CN1498976A - Desulfurizer based on nano composite calcium carbide and calcium oxide for steel - Google Patents
Desulfurizer based on nano composite calcium carbide and calcium oxide for steel Download PDFInfo
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- CN1498976A CN1498976A CNA021467536A CN02146753A CN1498976A CN 1498976 A CN1498976 A CN 1498976A CN A021467536 A CNA021467536 A CN A021467536A CN 02146753 A CN02146753 A CN 02146753A CN 1498976 A CN1498976 A CN 1498976A
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- calcium
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- magnesium
- calcium oxide
- steel
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- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
A nano-class composite calcium carbide (or calcium oxide)-base desulfurizing agent for steel contains calcium carbide or calcium oxide nanoparticles (65-95 wt.%), calcareous high-Al cement clinker, forsterite, magnesium powder, FeNi alloy powder and magnesium dihydride powder. Its advantages are high reaction speed, short reaction time, less temp lowering, low dosage and high quality of steel.
Description
1. technical field:
The invention belongs to nanometer novel material Application Areas.Utilize the high characteristics of nano material surface active to prepare nano combined carbide of calcium base and calcium oxide-based desulfurizing agent for iron or steel, the iron manufacturing process that is used for making steel uses as sweetening agent.
2. background technology:
Sulphur is one of major impurity in the steel, must remove to greatest extent in the smelting process of steel.The general employing 100% desulfurizing iron pre-treatment of external steel mill, the metallurgical scientific and technological guide requirement of China 2000-2005, annual production will be carried out the desulfurizing iron pre-treatment greater than 1,000,000 tons steel mill, whole nation hot metal pretreatment ratio will bring up to 60% by present 20%, and each big steel mill of the whole nation is being the effort of realizing this goal.
Along with the user is more and more tighter to the requirement of sulphur content in the steel, the importance of development desulfurization technology is more outstanding, also is the important means that product competitiveness improves in each big steel mill.
At present, the desulfurizing agent for iron or steel that generally adopts mainly is carbide of calcium and calcium oxide and metal magnesium powder both at home and abroad, and their mixture.Wherein carbide of calcium and calcium oxide cause its desulfurization rate and sweetening effectiveness all bad because itself volatility and dynamic conditions are not good, mainly are that the sorbent consumption amount is big, long reaction time, and hot metal temperature drop is big, and power consumption is big, and desulfurization depth is not good.The sweetening effectiveness of metal magnesium powder is better, still, also has some shortcomings, mainly is magnesium powder price height, is difficult for preserving, and production operation is also relatively more difficult.
The characteristic of nano material provides a kind of speed of response fast for us, and the reaction times is short, the high efficiency products that reaction effect is good.The purpose of product of the present invention is exactly to design a kind of product innovation that provides for some defectives that overcome the prior art existence.The application of this product can solve two problems that are difficult in the prior art solve, and (the one, the desulfurization cycle is long; The 2nd, desulfurization depth is not good), can improve the quality of China's steel, reduce consuming cost.
3. summary of the invention:
3.1 the present invention relates to the manufacturing of nano material, its manufacture method is to adopt the mechanical processing of high-energy ball milling and obtain the nano level product, the mechanical ball milling method is the both economical method for preparing manocrystalline powders in a large number, can satisfy requirements of mass production.Its process is:
3.1.1 adopt CLM turnery machine (Beijing state sharp superfine powder equipment company limited makes) that initial feed is crushed to 10-30um.
3.1.2 adopt QLM-IV sulfuration bed formula airflow milling (manufacturing of powder company of Shenyang Aircraft Inst.) with the raw material pulverizing of 10-30um to 2um.
3.1.3 the high-energy stirring shredder that adopts Ohio, USA continent UNION PROCESS company with the raw material pulverizing of 2um to 100nm level product.
3.2 the nano combined carbide of calcium base that the present invention relates to and the prescription of calcium oxide-based desulfurizing agent for iron or steel are:
3.2.1 the shared weight 65-75% of carbide of calcium, calcium high aluminium cement clinker 35-25%.
3.2.2 the shared weight 65-75% of carbide of calcium, forsterite 35-25%.
3.2.3 the shared weight 93-95% of carbide of calcium, the magnesium powder accounts for 7-5%.
3.2.4 the shared weight 93-95% of carbide of calcium, the magnesium-nickel alloy powder accounts for 7-5%.
3.2.5 the shared weight 93-95% of carbide of calcium, the magnesium hydride powder accounts for 7-5%.
3.2.6 the shared weight 65-70% of calcium oxide, calcium high aluminium cement clinker 35-30%.
3.2.7 the shared weight 65-70% of calcium oxide, forsterite 35-30%.
3.2.8 the shared weight 80-85% of calcium oxide, the magnesium powder accounts for 20-15%.
3.2.9 the shared weight 80-85% of calcium oxide, the magnesium-nickel alloy powder accounts for 20-15%.
3.2.10 the shared weight 80-85% of calcium oxide, the magnesium hydride powder accounts for 20-15%.
4. specific implementation method:
4.1 3.2.1-3.2.10 carries out weighing respectively by prescription, and is stand-by after weighing up.
Get a kind of prescription 4.2 appoint, the raw-material granularity of root tool is put into CLM turnery machine and QLM-IV sulfuration bed formula airflow milling respectively, is crushed to 2um.
4.3 appoint the raw material that is crushed to 2um get a kind of prescription together to put into the high-energy stirring shredder, be ground to 100nm after, sealing is preserved.
4.4 get a kind of product of prescription, use nitrogen as carrier gas, sweetening agent is blown in the molten iron, finish desulphurization reaction with the molten iron thorough mixing.The consumption of iron melt desulfurizing agent per ton is the 1-2 kilogram; Can make that sulphur is minimum in the molten iron reduces to below 0.001%, fully satisfy production requirement.
Claims (2)
1, a kind of nano level compound carbonizing calcium base and calcium oxide-based desulfurizing agent for iron or steel, it adds nano level calcium high aluminium cement clinker, forsterite, metal magnesium powder, magnesium hydride powder by nano level carbide of calcium or calcium oxide and is formed; Be mainly used in the steel-making iron manufacturing process and use as sweetening agent.Its compositing formula is as follows:
The shared weight 65-75% of carbide of calcium, the calcium high aluminium cement clinker accounts for 35-25% or forsterite accounts for 35-25%.
The shared weight 93-95% of carbide of calcium, metal magnesium powder account for 7-5% or the magnesium-nickel alloy powder accounts for 7-5% or the magnesium hydride powder accounts for 7-5%.
The shared weight 65-70% of calcium oxide, the calcium high aluminium cement clinker accounts for 35-30% or forsterite accounts for 35-30%.
The shared weight 80-85% of calcium oxide, metal magnesium powder account for 20-15% or the magnesium-nickel alloy powder accounts for 20-15% or the magnesium hydride powder accounts for 20-15%.
2, manufacture method is to adopt the processing of high-energy ball milling machinery to make product, and its detailed process is:
Adopt CLM turnery machine with raw material pulverizing to 10-30um; Adopt QLM-IV sulfuration bed formula airflow milling to be crushed to 2um again; Adopt the high-energy stirring shredder to be crushed to 100nm level product again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146753 CN1210415C (en) | 2002-11-06 | 2002-11-06 | Desulfurizer based on nano composite calcium carbide and calcium oxide for steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02146753 CN1210415C (en) | 2002-11-06 | 2002-11-06 | Desulfurizer based on nano composite calcium carbide and calcium oxide for steel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1498976A true CN1498976A (en) | 2004-05-26 |
| CN1210415C CN1210415C (en) | 2005-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02146753 Expired - Fee Related CN1210415C (en) | 2002-11-06 | 2002-11-06 | Desulfurizer based on nano composite calcium carbide and calcium oxide for steel |
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| CN (1) | CN1210415C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100384515C (en) * | 2006-07-28 | 2008-04-30 | 哈尔滨工业大学 | Normal temperature nanometer desulfurizing agent and its preparation process |
| CN104862450A (en) * | 2015-05-29 | 2015-08-26 | 宁国市华丰耐磨材料有限公司 | Method for enabling nano molten iron purifying modifier to be used in austenite ductile cast iron wear-resistant casting |
| CN104862451A (en) * | 2015-05-29 | 2015-08-26 | 宁国市华丰耐磨材料有限公司 | Method for applying nano molten iron purifying modificator to austenitic ductile iron cast ball |
| WO2017184760A2 (en) | 2016-04-20 | 2017-10-26 | West Virginia University Research Corporation | Methods, apparatuses, and electrodes for carbide-to-carbon conversion with nanostructured carbide chemical compounds |
| CN108588337A (en) * | 2018-06-07 | 2018-09-28 | 上海应用技术大学 | A kind of nanometer dephosphorization slag former and preparation method thereof suitable for middle high phosphorus molten steel |
| CN108754058A (en) * | 2018-06-07 | 2018-11-06 | 上海应用技术大学 | A kind of nano-hot metal composite desulfurizing agent and preparation method thereof |
| US10494264B2 (en) | 2013-03-15 | 2019-12-03 | West Virginia University Research Corporation | Process for pure carbon production, compositions, and methods thereof |
| US11306401B2 (en) | 2014-10-21 | 2022-04-19 | West Virginia University Research Corporation | Methods and apparatuses for production of carbon, carbide electrodes, and carbon compositions |
-
2002
- 2002-11-06 CN CN 02146753 patent/CN1210415C/en not_active Expired - Fee Related
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100384515C (en) * | 2006-07-28 | 2008-04-30 | 哈尔滨工业大学 | Normal temperature nanometer desulfurizing agent and its preparation process |
| US10494264B2 (en) | 2013-03-15 | 2019-12-03 | West Virginia University Research Corporation | Process for pure carbon production, compositions, and methods thereof |
| US10696555B2 (en) | 2013-03-15 | 2020-06-30 | West Virginia University Research Corporation | Process for pure carbon production |
| US11306401B2 (en) | 2014-10-21 | 2022-04-19 | West Virginia University Research Corporation | Methods and apparatuses for production of carbon, carbide electrodes, and carbon compositions |
| CN104862450B (en) * | 2015-05-29 | 2017-03-08 | 宁国市华丰耐磨材料有限公司 | Nano-hot metal purifies the method that alterant is used for austenic globe body wear resistance castings |
| CN104862451A (en) * | 2015-05-29 | 2015-08-26 | 宁国市华丰耐磨材料有限公司 | Method for applying nano molten iron purifying modificator to austenitic ductile iron cast ball |
| CN104862450A (en) * | 2015-05-29 | 2015-08-26 | 宁国市华丰耐磨材料有限公司 | Method for enabling nano molten iron purifying modifier to be used in austenite ductile cast iron wear-resistant casting |
| WO2017184760A3 (en) * | 2016-04-20 | 2018-01-04 | West Virginia University Research Corporation | Methods, apparatuses, and electrodes for carbide-to-carbon conversion with nanostructured carbide chemical compounds |
| CN109312479A (en) * | 2016-04-20 | 2019-02-05 | 西弗吉尼亚大学研究公司 | Method, equipment and the electrode of carbide-to-carbon conversion are carried out with nano-structured carbide compound |
| WO2017184760A2 (en) | 2016-04-20 | 2017-10-26 | West Virginia University Research Corporation | Methods, apparatuses, and electrodes for carbide-to-carbon conversion with nanostructured carbide chemical compounds |
| CN109312479B (en) * | 2016-04-20 | 2021-07-13 | 西弗吉尼亚大学研究公司 | Method, device and electrode for carbide-to-carbon conversion with nanostructured carbide compounds |
| US11332833B2 (en) | 2016-04-20 | 2022-05-17 | West Virginia Research Corporation | Methods, apparatuses, and electrodes for carbide-to-carbon conversion with nanostructured carbide chemical compounds |
| CN108588337A (en) * | 2018-06-07 | 2018-09-28 | 上海应用技术大学 | A kind of nanometer dephosphorization slag former and preparation method thereof suitable for middle high phosphorus molten steel |
| CN108754058A (en) * | 2018-06-07 | 2018-11-06 | 上海应用技术大学 | A kind of nano-hot metal composite desulfurizing agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1210415C (en) | 2005-07-13 |
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