CN1450887A - Antidandruff hair conditioning compositions - Google Patents

Antidandruff hair conditioning compositions Download PDF

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Publication number
CN1450887A
CN1450887A CN00819327.4A CN00819327A CN1450887A CN 1450887 A CN1450887 A CN 1450887A CN 00819327 A CN00819327 A CN 00819327A CN 1450887 A CN1450887 A CN 1450887A
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weight
alkyl
hair
applicable
composition
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戈兰姆·F·卡恩
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Procter and Gamble Ltd
Procter and Gamble Co
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Procter and Gamble Ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

Disclosed is an antidandruff hair conditioning composition comprising by weight: (a) from about 0.001% to about 10% of a polysilixane resin, wherein at least one substituent group of the resin possesses delocalised electrons; (b) from about 0.01% to about 10% of a surfactant; (c) from about 0.01% to about 10% of a viscosifying agent; (d) from about 0.001% to about 5% of salicylic acid; (e) from about 1% to about 75% of a C1 to C6 aliphatic alcohol; and water.

Description

Antidaudruff hair conditioning composition
Affiliated field
The present invention relates to contain the Wo 2008069000 of dandruff removing agent.Particularly, the Wo 2008069000 that the present invention relates to provide anti-dandruff effect and salubrious sense to have opsonic action simultaneously.
Background technology
At present, develop several different methods and be used for conditioning hair.These methods comprise from back coating hair conditioner such as non-washing type and the eccysis formula product of having one's hair wash, to attempting to obtain to clean conditioning shampoo with opsonic action simultaneously by single product.
Although the easy shampoo of conditioner would rather be selected to comprise by some consumer, considerable consumer more is ready to select for use more conventional conditioner prescription, and such prescription separates with the hair washing step and uses separately, generally uses after hair washing.Conditioning formulations can be eccysis formula product or non-washing type product, and can be made into emulsified body, cream frost, gel, spray and mousse form.This class is willing to more to select for use that the consumer of conventional conditioner prescription payes attention to is its stronger opsonic action, or payes attention to the convenience that can change the conditioning consumption according to the situation or the number of hairs of hair.
The favourable part of Antidaudruff hair conditioning composition is that said composition can be used for hair after the hair washing stage, thereby expects that it can effectively deposit on scalp.Particularly the non-washing type Wo 2008069000 is more favourable, because dandruff removing agent wherein can be retained in without rinsing on the hair, therefore can more effectively be deposited on the hair.The non-washing type compositions is more convenient in addition, because consumer's application product at any time need not to wait rinsing.
Simultaneously, the known conventional method that opsonic action is provided is by adopting hair conditioner such as cationic surfactant, cationic polymer, the polysiloxanes conditioner, hydrocarbon and other organic oil, and solid aliphatic series composition such as aliphatic alcohol, and their mixture provides.This class conditioner of known majority can provide various conditioning effects to hair, as moisture feeling, flexibility and antistatic property, but also known meeting makes hair have sticking or greasy or wax as feel.
Therefore, the Wo 2008069000 that contains above-mentioned conditioner can provide conditioning effect, but also can make hair have sticking or greasy or wax as feel.Therefore particularly, the non-washing type Wo 2008069000 feels stronger as sticking or greasy or the wax of hair because without rinse step, can making.Feel it is that most consumers is undesirable as sticking or greasy or the wax, particularly wish by hair conditioner composition can reach the consumer of anti-dandruff effect for those all the more so because this class consumer wishes that compositions also can provide salubrious usability (refreshing feeling).
In addition, care composition, particularly non-washing type compositions usually are difficult to coating, thereby can deposit too much conditioner unevenly.This can cause hair dirty, have coated sensation and make hair softening and lack texture.This is using compositions repeatedly and is being not obvious especially when having one's hair wash every day.
Recently, proposition can be used for hair conditioner with polyorganosiloxane resin.GB-A-2 has for example described the siloxysilicates of low viscosity organic functional in 297,757 (in conjunction with in the present invention as a reference), and has provided it and be used for the example of Wo 2008069000.
Based on foregoing, still need to provide the Antidaudruff hair conditioning composition that can reach anti-dandruff effect and salubrious sense and conditioning effect.
Also need to provide the Antidaudruff hair conditioning composition that can reach antipruritic and anti-dandruff effect.
Also wish to make and be easy to the compositions that acts on hair equably and deposit conditioner.
All advantages of the present invention and excellent effect never were provided in the prior art.
Summary of the invention
The present invention relates to a kind of Antidaudruff hair conditioning composition, wherein contain following component by weight:
(a) about 0.001% to about 10% polyorganosiloxane resin, wherein at least one substituent group of resin contains delocalized electron (delocalized electrons);
(b) about 0.001% to about 10% surfactant;
(c) about 0.01% to about 10% viscosity modifier (viscosifying agent);
(d) about 0.001% to about 5% salicylic acid;
(e) about 1% to about 75%C 1-C 6Aliphatic alcohol; And water.
Compositions of the present invention can provide the anti-dandruff effect, antipruritic effect, clearly sense and conditioning effect.Compositions of the present invention is easy to act on equably hair, and can make the conditioner uniform deposition, and viscosity and greasy feeling reduce.
Detailed Description Of The Invention
Though the present invention is summarised as the claims that spell out and know the qualification protection domain, believes and can understand the present invention better by following description.
All lists of references are all in full in conjunction with in the present invention as list of references of the present invention.Quoting of these documents is not to recognize that any definite content of the prior art is the claimed content of the present invention.
Here said " comprising " is meant and can adds other step and other composition that can not influence final result.This term comprises term " by ... form " and " substantially by ... form ".
Unless otherwise indicated, all percentage ratios, part and ratio are all to account for present composition gross weight.Therefore all these weight of ingredients listed do not comprise being purchased the carrier and the by-product that may comprise in the raw material all in its active quantities.
Here the term of Cai Yonging " non-washing type " is meant the Wo 2008069000 that does not have rinse step when using.Therefore, the non-washing type compositions generally is retained on the hair, eccysis when having one's hair wash in user's cleaning course next time.Generally comprise in the non-washing type care composition and be lower than about 5% anion surfactant, and generally comprise and be lower than about 5% non-ionic surface active agent.
Poly-silicon hydrogen alkane resin
Comprise polyorganosiloxane resin in the Wo 2008069000 of the present invention, wherein comprise delocalized electron at least one substituent group on the resin.Generally comprise the polyorganosiloxane resin of about 0.001% (weight) in this Wo 2008069000 of the present invention to about 10% (weight), preferred about 0.005% (weight) is to about 5% (weight), more preferably from about 0.01% (weight) is to about 2% (weight), and more preferably from about 0.1% (weight) is to about 1% (weight).
Polyorganosiloxane resin is highly cross-linked polysiloxanes system.Preparation during polyorganosiloxane resin by in monofunctional or two functional group's silane or both, introducing the trifunctional base and four functional group's silane produce crosslinked.Know in this area, the required crosslinking degree of preparation polyorganosiloxane resin will be different with being incorporated into concrete silane unit in the polyorganosiloxane resin.In general, think that the silicone materials that can form rigidity or the rigid siloxanyl monomers unit that contains capacity trifunctional base and four functional groups (thereby can take place full cross-linked) of filming after the drying is a polyorganosiloxane resin.Oxygen atom specifically is the sign of the crosslinked level of silicone materials with the ratio of silicon atom.It is generally acknowledged among the present invention that each silicon atom correspondence is polyorganosiloxane resins at least about the silicone materials of 1.1 oxygen atoms.Preferably, oxygen atom is at least about 1.2: 1.0 with the ratio of silicon atom.The silane that is used to prepare polyorganosiloxane resin comprises: monomethyl, dimethyl, trimethyl, single phenyl, diphenyl, aminomethyl phenyl, ethylphenyl, propyl group phenyl, mono-vinyl and methyl ethylene chlorosilane, and tetrachloro silicane.
