CN1476965A - Production method of multifunctional concrete block - Google Patents
Production method of multifunctional concrete block Download PDFInfo
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- CN1476965A CN1476965A CNA031455646A CN03145564A CN1476965A CN 1476965 A CN1476965 A CN 1476965A CN A031455646 A CNA031455646 A CN A031455646A CN 03145564 A CN03145564 A CN 03145564A CN 1476965 A CN1476965 A CN 1476965A
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Abstract
The production method of multifunctional concrete block includes the following steps: firstly, pouring decorative layer on the bottom portion of the mould, in the formula of the decorative layer the nano titanium dioxide or other nano particles are contained, then pouring a layer of concrete, making vibration or applying pressure to make it be compacted, then placing filling material as heat-insulating material into the mould, then pouring concrete into gap portion of the mould, utilizing vibration or pressurizing equipment to compact them, and forming, curing and demoulding.
Description
The present invention relates to the production method of the multifunctional concrete decorative block that uses in a kind of architectural engineering.
At present the decorative buiding block of concrete that uses in the architectural engineering is by the block machine disposal pressed moulding, rough surface, and decorative effect is relatively poor, does not have antibiosis and self-cleaning and a self light emission function.
The purpose of this invention is to provide a kind of photocatalysis that has, antibiosis and self-cleaning is arranged and absorb the concrete decorative block of waste gas or light-accumulated luminous function.
To achieve these goals, the present invention is earlier at mold bottom cast one deck decorative layer, raw material are nanoparticles such as water, chemical industry auxiliary material, cement, filler, pigment, nano titanium oxide in the decorative layer prescription, mix and stir well even back injection molding, placed about 1 hour behind the vibratory compaction, cast concrete in mould again, the filler that has added function of heat insulation through vibration or pressurization after making it closely knit in the above, again at mould gap cast concrete, the vibration or the pressurization make it closely knit, after the maintenance demoulding product.
In the decorative layer prescription, nano titanium oxide changed into luminescent material when producing luminous concrete segment or add luminescent material and nanoparticle simultaneously.
Nano material in the decorative layer prescription can adopt multiple, as nano titanium oxide, receive silica, nano-aluminium oxide, nano-sized iron oxide etc.The mixture that can add a kind of nanoparticle or several nanoparticles during interpolation.
In addition, can adopt way to obtain the self-cleaning building block of multifunctional antibiotic at common decorative block surface preparation one deck nano thin-film.
Utilize the present invention to produce multifunctional building block, make building block have antibiosis and self-cleaning, multiple function such as light-accumulated luminous is improved block surfaces intensity, weather resisteant etc., can reduce environmental pollution, improves the decoration function of concrete segment.
Fig. 1 is the cutaway view after pouring into a mould decorative layer at mold bottom and making it closely knit.
Fig. 2 is the cutaway view after pouring into a mould the ground floor concrete and making it closely knit.
Fig. 3 is the cutaway view behind the adding filler.
Fig. 4 is at mould gap cast concrete and the cutaway view after making it closely knit.
Shown in Figure 1, earlier at mold bottom cast decorative layer 1.Mould uses mould of plastics.Formula for raw stock is a white cement in the decorative layer: quartz sand: brightener: pigment: nano titanium oxide=1: 1-1.5: 0.02-0.03: 0.01-0.03: 0.01-0.05, and add water stir in right amount the back injection molding.Injection molding thickness is 2-5mm, is placed on vibratory compaction on the shake table then, discharges bubble, under normal temperature laboratory, placed about 1 hour, and time in winter proper extension, the time in summer suitably shortens.Observe its surface and touch its hardness, to be difficult for squishing into suitable with finger with hand.
The layer concrete 2 of in mould, pouring into a mould shown in Figure 2.Concrete strength is placed on vibratory compaction on the shake table then by the relevant concrete hollow block standard preparation of country.Notice during cast that concrete thickness should be behind vibratory compaction and the wall thickness basically identical (30mm) of normal concrete building block.
