CN1467337A - Conductive fiber cloth - Google Patents
Conductive fiber cloth Download PDFInfo
- Publication number
- CN1467337A CN1467337A CNA021408483A CN02140848A CN1467337A CN 1467337 A CN1467337 A CN 1467337A CN A021408483 A CNA021408483 A CN A021408483A CN 02140848 A CN02140848 A CN 02140848A CN 1467337 A CN1467337 A CN 1467337A
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- water
- electrocondution slurry
- fibre fabric
- conductive
- conductive fibre
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- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
An electrically conductive fibrous fabric is prepared by spraying the electrically conductive paint onto fibrous fabric made of animal wool, chemical fibres, polyester fibres, or cotton. Said electrically conductive paint is prepared from adhesive, color slurry, flame-retarding agent, softener, far infrared filler and electrically conductive powder. Its advantages are high electrothermal efficiency and stability, high resistance to water, flame, acid and alkali, far infrared nature, and soft handle.
Description
A kind of conductive fibre fabric relates to coating and field of textiles, particularly relates to a kind of conductive processing of fabric.
A kind of conductive fibre fabric, existing conductive fibre fabric is used under the aggravating activities state, coating failure, fault-layer-phenomenon can occur, thereby causes the permanent damages of conductive layer, the decay heating power.
A kind of conductive fibre fabric, the purpose of invention are to overcome the deficiency of existing electrocondution slurry performance, and the new prescription of an electrocondution slurry of invention is produced a kind of conductive fibre fabric.
The electrocondution slurry prescription is made up of adhesive, pigment printing paste, fire retardant, softener, far infrared filler and 6 kinds of components of conductive fine powder.Concrete prescription is as shown in the table:
| Component type | Nomenclature of drug | Consumption (weight %) | Concentration (%) | Specification | Characteristic |
| Adhesive | The acrylic acid resin solution | 7.5～8.5 | 9.37～ 12.14 | Industrial goods | Film formation at low temp, acid and alkali-resistance, bonding |
| Water-based PU resin SE-5050 | 5.5～6 | 7.23～ 9.23 | Industrial goods | Pliable and tough, water-fast washing, wear-resisting wiping | |
| Water-based PU resin SE-5018 | 5.5～6 | 7.23～ 9.23 | Industrial goods | Soft, dry and comfortable, waterproof, backwash elasticity, fabricbase is bonding | |
| Fire retardant | Ammonium phosphate (APP) | 3.5～ 4.75 | 5.55～ 6.37 | Industrial goods | Fire-retardant |
| TCPP | 3.5～4.5 | 5.55～ 6.08 | Industrial goods | Fire-retardant | |
| Water | 26.5～ 32.5 | 13.25～ 16.25 | Running water | Dilution | |
| Softener | The BS-230 amodimethicone | 4.5～5.5 | 6.71～ 7.25 | Industrial goods | Be soluble in hot and cold water, softness |
| The far infrared filler | Ceramic K-95 | ?2.75 | ?3.9～ ?4.7 | Particle diameter: 1 μ m | Contain multiple oxide, good far infrared |
| Conductive filler | Graphite microparticles | ?24～ ?30.75 | ?21.23～ ?26.85 | Particle diameter: 1 μ m | Be difficult for precipitation, satisfactory electrical conductivity |
| Mill base | Yellow slurry | ?7.5～9.5 | ?10.81～ ?12.66 | Industrial goods | Acid and alkali-resistance, fast light, weather-proof |
The preparing process of electrocondution slurry is as follows:
At normal temperatures and pressures, prepare fire retardant earlier, by institute's scalar in the above-mentioned table, get ammonium phosphate, fire retardant mixes the back and drops in the ball mill, add suitable quantity of water, after ball mill grinding 3-6 hour (abrading-ball adopts the stainless steel ball of the specification that varies in size), with adhesive acrylic acid resin solution, water-based PU resin SE-5050, water-based PU resin SE-5018, softener B S-230 amodimethicone, far infrared filler ceramic K-95, conductive filler graphite microparticles and yellow paint mill base and water drop into ball mill in no particular order, grind, milling time 6-16 hour, last discharging is loaded in the Plastic Drum of sealing, need stir during use.