The polyorganosiloxane resin that is applicable to this should have the substituent group that comprises delocalized electron.This substituent group can be selected from alkyl, aryl, alkoxyl, alkaryl, aralkyl, alkoxy aryl, aryloxy alkyl, and their mixture.Preferred aryl groups, aralkyl and alkaryl substituent group.More preferably alkaryl and aralkyl substituent group.Also more preferably alkaryl substituent group, particularly 2-phenyl propyl.Though wherein at least one substituent group should comprise delocalized electron, this resin of the present invention generally also contains the substituent group that other does not contain delocalized electron.These other substituent groups comprise hydrogen, hydroxyl, alkyl, alkoxyl, amino-functional base, and their mixture.
Preferred alkyl substituent group, particularly methyl substituents.Therefore, the present invention especially preferably adopts dimethyl (2-phenyl propyl) silyl ester.
Here the term of Cai Yonging " aryl " is meant and contains one or more homoatomic rings or heterocyclic functional group.Aryl functional group of the present invention can be unsubstituted or be substituted, and generally contains 3-16 carbon atom.Preferred aryl groups comprises: phenyl, and naphthyl, cyclopentadienyl group, anthryl, pyrene, pyridine, pyrimidine, but be not limited only to these.
Here the term of Cai Yonging " alkyl " is meant straight or branched hydrocarbon saturated or undersaturated, that be substituted or be unsubstituted, wherein contains 1-10 carbon atom, preferred 1-4 carbon atom.Therefore term " alkyl " comprises the alkenyl that contains 2-8 carbon atom, preferred 2-4 carbon atom and comprises 2-8 carbon atom, the alkynyl of preferred 2-4 carbon atom.Preferred alkyl comprises methyl, ethyl, and propyl group, isopropyl and butyl, but be not limited only to this.More preferably methyl, ethyl and propyl group.
Here the term of Cai Yonging " alkaryl " is meant the substituent group that contains moieties and aryl moiety, wherein moieties and silicone resin bonding.
Here the term of Cai Yonging " aralkyl " is meant the substituent group that contains aryl moiety and moieties, wherein aryl moiety and silicone resin bonding.
Can discern silicone materials and polyorganosiloxane resin easily according to the name of the abbreviation in " MDTQ " well known in the art nomenclature.In this system, polysiloxanes is described according to the different silicones monomeric unit that constitutes polysiloxanes.In brief, M represents monofunctional unit (CH 3) 3SiO 0.5D represents two functional group unit (CH 3) 2SiO; T represents trifunctional base unit (CH 3) SiO 1.5And Q represents four functional group's cell S iO 2The 1-apostrophe of unit symbol, M ' for example, D ' and T ', representative contains the siloxane unit of one or more non-methyl substituents, and each appearance all should specifically define.Therefore the polyorganosiloxane resin that preferably is applicable to this comprises at least one and has substituent M ', D ' or the T ' functional group who contains delocalized electron.The substituent group that preferably is applicable to this as mentioned above.In the MDTQ system, for the mol ratio of different units, itself or be target form under the symbol, represent all kinds of monomeric sums (or its meansigma methods) in the polysiloxanes, or the form that spells out, with the together complete description silicone materials of molecular weight.
The polyorganosiloxane resin that preferably is applicable to this is M ' Q resin, more preferably M ' 6Q 3, M ' 8Q 4And M ' 10Q 5, M ' 12Q 6Resin, and their mixture.
Preferred L ' Q resin is to comprise those of at least one group that contains delocalized electron, and it is substituted on each M ' functional group.Other substituent group is an alkyl in the preferred resin, particularly methyl.
The viscosity of polyorganosiloxane resin in the time of 25 ℃ that is applicable to this preferably is lower than about 5000mm 2s -1, more preferably less than about 2000mm 2s -1, also more preferably less than about 1000mm 2s -1, again more preferably less than about 600mm 2s -1Can adopt Cannon-Fenske conventional viscosity meter (ASTM D-445) to measure viscosity.
The example that is applicable to this commercially available polyorganosiloxane resin comprises the styryl polysiloxanes 1170-3100 available from General Electric.
The background material of polysiloxanes, comprise that the segmentation discussion to the preparation of polysiloxane fluid, natural gum and resin and polysiloxanes is found in Encyclopaedia of Polymer Science andEngineering (the 15th volume, the 2nd edition, 204-308 page or leaf, John Wiley ﹠amp; Sons, Inc., 1989), in conjunction with in the present invention as a reference.
Background material about suitable polyorganosiloxane resin comprises that the detailed description to its preparation is found in United States Patent (USP) 5,539,137; 5,672,338; 5,686,547 and 5,684,112.
Surfactant
Comprise surfactant in the Wo 2008069000 of the present invention.Surfactant can be selected from: cationic surfactant, anion surfactant, non-ionic surface active agent, amphoteric surfactant, and their mixture.Preferred Wo 2008069000 of the present invention comprises non-ionic surface active agent.Generally contain the surfactant of 0.001% (weight) of having an appointment in the Wo 2008069000 of the present invention to about 10% (weight), preferred about 0.005% (weight) is to about 5% (weight), more preferably from about 0.01% (weight) is to about 2% (weight), and more preferably from about 0.1% (weight) is to about 1% (weight).
Non-ionic surface active agent
Preferably comprise non-ionic surface active agent in the Wo 2008069000 of the present invention.
Ionic surfactant pack is drawn together those chemical compounds through hydrophilic oxyalkylene class and hydrophobic organic compound condensation generation, and hydrophobic organic compound can be the chemical compound of aliphatic series or alkyl aromatic character.
The preferred non-limiting example that is applicable to the non-ionic surface active agent in the shampoo Compositions of the present invention comprises following component:
(1) the polyoxyethylene condensation substance of alkyl phenol, for example its alkyl contains about 6 to the alkyl phenol of about 20 carbon atoms and the condensation product of oxygen ethylene formation, wherein the alkyl of alkyl phenol is the configuration of straight or branched, and the content of described oxygen ethylene is that every 1mol alkyl phenol about 10 is to about 60mol oxygen ethylene;
(2) those that obtain by the product and the condensation of oxygen ethylene of oxypropylene and ethylenediamine;
(3) the straight or branched configuration contains about 8 to the aliphatic alcohol of about 18 carbon atoms and the condensation product of oxygen ethylene formation, cocoanut oil alcohol oxygen ethylene condensation substance for example, wherein every 1mol cocoanut oil alcohol contains about 10 to about 30mole oxygen ethylene, and cocoanut oil alcohol partly contains about 10 to about 14 carbon atoms;
(4) formula [R 1R 2R 3N → O] the long-chain tertiary amine oxide, R wherein 1Comprise alkyl, thiazolinyl or monohydroxy alkyl contain 8 carbochains to about 18 carbon atoms of having an appointment, 0 to about 10 oxygen ethylene moieties and 0 to about 1 glyceryl part, R 2And R 3Contain about 1 to about 3 carbon atoms and 0 to about 1 hydroxyl, methyl for example, ethyl, propyl group, ethoxy or hydroxypropyl;
(5) the long-chain oxidation tertiary phosphine of formula [RR ' R " P → O]; wherein R comprises alkyl; thiazolinyl or monohydroxy alkyl; contain 8 carbochains to about 18 carbon atoms of having an appointment; 0 to about 10 oxygen ethylene moieties and 0 to 1 glyceryl part, and R ' and R " all is to contain about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms.
(6) long-chain dialkyl sulphoxide, comprising: contain 1 a short-chain alkyl or a hydroxyalkyl (normally methyl) and a long-chain hydrophobic group to about 3 carbon atoms, comprise and contain 8 alkyl approximately to about 20 carbon atoms, thiazolinyl, hydroxyalkyl, or the ketone alkyl, 0 to about 10 oxygen ethylene moieties and 0 to 1 glyceryl part;
(7) alkyl polysaccharide (APS) surfactant (for example alkyl poly glucoside), the example sees United States Patent (USP) 4,565,647, combination in the present invention as a reference in full, wherein disclose the APS surfactant, comprised in this surfactant containing about 6 to the hydrophobic group of about 30 carbon atoms with as the polysaccharide (for example polysaccharide glycosides) of hydrophilic group; Randomly, having polyalkylene oxide groups is connected hydrophobic group with hydrophilic group; And alkyl (that is hydrophobic part) can be saturated or undersaturated straight or branched, warp or (for example hydroxyl or the ring) that be unsubstituted; Preferred material is an alkyl polyglucoside, and it can be available from Henkel, ICI Americas and Seppic; And
(8) polyoxyethylene alkyl ether is suc as formula RO (CH 2CH 2O) nShown in the H those, and Polyethylene Glycol (PEG) glyceryl fatty ester are suc as formula R (O) OCH 2CH (OH) CH 2(OCH 2CH 2) nShown in the OH those, wherein n is 1 to about 200, preferably be about 20 to about 100, and R contains about 8 alkyl to about 22 carbon atoms.