Shown in Figure 3, in mould, put into filler 3 and 4, filler is selected the GPPS foamed plastics for use.In advance foamed plastics is processed into shape and the volume the same with normal concrete building block hole, and reins in reinforcing bar 5 and 6 with two bands and connect.Measure between them and they and the mould distance of wall all around with ocular estimate, adjust this distance and make this apart from the wall thickness of ordinary concrete hollow block, rein in thick basically identical.
Shown in Figure 4, live foamed plastics with hand, and to mould internal pore part cast concrete 7.With the mould gap water fill with and exceed mould a little, be placed on jolt ramming on the shake table then, the surface is floating.As mould after the jolt ramming less than, should add concrete and jolt ramming is floating once more again.The demoulding after natural curing 3-4 days under normal temperature laboratory, the sale of just can dispatching from the factory in natural curing 7-8 days under normal temperature laboratory after the demoulding.
The mould that should will pour decorative layer when adopting the insert mode of production earlier with positioner is fixed on vibration or the pressurized equipment, to put into mould with the insert of the same shape of normal concrete building block hole by positioner then, insert is used steel weldering system and is processed.Cast concrete in mould is filled with mould then, makes it closely knit with mode of vibration.Promote positioner then and make insert leave mould, in mould, just form like this with normal concrete building block two holes of a size.In hole,, these two holes are filled up GPPS foam-plastic blocks (with obtaining after the discarded foamed plastics pulverizing).Cast concrete again in the mould then, and exceed mould a little, adopt vibration or pressurized equipment to make its closely knit moulding, the demoulding after natural curing 3-4 days under normal temperature laboratory, under normal temperature laboratory natural curing 7-8 days again, the sale of just can dispatching from the factory.
Equipment can adopt the control of electronics, computer mode in process of production, makes it in batching, the time of pressurization, and strength control, what of inventory, the automatic adding of material reaches more accurate, realizes automated production.
When producing the luminous ornament building block, the decorative layer prescription should be white cement: quartz sand: brightener: pigment: luminescent material=1: 1-1.5: 0.02-0.03: 0.01-0.03: 0.01-0.1, prescription can be adjusted according to actual conditions, and an amount of nanoparticle can be added.
Block surfaces after the demoulding prepare one deck receive the material film have many methods to make.As liquid phase deposition, sol-gel process, chemical vapour deposition technique, thermal decomposition method, magnetron sputtering method etc.
When building block is prepared nano thin-film with sol-gel process, take by weighing a certain amount of metatitanic acid fourth fat, it is dissolved in the absolute ethyl alcohol, add acetylacetone,2,4-pentanedione again.Stir and add the mixed liquor of nitric acid and deionized water and absolute ethyl alcohol.More than the quantity of several materials than for metatitanic acid fourth fat: ethanol: water: nitric acid, acetylacetone,2,4-pentanedione=1: 18: 2: 0.02: 0.5.
The colloidal sol that the building block that utilizes equipment to clean is then prepared above putting into, speed with 1.5-2mm/s upwards proposes liquid level, and put into baking oven and be warmed to 450 ℃, make if desired that film is thicker to need to repeat above operation, building block is promoted from colloidal sol and oven dry repeatedly.
Claims (10)
1, a kind of production method of multifunctional concrete building block is by cement, sandstone, adds that chemical industry auxiliary material, pigment produces the building block with decoration function through injection molding.It is characterized in that: at mold bottom cast decorative layer, raw material are water, cement, filler, chemical industry auxiliary material, pigment and titanium oxide nanoparticles in the decorative layer prescription earlier.Pour into a mould a layer concrete more in the above,, make it closely knit, put into packing material then, at mould internal pore part cast concrete, make it closely knit again, after the maintenance demoulding, become product through pressurization and vibration through vibration or pressurization.
2, a kind of production method of multifunctional concrete building block is by cement, sandstone, add that chemical industry auxiliary material, pigment produces the concrete segment with decoration function through injection molding, it is characterized in that: at mold bottom cast decorative layer, the decorative layer prescription is made up of water, cement, filler, chemical industry auxiliary material, pigment, nano titanium oxide earlier.Use a positioner that is connecting the insert of following the general size of normal concrete building block hole then, insert is put into mould by the position of design in advance,, adopt vibration or pressuring method to make it closely knit then at mould internal pore part cast concrete.Promote positioner again, make insert leave mould, put into packing material in the hole of its formation, cast concrete in mould adopts the vibration pressuring method to make it closely knit again, obtains product after the maintenance demoulding.
3, a kind of production method of multifunctional concrete building block is by cement, sandstone, adds that chemical industry auxiliary material, pigment produces the building block with decoration function through injection molding.It is characterized in that: at mold bottom cast decorative layer, raw material are water, cement, filler, chemical industry auxiliary material, pigment and titanium oxide nanoparticles in the decorative layer prescription earlier.Pour into a mould a layer concrete more in the above,, make it closely knit through vibration or pressurization.Put into packing material then, at mould internal pore part cast concrete, make it closely knit again, after the maintenance demoulding, become product through pressurization and vibration.Add an amount of industrial residue (as: flyash, gangue, slag, kiln ash, lime, slag etc.), lightweight aggregate (haydite, pottery sand, expanded perlite, Peng Zhang Chi stone, shale, scoria, float stone, cinder etc.) in the concrete.
4, a kind of production method of multifunctional concrete building block is by cement, sandstone, add that chemical industry auxiliary material, pigment produces the concrete segment with decoration function through injection molding, it is characterized in that: at mold bottom cast decorative layer, the decorative layer prescription is made up of water, cement, filler, chemical industry auxiliary material, pigment, nano titanium oxide earlier.Use a positioner that is connecting the insert of following the general size of normal concrete building block hole then, insert is put into mould by the position of design in advance,, adopt vibration or pressuring method to make it closely knit then at mould internal pore part cast concrete.Promote positioner again, make insert leave mould, put into packing material in the hole of its formation, cast concrete in mould adopts the vibration pressuring method to make it closely knit again, obtains product after the maintenance demoulding.In concrete, add an amount of industrial residue (as: flyash, gangue, slag, kiln ash, lime, slag etc.), lightweight aggregate (haydite, pottery sand, expanded perlite, expansion shin stone, shale, scoria, float stone, cinder etc.).
5, a kind of production method of multifunctional building block is to add that by cement, sandstone chemical industry auxiliary material, pigment produces the multifunctional concrete building block with decoration function through injection molding.It is characterized in that: at mold bottom cast one deck decorative layer, the decorative layer prescription is made up of water, cement, filler, chemical industry auxiliary material, pigment, nano titanium oxide earlier.Adopt vibration or pressurization to make it closely knit.Cast concrete or be mixed with the concrete of industrial residue, lightweight aggregate in the above adopts vibration or pressuring method to make it closely knit again, becomes product after the maintenance demoulding.
6, according to claim 1,2,3,4 or 5 described multifunctional concrete building blocks, it is characterized in that: raw material are in the decorative layer prescription: water, cement, filler, chemical industry auxiliary material, luminescent material or pearlescent pigment.
7, according to claim 1,2,3,4 or 5 described multifunctional concrete building blocks, it is characterized in that: raw material are in the decorative layer prescription: water, cement, filler, chemical industry auxiliary material, luminescent material, add a kind of in pigment and the nanoparticle or the mixture of the two.
8, according to claim 1,2,3,4 or 5 described multifunctional concrete building blocks, it is characterized in that: raw material are in the decorative layer prescription: the mixture of water, cement, filler, chemical industry auxiliary material, pigment, a kind of nanoparticle or several nanoparticles.
9, according to wanting power to require 1,2,3,4 or 5 described multifunctional concrete building blocks, it is characterized in that: in the decorative layer prescription, do not contain nanoparticle, the building block behind the demoulding is covered at its surface preparation one deck nano thin-film or on its surface be coated with a kind of in one deck nanometer titanium dioxide titanium lamina, nano anti-biotic material, nano paint, the luminous paint.
10, it is characterized in that according to claim 1,2,3,4 or 5 described multifunctional concrete building blocks: in the decorative layer prescription, add rare earth or nano anti-biotic material.
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Cited By (9)
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EP1993725A1 (en) * | 2006-03-14 | 2008-11-26 | 3M Innovative Properties Company | Monolithic building element with photocatalytic material |
CN101337827A (en) * | 2008-08-03 | 2009-01-07 | 王格 | Light aggregate foam concrete building blocks and method for manufacturing same |
CN102518275A (en) * | 2011-12-20 | 2012-06-27 | 南京倍立达实业有限公司 | Nano self-cleaning fiber reinforced cement product and production method for same |
CN102531495A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业(集团)股份有限公司 | Concrete road edge stones capable of preventing moss from growing |
CN102837462A (en) * | 2012-09-18 | 2012-12-26 | 武汉龙泰开元沥青有限公司 | Concrete curb with decorative patterns and production method of concrete curb |
CN102875191A (en) * | 2012-08-25 | 2013-01-16 | 马鞍山豹龙新型建材有限公司 | Preparation process for aerated concrete block |
CN103360008A (en) * | 2013-07-25 | 2013-10-23 | 三明学院 | Decoration integrated self-insulation recycled concrete block and manufacturing method thereof |
CN103388295A (en) * | 2013-07-25 | 2013-11-13 | 济南黄河路桥工程公司 | Concrete pavement brick capable of degrading automobile exhaust and preparation method of concrete pavement brick |
CN103397585A (en) * | 2013-07-25 | 2013-11-20 | 济南黄河路桥工程公司 | Preparation method of concrete component capable of absorbing and degrading automobile tail gas |
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2003
- 2003-07-03 CN CNA031455646A patent/CN1476965A/en active Pending
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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US8389109B2 (en) | 2006-03-14 | 2013-03-05 | 3M Innovative Properties Company | Monolithic building element with photocatalytic material |
EP1993725A1 (en) * | 2006-03-14 | 2008-11-26 | 3M Innovative Properties Company | Monolithic building element with photocatalytic material |
EP1993725A4 (en) * | 2006-03-14 | 2013-08-07 | 3M Innovative Properties Co | Monolithic building element with photocatalytic material |
CN101337827A (en) * | 2008-08-03 | 2009-01-07 | 王格 | Light aggregate foam concrete building blocks and method for manufacturing same |
CN102518275A (en) * | 2011-12-20 | 2012-06-27 | 南京倍立达实业有限公司 | Nano self-cleaning fiber reinforced cement product and production method for same |
CN102531495A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业(集团)股份有限公司 | Concrete road edge stones capable of preventing moss from growing |
CN102875191A (en) * | 2012-08-25 | 2013-01-16 | 马鞍山豹龙新型建材有限公司 | Preparation process for aerated concrete block |
CN102837462A (en) * | 2012-09-18 | 2012-12-26 | 武汉龙泰开元沥青有限公司 | Concrete curb with decorative patterns and production method of concrete curb |
CN103360008A (en) * | 2013-07-25 | 2013-10-23 | 三明学院 | Decoration integrated self-insulation recycled concrete block and manufacturing method thereof |
CN103388295A (en) * | 2013-07-25 | 2013-11-13 | 济南黄河路桥工程公司 | Concrete pavement brick capable of degrading automobile exhaust and preparation method of concrete pavement brick |
CN103397585A (en) * | 2013-07-25 | 2013-11-20 | 济南黄河路桥工程公司 | Preparation method of concrete component capable of absorbing and degrading automobile tail gas |
CN103388295B (en) * | 2013-07-25 | 2015-05-13 | 济南黄河路桥工程公司 | Concrete pavement brick capable of degrading automobile exhaust |
CN103397585B (en) * | 2013-07-25 | 2015-05-13 | 济南黄河路桥工程公司 | Preparation method of concrete component capable of absorbing and degrading automobile tail gas |
CN103360008B (en) * | 2013-07-25 | 2015-12-02 | 三明学院 | Decoration integrated self-insulation recycled concrete block and manufacturing method thereof |
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