate material through what repetition test research was made; this product is compared with heat insulating paste; it is low to have thermal conductivity, and unit weight is light, the ultimate compression strength height; water-tolerant, the characteristics of short construction period.Material has advantages such as intensity height, strong, the bonding easy construction of formability, saw property be good simultaneously.Its Main Feature is done as follows:
(1) thermal conductivity is lower, and unit weight is light.
(2) raw materials for production are nontoxic, tasteless, free of contamination material, and production technique is simple, and cost of investment is low.
(3) this product can be recycled, and can not produce any pollution to surrounding environment in production, the construction process.
(4) the intensity height, do not ftracture, not hollowing, no dust pollution.This product has sound-absorbing, heat insulation, damping, from the strong characteristic of respiratory function.
Description of drawings
Fig. 1 is the matrix material warming plate technological process of production
Among the figure: 1-adds water with polygorskite, mineral wool; The 2-high speed dispersion; 3-adds sepiolite; 4--stirs; 5-adds neutral water glass or silicon sol; 6-methylate Mierocrystalline cellulose, carboxymethyl cellulose or guar gum flour; 7-mixes; 8-adds useless phenol formaldehyde foam powder or waste polyurethane foam powder; 9-adds perlite, flyash; The 10-secondary mixes; 11-moulding, drying; 12-detects; 13 packings.
Embodiment
Matrix material warming plate raw material of the present invention is for useless phenol formaldehyde foam powder, flyash, pearlstone, mineral wool, glass wool, sepiolite, polygorskite, as the neutral water glass of mineral binder bond, form as the methylcellulose gum and the water of organic binder bond, and feed composition is by following proportioning (weight %) preparation:
Useless phenol formaldehyde foam powder-15%; Flyash-7%; Perlite-15%; Sepiolite-10%; Polygorskite-5%; Mineral wool-10%; Water glass-2.75%; Methylcellulose gum-0.25%; Water-35%.
By after polygorskite, mineral wool added water carrying out high speed dispersion, adding sepiolite stirs, add neutral water glass and methylcellulose gum afterwards again and mix, the useless phenol formaldehyde foam powder of adding, flyash and perlite remix, last injection molding, shaping and drying are made matrix material warming plate of the present invention then.

Claims (3)

1, a kind of matrix material warming plate, it is characterized in that: matrix material warming plate raw material is to be heat-insulation base material with the useless phenol formaldehyde foam powder (or waste polyurethane foam powder) of industrial waste, flyash is filler, pearlstone is an aggregate, mineral wool, glass wool, sepiolite, polygorskite is a strongthener, neutral water glass or silicon sol are mineral binder bond, methylcellulose gum or carboxymethyl cellulose or guar gum flour are organic binder bond, by with polygorskite, mineral wool adds water carry out high speed dispersion after, adding sepiolite stirs, add neutral water glass and methylcellulose gum afterwards again and mix, add useless phenol formaldehyde foam powder then, flyash and perlite remix, last injection molding, shaping and drying is made matrix material warming plate of the present invention.
Matrix material warming plate feed composition of the present invention is prepared by following proportioning (weight %):
Useless phenol formaldehyde foam powder (or waste polyurethane foam powder) 10-30%;
Flyash 2-8%;
Perlite 5-30%;
Sepiolite 5-15%;
Polygorskite 5-10%;
Mineral wool 2-10%;
Neutral water glass or silicon sol 2.0-5.0%;
Guar gum flour, methylcellulose gum or carboxymethyl cellulose 0.15-1.5%;
Water 35-50%.
2, by the described matrix material warming plate of claim 1, it is characterized in that: matrix material warming plate feed composition is prepared by following proportioning (weight %):
Useless phenol formaldehyde foam powder-15%; Flyash-7%; Perlite-15%; Sepiolite-10%; Polygorskite-5%; Mineral wool-10%; Water glass-2.75%; Methylcellulose gum-0.25%; Water-35%.
3, by the described matrix material warming plate of claim 1, it is characterized in that: matrix material warming plate feed composition is prepared by following proportioning (weight %):
Waste polyurethane foam powder-20%; Flyash-5%; Perlite-15%; Sepiolite-5%; Polygorskite-5%; Mineral wool-8%; Silicon sol-1.5%; Carboxymethyl cellulose-0.5%; Water-40%.
CNB021591512A 2002-12-30 2002-12-30 Composite material thermal insulation plate Expired - Fee Related CN1278997C (en)

