CN1511452A - Agricultural compositino for preventing and controlling nematode and its preparing method and use - Google Patents
Agricultural compositino for preventing and controlling nematode and its preparing method and use Download PDFInfo
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- CN1511452A CN1511452A CNA021596735A CN02159673A CN1511452A CN 1511452 A CN1511452 A CN 1511452A CN A021596735 A CNA021596735 A CN A021596735A CN 02159673 A CN02159673 A CN 02159673A CN 1511452 A CN1511452 A CN 1511452A
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Abstract
The agricultural composition for preventing and controlling nematode contains nematicide and chitin. It has the double effects of killing nematode and raising plant immunity and thus has obvious effect of preventing and controlling nematode. The present invention also relates to agricultural composition comprising the nematicide composition and fertilizer with the functions of purifying soil, raising plant resistance, providing plant with nutrients and preventing and controlling nematode and diseases.
Description
[technical field]
The present invention relates to a kind of nematicidal composition that contains nematocide and chitin class material, because the nematicide that adopts combination has nematicide and the effect that increases the immunity of plant two aspects own, therefore, the effect of control nematode is very obvious.In addition, the invention still further relates to the agriculturally useful compositions of forming by described nematicidal composition and fertilizer.This agriculturally useful compositions has purification, cleaning soil, improves the resistance of plant, and supplies with the required nutrient of crop, multiple efficacies such as pest control treatment.
[background technology]
Plant nematode is one of plant infectious cause of disease, and they extensively colonize on root, stem, leaf, flower, bud and the kind reality of each plant species, make plant that various nematodosis take place.The plant nematode overwhelming majority is the male and female similar shape, and promptly female male worm all is wire, and elongated transparent, polypide is very little.General body is long only 1 millimeter, and wide 0.05 millimeter of body will just can be seen clearly by disecting microscope.Kind of this class nematode and quantity are all a lot, and it is extensive again to distribute, and every have the place of soil and water all might exist.Also having the minority Plant nematode is that male and female are difform, and female worm resembles a pear in shape, sphere or cryptomere, and male worm still is wire.Modal as root-knot nematode, Cyst nematode, reniform nematode etc., they all are most important pathogenic nematodes.
Harmful to plant at present nematode, the kind more than 40 that has in China's discovery mainly contains rhabditis axei, root-knot nematode, cyst roundworm, pratylenchus etc.Wherein crop is endangered root-knot nematode and cyst roundworm most serious of all, the crop that is mainly endangered has cucumber, peanut, soybean, paddy rice, wheat, potato, tobacco, beet, citrus, crudefiber crop etc.The general generation of nematode just can make this class crop failure 10%~40%, can reduce 70%~80% when serious, even total crop failure, and its extent of injury has some idea of.
Because nematode is a kind of lower animal, individual tiny, but nematode polypide inside has flourishing digestive system and genital system, draws its needed nutrition in plant corpus.Nervous system, other animals of excretory system geometric ratio want simple many, generally will just can see these interiors clearly under high-power microscope.Plant nematode has very big harmfulness, cause the mechanical damage except that the nutrition of drawing the host with to plant tissue, the esophageal gland of Plant nematode also can be secreted noxious material, these materials contain multiple digestive ferment, bring out host tissue various pathological changes take place, and can make plant tissue cell's overdevelopment, form megabacterium, or cell mesoglea dissolving causing cell is decomposed, cell wall is destroyed, causes root and cortex to form cavity and cell death.Modal phenomenon is that the plant cell volume expands, and most typical is exactly the root-knot nematode formed megabacterium behind the plant of causing harm, and the result can form the knurl that differs in size " root knot " on root; After and for example similes thorne is caused harm citrus, cell wall is decomposed, the cortex of the killed root of result forms typical cavity, causes root-rot mashed at last; The nematode secretion that also has then shows had strong inhibitory effects, and root is stopped growing, and plant growing is suppressed and shows dwarfing.More than performance illustrates that the chemical action of Plant nematode secretion can finally make plant growing weak to the influence of plant cell and tissue generation, and output reduces, and the product qualitative change is bad, even dead.In addition, the nematode that has can transmitted virus, and makes plant that certain virus disease take place, and like this, has increased and enlarged the generation of virus disease, and this harmfulness also is sizable.Simultaneously, nematode also interacts with other cause of diseases such as fungi, bacterium, and common causing a disease caused compound disease, increases the weight of the generation of disease.