Preferably the polyethyleneglycol derivative with the glyceride described in above-mentioned (8) is used as non-ionic surface active agent in the present composition.
The polyethyleneglycol derivative that is applicable to this glyceride comprises water solublity and the polyethyleneglycol derivative that is applicable to the various glyceride of Wo 2008069000.That the polyethyleneglycol derivative that is applicable to this glyceride comprises is single-, two-and Three-glycerol ester and their mixture.
One class is applicable to that the polyethyleneglycol derivative of this glyceride is those shown in general formula (I):
Figure A0081932700091
Wherein ethoxylation degree n is about 4 to about 200, preferably is about 5 to about 150, be more preferably 20 to about 120, and wherein R comprises aliphatic group, contains in the group to have an appointment 5 to about 25 carbon atoms, preferably contains about 7 to about 20 carbon atoms.
The polyethyleneglycol derivative of the glyceride that is suitable for can be the polyethyleneglycol derivative of castor oil hydrogenated.For example, PEG-20 castor oil hydrogenated, PEG-30 castor oil hydrogenated, PEG-40 castor oil hydrogenated, the PEG-45 castor oil hydrogenated, PEG-50 castor oil hydrogenated, PEG-54 castor oil hydrogenated, PEG-55 castor oil hydrogenated, PEG-60 castor oil hydrogenated, PEG-80 castor oil hydrogenated and PEG-100 castor oil hydrogenated.What preferably be applicable to the present composition is the PEG-60 castor oil hydrogenated.
The polyethyleneglycol derivative of the glyceride that other is suitable for can be stearic polyethyleneglycol derivative.For example, PEG-30 stearate, PEG-40 stearate, PEG-50 stearate, PEG-75 stearate, PEG-90 stearate, PEG100 stearate, PEG-120 stearate and PEG-150 stearate.What preferably be applicable to the present composition is the PEG-100 stearate.
The content of the polyethyleneglycol derivative of glyceride preferably accounts for 0.001% (weight) of the present composition to about 10% (weight) in the Wo 2008069000 of the present invention, preferably be about 0.005% (weight) to about 5% (weight), be more preferably 0.01% (weight) to about 2% (weight), more preferably from about 0.1% (weight) is to about 1% (weight).
Preferably, the glycol ether with above (3) or (8) described aliphatic alcohol is used as non-ionic surface active agent in the present composition.
The aliphatic alcohol glycol ether that is applicable to this comprises all kinds of aliphatic alcohol glycol ethers that are applicable in the hair composition.The non-limiting example of aliphatic alcohol glycol ether comprises: cetyl polyoxyethylene ether (ceteth) series compound such as ceteth-1 to ceteth-45, and it is the glycol ether of spermol, wherein the number of the existing ethylene glycol part of numeral; Stearyl polyoxyethylene ether (steareth) series compound such as steareth-1 to 100, it is the glycol ether of stearyl alcohol, wherein the number of the existing ethylene glycol part of numeral; Spermaceti/stearyl polyoxyethylene ether ceteareth-1 to ceteareth-50, and be the glycol ether of spermaceti/stearyl alcohol, spermaceti/stearyl alcohol is a kind of fatty alcohol mixture that mainly contains spermol and stearyl alcohol, wherein the number of the existing ethylene glycol part of numeral; The polyoxyethylene ether of branched-chain alcoho, branched-chain alcoho such as octyldodecanol, lauryl pentadecanol, hexyldecanol and isooctadecanol; And their mixture.That preferably be applicable to this is ceteareth-20.
The content of aliphatic alcohol glycol ether preferably accounts for 0.001% (weight) of total composition to about 10% (weight) in the Wo 2008069000 of the present invention, preferably be about 0.005% (weight) to about 5% (weight), be more preferably 0.01% (weight) to about 2% (weight), more preferably from about 0.1% (weight) is to about 1% (weight).
Cationic surfactant
Can contain one or more cationic surfactants in the present composition.The cationic surfactant that is applicable to the present composition contains amino or quaternary ammonium part.The cationic surfactant that is applicable to this is found in the following document: McCutcheon ' s that M.C. publishing company publishes, Detergents ﹠amp; Emulsifiers (North America version 1979); People such as Schwarz work Surface ActiveAgents Their Chemistry and Technology (New York:Interscience publishing house, 1949); United States Patent (USP) 3,155,591 (Hilfer, on November 3rd, 1964 authorized); United States Patent (USP) 3,929,678 (people such as Laughlin, December was authorized on the 30th in 1975); United States Patent (USP) 3,959,461 (people such as Bailey, on May 25th, 1976 authorized); United States Patent (USP) 4,387,090 (authorize June 7 nineteen eighty-three for Bolich, Jr.).
The cationic surfactant material that contains quaternary ammonium salt that is applicable to this is those compositions shown in following general formula:
Figure A0081932700101
R wherein 1-R 4Be to contain 1 aliphatic group approximately independently of one another, or contain 1 aromatics approximately, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or alkaryl to about 22 carbon atoms to about 22 carbon atoms; And X is into salt anionic, for example is selected from halogen, (for example chlorine, bromine), acetate, citrate, lactate, ethanol acid group, phosphate radical, nitrate anion, sulfate radical, and alkyl sulfate group.Except that comprising carbon atom and hydrogen atom, also can comprise ehter bond in the aliphatic group, and other group such as amino.Long-chain aliphatic group for example contains 12 carbon atoms or more high-grade long-chain aliphatic group approximately, and it can be saturated or undersaturated.Preferred especially mono-long chain (list-C for example 12-C 22, preferred C 12-C 18, more preferably C 16Aliphatic series, preferred alkyl), two-short chain (C for example 1-C 3Alkyl, preferred C 1-C 2Alkyl) quaternary ammonium salt.
The salt of primary aliphatic amine, secondary fatty amine and uncle's fatty amine also is the cationic surfactant material that is suitable for.The alkyl of these amine preferably contains 12 approximately to about 22 carbon atoms, and can replace or be unsubstituted.These amine that are applicable to this comprise the amino propyl group dimethylamine of stearoyl, the diethyllaminoethyl stearmide, dimethyl stearylamine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, myristyl amine, tridecyl amine, ethyl stearylamine, N-Adeps Bovis seu Bubali propane diamine, ethoxylation (5mol ethylene oxide) stearylamine, dihydroxy ethyl stearylamine, and eicosyl two lauryl amines.The amine salt that is suitable for comprises the halogen thing, acetate, phosphate, bromate, citrate, lactate and alkyl sulfate.This class salt comprises: hydrochloric acid stearylamine, Semen sojae atricolor amine chloride, formic acid stearylamine, N-Adeps Bovis seu Bubali propane diamine dichloride, the amino propyl-dimethyl amine citrate of stearoyl, cetyl trimethyl ammonium chloride, and two cetyl alkyl dimethyl ammonium chlorides.What preferably be applicable to the present composition is the cetyl trimethyl ammonium chloride.Be applicable to that cationic amine surfactant of the present invention sees: United States Patent (USP) 4,275,055 (Nachtigal waits the people, on June 23rd, 1981 authorized) is in conjunction with in the present invention as a reference.
If contain cationic surfactant, then its content preferably account for total composition about 0.1% (weight) to about 10% (weight), more preferably from about 0.25% (weight) is to about 5% (weight), more preferably from about 0.3% (weight) is to about 0.7% (weight).
