CN102173715B - Building interlayer insulation inorganic fireproofing heat insulation board and preparation method thereof - Google Patents

Building interlayer insulation inorganic fireproofing heat insulation board and preparation method thereof Download PDF

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Publication number
CN102173715B
CN102173715B CN201110040143A CN201110040143A CN102173715B CN 102173715 B CN102173715 B CN 102173715B CN 201110040143 A CN201110040143 A CN 201110040143A CN 201110040143 A CN201110040143 A CN 201110040143A CN 102173715 B CN102173715 B CN 102173715B
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China
Prior art keywords
parts
heat insulation
water
fire
warming plate
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Expired - Fee Related
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CN201110040143A
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Chinese (zh)
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CN102173715A (en
Inventor
王艳锦
王建春
张春山
王博儒
王博征
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XINYANG TIANYI ENERGY SAVING TECHNOLOGY CO., LTD.
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XINYANG TIANYI ENERGY SAVING TECHNOLOGY Co Ltd
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Priority to CN201110040143A priority Critical patent/CN102173715B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Building Environments (AREA)

Abstract

The invention relates to a building interlayer insulation inorganic fireproofing heat insulation board. The building interlayer insulation inorganic fireproofing heat insulation board is prepared from expanded perlite particles, converter slag particles, rock wool, silica sol or quick-dissolving sodium silicate, and a waterproofing agent by the method. The heat insulation board can improve the fire prevention capacity of a heat insulation system of a high-rise building; with high fire resistance, the heat insulation board can effectively prevent fire from spreading during fire and has the functions of fire prevention and separation; moreover, the heat insulation board has the advantages of high heat insulation property, non-toxicity, innocuity, light volume weight and the like.