Whole world nematicide medicament kind has 30 kinds approximately at present, and commonly used is no more than 10 kinds, can be divided into halogenated hydrocarbon, sulfuration isosulfocyanate, carbamates and organic phosphates by its chemical constitution.The agricultural chemicals that present China is used for the controlling plant nematode mainly contains Nemacur, furans pellet, Aldicarb etc., and these agricultural chemicals are big to the person poultry toxicity, and environmental pollution is serious, even can produce poisoning.For this reason, people attempt to solve this problem by the mode of safe, for example, CN1060945A discloses a kind of nematicidal composition that contains Nemacur, it comprises for example combination of α-Nai Yisuan of Nemacur and safener, though still part solves the drug injury problem that plant is produced, its safe effect to the user is also unsatisfactory.
The nematocidal active material that also once adopted natural origin in the prior art for example microorganism secondary metabolite is prevented and treated causing harm of nematode, and commercial product arranged, for example Royal 300, Royal 350, Bioact etc. are in the control efficiency instability of these products.For example, CN85104021A discloses a kind of chitin-protein complex with eelworm-killing activity; The secondary metabolite that CN1297996A discloses a kind of microorganism-thick wall cell verticil is the mematocide of main active.In addition, about also having reported the C that adopts control fertilizer in the document: N weight ratio and employing fertilizer and chitin class combinations of substances suppress the growth of plant nematode in the soil.Referring to, for example CN1324213A, US5057141A.But the actual nematicide effect of biogenic nematocide of the prior art is unsatisfactory.For this reason, still just need safer working substance nematocide.
The present inventor has carried out deep discovering at the deficiencies in the prior art, adopt nematocide and the chitin class combinations of substances that can improve crop anti-adversity, can improve the resistivity of crop, nematode is had the synergy killing action, reach purpose nematode control.In addition, also find, above-mentioned nematicide combination is used with fertilizer and soil conditioner, can reach safe in utilization, the purpose of purification, cleaning soil, the two is used in combination, both can improve the resistance of plant, supply with the required nutrient of crop, can reach multiple efficacies such as pest control treatment again, achieve many things at one stroke, so finished the present invention.
[summary of the invention]
The purpose of this invention is to provide a kind of nematicidal composition, it comprises nematocide and chitin class material.
Another object of the present invention provides a kind of agriculturally useful compositions, and it is made up of fertilizer and described nematicidal composition.
A further object of the present invention provides a kind of method for preparing described agriculturally useful compositions.
Herein, described nematocide is selected from Avermectin, methylamino avermectin and salt thereof (example hydrochloric acid salt or benzoate), nemamort, nemagon, phonamiphos, benzene line phosphine, Isofenphos methyl, cadusafos and oxamyl.The preferably nematocide of low toxicity such as Avermectin, methylamino avermectin and salt example hydrochloric acid salt and benzoate.
Herein, described chitin class material is chitin or takes off the acetyl chitin.Chitin can be natural chitin such as the crude extract of shrimp shell, crab shell, insect shell or hypha,hyphae (molecular weight about 1,000,000-2,000,000), the chitin (molecular weight about 300,000-700,000) after also purifying.Taking off the acetyl chitin can be chitan or chitan derivative, their known can acquisitions by chitin is deacetylated.In fact operable chitan can be oligomer and/or the polymer with any molecular weight among the present invention.Preferably, the present invention uses water miscible chitan.