Electrocondution slurry is a grass green, and the multi-functional conductive fibre fabric of the finished product of preparation also is grass green, adopts different mill bases, can change the electrocondution slurry color, thereby satisfies the different color demand of conductive fibre fabric.
The manufacture craft of conductive fibre fabric is as follows:
Adopt the cloth of finished products such as animal fiber, chemical fibre, polyester-cotton blend or cotton textiles or grey cloth as ground, be regardless of color, thickness is equal, and fiber substrate cloth is contained in fixedly on the discharging frame.Pack into after electrocondution slurry stirred in the plastic containers, enter booster pump through plastic conduit, by shower nozzle, with the vaporific fiber substrate cloth surface that evenly is sprayed on; Fiber substrate cloth transmits through mechanical speed stabilizing, transfer rate be 3-6 rice/minute, enter the oven dry of baking and curing passage, the conductive fibre fabric with baking and curing fitly is received on the rewinding frame at last, is finished product.
Also can adopt the mode of wire mark preparation, glue spreader preparation or manual brushing preparation that electrocondution slurry is sprayed on the fiber substrate cloth, also can directly contaminate fiber substrate cloth, form the double-sided overall conduction with this slurry.
According to different purposes and requirement, suitably adjust the consumption of each component of electrocondution slurry, promptly can be made into conductive fibre fabric with different surfaces electricity the approximate ratio of the circumference of a circle to its diameter as calculated by Zu Chongzhi i.e. between 3.1415926 and 3.1415927
Beneficial effect of the present invention is, nontoxic, the environmental protection of used electrocondution slurry; Conductive fibre fabric can be made at normal temperatures and pressures, and technology is simply efficient, can adapt to suitability for industrialized production; The conductive fibre fabric of producing is except that having general fibre fabric sofetening, comfortable feel, can rubbing the characteristic of folding use, have water proofing property, anti-flammability, anti-Acidity of Aikalinity, the characteristic that also has far infrared, and electrothermal efficiency height, unattenuated, not oxidation, the stable performance of switching on for a long time, end temperature is solidified, uniformity of temperature profile.The conductive fibre fabric of finished product is added corresponding electrode, can be made into various electric heating end product, be adapted at 1.2～380 volts of AC and DC voltages and use
A kind of embodiment of conductive fibre fabric is as follows:
Embodiment one:
Electrocondution slurry is filled a prescription as following table:
| Component type | Nomenclature of drug | Consumption (weight %) | Concentration (%) | Specification |
| Adhesive | The acrylic acid resin solution | ????8.5 | ????12.14 | Industrial goods |
| Water-based PU resin SE-5050 | ????6 | ????9.23 | Industrial goods | |
| Water-based PU resin SE-5018 | ????6 | ????9.23 | Industrial goods | |
| Fire retardant | Ammonium phosphate (APP) | ????3.5 | ????5.83 | Industrial goods |
| ???TCPP | ????3.5 | ????5.83 | Industrial goods | |
| Water | ????26.5 | ????13.25 | Running water | |
| Softener | The BS-230 amodimethicone | ????4.5 | ????7.25 | Industrial goods |
| The far infrared filler | Ceramic K-95 | ????2.75 | ????4.7 | Particle diameter: 1 μ m |
| Conductive filler | Graphite microparticles | ????30.75 | ????26.85 | Particle diameter: 1 μ m |
| Mill base | Yellow slurry | ????8 | ????11.59 | Industrial goods |
At room temperature; by institute's scalar in the last table; grind fire retardant earlier, get ammonium phosphate, fire retardant mixing back input ball mill, add suitable quantity of water; grind after 6 hours and shut down; add other components again and grind (drop into order can in no particular order), milling time is no less than 10 hours, and ball milling adopts the stainless steel ball of Φ 42mm, Φ 38mm, Φ 32mm, Φ 28mm, Φ 16mm; last discharging is loaded in the sealed plastic container, and is stand-by.The electrocondution slurry color is a grass green.During the ball milling fire retardant, add 1/4th water, remaining water adds when other components feed intake.