Anion surfactant
Can comprise one or more anion surfactants in the present composition.If comprise, the content of anion surfactant is lower than about 10% (weight) in the preferred present composition, preferably is lower than about 5% (weight), more preferably less than about 2% (weight), more preferably less than about 1% (weight), more preferably 0% (weight).Here " anion surfactant " of Cai Yonging is meant anion surfactant and the zwitterionic surfactant or the amphoteric surfactant that have the anionic group that links to each other under compositions pH, or their mixture.
Viscosity modifier
Also contain viscosity modifier (viscosity modifiers) in the present composition.The various viscosity modifiers of Wo 2008069000 that are applicable to all are applicable to this.If comprise viscosity modifier, its content generally accounts for about 0.01% (weight) of total composition to about 10% (weight), and preferred about 0.05% (weight) is to about 5% (weight), and more preferably from about 0.1% (weight) is to about 3% (weight).The indefiniteness tabulation of the viscosity modifier that is suitable for is found in CTFA International Cosmetic IngredientDictionary and Handbook (the 7th edition, Wenninger and McEwen compile, international cosmetics, toilet articles and fragrance association, company, Washington, D.C., 1997), in conjunction with in the present invention as a reference.
The viscosity modifier that is applicable to this comprises the shearing sensibility viscosity modifier.Here the term of Cai Yonging " the shearing sensibility viscosity modifier is meant " can form the viscosity modifier of the compositions of viscosity reduction under low shear rate.Shear rate (s -1) may be defined as material velocity (ms -1) with the ratio of the distance (m) that begins by stationary object.Shear rate is lower than about 250s -1Can be called as " low shear rate ".The various shearing sensibility viscosity modifiers of hair nursing that are applicable to all are applicable to this.But the viscosity modifier that preferably is applicable to the present composition is a shear rate is lower than about 100s -1, more preferably less than about 50s -1The time viscosity reduce those.In addition, preferred shearing sensibility viscosity modifier is to be 50s in shear rate -1Can make composition viscosity reduce more than about 30%, preferred reduce more than about 50%, more preferably reduce more than about 70%, more preferably reduce more than about 80% those.
The viscosity modifier that preferably is applicable to this is can form viscosity also to those compositions of the compositions of aqueous phase electrolyte sensitivity, and these compositions are called as " brine sensitivity viscosity modifier " hereinafter.Background material about the characteristic of brine sensitivity viscosity modifier is found in American Chemical SocietySymposium Series ((1991), 462 volumes, 101-120 page or leaf), in conjunction with in the present invention as a reference.Variously be applicable to that the brine sensitivity viscosity modifier in the Wo 2008069000 all is applicable to this.
The example of the viscosity modifier that is suitable for comprises synthetic hectorite (hectorite), carboxylic acids anionic polymer/copolymer, carboxylic acids anion cross linked polymer/copolymer.Preferably be applicable to this carboxylic acids anion cross linked polymer and copolymer.More preferably carboxylic acids anion cross-linked copolymer, but be not limited only to this.
The synthetic hectorite that is applicable to this is synthesizing flaky silicate such as sodium magnesium silicate.The example of the synthetic hectorite that is suitable for comprises available from those of the commodity Laponite by name of Laporte Plc. (United Kingdom).
The carboxylic acids anionic copolymer that is applicable to this can be the cross-linked copolymer of carboxylic acid and alkyl carboxylic acid ester's hydrophobically modified, and has amphiphilic nature.These carboxylic acids anionic copolymers can be obtained by following composition copolymerization: 1) carboxylic acid monomer, as acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, fumaric acid, .beta.-methylacrylic acid or α-Lv Bingxisuan, 2) wherein alkyl contains 1 carboxylate to about 30 carbon atoms, and preferred 3) cross-linking agent shown in the following formula:
Figure A0081932700121
R wherein 1Be H or contain about 1 alkyl to about 30 carbon atoms; Y 1, be O independently of one another, CH 2O, COO, OCO,
Figure A0081932700131
Or
Figure A0081932700132
R wherein 2Be H or contain about 1 alkyl to about 30 carbon atoms; And Y 2Be selected from (CH 2) M ", (CH 2CH 2O) mOr (CH 2CH 2CH 2O) m, m wherein " is 1 to about 30 integer.
The carboxylic acids anionic copolymer that is applicable to this is the acrylic acid/alkyl acrylate that is shown below:
Figure A0081932700133
R wherein 2Be H or contain about 1 alkyl, wherein at least one R independently to about 30 carbon atoms 2Be H, R 1Definition as above, n, n ', m and m ' are integers, wherein n+n '+m+m ' is about 40 to about 100, n " to be 1 to about 30 integer, and should to make the molecular weight of copolymer be about 5000 to about 3,000,000 to the qualification of P.
Can add in the nertralizer and carboxylic acids anionic copolymer of the present invention.The non-limiting example of these nertralizers comprises sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine (DIPA), amino methyl propanol, trometamol, tetrahydroxypropyl ethylenediamine, and their mixture.
The non-limiting example of the carboxylic acids anion viscosity modifier that is suitable for, comprise that its preparation details is found in United States Patent (USP) 3,940,351; 5,288,814; 5,349,030; 5,373,044 and 5,468,797, all in conjunction with in the present invention as a reference.Carboxylic acids anion viscosity modifier comprises the following product that is purchased: available from B.F.Goodrich, Cleveland, OH, the trade mark of USA is called Pemulen TR-1, Pemulen TR-2, Carbopol 980, and Carbopol 981, Carbopol ETD-2020, the product of CarbopolETD-2050 and Carbopol Ultrez 10.Preferred Carbopol ETD-2020, Carbopol ETD-2050 and Carbopol Ultrez 10, particularly Carbopol Ultrez 10.
For improving coating, reduce viscosity and improving glossy viewpoint, the viscosity modifier that especially preferably is applicable to this is a carboxylic acids anion viscosity modifier, as Carbopol Ultrez 10.
Dandruff removing agent
Contain dandruff removing agent in the present composition.The general dandruff removing agent that adopts safe and effective amount.The consumption of dandruff removing agent accounts for about 0.001% (weight) of total composition to about 5% (weight), and preferred about 0.01% (weight) is to about 5% (weight), and more preferably from about 0.03% (weight) is to about 1% (weight).
Comprise salicylic acid in the present composition as dandruff removing agent.Remove salicylic acid itself, be applicable to that this salicylic acid also comprises Salicylate such as sodium salicylate and salicyclic acid derivatives.But for the unfavorable viewpoint that reacts to each other that other component in anti-dandruff effect and antipruritic effect and reduction and the compositions is provided, preferred salicylic acid itself.
Except that salicylic acid, also comprise other anti-dandruff composition in the compositions of the present invention.The various dandruff removing agents that are applicable to Haircare composition all are applicable to this.The non-limiting example of the dandruff removing agent that is suitable for comprise two (oxidation of 2-mercaptopyridine) zinc (zinc pyrithione, ZPT), sulfur (sulphur), selenium sulfide, coal tar, piroctone oleyl amine (piroctone olamine), ketoconazole and Climbazole (climbazole).
C 1-C 6Aliphatic alcohol
The optional C that contains in the present composition 1-C 6, preferred C 2-C 3, more preferably C 2Aliphatic alcohol.The content of aliphatic alcohol generally accounts for about 1% (weight) of total composition to about 75% (weight), preferred about 10% (weight) is to about 40% (weight), more preferably from about 15% (weight) is to about 30% (weight), and more preferably from about 18% (weight) is to about 26% (weight).
Water
Generally also contain water in the present composition.The content of water generally accounts for about 25% (weight) of total composition to about 99% (weight), and preferred about 50% (weight) is to about 98% (weight), and more preferably from about 65% (weight) is to about 95% (weight).
Sensitizer
Also can contain sensitizer (sensate) in the conditioner for hair compositions of the present invention.Here the term of Cai Yonging " sensitizer " is meant the composition that is used for can causing behind the skin appreciable changed condition, for example, hotness, creeping chill, sensations such as salubrious sense, but be not limited only to this.
The consumption of sensitizer preferably accounts for about 0.001% (weight) of total composition to about 10% (weight), and more preferably from about 0.005% (weight) is to about 5% (weight), and more preferably from about 0.01% (weight) is to about 1% (weight).