Description

Building zone segregation inorganic fire warming plate and preparation method thereof
Technical field
The invention belongs to the building thermal insulation material field, is a kind of building zone segregation inorganic fire warming plate and preparation method thereof.
Background technology
In recent years, along with the continuous prosperity and development of economy, economic construction is maked rapid progress, Highrise buildings is also rised sheer from level ground like rain the back spring bamboo in big or middle city and even small city.Because Highrise buildings is high, the number of plies is many, and functions of use is complicated, and personnel are intensive, in case presence of fire, fire spread is rapid, evacuating personnel and fire attack difficulty, certainly will lead to loss greatly, injures and deaths are big.Because Highrise buildings itself has the internal gas flow recycle system, building heat preservation is heat insulation essential, and at present, the lagging material overwhelming majority that China's Highrise buildings adopts all is the organic foaming insulation board of polymer, like EPS (molded polystyrene cystose), XPS etc.Their defective is to have a little Mars to burn at once, and rate of propagation is exceedingly fast.Since so dangerous, why also used so on a large scale such as organic insulation materials such as EPS, XPS? This is because of these lower cost for material, high insulating effect, and certain mechanical strength and snappiness are arranged, and water-intake rate is low, and easy construction is prone to cutting.According to the data that ANS technical institute (NIST) announces, EPS warming plate thermal conductivity is 0.041, and the XPS warming plate then is 0.03, and heat-insulating property is very good.But their shortcoming also clearly: inflammable and easy to be aging.In a single day these lagging materials burn, it is very fast to overdo, and produces a large amount of poisonous and harmful flue gases simultaneously, is a great potential safety hazard.According to statistics, only in Beijing, what the Highrise buildings lagging material more than 90% adopted all is this family macromolecule foaming insulation board.In recent years repeatedly fire causes by these inflammable lagging materials.Therefore, need study novel Highrise buildings zone segregation fire protection flame retarding lagging material,, avoid and reduce fire injures and deaths and property damage for the escape of fire of high-rise building offers an opportunity.
Summary of the invention
The purpose of this invention is to provide a kind of fire resistance property that can improve the Highrise buildings heat-insulation system, stop fire spread, play fire prevention partition, fire-retardant, and nontoxic, harmless building zone segregation inorganic fire warming plate.
Another object of the present invention provides a kind of preparation method who prepares building zone segregation inorganic fire warming plate.
Realize that the technical scheme that the object of the invention is taked is: this warming plate is that the preparation of raw material by following weight part forms: particle diameter is that 50~70 parts in 1~4mm expanded perlite granule material, particle diameter are 4~8 parts of the converter slag particulate material of 1 ~ 2mm, 7~12 parts of rock wools, silicon sol or 15~25 parts of powdery quick dissolved sodium silicates, 2~6 parts of the water-resisting agents that Fibre diameter is 0.1 ~ 0.5mm; What wherein, water-resisting agent adopted is inorganic aluminate water-proof agent or concrete waterproofer or waterproofing agent of organosilicon.
Warming plate of the present invention prepares by following step:
1) gets 15~25 parts of 7~12 parts of 50~70 parts in expanded perlite granule material that particle diameter is 1~4mm, 4~8 parts of converter slag particulate material that particle diameter is 1 ~ 2mm, rock wools that Fibre diameter is 0.1 ~ 0.5mm and silicon sol or powdery quick dissolved sodium silicates and 2~6 parts of water-resisting agents by weight ratio; Behind the uniform mixing; It is subsequent use to process compound; Wherein, the powdery quick dissolved sodium silicate must the weight ratio by 1:1 add the clear water dissolving before mixing;
2) get compound and add water, under normal temperature condition, mix, process the mixing wet feed by the weight ratio of Hun He Liao ︰ water=1 ︰ 1.5~3;
3) will mix wet feed and insert in the slab mould of pressing machine, be the wet base of warming plate through pressing machine compression moulding;
4) dry: the wet base of warming plate is inserted in the stoving oven dry, 100~150 ℃ of bake out temperatures, drying time 8~12 hours, take out the oven dry back, is the fireproof heat insulating board finished product.
The present invention selects for use above-mentioned raw materials to make up, and through the synergy of each raw material effect, makes the warming plate of making have higher intensity, toughness and good fire prevention, exhausted combustion, heat insulation, sound insulation, protection against the tide, performance such as anticorrosion.In the raw material of being prepared, the inside of pearlstone is polynuclear plane, have nontoxic, tasteless, do not fire, in light weight, effect such as thermal insulation and sound absorption qualities are good; Rock wool is to be main raw material with selected natural rock, blast-furnace slag; Add the auxiliary material of some amount; The regenerated fiber of processing through high-temperature fusion winding-up; Have do not fire, nontoxic, characteristics such as thermal conductivity is low, sound absorption qualities good, insulation, chemical stability is good, life cycle is long, be the desirable heat preserving and insulating material of generally acknowledging both at home and abroad; And the granule interior of converter slag has a lot of micropores, and has high compression strength; These three kinds of raw materials are with after silicon sol or quick dissolved sodium silicate mix; Make the warming plate of making not only can play fire prevention, fire-retardant and insulation, heat insulation effect; And have stronger cohesion and a cohesive strength; And can increase the ultimate compression strength of warming plate, under the effect of adding water-resisting agent, strengthened the hydrophobic nature of warming plate and the repellency of moisture simultaneously.
According to the building zone segregation inorganic fire warming plate that the batching of such scheme is processed, its beneficial effect is:
1, the density of this warming plate is at 350Kg/M 3Below, thermal conductivity 0.060~0.085 W/mK has that unit weight is light, a good heat insulating, distinguishing features such as ultimate compression strength is high, avidity is strong, good toughness, shrinking percentage are little, easy construction.
2, the warming plate of processing can effectively improve the fire resistance property of building heat insulation system, and its fire protection flame retarding property is good, when occurring catching fire, can stop fire spreading effectively, and has good heat preservation and insulation.
3, this warming plate all adopts nontoxic, harmless natural mineral raw, and have the good adsorption detoxifying properties and tasteless, nontoxic, do not fire, advantage such as unit weight is light, can receive excellent environment protecting with the warming plate of its making.
Embodiment
The proportioning raw materials of fireproof heated board of the present invention and preparation method are through studying for a long period of time and a large amount of experiment gained by the contriver; Its each component raw material is in the following weight parts ratio range; All can receive good effect: this fireproof heated board is that the preparation of raw material by following weight part forms: particle diameter is 50~70 parts in the expanded perlite granule material of 1~4mm, 4~8 parts of the converter slag particulate material that particle diameter is 1 ~ 2mm, 7~12 parts of rock wools, silicon sol or 15~25 parts of quick dissolved sodium silicates, 2~6 parts of the water-resisting agents that Fibre diameter is 0.1 ~ 0.5mm; What wherein, water-resisting agent adopted is inorganic aluminate water-proof agent or concrete waterproofer or waterproofing agent of organosilicon.
Embodiment 1
The weight part proportioning of each component raw material of fireproof heated board of the present invention can be: particle diameter is 50 parts in the expanded perlite granule material of 1~4mm, 4 parts of the converter slag particulate material that particle diameter is 1 ~ 2mm, 7 parts of rock wools, silicon sol or 15 parts of quick dissolved sodium silicates, 2 parts of the water-resisting agents that Fibre diameter is 0.1 ~ 0.5mm.
Embodiment 2
The weight part proportioning of each component raw material of fireproof heated board of the present invention also can be: particle diameter is 60 parts in the expanded perlite granule material of 1~4mm, 6 parts of the converter slag particulate material that particle diameter is 1 ~ 2mm, 10 parts of rock wools, silicon sol or 20 parts of quick dissolved sodium silicates, 4 parts of the water-resisting agents that Fibre diameter is 0.1 ~ 0.5mm.
Embodiment 3
The weight part proportioning of each component raw material of fireproof heated board of the present invention can also be: particle diameter is 70 parts in the expanded perlite granule material of 1~4mm, 8 parts of the converter slag particulate material that particle diameter is 1 ~ 2mm, 12 parts of rock wools, silicon sol or 25 parts of quick dissolved sodium silicates, 6 parts of the water-resisting agents that Fibre diameter is 0.1 ~ 0.5mm.
The preparation method of fireproof heated board of the present invention is: from the pearlstone of pulverizing, filter out the expanded perlite granule material that particle diameter is 1~4mm earlier; Filter out the converter slag particulate material that particle diameter is 1 ~ 2mm in the converter slag of pulverizing; Measure rock wool and silicon sol or powdery quick dissolved sodium silicate and the water-resisting agent that the expanded perlite granule material, converter slag particulate material, the Fibre diameter that filter out are 0.1 ~ 0.5mm by said proportioning again; Behind the uniform mixing, process compound; The compound of processing being added water by the weight ratio of Hun He Liao ︰ water=1 ︰ 1.5~3, under normal temperature condition, mix and process the mixing wet feed, will mix wet feed again and insert in the slab mould of pressing machine, is the wet base of warming plate through pressing machine compression moulding; At last the wet base of warming plate is inserted in the stoving oven and dry, 100~150 ℃ of bake out temperatures, drying time 8~12 hours, take out the oven dry back, promptly processes fireproof heated board.Warming plate is of a size of: long 500~1000mm, wide 300~500mm, high 20~100mm.When carrying out the mix of fireproof heated board, if what select for use is silicon sol in the proportion raw material, it be a kind of polymeric silica microparticulate in water or the colloidal solution of organic solvent, can be directly after purchasing and other raw materials mix; If what select for use is the powdery quick dissolved sodium silicate in the batching, must with other raw materials mix before add the clear water dissolving by the weight ratio of 1:1 earlier and stir after re-use.
In building operation, improving building system structure fire savety is the key of fire safety. it is key element wherein that fireproof jointing sheath, fire prevention cut off.To adding the fireproof thermal-insulation layer of one deck between existing Highrise buildings adjacent layers, can improve fire resistance greatly as the isolation strip.Through verification experimental verification; The burning area of no fireproof jointing sheath polyurethane thermal insulation system is that 5 times of fireproof jointing sheath spraying polyurethane system are arranged; When actual fire takes place; It is long more that inorganic heat insulation material reaches time of burning-point (fluxing point) temperature, create more opportunity then can for fire rescue and personnel escape.Therefore, at the warming plate that the zone segregation band setting of Highrise buildings has excellent fire prevention, heat-insulating property, can effectively stop spreading of when the presence of fire intensity of a fire.

Claims (1)

1. one kind prepares the method for building zone segregation inorganic fire warming plate, it is characterized in that: it is by following step preparation:
1) gets 15~25 parts of 7~12 parts of 50~70 parts in expanded perlite granule material that particle diameter is 1~4mm, 4~8 parts of converter slag particulate material that particle diameter is 1 ~ 2mm, rock wools that Fibre diameter is 0.1 ~ 0.5mm and silicon sol or powdery quick dissolved sodium silicates and 2~6 parts of water-resisting agents by weight ratio; Wherein, What water-resisting agent adopted is inorganic aluminate water-proof agent or concrete waterproofer or waterproofing agent of organosilicon; Behind the uniform mixing; It is subsequent use to process compound, and wherein, the powdery quick dissolved sodium silicate must the weight ratio by 1:1 add the clear water dissolving before mixing;
2) get compound and add water, under normal temperature condition, mix, process the mixing wet feed by the weight ratio of Hun He Liao ︰ water=1 ︰ 1.5~3;
3) will mix wet feed and insert in the slab mould of pressing machine, be the wet base of warming plate through pressing machine compression moulding;
4) dry: the wet base of warming plate is inserted in the stoving oven dry, 100~150 ℃ of bake out temperatures, drying time 8~12 hours, take out the oven dry back, is the fireproof heat insulating board finished product.
CN201110040143A 2011-02-17 2011-02-17 Building interlayer insulation inorganic fireproofing heat insulation board and preparation method thereof Expired - Fee Related CN102173715B (en)

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102304948B (en) * 2011-09-19 2013-06-19 青岛文创科技有限公司 Method for processing light fireproof insulation board
CN102501304A (en) * 2011-11-22 2012-06-20 李金峰 Process for working insulation board
CN102491666B (en) * 2011-11-22 2013-01-02 青岛文创科技有限公司 Processing technology for improved thermal insulation plate
CN102677850B (en) * 2012-05-29 2013-11-13 信阳天意节能技术有限公司 Outer wall vacuum inorganic heat-preserving decorating plate and preparation method thereof
CN105503118B (en) * 2015-12-15 2017-12-22 中国地质科学院郑州矿产综合利用研究所 Perlite insulation board with good comprehensive performance and preparation method thereof
CN105948681A (en) * 2016-04-21 2016-09-21 中国建材国际工程集团有限公司 Composite fireproof insulation material and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU463648A1 (en) * 1973-05-28 1975-03-15 Всесоюзный Научно-Исследовательский И Проектный Институт "Теплопроект" Thermal Insulation Composition
CN1057659A (en) * 1990-06-23 1992-01-08 龙昂 Composite heat insulatant thermal insulation material
EP1158095A2 (en) * 2000-05-24 2001-11-28 Armstrong World Industries, Inc. Durable acoustical panel and method of making the same
CN1511808A (en) * 2002-12-30 2004-07-14 北京市建筑材料科学研究院 Composite material thermal insulation plate
CN1978375A (en) * 2005-11-30 2007-06-13 甘肃省建材科研设计院 Light aggregate concrete heat insulating plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU463648A1 (en) * 1973-05-28 1975-03-15 Всесоюзный Научно-Исследовательский И Проектный Институт "Теплопроект" Thermal Insulation Composition
CN1057659A (en) * 1990-06-23 1992-01-08 龙昂 Composite heat insulatant thermal insulation material
EP1158095A2 (en) * 2000-05-24 2001-11-28 Armstrong World Industries, Inc. Durable acoustical panel and method of making the same
CN1511808A (en) * 2002-12-30 2004-07-14 北京市建筑材料科学研究院 Composite material thermal insulation plate
CN1978375A (en) * 2005-11-30 2007-06-13 甘肃省建材科研设计院 Light aggregate concrete heat insulating plate

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Address after: 464100 Henan Pingqiao District, Xinyang Province five mile Private Economic Experimental Zone

Patentee after: XINYANG TIANYI ENERGY SAVING TECHNOLOGY CO., LTD.

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