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Application Number Priority Date Filing Date Title
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CN1278997C CN1278997C (en) 2006-10-11

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Publication number Priority date Publication date Assignee Title
CN100370089C (en) * 2006-01-12 2008-02-20 黄菁华 Hard polyurethane foam board composite energy-saving wall and its construction process
CN100424029C (en) * 2007-01-29 2008-10-08 袁长兵 Attapulgite insulated brick for sun-light green-house
CN100504005C (en) * 2006-11-17 2009-06-24 陈天云 Decorative glass steel sandwiched heat insulation board
CN101793340A (en) * 2010-04-06 2010-08-04 重庆再升科技发展有限公司 Vacuum insulated panel core material and manufacturing method thereof
WO2011066789A1 (en) * 2009-12-01 2011-06-09 福建赛特新材股份有限公司 Core material, its manufacturing method and vacuum insulation panel used the core material
CN102173715A (en) * 2011-02-17 2011-09-07 信阳天意节能技术有限公司 Building interlayer insulation inorganic fireproofing heat insulation board and preparation method thereof
CN102180639A (en) * 2011-02-24 2011-09-14 卢清友 Environment-friendly light heat-insulating material and manufacturing method thereof
CN102503526A (en) * 2011-10-24 2012-06-20 沈阳建筑大学 Foam concrete with large-dosage polystyrene particles and preparation method thereof
CN102503288A (en) * 2011-11-23 2012-06-20 北京工业大学 Preparation method of A1-grade thermal isolation and heat insulation plate for building
CN102503348A (en) * 2011-11-10 2012-06-20 李春普 Method for manufacturing compound heat-preserving board
CN102503252A (en) * 2011-10-13 2012-06-20 林文晖 Light building exterior wall fireproof and heat insulating material prepared by slag rock wool
CN102515648A (en) * 2011-12-26 2012-06-27 李金峰 Perlite exterior wall insulation board and processing method thereof
CN102619290A (en) * 2012-04-17 2012-08-01 卞修清 Fireproof vertical filament inorganic silicon fiber insulation board
CN102748560A (en) * 2012-07-09 2012-10-24 关志强 Method for production of vacuum insulation plate via reutilization of rigid polyurethane foam
CN102850032A (en) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 Seepage-proof thermal insulation wall material containing fibrous material
CN103012738A (en) * 2013-01-11 2013-04-03 陕西煤业化工技术研究院有限责任公司 Modified fly ash reinforced hard polyurethane foam material and preparation method thereof
CN103159432A (en) * 2013-03-19 2013-06-19 郭漫笳 Mineral wool board with tea powder and tea polyphenol and method for preparing same
CN103265262A (en) * 2013-04-19 2013-08-28 安徽相变保温材料有限公司 Inorganic composite insulation board and preparation method thereof
CN104295857A (en) * 2013-07-15 2015-01-21 宁波康拜恩电器有限公司 Thermal insulating layer of refrigerator or freezer
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CN105017755A (en) * 2014-04-23 2015-11-04 徐义祥 Waterproof heat insulation material and preparation method thereof
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CN107514115A (en) * 2017-08-22 2017-12-26 智慧超洋建设工程股份有限公司 A kind of fireproof heat insulating exterior wall composite decorating board

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CN100504005C (en) * 2006-11-17 2009-06-24 陈天云 Decorative glass steel sandwiched heat insulation board
CN100424029C (en) * 2007-01-29 2008-10-08 袁长兵 Attapulgite insulated brick for sun-light green-house
WO2011066789A1 (en) * 2009-12-01 2011-06-09 福建赛特新材股份有限公司 Core material, its manufacturing method and vacuum insulation panel used the core material
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CN102503288A (en) * 2011-11-23 2012-06-20 北京工业大学 Preparation method of A1-grade thermal isolation and heat insulation plate for building
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CN104295857A (en) * 2013-07-15 2015-01-21 宁波康拜恩电器有限公司 Thermal insulating layer of refrigerator or freezer
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US20150343666A1 (en) * 2014-05-30 2015-12-03 Guang Zhou Zong Bao Xian Wei Zhi Pin Co., Ltd. Fiber reinforcement aerated thermal insulation plate and preparation process thereof
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