Be applicable to that the various sensitizers in the hair care composition all are applicable to this.The indefiniteness of the sensitizer that is suitable for enumerated being found in GB-B-1315626, GB-B-1404596 and GB-B-1411785 are all in conjunction with in the present invention as a reference.Be applicable to that preferably the sensitizer in the present composition is a Camphora, menthol, I-isopulegol, ethyl menthane carbonyl amide (carboxamide) and trimethyl isopropyl butanamide.
Optional components
Also can contain multiple optional components in the conditioner for hair compositions of the present invention.Some non-limiting example of these optional components is as follows.
Cation opsonizing agent
Also can contain one or more cationic polymer conditioners in the present composition.The cationic polymer conditioner is preferably water miscible.If contain cationic polymer, its content preferably accounts for about 0.001% (weight) of total composition to about 20% (weight), and more preferably from about 0.005% (weight) is to about 10% (weight), and preferred about 0.01% (weight) is to about 2% (weight).
Can be fully soluble in water when " water-soluble cationic polymer " is meant under 25 ℃ with concentration 0.1% water-soluble (distilled water or analog), form through the basic clear solutions of perusal.Preferred polymers can dissolve fully that to form concentration be 0.5% basic settled solution, and more preferably concentration is 1.0%.
Here the term of Cai Yonging " polymer " should comprise by a kind of monomer or the material that obtained by two kinds of monomers (that is copolymer) or multiple monomer polymerization.
The weight average molecular weight of cationic polymer of the present invention generally is at least about 5,000, generally is at least about 10,000, and is lower than about 100000000.Preferably, molecular weight is about 100,000 to about 2000000.Cationic polymer generally comprises the cation nitrogen moiety, as quaternary ammonium or cation amino part, and their mixture.
Cationic charge density preferably is at least about 0.1meq/g, more preferably is at least about 0.5meq/g, more preferably is at least about 1.1meq/g, most preferably is at least about 1.5meq/g.Usually, for practical purposes, the cationic charge density of cationic polymer is lower than about 7meq/g, preferably is lower than about 5meq/g, more preferably less than about 3.5meq/g, more preferably less than about 2.5meq/g.Cationic nitrogen content in the cationic polymer can adopt Kjeldahl (American Pharmacopeia-chemical test-＜461〉N2 method 11).The cationic charge density of polymer can be by Goddard and Gruber at " polymer science in cosmetics and the personal-care supplies and technology " (Principles of Polymer Scienceand Technology in Cosmetics and Personal Care, Marcel Dekker, New York, 1999, ISBN 0-8247) the 259th page of described content drawn by the cationic nitrogen cubage.Those skilled in the art can understand that the charge density of some amido polymer can be different with the isoelectric point, IP of pH and amino.Under the pH condition, charge density should be in above-mentioned limited range in use.
Satisfy the requirement of dissolubility standard as long as be applicable to the anionic counter-ion of cationic polymer.The counter ion counterionsl gegenions that are suitable for comprise: halogen (for example, Cl, Br, I, or F, preferred Cl, Br, or I), sulfate radical and methylsulfate.Also being suitable for of other, above-mentioned enumerating is nonexcludability.
The cation nitrogen moiety generally is present on the part of overall monomeric unit of cationic hair conditioning polymer with the substituent group form.Therefore cationic polymer can comprise that the monomeric unit that quaternary ammonium or cationic amine replace is referred to herein as the unitary copolymer of the unitary non-cationic of spacer monomers, terpolymer etc. with other.These polymer are known in the art, and majority is found in CTFAInternational Cosmetic Ingredient Dictionary and Handbook (the 7th edition, Wenninger and McEwen compile, The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C., 1997).
The cationic polymer that is suitable for for example comprises: have cationic amine or quaternary ammonium functional group's the vinyl monomer and the copolymer of water solublity spacer monomers, wherein the water solublity spacer monomers for example is: acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone.Monomer by alkyl and dialkyl group replacement preferably contains C 1-C 7Alkyl, more preferably C 1-C 3Alkyl.Other spacer monomers that is suitable for comprises vinyl esters, vinyl alcohol (being obtained by the hydrolysis of polyvinyl acetate base ester), maleic anhydride, propylene glycol and ethylene glycol.
According to the concrete kind and the pH of compositions, wherein cationic amine can be primary amine, secondary amine or tertiary amine.General preferred primary amine and tertiary amine, particularly tertiary amine.
The vinyl monomer polymerizable that amine replaces forms the form of amine, can randomly change into ammonium through quaternization then.Amine also can be similarly through quaternized after forming polymer.For example, the tertiary amine functional group can be taken place quaternized with the reactant salt of formula R ' X, and R ' is a short-chain alkyl in the formula, preferred C 1-C 7Alkyl, more preferably C 1-C 3Alkyl, and X is the anion that can form water soluble salt with quaternary ammonium.
The cation amino and the quaternary ammonium monomer that are suitable for for example comprise by the vinyl compound of following replacement: the dialkyl aminoalkyl acrylate, the dialkyl aminoalkyl methacrylate, the alkyl monosubstituted amino alkyl acrylate, the alkyl monosubstituted amino alkylmethacrylate, trialkyl methacryloxypropyl alkylammonium salt, trialkyl acryloyloxyalkyl ammonium salt, the diallyl quaternary ammonium salt, and contain vinyl quaternary ammonium monomer such as the pyridine that cation contains azo-cycle, imidazoles and quaternized ketopyrrolidine, alkyl vinyl imidazoles for example, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.And these monomeric moieties are low alkyl group preferably, as C 1-C 3Alkyl, more preferably C 1-C 2Alkyl.Be applicable to that the vinyl monomer that this amine replaces comprises the dialkyl aminoalkyl acrylate, dialkyl aminoalkyl methacrylate, dialkyl aminoalkyl acrylamide and dialkyl aminoalkyl Methacrylamide, wherein alkyl C preferably 1-C 7Alkyl is more preferably C 1-C 3Alkyl.
Cationic polymer of the present invention can comprise the mixture derived from the monomer of amine and/or quaternary ammonium-substituted and/or the monomeric monomeric unit of compatible spacer.
The cationic hair conditioning polymer that is suitable for for example comprises: the copolymer (being called Polyquaternium-16 by cosmetics, toilet articles and fragrance association " CTFA " on industry) of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (for example chloride), as can be available from BASFWyandotte Corp. (Parsippany, NJ, trade mark USA) is called those products of LUVIQUAT (for example LUVIQUAT FC 370); The copolymer of 1-vinyl-2 ketopyrrolidine and dimethyl amino ethyl methacrylate (on industry, being called Polyquaternium-11) by CTFA, as available from Gaf Corporation (Wayne, NJ, trade mark USA) are called those products of GAFQUAT (for example GAFQUAT 755N); The polymer of cation diallyl quaternary ammonium, for example comprise: the copolymer of dimethyl diallyl ammonium chloride and acrylamide and dimethyl diallyl ammonium chloride and homopolymer, (CTFA) is called as Polyquaternium 7 and Polyquaternium 6 respectively on industry; Contain the inorganic acid salt of the amino-Arrcostab of the homopolymer of unsaturated carboxylic acid of 3-5 carbon atom and copolymer, see United States Patent (USP) 4,009,256.
The cationic polymer that preferably is applicable to this is the cationic polymer and the copolymer of polysaccharide.Be applicable to that cationic polysaccharide of the present invention comprises those polymer and derivants based on 5 or 6 carbon sugar, it for example can be through becoming water miscible with the ethylene oxide reaction.These polymer can pass through several arrangements and polymer-bound, as 1, and 4-α, 1,4-β, 1,3-α, 1,3-β and 1,6 key.Monomer can be the straight or branched geometric configuration.
The non-limiting example of the cationic polysaccharide that is suitable for comprises based on those of following ingredients: cellulose; hydroxy alkyl cellulose; starch; hydroxyalkyl starch; polymer based on Ah (La Bai) sugar monomer; derived from the xylose polymer of monomers; polymer derived from fucose; polymer derived from fructose; based on containing the polymer of acid sugar as galacturonic acid and glucuronic acid; based on amine sugar breast as galactosamine and the glycosamine polymer of acetyl glucosamine particularly; polymer based on 5 yuan of rings or 6 yuan of cyclopolyols; based on the polymer of galactose, based on the mannose polymer of monomers, and based on the polymer of the galactomannan copolymer that is called as guar gum.