Nematocide and chitin class combinations of substances that the present invention adopts, can reduce on the one hand for example toxicity of organic phosphor and carbamate chemicals for agriculture of used nematocide, make agricultural chemicals in the process of using and discharging to user and Environmental security, on the other hand, this combination can be by improving crop resistivity and to the killing action of nematode, reach purpose to nematode control.Surprising, combination of the present invention has the nematicide effect of synergy.
Nematicidal composition of the present invention can be made various preparations with the method for routine, for example, and wetting powder, missible oil, suspending agent, granula, soluble granula, soluble powder etc.But preferably making granula with fertilizer uses.
The present inventor finds that also above-mentioned nematicidal composition is particularly suitable for using with fertilizer or soil growth regulator.The two is used in combination, and can reach safe in utilization, the purpose of purification, cleaning soil, and the two is used in combination, and both can improve the resistance of plant, supplies with the required nutrient of crop, can reach multiple efficacies such as pest control treatment again, achieves many things at one stroke.During actual the use, the effect of control nematode is very obvious.
In this article, for reaching the nematicide effect that cooperates nematicidal composition, described fertilizer can be selected nitrogen, phosphorus and the potash fertilizer of aequum for use.Preferably select urea, MAP and potassium sulphate for use.Urea (containing 46.3%N): MAP (powdery) (main nutrient is P): (main nutrient is KO to potassium sulphate
2)=140-180: 110-150: 180-220.
In addition, for reaching the purpose of purification, cleaning soil, can also add the mud powder, described mud powder contains great number of organic matters, and for example You Jizhi amount reaches 70%.The mud powder can be various sources, for example, and half congealed mud, lake mud, municipal sludge etc.
When the preparation agriculturally useful compositions, convenient for granulation, can also add and add processing auxiliary material such as adhesive.Adhesive can be conventional the viscosity organic material for example or have natural material such as the clay or the mud of adhesive property.
Agriculturally useful compositions of the present invention can adopt for example following method preparation: at first urea, MAP, potassium sulphate, mud powder and binding agent are mixed in proportion, it is carried out elementary granulation; With nematocide and chitin class material according to 1: 1-100 (w/w) is preferably 1: the ratio combination of 5-50 forms nematicidal composition of the present invention; Complex is mixed pulverizing, granulation again with elementary granulation; Packing then.Above-mentioned nematocide kill the line electuary as therapeutic agent, chitin class material is as immunizing agent, urea, MAP, potassium sulphate, mud powder are as inorganic and organic fertilizer component.
In the specific embodiment, for example, constituent and proportioning can be as follows in the agriculturally useful compositions: (w/w)
Urea (containing 46.3%N) 140-180
MAP (powdery) (main nutrient is P) 110-150
Potassium sulphate (main nutrient is KO2) 180-220
Nematicidal composition 5-20 of the present invention
Mud powder (70% organic matter) 310-370
Binding agent 30-70
Its preferred range is as follows: (w/w)
Urea (containing 46.3%N) 150-170
MAP (powdery) (main nutrient is P) 120-140
Potassium sulphate (main nutrient is KO2) 190-210
Nematicidal composition 10-15 of the present invention
Mud powder (70% organic matter) 330-350
Binding agent 40-60
Described nematicidal composition of the present invention is the nematocide mentioned above and the composition of chitin class material.
The application dosage of nematicidal composition of the present invention is 50-2, and 000 gram/mu is preferably 50-500 gram/mu.For agriculturally useful compositions of the present invention, amount of application is 10-50 kilogram/mu, is preferably 20-30 kilogram/mu.
Agriculturally useful compositions of the present invention combines fertilizer and agricultural chemicals advantage together, reached and to have supplied with the crop fertility, can effectively prevent and treat nematode again, cleaning soil improves crop anti-adversity, thereby has reached the effect of biological control, and applied range, be applicable to all kinds of vegetable melon and fruits, field crop, various nematodiasises such as the woods.Said preparation is with low cost, both can make base fertilizer and use, and also can make base manure and topdress.Can be widely used in various crops.