At normal temperatures and pressures, pack into after ground electrocondution slurry stirred in the plastic containers, enter booster pump, evenly drop on the cloth surface so that yi word pattern is vaporific,, enter drying tunnel and carry out baking and curing after mechanical speed stabilizing transmits through shower nozzle through piping.Bake out temperature drying time in the time of 120 ℃ is 5 minutes, and drying time is 8 minutes in the time of 100 ℃, and drying time is 12 minutes in the time of 80 ℃.
Prepared conductive fibre fabric surface resistivity is 6.5 * 10 Ω/◇, can be widely used in heating, the insulation of low pressure articles for daily use, as is applied to low pressure heat supply articles for use such as seat cushions, Clothing with electric heating device, electric blanket, Electric cushion pillow, electric heating shoes and cap.
Embodiment two:
Electrocondution slurry is filled a prescription as following table:
| Component type | Nomenclature of drug | Consumption (%) | Concentration (%) | Specification |
| Adhesive | The acrylic acid resin solution | ????8.5 | ????11.64 | Industrial goods |
| Water-based PU resin SE-5050 | ????6 | ????8.82 | Industrial goods | |
| Water-based PU resin SE-5018 | ????6 | ????8.82 | Industrial goods | |
| Fire retardant | Ammonium phosphate (APP) | ????3.5 | ????5.55 | Industrial goods |
| ????TCPP | ????3.5 | ????5.55 | Industrial goods | |
| Water | ????28 | ????14 | Running water | |
| Softener | The BS-230 amodimethicone | ????4.5 | ????6.92 | Industrial goods |
| The far infrared filler | Ceramic K-95 | ????2.75 | ????4.47 | Particle diameter: 1 μ m |
| Conductive filler | Graphite microparticles | ????29.25 | ????25.54 | Particle diameter: 1 μ m |
| Mill base | Yellow slurry | ????9.5 | ????12.66 | Industrial goods |
The preparation of electrocondution slurry is identical with embodiment one with the manufacture craft of conductive fibre fabric.
The surface resistivity of prepared conductive fibre fabric is 1.2 * 10
2Ω/◇ can be applicable to 24 volts of following combined-voltages and uses, and can be applicable to Sofa with electricity heating device, products such as over blanket.
Embodiment three:
Electrocondution slurry is filled a prescription as following table:
| Component type | Nomenclature of drug | Consumption (%) | Concentration (%) | Specification |
| Adhesive | The acrylic acid resin solution | ????8.5 | ????11.33 | Industrial goods |
| Water-based PU resin SE-5050 | ????6 | ????8.57 | Industrial goods | |
| Water-based PU resin SE-5018 | ????6 | ????8.57 | Industrial goods | |
| Fire retardant | Ammonium phosphate (APP) | ????4 | ????6.06 | Industrial goods |
| ??TCPP | ????3.75 | ????5.72 | Industrial goods | |
| Water | ????29 | ????14.5 | Running water | |
| Softener | The BS-230 amodimethicone | ????4.5 | ????6.71 | Industrial goods |
| The far infrared filler | Ceramic K-95 | ????2.75 | ????4.33 | Particle diameter: 1 μ m |
| Conductive filler | Graphite microparticles | ????27.5 | ????24.33 | Particle diameter: 1 μ m |
| Mill base | Yellow slurry | ????8 | ????10.81 | Industrial goods |
The preparation of electrocondution slurry is identical with embodiment one with the manufacture craft of conductive fibre fabric.
The surface resistivity of prepared conductive fibre fabric is 3 * 10
2Ω/◇ can be applicable to 24～36 volts of combined-voltages and uses, and can be applicable to the greenhouse of agricultural, constant temperature etc.