Be preferred for making hair to have gloss and conditioning effect, and can reduce the cationic polymer of the cationic polymer, particularly cellulose derivative that are based on cellulose and acetyl glucosamine derivant of viscosity and greasy.The non-limiting example of the cationic polymer that is suitable for is that those are available from Amerchol Corp. (Edison, NJ, USA) salt that the epoxide reaction that is replaced by hydroxyethyl-cellulose and trimethyl ammonium obtains, (CTFA) is called as Polyquaternium 10 on industry.The background material of these polymer and preparation thereof is found in United States Patent (USP) 3,472, and 840 (Stone, on October 14th, 1969 authorized) are in conjunction with in the present invention as a reference.The cationic cellulose of other type comprises the polymer quaternary ammonium salt that the epoxide reaction of hydroxyethyl-cellulose and the replacement of lauryl dimethyl ammonium obtains, (CTFA) is called as Polyquaternium 24 on industry, can be available from AmercholCorp. (Edison, NJ, USA) and the polyquaternary ammonium salt that obtains of hydroxyethyl-cellulose and diallyldimethylammonium chloride reaction, (CTFA) is called as Polyquaternium 4 on industry, can be available from NationalStarch (Salisbury, NC, USA).
The cation copolymer that is applicable to saccharide of the present invention comprises those that contain following sugar monomer: glucose, galactose, mannose, arabinose, xylose, fucose, fructose, glycosamine, galactosamine, glucuronic acid, galacturonic acid, and 5 yuan of rings or 6 yuan of cyclopolyols.The methylol, ethoxy and the hydroxypropyl derivatives that also comprise above-mentioned sugar.When sugar in the copolymer each other during bonding, they can be through multiple arrangement mode bonding, as 1, and 4-α, 1,4-β, 1,3-α, 1,3-β and 1,6 key.Any other monomer also is suitable for, as long as the polymer of gained is applicable in the hair nursing field.Monomeric other non-limiting example that is applicable to this comprises dimethyl diallyl ammonium chloride, dimethyl amino ethyl methacrylate, diethyl diallyl ammonium chloride, N, N-diallyl, N, N-dialkyl group ammonium halide, and analog.
As mentioned above, cationic polymer of the present invention is water miscible.But this does not also mean that it must dissolve in the compositions.But the preferred cationic polymer dissolves in said composition, or dissolves in the complex coacervate that is made of cationic polymer and anionic materials in the compositions.Cationic polymer can form complex coacervate with anion surfactant or the optional anionic polymer (for example kayexalate) that adds in the present composition.
Long-chain alcohol
Also can contain long-chain alcohol in the compositions of the present invention.Here the term of Cai Yonging " long-chain alcohol " is meant the alcohol of the catenation that contains 8 or 8 above carbon atoms.They can be straight or brancheds, saturated or undersaturated.Used alcohol generally contains 8-30 carbon atom.
The various long-chain alcohols of hair nursing that are applicable to all are applicable to this.But preferably contain C 10-C 22Alcohol of carbochain and composition thereof more preferably contains C 12-C 20Alcohol of carbochain and composition thereof also more preferably contains C 16-C 18Alcohol of carbochain and composition thereof.Excellent straight chain saturated alcohols.
The alcohol that preferably is applicable to this is to contain monohydroxy part (monohydric alcohol), those of dihydroxy part (dihydroxylic alcohols) or trihydroxy part (trihydroxylic alcohol).More preferably monohydric alcohol.
The mixture that contains long-chain alcohol in the preferred present composition.More preferably C 16And C 18The mixture of long-chain alcohol.More preferably C 16With C 18Ratio be 3: 2.
If contain long-chain alcohol in the present composition, its content preferably accounts for about 0.1% (weight) of total composition to about 20% (weight), and more preferably from about 0.25% (weight) is to about 10% (weight), and most preferably from about 0.5% (weight) is to about 5% (weight).
The polysiloxanes conditioner
Can randomly contain other polysiloxanes conditioning component in the present composition.The polysiloxanes conditioning component can comprise Y 7175, non-volatile polysiloxanes, or their mixture.Known in the art, " non-volatile " that adopted herein is meant the silicone materials that does not at room temperature almost have or do not have tangible vapour pressure.
The polysiloxanes conditioning component that is applicable to this can be a polysiloxane fluid, polysiloxanes natural gum, polyorganosiloxane resin and/or their mixture.The polysiloxanes hair conditioner that some is suitable for, and be used for the non-limiting example of the optional suspending agent of these polysiloxanes can be referring to WO-A-94/08557 people such as () Brock, United States Patent (USP) 5,756,436 (people such as Royce), United States Patent (USP) 5,104,646 (people such as Bolich Jr.), United States Patent (USP) 5,106,609 (people such as Bolich Jr.) and the U.S. issue patent 34,584 (people such as Grote), British patent 849 again, 433, it is all in conjunction with in the present invention as a reference.
The polyorganosiloxane resin that is applicable to this comprises that the background material of its preparation details is found in United States Patent (USP) 5,539,137; 5,672,338; 5,686,547 and 5,684,112.
The polysiloxane fluid that is applicable to the present composition comprises polysiloxane oil, and it is that viscosity is lower than 1000000mm in the time of 25 ℃ 2s -1, preferably be about 5-1000000mm 2s -1, 10-600 more preferably, 000mm 2s -1, be more preferably 10-500000mm 2s -1, be most preferably 10-350000mm 2s -1Flowable silicone materials.Can measure viscosity by glass capillary tube viscometer, method is as being disclosed in as described in the test method CTM0004 of Dow Corning company (on July 20th, 1970).
The polysiloxane oil that is suitable for comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-aralkyl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer, and their mixture.Other insoluble non-volatile polysiloxane fluid with conditioning characteristic also is suitable for.
The polysiloxane oil that is applicable to said composition comprises poly-alkyl or the poly-aryl siloxanes that is shown below:
Figure A0081932700201
Wherein R is aliphatic, preferred alkyl or thiazolinyl or aryl, and R can replace or be unsubstituted, and x is 1 to about 8000 integer.The R group that is unsubstituted that is suitable for comprises: the aromatics and the aryl that replace with halogen that alkoxyl, aryloxy group, alkaryl, aralkyl, alkyl amino, and replace through ether, hydroxyl replace.The R base that is suitable for also comprises cationic amine and quaternary ammonium group.
Aliphatic series or aryl at the siloxanes chain substitution can be various structures, as long as the polysiloxanes of gained at room temperature is still fluid, hydrophobic, and nonirritant, avirulence and other detrimental effect when being used for hair, with other component compatibility in the Wo 2008069000 of the present invention, under regular service conditions and storage requirement, be chemically stable, and be insoluble to compositions of the present invention, and can get final product by conditioning hair.
Two R groups on the silicon atom in each silicone monomers unit can be identical or different.Preferred two R groups are identical groups.
Preferred alkyl and alkenyl group are C 1-C 5Alkyl and thiazolinyl, more preferably C 1-C 4, C most preferably 1-C 2Contain other alkyl-, thiazolinyl-or the group of alkynyl (as alkoxyl, alkaryl, and alkyl amino) aliphatic series part can be a straight or branched, and preferably contains 1-5 carbon atom, more preferably contains 1-4 carbon atom, also more preferably 1-3 carbon atom, most preferably 1-2 carbon atom.As mentioned above, the R substituent group here also can contain the amino-functional base, alkyl amino for example, and it can be primary amine, secondary amine, tertiary amine or quaternary ammonium.These comprise single-, two-and trialkyl amino and alkoxy amino, wherein the chain length of aliphatic series part preferably as mentioned above.The R substituent group also can be replaced by other group, these other groups such as halogen (for example chlorine, fluorine, and bromine), halogenated aliphatic group and aryl, and hydroxyl (for example hydroxyl replace aliphatic group).The halo R group that is suitable for can comprise, for example, and three halos (preferred fluorine) alkyl, as-R 1-C (F) 3, R wherein 1Be C 1-C 3Alkyl.The example of these polysiloxanes comprises poly-methyl-3,3,3 trifluoropropyl siloxanes.
The R base that is suitable for comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxanes is a polydimethylsiloxane, poly-di-ethyl siloxane, and PSI.Polydimethylsiloxane is particularly preferred.Other R base that is suitable for comprises: methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.3 R groups that are positioned at polysiloxanes end-blocking place can be identical or different.
Spendable non-volatile poly-alkylsiloxane fluid comprises for example polydimethylsiloxane.This class siloxanes for example can be available from the Viscasil R of General Electric company and SF 96 series of products, and available from Dow Corning 200 series of products of Dow Corning.
Spendable poly-alkaryl siloxanes fluids comprises for example PSI.This class siloxanes for example can be available from the SF 1075 aminomethyl phenyl fluids of General Electric company or available from the 556 used for cosmetic fluids of Dow Corning.
Spendable polyether siloxane copolymer comprises the polydimethylsiloxane (for example Dow Corning DC-1248) of for example polypropylene oxide modification, although the mixture of ethylene oxide or ethylene oxide and propylene oxide also is suitable for.For insoluble polysiloxanes, the content of ethylene oxide and polypropylene oxide must be enough low, dissolves in the water and the present composition to prevent it.
Other polysiloxane fluid that is suitable for being used in the polysiloxanes conditioner is insoluble silicone gums (silicone gum).This class glue be in the time of 25 ℃ viscosity more than or equal to the polysiloxane material of 1000000 centistokes.Silicone gums is found in United States Patent (USP) 4,152,416; The Chemistry and Technology of Silicones (New York:Academic publishing house, 1968) of Noll and Walter work; And see General Electric Silicone Rubber Product Data Sheet SE30, and SE 33, SE 54 and SE 76, and these are all in conjunction with in the present invention as a reference.The weight average molecular weight of silicone gums (mass molecular weight) generally is higher than about 200000, generally be about 200000 to about 1,000,000, its instantiation comprises polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer, and their mixture.
The polysiloxanes conditioner also can comprise polydimethylsiloxane glue, and (viscosity is greater than about 1,000,000 centistoke) and polydimethyl siloxane oil (viscosity is about 10 to about 100,000 centistoke) mixture, wherein the ratio of glue and fluid is about 30: 70 to about 70: 30, preferred about 40: 60 to about 60: 40.
The excursion of the number average bead diameter of optional polysiloxanes component is very wide, and it be there is no particular restriction, decides according to prescription and/or required characteristic.The number average bead diameter that is preferred among the present invention is about 10 nanometers usually to about 100 microns, is more preferably 30 nanometers to about 20 microns.
The background material of polysiloxanes comprises that the discussion of the manufacture method of polysiloxane fluid, glue and resin and polysiloxanes partly is found in polymer science and technology encyclopedia (15 volumes, the 2nd edition, 204-308 page or leaf, John Wiley ﹠amp; Sons, Incorporated, 1989).
Other optional components
Can contain in the compositions of the present invention and multiplely be suitable for making compositions to be more suitable for making up or attractive in appearance or make it have other optional components of other effect.These conventional optional components are well known to those skilled in the art.
Multiple supplementary element can be added in the present composition.These compositions comprise: other hair conditioning composition such as pantothenylol, pantethine (panthetine), pantothenic acid (pantotheine), general benzyl ethyl ether (panthenylethyl ether), and their mixture; Vitamins hair conditioning composition such as vitamin E (DL-α tocopherol acetate), vitamin B (as nicotiamide), and their mixture; Other solvent is as hexanediol; Hair fixing copolymer those as in WO-A-94/08557, describing, the document is in conjunction with in the present invention as a reference; Detersive surfactant such as anion, nonionic, both sexes and zwitterionic surfactant; Additional viscosity modifiers and suspending agent, as xanthan gum, guar gum, hydroxyethyl-cellulose, triethanolamine, methylcellulose, starch and starch derivatives; The methanol amide of viscosity modifier such as long-chain fatty acid is as coconut monoethanol amide; Crystalline suspending agent; Pearlescent additive such as glycol distearate; Opacifier such as polystyrene; Antiseptic such as phenyl phenol, benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea and hydantoin; Polyvinyl alcohol; Ethanol; The pH regulator agent, as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is general as potassium acetate and sodium chloride; Coloring agent is as FD﹠amp; C or D﹠amp; Any in the C dyestuff; Hair oxidation (bleaching) agent, as hydrogen peroxide, perboric acid and persulfate; The hair Reducing agent is as thioglycolate salt; Essence; Chelating agen is as tetrasodium ethylenediamine tetraacetate; Antioxidant/ultraviolet filtering agent such as octyl methoxycinnamate, benzophenone-3 and DL-α tocopherol acetate, and polymeric plasticizer, as glycerol, adipic acid diisobutyl ester, butyl stearate, and propylene glycol.The consumption of these optional members generally accounts for about 0.001% (weight) of total composition respectively to about 10.0% (weight), and preferred about 0.01% (weight) is to about 5.0% (weight).
Product form
Hair conditioner composition of the present invention can be formulated into various product forms, comprises the cream frost, gel, and aerosol or non-aerosol type foam, mousse and spray, but be not limited only to this.The preparation mousse can adopt propellant such as propane, butane, pentane, dimethyl ether, hydrofluorocarbons, CO when foam and spray 2, N 2O, or do not add propellant (in pumping formula spray or pumping formula foam packing, adopting air) especially as propellant.
Usage
Wo 2008069000 of the present invention can be used to nurse one's health human hair according to a conventional method.Can be with the compositions of effective dose, generally be about 1g to about 50g, preferably about 1g extremely about 20g be applied on the hair.Generally comprise during the set of applications compound with hands and finger or suitable instrument such as comb or hair brush compositions thoroughly is coated on the hair, to guarantee good coating.Then compositions is retained on the hair, when remaining into consumer's hair washing next time usually.
Therefore, the method for preferred hair conditioning may further comprise the steps: (a) Wo 2008069000 with effective dose is coated on hair moistening, moist or that do, (b) with hands and finger or suitable instrument compositions thoroughly is coated on the hair.
The step that also can comprise usefulness water rinse hair that this method is optional.
Embodiment
Following examples further specify the preferred specific embodiments in the scope of the invention.These embodiment only are used for illustrative purposes, and should not think limitation of the invention, because under the condition that does not deviate from the spirit or scope of the present invention, can carry out multiple modification to the present invention.All the components is all with the weight percent meter of active component.