[embodiment]
Following examples are used to illustrate the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
Urea 162, MAP 137Kg, potassium sulphate 180Kg, mud powder 338.5Kg and polyethylene glycol (molecular weight 5000) 35Kg is mixed elementary granulation; Again nematocide Nemacur 1Kg is combined with chitin 10Kg, form complex; Above-mentioned elementary granulation and complex are mixed pulverizing, granulation again; Obtain product of the present invention after the packing.
Embodiment 2
Urea 140, MAP 110Kg, potassium sulphate 200Kg, mud powder 310Kg and carboxymethyl cellulose 50Kg are mixed elementary granulation; Again nematocide Avermectin 1.25Kg is combined with chitin 7.5Kg, form complex; Above-mentioned elementary granulation and complex are mixed pulverizing, granulation again; Obtain product of the present invention after the packing.
Embodiment 3
Urea 180, MAP 150Kg, potassium sulphate 220Kg, mud powder 370Kg and clay 65Kg are mixed elementary granulation; Again nematocide methylamino avermectin 1.0Kg is combined with chitan (molecular weight 30000) 5Kg, form complex; Above-mentioned elementary granulation and complex are mixed pulverizing, granulation again; Obtain product of the present invention after the packing.
Embodiment 4
Urea 180, MAP 150Kg, potassium sulphate 220Kg, mud powder 370Kg and clay 65Kg are mixed elementary granulation; Again nematocide oxamyl 1.0Kg is combined with chitan (molecular weight 30000) 15Kg, form complex; Above-mentioned elementary granulation and complex are mixed pulverizing, granulation again; Obtain product of the present invention after the packing.
Biological Examples 1 synergy test
Soil sampling, is provided with respectively by test requirements document after 48 hours with oven drying (55 ℃):
Handle 1: water dilutes 0.6% Avermectin wetting powder or 0.9% abamectin emulsifiable concentrate with low amounts of water, mix with the soil of above-mentioned drying, final water content is 60%, and the content of active ingredient Avermectin is respectively 100mg/Kg, 50mg/Kg, 25mg/Kg, 12.5mg/Kg and 6.25mg/Kg dry ground totally 5 divisional processing;
Handle 2: chitin is mixed with the soil of above-mentioned drying, and chitin content is 600mg/Kg, 300mg/Kg, 150mg/Kg, 75mg/Kg and 37.5mg/Kg dry ground, adds water and makes this mixture water content reach 60%;
Handle 3: the nematicidal composition among the embodiment 2 is mixed with the soil of above-mentioned drying, and the content of nematicidal composition is 80mg/Kg, 40mg/Kg, 20mg/Kg, 10mg/Kg and 5mg/Kg dry ground, adds water and makes this mixture water content reach 60%;
Handle 4: blank makes it water content with the Tu Jiashui of above-mentioned drying and reaches 60%.
3 repetitions are established in each processing.By 7 days, 14 days, 21 days and 28 days inoculation nematodes, observe 24 hours survival nematode numbers respectively.
Lethality and corrected mortality computing formula are as follows:
Lethality (%)=(1-handles the preceding total borer population of back borer population alive/processing) * 100
Corrected mortality (%)=(1-processed group lethality/blank group lethality) * 100
Calculate the LC that each is handled according to corrected mortality with POLO software
50Value (lethal concentration of 50)
The synergy co-toxicity coefficient is calculated as follows:
This method at first is to measure the toxicity regression line of each single agent and mixture, calculates the lethal dose of 50 (LD
50) or the lethal concentration of 50 (LC
50), be the standard medicament with wherein a kind of single agent then, its LD
50Or LC
50Toxicity index as 100, calculate the toxicity index of other single agent and mixture again.Theoretical toxicity index and actual toxicity index according to mixture are calculated co-toxicity coefficient (CTC).The CTC value is synergistic effect greater than 100; Less than 100, be antagonism; Near 100, be summation action.
The LD of toxicity index (TI)=standard medicament
50The LD of/common reagent agent
50* 100
The LD of actual toxicity index (the ATI)=standard medicament (A medicament) of mixture
50The LD of/mixture
50* 100
B%+ in the TI * mixture of A%+B medicament in the TI * mixture of theoretical toxicity index (the TTI)=A medicament of mixture
The co-toxicity coefficient of mixture (CTC)=ATI/TTI * 100
The results are shown in Table 1,2.
Table 1 Avermectin and chitin and mixture LC thereof
50Value and CTC value
Handle | ???????????????LC 50Value (mg/Kg) | |||
7 (my god) | 14 (my god) | 21 (my god) | 28 (my god) | |
Handle 1 | ?7.32 | ?11.23 | ?20.43 | ?38.98 |
Handle 2 | ?345.56 | ?289.31 | ?335.91 | ?378.23 |
Handle 3 | ?17.28 | ?21.36 | ?35.67 | ?44.47 |
The CTC value | ?263.09 | ?298.50 | ?293.74 | ?379.14 |
Table 2 Avermectin and chitin are used the toxicity test co-toxicity coefficient with
Medicament title LC
50(mg/Kg) toxicity index co-toxicity coefficient
Avermectin (A) 7.32000TIa 100CTC 263.0896
Chitin (B) 345.560000TIb 2.11830073
A+B????????????????17.280000ATI?????42.3611111
TTI?????16.1014006
Avermectin (A) 11.23000TIa 100CTC 298.5032
Chitin (B) 289.310000TIb 3.88164944
A+B????????????????21.360000ATI?????52.5749064
TTI?????17.6128424
Avermectin (A) 20.43000TIa 100CTC 293.7354
Chitin (B) 335.910000TIb 6.08198625
A+B????????????????35.670000ATI??????57.275021
TTI?????19.4988454
Avermectin (A) 38.98000TIa 100CTC 379.1397
Chitin (B) 378.230000TIb 10.3058985
A+B????????????????44.470000ATI?????87.6545986
TTI?????23.1193416
By table 1 and table 2 as can be known co-toxicity coefficient illustrate that all greater than 100 said composition has obvious synergistic effect.
Biological Examples 2
Nematicidal composition among the embodiment 1 is diluted with water to 500,800 and 1000 times by test requirements document, contrasts as medicament, use clear water as blank with Nemacur.3 repetitions are established in each processing.Soil sampling, adds above-mentioned soup and makes soil moisture content reach 60% after 48 hours with oven drying (55 ℃).By 7 days, 14 days, 21 days and 28 days inoculation root-knot nematodes, observe 24 hours survival nematode numbers.Lethality and corrected mortality computing formula are as follows:
Lethality (%)=(1-handles the preceding total borer population of back borer population alive/processing) * 100
Corrected mortality (%)=(1-processed group lethality/blank group lethality) * 100
Corrected mortality is the indoor control effect.
The results are shown in Table 3.
The control efficiency of table 3 table 1 pair sweet potato stem nematode (indoor inoculation test)
Handle 500 times of liquid | Control efficiency (%) | |||
7 (my god) | 14 (my god) | 21 (my god) | 28 (my god) | |
?100 | ?100 | ?100 | ?100 | |
800 times of liquid | ?100 | ?100 | ?98.2 | ?98.5 |
1000 times of liquid | ?100 | ?97.4 | ?93.5 | ?90.1 |
Nemacur *600 times of liquid (contrast) | ?100 | ?96.3 | ?80.6 | ?65.1 |
*Nemacur is 10% granule, and Bayer A.G produces, and for consistent with test nematicidal composition application method, is convenient to comparison, water stripping during use.
By last table 3 as seen, the nematicide effect of agriculturally useful compositions of the present invention obviously has and is better than conventional Nemacur preparation.Biological Examples 3
The nematicidal composition of embodiment 1 is diluted with water to 500,800 and 1000 times by test requirements document, and every mu of ground sprinkles dispenser liquid 80~100Kg at root.4 repetitions are established in each processing.Potato piece with results during investigation carries out classification, calculates disease index, calculates control efficiency according to disease index.It is 0 grade that the potato piece does not have nematode harm, cause harm area be 1 grade below 1/4, the area of causing harm is 2 grades 1/4~1/2, the area of causing harm is 3 grades 1/2~3/4, the area of causing harm is 4 grades greater than 3/4.
Disease index=∑ (progression * potato piece weight)/(investigating total potato weight * the highest sick progression) * 100
Control efficiency (%)=(1-treatment region disease index/check plot disease index) * 100
The results are shown in Table 4.
The control efficiency (field experiment) of table 4 pair sweet potato stem nematode
Handle | Disease index | Control efficiency (%) |
500 times of liquid | 9.1 | ?82.1 |
800 times of liquid | 11.4 | ?77.6 |
1000 times of liquid | 16.7 | ?67.2 |
600 times of liquid of Nemacur (contrast) | 18.2 | ?64.2 |
Blank (contrast) | 50.9 | ?0 |
*Nemacur is 10% granule, and Bayer A.G produces, and for consistent with test nematicidal composition application method, is convenient to comparison, water stripping during use.
By last table 4 as seen, the nematicide effect of agriculturally useful compositions of the present invention obviously has and is better than conventional Nemacur preparation.
Biological Examples 4
Stubble is a cucumber before selecting, and the serious green house of nematodosis generation is a practice ground.The agriculturally useful compositions of embodiment 1 is diluted with water to 500,800 and 1000 times by test requirements document, and every mu of ground sprinkles dispenser liquid 50Kg at root.4 repetitions are established in each processing.Contrast as medicament with Nemacur, use clear water as blank.Handle back investigation in the 15th day, with 5 point samplings, 10 strains are dug in every sub-district, check the root incidence, and disease index is calculated in the classification record.
Disease index=∑ (progression * potato piece weight)/(investigating total potato weight * the highest sick progression) * 100
Control efficiency (%)=(1-treatment region disease index/check plot disease index) * 100
The results are shown in Table 5.
The control efficiency (field experiment) of table 5 pair cucumber root-knot nematode
Handle | Disease index | Control efficiency (%) |
500 times of liquid | 7.1 | ?76.9 |
800 times of liquid | 10.2 | ?66.8 |
1000 times of liquid | 11.3 | ?63.2 |
600 times of liquid of Nemacur (contrast) * | 13.2 | ?57.0 |
Blank (contrast) | 30.7 | ?0 |
*Nemacur is 10% granule, and Bayer A.G produces, and for consistent with test nematicidal composition application method, is convenient to comparison, water stripping during use.
By last table 5 as seen, the nematicide effect of agriculturally useful compositions of the present invention obviously has and is better than conventional Nemacur preparation.
Biological Examples 5
Stubble is cucumber or tomato before selecting, and the serious green house of nematodosis generation is a practice ground.The agriculturally useful compositions of embodiment 1 is pressed test requirements document, establish 3 processing by the 100g that whenever spreads manuer in holes, 150g and 200g before tomato is transplanted, the every cave 10g of Nemacur 10% granule does the contrast of standard medicament, establishes and does not execute agriculturally useful compositions or Nemacur blank.Handle back investigation in the 15th day, with 5 point samplings, 10 strains are dug in every sub-district, check the root incidence, and disease index is calculated in the classification record.
Disease index=∑ (progression * potato piece weight)/(investigating total potato weight * the highest sick progression) * 100
Control efficiency (%)=(1-treatment region disease index/check plot disease index) * 100
The results are shown in Table 6.