Embodiment four
Electrocondution slurry is filled a prescription as following table:
| Component type | Nomenclature of drug | Consumption (%) | Concentration (%) | Specification |
| Adhesive | The acrylic acid resin solution | ??7.5 | ????9.37 | Industrial goods |
| Water-based PU resin SE-5050 | ??5.5 | ????7.23 | Industrial goods | |
| Water-based PU resin SE-5018 | ??5.5 | ????7.23 | Industrial goods | |
| Fire retardant | Ammonium phosphate (APP) | ??4.75 | ????6.37 | Industrial goods |
| ??TCPP | ??4.5 | ????6.08 | Industrial goods | |
| Water | ??32.5 | ????16.25 | Running water | |
| Softener | The BS-230 amodimethicone | ??5.5 | ????7.23 | Industrial goods |
| The far infrared filler | Ceramic K-95 | ??2.75 | ????3.9 | Particle diameter: 1 μ m |
| Conductive filler | Graphite microparticles | ??24 | ????21.23 | Particle diameter: 1 μ m |
| Mill base | Yellow slurry | ??7.5 | ????12.5 | Industrial goods |
The preparation of electrocondution slurry is identical with embodiment one with the manufacture craft of conductive fibre fabric.
The surface resistivity of prepared conductive fibre fabric is 1 * 10
3Ω/◇ uses applicable to 36 volts of above combined-voltages, can be applicable to room heating etc.
Claims (4)
1. conductive fibre fabric, it is characterized in that: the cloth of employing animal fiber, chemical fibre, polyester-cotton blend or textile finished product or grey cloth are as ground, fiber substrate cloth is contained in fixedly on the discharging frame, pack into after electrocondution slurry stirred in the plastic containers, enter booster pump through plastic conduit, pass through shower nozzle, with the vaporific fiber substrate cloth surface that evenly is sprayed on, fiber substrate cloth transmits through mechanical speed stabilizing, transfer rate be 3-6 rice/minute, enter the oven dry of baking and curing passage, the conductive fibre fabric with baking and curing fitly is received on the rewinding frame at last; Electrocondution slurry prescription (weight %) is as follows:
(1) adhesive: acrylic acid resin solution 7.5～8.5%
Water-based PU resin SE-5050 5.5～6%
Water-based PU resin SE-5018 5.5～6%
(2) fire retardant: ammonium phosphate 3.5～4.75%
TCPP????????????????????????3.5～4.5％
Water 26.5～32.5%
(3) softener: BS-230 amodimethicone 4.5～5.5%
(4) far infrared filler: ceramic K-95 2.75%
(5) conductive filler: graphite microparticles 24～30.75%
(6) mill base: yellow slurry 7.5～9.5%
The preparation method of electrocondution slurry is: at normal temperatures and pressures, prepare fire retardant earlier, by aforementioned consumption, get ammonium phosphate, fire retardant mixes the back and drops in the ball mill, add suitable quantity of water, after ball mill grinding 3-6 hour, with adhesive acrylic acid resin solution, water-based PU resin SE-5050, water-based PU resin SE-5018, softener B S-230 amodimethicone, far infrared filler ceramic K-95, the conductive filler graphite microparticles, yellow paint mill base and water drop into ball mill in no particular order, grind, milling time is 6-16 hour, last discharging is loaded in the Plastic Drum of sealing, stirs during use.
2. conductive fibre fabric as claimed in claim 1, it is characterized in that: described spraying method adopts the mode of wire mark preparation, glue spreader preparation or manual brushing preparation that electrocondution slurry is sprayed on the fiber substrate cloth, perhaps directly contaminates fiber substrate cloth with electrocondution slurry.
3. conductive fibre fabric as claimed in claim 1 is characterized in that: described electrocondution slurry prescription adopts different pigment printing pastes, changes the electrocondution slurry color.