Example I-III (% weight)
I (gel) II (gel) III (gel)
Carbopol?Ultrez?10 *1 0.50 0.50 - A
Carbopol?934 *2 - - 0.50 A
Polyquaternium?10 *3 - - 0.05 A
Ethanol (degeneration) 25.00 20.00 25.00 B
The PEG-60 castor oil hydrogenated *4 0.15 0.10 0.15 B
Ceteareth-20 *5 0.15 - 0.15 B
Natural menthol *6 0.5 - 0.5 B
Natural camphor *7 0.05 - 0.05 B
The I-isopulegol *8 - 0.2 - B
The piroctone oleyl amine *9 - 0.5 - B
Salicylic acid 0.1 0.1 0.01 B
Two (oxidation of 2-mercaptopyridine) zinc *10 - - 0.1 B
Nicotiamide *11 0.05 0.05 0.05 B
Vitamin E *12 0.05 0.05 0.05 B
Hydrolytic collagen *13 0.01 0.01 0.01 B
Pantothenylol *14 0.05 0.05 0.05 B
General benzyl ethyl ether *15 0.5 0.5 0.05 B
Octyl methoxycinnamate 0.09 0.09 0.09 B
Benzophenone-3 0.09 0.09 0.09 B
Dl-α-tocopherol acetate 0.03 0.03 0.03 B
Lactic acid - - 0.05 B
Essence 0.35 0.25 0.35 B
Triethanolamine 0.40 0.30 0.40 C
Polydimethylsiloxane *16 - - 0.05 C
2-phenyl propyl M ' Q resin *17 0.5 1.0 0.5 C
Water In right amount In right amount In right amount
The component definition
*1 Carbopol Ultrez 10:Carbopol Ultrez 10 is available from BF Goodrich
*2 Carbopol 934:Carbopol 934 are available from BF Goodrich
*3 Polyquaternium 10:Polymer JR30M are available from Amerchol
*4 PEG, 60 castor oil hydrogenated: Cremophor RH-60, available from BASF
*5 Ceteareth-20:JH200 are available from Dr Kolb
*6 natural menthols: the menthol crystal, available from Jiangsu
*7 natural camphors: natural camphor powder BP80, available from Shanghai Essential Oils
*8 I-isopulegols: Coolant P, available from Takasago
*9 piroctone oleyl amine: Octopirox are available from Hoechst
*10 pairs of (oxidation of 2-mercaptopyridine) zinc: two (oxidation of 2-mercaptopyridine) zinc U/2, available from ArchBiocides
*11 nicotiamide: available from Roche
*12 vitamin Es: Emix-d is available from Eisai
*13 hydrolytic collagens: Peptein 2000 is available from Hormel
*14 pantothenylol: available from Roche
*15 general benzyl ethyl ethers: available from Roche
*16 polydimethylsiloxane: DC200 is available from Dow Corning
*17 2-phenyl propyl M ' Q resins: styryl polysiloxanes 1170-3100, available from General Electric
Preparation method
All A compositions are added in the entry, fully stir until forming homogeneous solution at ambient temperature.With all the components B mixed together, add then in the homogeneous solution of composition A.The all the components that adds C then, and fully mix gained solution.
EXAMPLE IV-V (% weight)
IV V (gel)
Carbopol?Ultrez?10 *1 - 0.40 A
Acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer *2 0.60 - A
Spermol *3 1.00 - B
Stearyl alcohol *4 1.00 1.50 B
Ammonium lauryl sulfate *5 - 0.20 B
The PEG-100 stearate *6 0.13 - B
Polyquaternium?10 *7 - 0.10 C
Phenyl M ' Q resin *8 - 0.10 C
2-phenyl propyl M ' Q resin *9 0.50 - C
Ethanol (degeneration) 30.00 15.00 C
The I-isopulegol *10 0.50 0.05 C
Salicylic acid 0.1 0.1 C
Two (oxidation of 2-mercaptopyridine) zinc *11 0.03 - C
Vitamin E *12 0.05 0.05 C
Hydrolytic collagen *13 0.01 0.01 C
Pantothenylol *14 0.05 0.05 C
General benzyl ethyl ether *15 0.05 0.05 C
Octyl methoxycinnamate 0.10 - C
Benzophenone-3 0.02 - C
Dl-α-tocopherol acetate 0.03 0.03 C
Lactic acid 0.15 0.10 C
Phenyl phenol 0.20 0.20 C
DMDM Hydantoin - 0.05 C
EDTA four sodium - 0.30 C
Essence 1.00 0.80 C
Triethanolamine 0.40 0.20 D
Water In right amount In right amount
The component definition
*1 Carpopol Ultrez 10:Carbopol Ultrez 10 is available from BF Goodrich
*2 acrylate/acrylic acid C10-30 alkyl ester cross-linked polymer: Pemulen TR2, available from BF Goodrich
*3 spermols: Konol series, available from Shin Nihon Rika
*4 stearyl alcohols: Konol series, available from Shin Nihon Rika
*5 ammonium lauryl sulfate: Empicol AL30, available from Alright ﹠amp; Wilson
*6 PEG100 stearate: Myrj 59 are available from ICI Surfactants
*7 Polyquaternium 10:Polymer JR30M are available from Amerchol
*8 phenyl M ' Q resin: according to GB-A-2,297,775 explanation preparation
*9 2-phenyl propyl M ' Q resins: styryl polysiloxanes 1170-3100, available from GeneralElectric
*10 I-isopulegols: Coolant P, available from Takasago
*11 pairs of (oxidation of 2-mercaptopyridine) zinc: two (oxidation of 2-mercaptopyridine) zinc U/2, available from ArchBiocides
*12 vitamin Es: Emix-d is available from Eisai
*13 hydrolytic collagens: Peptein 2000 is available from Hormel
*14 pantothenylol: available from Roche
*15 pantothenylol ethylethers: available from Roche
Preparation method
All A compositions is water-soluble, be heated to 80 ℃ then.Add all B compositions.Simultaneously through recirculation this solution is cooled to 30 ℃ by plate type heat exchanger then through high shear mixing.Cooldown rate remained on 1.0 to 1.5C/ minutes, added about 50% components D then, and promptly triethanolamine mixes this solution until homogenizing.Add all the components C then, and gained solution is reached uniform distribution through high shear mixing until grain graininess.Stop then recirculation prevent in and in the complete process shear stress destroy product.Add remaining D composition, until reaching specific pH and viscosity.
The disclosed specific embodiments of the foregoing description I-V has multiple advantage.For example, they can provide anti-dandruff effect, antipruritic effect, clearly sense and conditioning effect, and they are easy to act on hair, and can make the conditioner uniform deposition, can reduce viscosity and greasy feeling simultaneously.
It should be understood that the embodiments described herein and specific embodiments only are used for illustrative purposes, and those skilled in the art under the conditions without departing from the spirit and scope of the present invention can multiple improvement of corresponding proposition or change.

Claims (7)

1. Antidaudruff hair conditioning composition, wherein contain following component by weight:
(a) about 0.001% to about 10% polyorganosiloxane resin, wherein at least one substituent group of this resin contains delocalized electron;
(b) about 0.001% to about 10% surfactant;
(c) about 0.01% to about 10% viscosity modifier;
(d) about 0.001% to about 5% salicylic acid;
(e) about 1% to about 75% C 1-C 6Aliphatic alcohol; And water.
2. the Antidaudruff hair conditioning composition of claim 1 wherein also contains the sensitizer of 0.001% weight to about 10% weight of having an appointment.
3. the Antidaudruff hair conditioning composition of claim 1, wherein glass or plastic containers.
4. the Antidaudruff hair conditioning composition of claim 1, the polyorganosiloxane resin substituent group that wherein contains delocalized electron is selected from aryl, aralkyl and alkaryl.
5. the Antidaudruff hair conditioning composition of claim 4, the polyorganosiloxane resin substituent group that wherein contains delocalized electron is selected from alkaryl.
6. the Antidaudruff hair conditioning composition of claim 1, wherein the viscosity of polyorganosiloxane resin in the time of 25 ℃ is lower than about 5000mm 2s -1
7. the Antidaudruff hair conditioning composition of claim 1, wherein said composition is the non-washing type compositions.
CN00819327.4A 2000-03-17 2000-03-17 Antidandruff hair conditioning compositions Pending CN1450887A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2000/007301 WO2001070180A1 (en) 2000-03-17 2000-03-17 Antidandruff hair conditioning compositions

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CN1450887A true CN1450887A (en) 2003-10-22

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JP (1) JP2003527406A (en)
CN (1) CN1450887A (en)
AU (1) AU2000239004A1 (en)
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WO (1) WO2001070180A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0318160D0 (en) * 2003-08-02 2003-09-03 Ssl Int Plc Parasiticidal composition
US9642788B2 (en) * 2014-04-25 2017-05-09 The Procter & Gamble Company Shampoo composition comprising gel matrix and histidine

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2227864A1 (en) * 1973-05-04 1974-11-29 Poukanitcharov Tzeko Dermatological compsn to treat allergic conditions - esp. dandruff, contg. salicylic acid, resorcinol, chloral hydrate and tinctures of veratrium and benjoin
GB2245279B (en) * 1990-06-20 1993-04-07 Unilever Plc Shampoo composition
WO2000006101A1 (en) * 1998-07-30 2000-02-10 The Procter & Gamble Company Hair care compositions

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EP1263393A1 (en) 2002-12-11
AU2000239004A1 (en) 2001-10-03
WO2001070180A1 (en) 2001-09-27
MXPA02009062A (en) 2003-03-12
JP2003527406A (en) 2003-09-16

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