The control efficiency (field experiment) of table 6 pair tomato root-knot eelworm
Handle | Disease index | Control efficiency (%) |
The 100g agriculturally useful compositions | 7.3 | 77.9 |
The 150g agriculturally useful compositions | 5.6 | 83.1 |
The 200g agriculturally useful compositions | 2.2 | 93.3 |
Nemacur 20g (contrast) * | 11.2 | 66.2 |
Blank (contrast) | 33.1 | 0 |
*Nemacur is 10% granule, and Bayer A.G produces, and for consistent with test nematicidal composition application method, is convenient to comparison, water stripping during use.
By last table 4 as seen, the nematicide effect of agriculturally useful compositions of the present invention obviously has and is better than conventional Nemacur preparation.This shows that the effect of present composition control nematode is very obvious.
Though above the present invention is described in detail with a general description of the specific embodiments on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, not departing from the these modifications or improvements basically of spirit of the present invention, all belong to the scope of protection of present invention.
Claims (8)
1. nematicidal composition, it is characterized in that, it comprises the nematocide and the chitin class material of nematicide effective dose, wherein, described nematocide is selected from: Avermectin, methylamino avermectin and salt thereof, nemamort, nemagon, phonamiphos, benzene line phosphine, Isofenphos methyl, cadusafos, carbofuran and oxamyl, the weight ratio of nematocide and chitin class material is 1: 1-100.
2. according to the nematicidal composition of claim 3, wherein the ratio of nematocide and chitin class material is 1: 5-50.
3. according to arbitrary nematicidal composition of claim 1-2, wherein, chitin class material is selected from: chitin and chitan.
4. an agriculturally useful compositions of being made up of fertilizer, nematocide and chitin class material is characterized in that, the proportioning of the composition of described fertilizer and nematocide and chitin class material is (w/w)
Urea 140-180
MAP 110-150
Potassium sulphate 180-220
Nematicide combination 5-20
Mud powder 310-370
Binding agent 30-70
Wherein the nematicide line is combined into nematocide and chitin class material, and the weight ratio of nematocide and chitin class material is 1: 1-100.
5. according to the agriculturally useful compositions of claim 4, wherein, the composition of described fertilizer and nematocide component and proportioning are (w/w)
Urea 150-170
MAP 120-140
Potassium sulphate 190-210
Nematicide combination 10-15
Mud powder 330-350
Binding agent 40-60
Wherein the nematicide line is combined into nematocide and chitin class material, and the weight ratio of nematocide and chitin class material is 1: 1-100.
6. according to the agriculturally useful compositions of claim 5, wherein, described binding agent is selected from polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose and clay.
7. according to arbitrary agriculturally useful compositions of claim 4-6, wherein, described nematocide Avermectin, methylamino avermectin and salt thereof, nemamort, nemagon, phonamiphos, benzene line phosphine, Isofenphos methyl, cadusafos, carbofuran and oxamyl.
8. according to the manufacture method of arbitrary agriculturally useful compositions of claim 4-7, at first urea, MAP, potassium sulphate, mud powder and binding agent are mixed, it is carried out elementary granulation according to proportioning; Nematocide is combined with chitin, form complex; Complex is mixed pulverizing, granulation again with elementary granulation; Packing then.
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CN101891560A (en) * | 2010-07-24 | 2010-11-24 | 东莞市瑞德丰生物科技有限公司 | Pesticide-added fertilizer containing avermectins and oligosaccharide and preparation method thereof |
CN102365950A (en) * | 2011-10-28 | 2012-03-07 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide-containing composition for controlling acarid, and application and method thereof |
CN102365950B (en) * | 2011-10-28 | 2012-11-14 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide-containing composition for controlling acarid, and application and method thereof |
CN102342278A (en) * | 2011-11-09 | 2012-02-08 | 江西海科瑞特作物科学有限公司 | Sterilization composition containing cyproconazole and chitin |
CN103430950A (en) * | 2013-08-22 | 2013-12-11 | 山东省联合农药工业有限公司 | Nematode-killing composition containing abamectin and furfural |
CN103430950B (en) * | 2013-08-22 | 2014-07-09 | 山东省联合农药工业有限公司 | Nematode-killing composition containing abamectin and furfural |
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