4. the purposes of the conductive fibre fabric of a claim 1, it is characterized in that: this conductive fibre fabric is used for heating, the insulation of low pressure articles for daily use, and the greenhouse of agricultural heats between constant-temperature house
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021408483A CN1467337A (en) | 2002-07-10 | 2002-07-10 | Conductive fiber cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA021408483A CN1467337A (en) | 2002-07-10 | 2002-07-10 | Conductive fiber cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1467337A true CN1467337A (en) | 2004-01-14 |
Family
ID=34147682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA021408483A Pending CN1467337A (en) | 2002-07-10 | 2002-07-10 | Conductive fiber cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1467337A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101719392B (en) * | 2009-12-30 | 2011-06-29 | 内蒙古大学 | Preparation method of screen printing water-based conductive paste based on carbon-copper composite packing |
| CN102522138A (en) * | 2011-11-15 | 2012-06-27 | 中国科学院上海应用物理研究所 | Carbon nanometer material-cotton fiber composite conductive material, and preparation method and use thereof |
| CN101405453B (en) * | 2006-03-20 | 2012-09-05 | 纳幕尔杜邦公司 | Fabrics comprising ceramic particles and methods for making them |
| CN105469891A (en) * | 2014-08-29 | 2016-04-06 | 上海硅邦电子科技发展有限公司 | Halogen-free flame-retardant mixed liquor and preparation method thereof and flame-retardant conductive fabric and preparation method thereof |
| CN105755819A (en) * | 2016-03-24 | 2016-07-13 | 临沂中瑞防辐射科技有限公司 | Fireproof electromagnetic shielding and radiation protection cloth |
| CN105778673A (en) * | 2014-12-22 | 2016-07-20 | 中国中化股份有限公司 | Aqueous conductive paint, preparation method and applications thereof |
| CN108115066A (en) * | 2017-12-15 | 2018-06-05 | 中国第二重型机械集团德阳万航模锻有限责任公司 | Forging cloth and its application process with heat preservation and lubricating action |
| CN108708184A (en) * | 2018-06-19 | 2018-10-26 | 陈敬学 | A kind of electric heating textile cloth and preparation method thereof and its manufactured underwear |
| CN114381933A (en) * | 2022-01-26 | 2022-04-22 | 开封市中材新型建材有限责任公司 | Conductive polyester fiber surface felt and preparation process thereof |
-
2002
- 2002-07-10 CN CNA021408483A patent/CN1467337A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101405453B (en) * | 2006-03-20 | 2012-09-05 | 纳幕尔杜邦公司 | Fabrics comprising ceramic particles and methods for making them |
| CN101719392B (en) * | 2009-12-30 | 2011-06-29 | 内蒙古大学 | Preparation method of screen printing water-based conductive paste based on carbon-copper composite packing |
| CN102522138A (en) * | 2011-11-15 | 2012-06-27 | 中国科学院上海应用物理研究所 | Carbon nanometer material-cotton fiber composite conductive material, and preparation method and use thereof |
| CN102522138B (en) * | 2011-11-15 | 2013-11-06 | 中国科学院上海应用物理研究所 | Carbon nanometer material-cotton fiber composite conductive material, and preparation method and use thereof |
| CN105469891A (en) * | 2014-08-29 | 2016-04-06 | 上海硅邦电子科技发展有限公司 | Halogen-free flame-retardant mixed liquor and preparation method thereof and flame-retardant conductive fabric and preparation method thereof |
| CN105778673A (en) * | 2014-12-22 | 2016-07-20 | 中国中化股份有限公司 | Aqueous conductive paint, preparation method and applications thereof |
| CN105778673B (en) * | 2014-12-22 | 2019-02-15 | 中国中化股份有限公司 | A kind of waterborne conductive coating and its preparation method and application |
| CN105755819A (en) * | 2016-03-24 | 2016-07-13 | 临沂中瑞防辐射科技有限公司 | Fireproof electromagnetic shielding and radiation protection cloth |
| CN108115066A (en) * | 2017-12-15 | 2018-06-05 | 中国第二重型机械集团德阳万航模锻有限责任公司 | Forging cloth and its application process with heat preservation and lubricating action |
| CN108708184A (en) * | 2018-06-19 | 2018-10-26 | 陈敬学 | A kind of electric heating textile cloth and preparation method thereof and its manufactured underwear |
| CN114381933A (en) * | 2022-01-26 | 2022-04-22 | 开封市中材新型建材有限责任公司 | Conductive polyester fiber surface felt and preparation process thereof |
| CN114381933B (en) * | 2022-01-26 | 2023-12-05 | 开封市中材新型建材有限责任公司 | Conductive polyester fiber surface felt and preparation process thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |