CN1194658C - Hair care compositions - Google Patents
Hair care compositions Download PDFInfo
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- CN1194658C CN1194658C CNB998089745A CN99808974A CN1194658C CN 1194658 C CN1194658 C CN 1194658C CN B998089745 A CNB998089745 A CN B998089745A CN 99808974 A CN99808974 A CN 99808974A CN 1194658 C CN1194658 C CN 1194658C
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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Abstract
According to the present invention there is provided a hair care composition comprising: (a) cationic saccharide polymer or copolymer wherein the cationic polymer has a charge density of greater than about 1.5 meq/g, preferably greater than about 1.6 meq/g, more preferably greater than about 1.7 meq/g, even more preferably greater than about 1.8 meq/g; and (b) less than about 5 %, preferably less than about 2 %, more preferably less than about 1 %, even more preferably 0 %, by weight, of anionic surfactant. The compositions of the present invention provide good conditioning/shine to the hair with reduced feelings of tackiness and greasiness.
Description
Technical field
The present invention relates to Haircare composition.More specifically, the present invention relates to provides good conditioning effect/gloss to hair, the Haircare composition of cohesiveness and oleaginous sensation minimizing simultaneously.
Background technology
Hair can be subjected to the multiple effect that may cause infringement usually.These effects comprise with shampoo washing hair, rinsing, drying, heating, combing, typing, hair-waving, painted, to be exposed to various natural environment medium.Thereby because the removal of natural oil, other natural conditioning and moist composition in the wearing and tearing of hair surface, hair, hair often is in drying, coarse, matt or fly to stick up the state of (frizzy).
People have developed several different methods and have alleviated the problems referred to above.These methods comprise to be used super soft shampoo composite, uses and attempt to be cleaned simultaneously and the hair conditioning shampoo of conditioning hair and use Wo 2008069000 such as rinsing type (rinse-off) product and leave (leave-on) product by single product.
The leave Haircare composition provides additional benefit than other scheme.For example, owing to conditioning component is stayed on the hair, so the leave compositions is more economical and the time that work is longer.Needn't wait and rinse this product because consumer can use this product at any time, so it uses this product more convenient.And this product can be applied on the hair portion that needs most the conditioning effect.
Cationic polysaccharides known in this field can be used for providing the conditioning effect.Referring to, as WO-A-97/35542, WO-A-97/35545 and WO-A-97/35546, all these document descriptions the purposes of cationic polysaccharides in conditioning shampoo composition.GB-A-2,211,192 have described the purposes of cationic polysaccharides in rinsing type care composition.DE-A-4,326,866 have described the compositions of the cation polysaccharide that uses before having one's hair cut.JP-54 138 133 has described the hair product compositions that contains polypeptide and cationic cellulose.But also known these cationic polysaccharides cause and are clamminess or cohesiveness.This may make consumer feel that hair is dirty or the oils and fats sense is arranged, and especially uses when not having the leave care composition of rinse step.
It has surprisingly been found that now cationic charge density has brought improved gloss/conditioning benefit greater than cationic saccharide base polymer and the copolymer of about 1.5meq/g to hair, adhesion sense simultaneously and oils and fats sense reduce.
Do not wish to be bound by any theory, it is believed that high-cation charge density makes polymer have more substantivity (substantive) to hair, thereby the good conditioning effect is provided.Negative charge on cation group and the hair interacts.Because the frequency that occurs along the described cation group of polymer increases, so binding site occurs more frequently.More frequent interaction may " be drawn main polymer chain " closely, and itself and hair fiber are more closely connected each other, thereby reduces the degree of depth of hydrocarbon layer, reduces itself and other surface and as the skin on the finger interactional trend takes place.Therefore, because polymer and hair connect each other closely, make the adhesion sense reduce and increase the gloss of hair.
Summary of the invention
According to the present invention, Haircare composition is provided, it comprises:
(a) cationic saccharide base polymer or copolymer, wherein the charge density of cationic polymer greater than about 1.5meq/g, be preferably greater than about 1.6meq/g, more preferably greater than about 1.7meq/g even more preferably greater than about 1.8meq/g; With
(b) approximately less than 5%, preferred approximately less than 2%, more preferably from about less than 1% even the anion surfactant of more preferably 0% weight.
The cohesiveness of compositions of the present invention and oil reduction provide good conditioning/gloss benefit simultaneously.
Unless stated otherwise, all concentration of the present invention and ratio are all in the weight of Haircare composition.
Unless stated otherwise, all average number averages are the weight average numbers.
Detailed Description Of The Invention
Haircare composition of the present invention comprises two kinds of main components, i.e. the cationic polymer of saccharide or copolymer and less than 5% anion surfactant.To describe these compositions in detail below.
Term used herein " (tacky) of adhesion " and " cohesiveness (tackiness) " mean after using some Haircare compositions the viscosity sense of hair.
Term used herein " leave " means plan at the Haircare composition that does not have to use under the rinse step.Therefore, the leave compositions will be stayed on the hair usually up to consumer cleans custom hair washing is sent out next time according to it till.The leave compositions comprises approximately the anion surfactant less than 5% usually, and comprises the non-ionic surface active agent less than 5% usually.
Cationic saccharide base polymer or copolymer
A basic feature of the present composition is its cationic polymer or copolymer that comprises saccharide.The cationic charge density of the cation saccharide of the present composition greater than about 1.5meq/g, be preferably greater than about 1.6meq/g, more preferably greater than about 1.7meq/g even more preferably greater than about 1.8meq/g.The cationic charge density of cationic polymer usually less than about 5meq/g, preferably less than about 3.5meq/g, be more preferably less than about 2.5meq/g even be more preferably less than about 2.2meq/g.
" cationic charge density " of polymer refers to constitute the ratio of the molecular weight of positive charge number on the monomeric unit of polymer and described monomeric unit, that is:
The cationic charge density of the cationic polymer of this paper can use Kjeldahl method (American Pharmacopeia-test chemical＜461〉nitrogen determination-method II) to measure.The charge density that those skilled in the art will recognize that some polymer herein can change according to the isoelectric point, IP of pH value and cationic charge group.Charge density should be in the above range under the pH that expection is used.
Cation saccharide of the present invention comprises about 1% usually to about 10%, preferred about 2% to about 5%, more preferably from about 2.3% to about 3% even more preferably from about 2.5% cationic nitrogen to about 2.9% weight.
The concentration of cation saccharide should be enough to the conditioning effect that provides required.This class range of concentrations normally whole composition weight about 0.001% to about 20%, preferred about 0.005% to about 10%, more preferably from about 0.01% to about 2%, also more preferably from about 0.05% to about 1%.
The mean molecule quantity normally about 5000 that is used for cation saccharide herein is to about 10,000,000, preferred about 100,000 to about 5,000,000, more preferably from about 500,000 to about 2,000,000 even more preferably from about 1,000,000 to about 1,500,000.
Be applicable to cation saccharide of the present invention comprise cationic polysaccharides and the saccharide cation copolymer, cationic polysaccharides preferably.
Be applicable to that cationic polymer of the present invention is cationic saccharide base polymer and copolymer.Be applicable to that cationic polysaccharides among the present invention comprises based on those polymer of the sugar of 5 or 6 carbon and as it is derived and makes water soluble derivative with oxirane.These polymer can be by any of several arrangements as 1,4-α, 1, and 4-β, 1,3-α, 1,3-β and 1,6 key link together.Monomer can be the straight or branched geometry arrangement.
The suitable unrestriced example of cationic polysaccharides comprises based on those of following material: cellulose and hydroxy alkyl cellulose; Starch and hydroxyalkyl starch; Based on the arabinose polymer of monomers; Polymer by the xylose monomer derived; By the fucose derived polymers; Polymer by the fructose monomer derived; Polymer based on acidiferous sugar monomer such as galacturonic acid and glucuronic acid; Based on amine sugar monomer such as galactosamine and the glycosamine polymer of acetylglucosamine particularly; Polyhydric alcohol polymer of monomers based on 5 or 6 Yuans rings; Based on the galactose polymer of monomers; Based on the mannose polymer of monomers with based on the galactomannan polymer of monomers.
Preferably be used for providing the cationic polymer of gloss and conditioning effect and cohesiveness and oil minimizing to be based on the cationic polymer of cellulose, hydroxy alkyl cellulose, acetyl glucosamine and derivant to hair.The preferred cationic polymer that is based on hydroxy alkyl cellulose is particularly based on the cationic polymer of hydroxyethyl-cellulose.The non-limiting instance of suitable cationic polymers is to derive from AmercholCorp. (Edison with the epoxide reactive salt that hydroxyethyl-cellulose and trimethyl ammonium replace, NJ, USA) those polymer are called Onamer M 0 (Polyquatemium 10) at industrial (CTFA).The background knowledge of these polymer and preparation method thereof sees United States Patent (USP) 3,472, and 840 (being issued to Stone on October 14th, 1969) are incorporated herein the document as a reference.The cationic cellulose of other type comprises the polymer quaternary ammonium salt that the epoxide reaction of hydroxyethyl-cellulose and the replacement of lauryl dimethyl ammonium obtains, be called Polyquatemium 24 at industrial (CTFA), derive from Amerchol Corp. (Edison, NJ, USA); The polymer quaternary ammonium salt that the reaction of hydroxyethyl-cellulose and diallyldimethylammonium chloride obtains is called Polyquaternium 4 at industrial (CTFA), derive from National Starch (Salisbury, NC, USA).
Be applicable to that the cationic saccharide analog copolymer among the present invention comprises those that contain following sugar monomer and its derivant: glucose, galactose, mannose, arabinose, xylose, fucose, fructose, glycosamine, galactosamine, glucuronic acid, galacturonic acid and 5 or 6 Yuans cyclopolyols.The methylol, ethoxy and the hydroxypropyl derivatives that also comprise above-mentioned sugar.When the sugar in the copolymer was connected to each other, they can be by any of several arrangements as 1,4-α, 1, and 4-β, 1,3-α, 1,3-β and 1,6 chain are bonded together.As long as the polymer of gained is applicable to hair care, can use other any monomer.Other the monomeric limiting examples that is suitable for use in herein comprises dimethyl diallyl ammonium chloride, dimethyl amino ethyl methacrylate, diethyl diallyl ammonium chloride, N, N-diallyl-N, N-dialkyl group ammonium halide etc.
Anion surfactant
Second basic feature of the present composition be compositions comprise less than about 5%, preferably less than about 4%, be more preferably less than about 2% even be more preferably less than about 1% even be preferably the anion surfactant of 0% weight again.Term used herein " anion surfactant " means anion surfactant and amphion or the amphoteric surfactant that has the anion linking group under the pH of compositions, or its combination.
The example of anion surfactant is alkyl sulfate and alkyl ether sulfate.These materials have general formula R OSO separately
3M and RO (C
2H
4O)
xSO
3M, wherein R is alkyl or the alkenyl with about 30 carbon atoms of about 8-, and x is the integer of 1-10, and M is a cation, as ammonium, alkanol ammonium (as triethanol ammonium), monovalence metal cation (as sodium and potassium) and multivalent metal cation (as magnesium and calcium).
Other example of anion surfactant is to meet formula [R
1-SO
3-M] the water soluble salt of organic sulfur acid reaction product, R wherein
1Be to have about 8 aliphatic hydrocarbyls straight or branched, saturated to about 24 carbon atoms, M is a cation as indicated above.
Other example of anion surfactant is with isethionic acid fatty acid to be carried out esterification also with the product of the neutral fatty acid of sodium hydroxide, and wherein, for example, fatty acid is what obtained by Oleum Cocois or palm-kernel oil; Or the sodium of the fatty acid amide of methyl taurate or potassium salt, wherein, fatty acid for example is what obtained by Oleum Cocois or palm-kernel oil.
Other example of anion surfactant is a succinate, and the example comprises N-octadecyl sulfo-succinic acid disodium, lauryl sulfo-succinic acid disodium, lauryl sulfo-succinic acid diammonium, diamyl succinate sodium sulfonate, succinic acid dihexyl sodium sulfonate and aerosol OT.
Other example of anion surfactant comprises the alkene sulfonate with about 10-24 carbon atom.In this article, term " alkene sulfonate " refers to by the sulfur trioxide that does not cooperate alpha-olefin be carried out sulfonation, subsequently by under a kind of condition, acidic reaction mixture being neutralized, make formed any sultone hydrolysis in the reaction and obtain corresponding hydroxyl alkane sulfonate.
Another kind of anion surfactant is β-alkoxyl sulfonate.The general formula of these surfactants is
Wherein, R
1For having the straight chained alkyl of about 6-20 carbon atom, R
2For having the low alkyl group of about 1-3 carbon atom, M is foregoing water-soluble cationic.
Optional components
Haircare composition of the present invention can further contain many optional components.Hereinafter provide some limiting examples of these optional components.
The polysiloxanes conditioner
Compositions of the present invention can be chosen wantonly and comprise the polysiloxanes conditioning component.The polysiloxanes conditioning component can comprise Y 7175, fixedness polysiloxanes or its mixture.Term " fixedness " is meant under environmental condition herein, has very little or does not have the polysiloxanes material of obvious vapour pressure, and this is that those skilled in the art are understandable.Boiling point under 1 atmospheric pressure (atm) preferably is at least about 250 ℃, and is more preferably at least about 275 ℃, first-selected at least about 300 ℃.At 25 ℃ or more under the low temperature, the preferably about 0.2mmHg of vapour pressure is more preferably about 0.1mmHg.
Polysiloxanes conditioning component used herein can be polysiloxane fluid, polysiloxane gums, polyorganosiloxane resin and composition thereof.The list of references that discloses some limiting examples of the optional suspending agent that some suitable polysiloxanes hair conditioners and polysiloxanes use comprises WO-A-94/08557 (Brock etc.), United States Patent (USP) 5,756,436 (Royce etc.), United States Patent (USP) 5,104,646 (Bolich Jr. etc.), United States Patent (USP) 5,106,609 (Bolich Jr. etc.), the U.S. is granted patent 34 again, 584 (Grote etc.), British patent 849,433 are incorporated herein by reference these documents.
Polyorganosiloxane resin (silicone resin) is highly cross-linked siloxane systems, and wherein crosslinked is in the polyorganosiloxane resin production process, trifunctional and four functional silanes are mixed in simple function or two senses or simple function and two functional silanes and introduces.Just as known in the art, can change according to the specific silane unit that mixes in the polyorganosiloxane resin for forming the required degree of cross linking of polyorganosiloxane resin.Usually, can consider to adopt and have abundant trifunctional and four functional silicone monomeric units (thereby crosslinked fully) so that they are dried to the polysiloxanes material of rigidity or hard film as polyorganosiloxane resin.The ratio of oxygen atom and silicon atom shows the crosslinked level in concrete polysiloxanes material.It will be polyorganosiloxane resin of the present invention usually that the ratio of oxygen atom and silicon atom is at least about 1.1 polysiloxanes material.The preferred oxygen atom was at least about 1.2: 1.0 with the ratio of silicon atom.The silane that is used to produce polyorganosiloxane resin comprises monomethyl, dimethyl, trimethyl, a phenyl, diphenyl, aminomethyl phenyl, ethylphenyl, propyl group phenyl, a vinyl and methyl ethylene chlorosilane and tetrachloro silicane.
If contain polyorganosiloxane resin, it accounts for about 0.001% to about 10%, preferred about 0.005% to about 5%, more preferably from about 0.01% to about 2% even more preferably from about 0.1% to about 1% of whole composition weight usually.
The present invention can use any polyorganosiloxane resin that is suitable for use in the Haircare composition, comprise contain hydrogen, hydroxyl, alkyl, aryl, alkoxyl, alkaryl, aralkyl, aralkoxy, aryloxy alkyl and alkylamino substituent those.But preferred polyorganosiloxane resin has the substituent group that at least one has delocalized electron.This substituent group can be selected from alkyl, aryl, alkoxyl, alkaryl, aralkyl, aralkoxy, aryloxy alkyl and combination thereof.Aryl, aralkyl and alkaryl substituent group are preferred.Aralkyl and alkaryl substituent group are preferred.Further preferably alkaryl substituent group, particularly 2-phenylpropyl.Although preferably at least one substituent group has delocalized electron, resin herein also has other substituent group that does not have delocalized electron usually.Other substituent group of this class can comprise hydrogen, hydroxyl, alkyl, alkoxyl, amido functional group and composition thereof.Preferably alkyl substituent, particularly methyl substituents.
Term used herein " aryl " means the functional group of containing one or more homoannular or heterocyclic rings.The aryl functional group of this paper can be unsubstituted or replace, and contain 3 to 16 carbon atoms usually.Preferred aryl groups is including but not limited to phenyl, naphthyl, cyclopentadienyl group, anthryl, pyrene, pyridine and pyrimidine.
That term used herein " alkyl " means is saturated or undersaturated, replacement or the hydrocarbon with 1 to 10 carbon atom, preferred 1 to 4 carbon atom unsubstituted, straight or branched.Therefore, term " alkyl " comprises the alkenyl with 2 to 8 carbon atoms, preferred 2 to 4 carbon atoms and has the alkynyl of 2 to 8 carbon atoms, preferred 2 to 4 carbon atoms.Preferred alkyl is including but not limited to methyl, ethyl, propyl group, isopropyl and butyl.More preferably methyl, ethyl and propyl group.
Term used herein " alkaryl " means the substituent group that comprises a moieties and an aryl moiety, and wherein moieties is connected on the silicone resin.
Term used herein " aralkyl " means the substituent group that comprises an aryl moiety and a moieties, and wherein aryl moiety is connected on the silicone resin.
Polysiloxanes material, particularly polyorganosiloxane resin can be easily according to well known to a person skilled in the art i.e. " MDTQ " nomenclature identification of shorthand nomenclature system.In this system, polysiloxanes is that the various siloxanyl monomers unit according to the existence that constitutes polysiloxanes is described.In brief, symbol M is represented simple function unit (CH
3)
3SiO
0.5D represents two functional unit (CH
3)
2SiO; T represents trifunctional units (CH
3) SiO
1.5Q represents four functional unit SiO
2Unit symbol apostrophe such as M ', D ', T ', the one or more substituent groups of Q ' representative except that methyl, all need concrete definition at every turn.Therefore, preferred polyorganosiloxane resin used herein has at least one M ', D ', T ', Q ' functional group, and this functional group has a substituent group with delocalized electron.Preferred substituted as hereinbefore defined.In the MDTQ system, various unitary mol ratios perhaps indicate the unitary total number of every class (or meansigma methods) expression in the polysiloxanes with the subscript of symbol, perhaps show with concrete indicated ratio and binding molecule scale, thereby finish description to the polysiloxanes material.
The polyorganosiloxane resin that the present invention uses is MQ and M ' Q resin preferably, is more preferably M ' Q resin, especially M '
6Q
3, M '
8Q
4, M '
10Q
5, M '
12Q
6Resin and composition thereof.Preferred L ' Q resin is that those have the group that contains delocalized electron that at least one replaces in each M ' functional group.More preferably other substituent group in the resin is an alkyl, especially methyl.
Polyorganosiloxane resin used herein is in the time of 25 ℃, and preferred viscosities is less than about 5000mm
2s
-1, be more preferably less than about 2000mm
2s
-1, further preferably less than about 1000mm
2s
-1, also preferably less than about 600mm
2s
-1Can measure viscosity by Cannon-Fenske Routine Viscometer (ASTM D-445).
Be suitable for use in the background knowledge of polyorganosiloxane resin herein, comprise that the detailed description of its preparation method can see United States Patent (USP) 5,539,137,5,672,338,5,686,547 and 5,684,112, these patents are introduced the present invention as a reference.
The polysiloxane fluid that is used in the present composition comprises polysiloxane oil (silicone oil), and this polysiloxane oil is in the time of 25 ℃, and viscosity is less than 1,000,000mm
2s
-1, be preferably about 5-1,000,000mm
2s
-1, about 10-600 more preferably, 000mm
2s
-1, about 10-500 more preferably, 000mm
2s
-1, most preferably be about 10-350,000mm
2s
-1Flowable polysiloxanes material.This viscosity can be measured by the described glass capillary tube viscometer of Dow Corning Corporate Test Method CTM0004 as on July 20th, 1970.Suitable polysiloxane oil comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-aralkyl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer and composition thereof.Also can use other to have the polysiloxane fluid of insoluble, the fixedness of conditioning performance.
Used polysiloxane oil comprises poly-alkyl or the poly-aryl siloxanes that meets following formula in this compositions:
Wherein R is aliphatic, and preferably alkyl or alkenyl or aryl, R can be to replace or unsubstituted, and x is about 1 to about 8000 integer.Suitable unsubstituted R base comprises that alkoxyl, aryloxy group, alkaryl, aralkyl, alkylamino and ether replace, hydroxyl replaces replaces with halogen aliphatic group and aryl.The suitable R group also comprises cationic amine and quaternary ammonium group.
Aliphatic series or aryl at the siloxanes chain substitution can be any structures, as long as the polysiloxanes of gained at room temperature keeps fluid, is hydrophobic, non-stimulated when being coated on hair, avirulence or harmless, can be compatible with other composition in the Haircare composition as herein described, chemical property is stable under the use of routine and condition of storage, is insoluble in compositions of the present invention and can conditioning hair.
Two R groups on the silicon atom of each monomer polysiloxane unit can be identical or different groups.Preferred two R groups are represented identical group.
Preferred alkyl and alkenyl substitutents are C
1-C
5Alkyl and alkenyl are more preferably C
1-C
4Alkyl and alkenyl most preferably are C
1-C
2Alkyl and alkenyl.Other contain alkyl-, alkenyl-or the aliphatic series part of the group (as alkoxyl, alkaryl and alkylamino) of alkynyl can be straight or branched, preferably have 1 to 5 carbon atom, more preferably have 1 to 4 carbon atom, also more preferably have 1 to 3 carbon atom, most preferably have 1 to 2 carbon atom.As previously discussed, the R substituent group of this paper also can contain amido functional group, and as alkylamino, it can be primary, secondary, tertiary amine or quaternary ammonium.These comprise single-, two-and three-alkyl amino and alkoxy amino, wherein the chain length of aliphatic series part is preferably as indicated above.The R substituent group also can with other group such as halogen (as, chlorine, fluorine and bromine), halogenated aliphatic group or aryl and hydroxyl (aliphatic group that replaces as hydroxyl) replace.Suitable halogenated R base can comprise the alkyl as three halos (preferred fluoro), as-R
1-C (F)
3, R wherein
1Be C
1-C
3Alkyl.The example of this class polysiloxanes comprises poly-methyl-3,3, the 3-trifluoropropyl siloxane.
The suitable R base comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxanes is polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Polydimethylsiloxane is particularly preferred.Other suitable R base comprises methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.End capped three the R bases in polysiloxanes end also can be represented identical or different group.
Operable nonvolatile poly-alkylsiloxane fluid comprises as polydimethylsiloxane.These siloxanes can for example obtain with its Viscasil R and SF 96 series from General Electric Co. Limited, and obtain with its Dow Corning 200 series from DowCorning.
Operable polyoxyethylene alkyl aryl radical siloxane fluid also comprises as PSI.These siloxanes can be as obtaining with 556Cosmetic Grade Fluid with SF 1075 aminomethyl phenyl fluids or from Dow Corning from General Electric Co. Limited.
Operable polyether siloxane copolymer comprises as the polydimethylsiloxane of poly(propylene oxide) modification (as Dow CorningDC-1248), although also can use the mixture of oxirane or oxirane and expoxy propane.For insoluble polysiloxanes, the amount of oxirane and expoxy propane should be enough low, to prevent its dissolubility in the compositions of water and this paper.
Other the suitable polysiloxane fluid that is used for the polysiloxanes conditioner is insoluble silicone gum (silicone gum).These sizing materials be viscosity under 25 ℃ more than or equal to 1,000, the polysiloxane material of 000 centistoke.Silicone gum is described in United States Patent (USP) 4,152,416; Noll and Walter,
Chemistry and Technology of Silicones (polysiloxanes chemistry and technology), NewYork:Academic Press 1968 and General Electric Silicone Rubber Product DataSheets SE 30, SE 33, among SE 54 and the SE 76, all these files introduced the present invention as a reference.The mass molecular weight that silicone gum has usually (mass molecular weight) surpasses about 200,000, usually about 200,000 and about 1,000, between 000, its instantiation comprises polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer and composition thereof.
The polysiloxanes conditioner also can comprise the polydimethylsiloxane sizing material, and (viscosity is greater than about 1,000,000 centistoke) and polydimethyl siloxane oil (viscosity is about 10 to about 100, between 000 centistoke), wherein said sizing material and fluidic ratio are about 30: 70 to about 70: 30, preferably about 40: 60 to about 60: 40.
The number average bead diameter of optional polysiloxanes component can unrestrictedly change on a large scale, and this depends on prescription and/or required characteristic.Being preferred for the common scope of number average bead diameter of the present invention is extremely about 100 microns of about 10 nanometers, is more preferably about 30 nanometers to about 20 microns.
About the background knowledge of polysiloxanes comprises that the part of the preparation method that polysiloxane fluid, sizing material and resin and polysiloxanes are discussed can see
Encyclopaedia of Polymer Science and Engineering (polymer science and engineering encyclopedia)(the 15th volume, second edition, 204-308 page or leaf, John Wiley﹠amp; Sons, Incorporated, 1989), be introduced into this paper as a reference.
From improving glossy viewpoint, preferred polysiloxanes conditioner is a polyorganosiloxane resin.
Cation opsonizing agent
Compositions of the present invention also can comprise one or more additional cationic polymer conditioners.The cationic polymer conditioner is preferably water miscible.The total amount of the cationic polymer in compositions of the present invention normally about 0.001% to about 20% weight, be about 0.005% to about 10% weight, preferably about 0.01% to about 2% weight more generally.
" water solublity " cationic polymer refers to such polymer: its 25 ℃, in water (distilled water or quite thing), fully be dissolved in the water with 0.1% concentration, form naked eyes and see limpid basically solution.Preferably, this polymer fully dissolves the limpid substantially solution of formation with 0.5% concentration, is more preferably with 1.0% concentration and forms limpid substantially solution.
Term " polymer " used in the present invention " will comprise the material that obtains through one type monomer polymerization or two kinds (they being copolymer) or polytype monomer polymerization.
The weight average molecular weight of cationic polymer of the present invention generally is at least about 5000, normally at least about 10000, and less than about 10,000,000.Preferably, molecular weight from about 100,000 to about 2000,000.Cationic polymer has cation nitrogen part for example quaternary ammonium or cation amino part and composition thereof usually.
Cationic charge density is preferably at least about 0.1meq/g, more preferably at least about 0.5meq/g, more preferably at least about 1.1meq/g, further preferably at least about 1.2meq/g.For practical application, the cationic charge density of this cationic polymer less than about 7meq/g, preferably less than about 5meq/g, be more preferably less than about 3.5meq/g, most preferably less than about 2.5meq/g.Can use Kjeldahl method (American Pharmacopeia-test chemical-＜461〉N2 method-method II) to determine the cationic charge density of cationic polymer.Persons of ordinary skill in the art will recognize that the charge density that contains amino polymer can change with pH and amino isoelectric point, IP.Charge density should be in above-mentioned scope under the pH that expection is used.
As long as satisfy the water solublity standard, cationic polymer can use any anionic counter ion.Suitable counter ion comprises halogen (as chlorine, bromine, iodine or fluorine, preferred chlorine, bromine or iodine) ion, sulfate radical, methylsulfate.Also can use other counter ion, because above-mentioned to enumerate right and wrong exclusive.
The cation nitrogen moiety exists as the substituent form on the part of the whole monomeric unit of cationic hair conditioning polymer usually.Therefore, cationic polymer can comprise monomeric unit and other unitary copolymer of non-cationic that is referred to herein as the basic monomeric unit in interval, the ter-polymers etc. of quaternary ammonium or cationic amine replacement.This base polymer is as known in the art,
CTFA International Cosmetic Ingredient Dictionary and Handbook (international cosmetic composition dictionary of CTFA and hands Volume), the 7th edition, edit in (The Cosmetic, Toiletry andFragrance Association, Inc., Washington, D.C., 1997) by Wenninger and McEwen and can find various polymer.
Suitable cationic polymers for example comprises having vinyl monomer and the water solublity basic monomer in interval such as acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and the vinylpyrrolidone copolymers of cationic amine or quaternary ammonium functional group.The monomer that alkyl and dialkyl group replace preferably has C
1-C
7Alkyl, be more preferably C
1-C
3Alkyl.Other suitable interval base monomer comprises vinyl esters, vinyl alcohol (being prepared by the hydrolysis of polyvinyl acetate), maleic anhydride, propylene glycol and ethylene glycol.
The particular types and the pH that depend on compositions, cationic amine can be primary, the second month in a season or tertiary amine.The usually preferred second month in a season and tertiary amine, especially tertiary amine.
The vinyl monomer that amine replaces can carry out polymerization with the form of amine, randomly can become ammonium salt by the season reaction conversions then.Also can before forming polymer, carry out seasonization similarly to amine.For example, by with general formula be the reactant salt of R ' X, can carry out seasonization to tertiary amine functional group, in described general formula, R ' is a short-chain alkyl, preferably C
1-C
7Alkyl, be more preferably C
1-C
3Alkyl, X are the aniones that forms water soluble salt with quaternary ammonium.
Suitable cation amino and quaternary ammonium monomer for example comprise, vinyl compound with the following groups replacement, these groups are propenoic acid dialkyl aminoalkyl esters, the methacrylic acid dialkyl aminoalkyl ester, acrylic acid alkyl monosubstituted amino Arrcostab, methacrylic acid alkyl monosubstituted amino Arrcostab, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salt and have ring such as a pyridine that contains the ring-type cationic nitrogen, the vinyl quaternary ammonium monomer of the ketopyrrolidine of imidazoles and seasonization is as the alkyl vinyl imidazoles, alkylvinylpyridines and alkyl vinyl ketopyrrolidine.These monomeric moieties are low alkyl group such as C preferably
1-C
3Alkyl, be more preferably C
1And C
2Alkyl.Be applicable to that the vinyl monomer that amine of the present invention replaces comprises propenoic acid dialkyl aminoalkyl ester, methacrylic acid dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide, dialkyl aminoalkyl Methacrylamide, wherein alkyl C preferably
1-C
7Alkyl, be more preferably C
1-C
3Alkyl.
Cationic polymer of the present invention can comprise derived from amine-and/or the monomer of quaternary ammonium-substituted and/or mixture of the monomeric monomeric unit of compatible spacer base.
Suitable cationic hair conditioning polymer comprises, for example: the copolymer of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (as villaumite) (being called Polyquaternium-16) at industrial (CTFA), such as from BASF Wyandott Corp. (Parsippany, NJ, USA) those that obtain with trade name LUVIQUAT (for example LUVIQUAT FC 370); The copolymer of l-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate (being called Polyquaternium-11) at industrial (CTFA), such as from GAF Corporation (Wayne, NJ, USA) those that obtain with trade name GAFQUAT (as GAFQUAT 755N); The polymer of cation diallyl quaternary ammonium, comprise, for example, the copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride is called Polyquaternium 6 and Polyquaternium 7 at industrial (CTFA); And the inorganic acid salt with amino-Arrcostab of the homopolymer of undersaturated carboxylic acid of 3 to 5 carbon atoms and copolymer, as United States Patent (USP) 4,009,256 is described, is incorporated herein by reference.
As discussed above, cationic polymer of the present invention is water miscible.But this is not to mean it must be dissolved in the compositions.But preferred described cationic polymer or be dissolved in the compositions perhaps is dissolved in by in the complex coacervation mutually in the formed compositions of cationic polymer and anionic species.Can add the complex coacervation phase that anion surfactant in the present composition or anionic polymer form cationic polymer with optional.
Sensory agent
Haircare composition of the present invention also can comprise a kind of sensory agent (sensate).Terminology used here " sensory agent " means after being coated on the hair, causes the material of the sensation that the situation that perceives changes, described situation Change Example as but be not limited to heat, cold, salubrious etc.
The preferable amount of sensory agent is about 0.001% to about 10%, more preferably from about 0.005% to about 5%, most preferably from about 0.01% to about 1% of a whole composition weight.
The present invention can use any sensory agent that is suitable in the Haircare composition.The tabulation of the suitable sensory agent of nonrestrictive illustrative can see GB-B-1315626, GB-B-1404596 and GB-B-1411785, and these documents are introduced the present invention as a reference.The sensory agent that is preferred in the present composition is Camphora, menthol, the different pulegol of 1-, ethyl menthane formamide and trimethyl isopropyl butanamide.
C
1-C
6Aliphatic alcohol
Compositions of the present invention can be chosen wantonly and comprise C
1-C
6, preferred C
2-C
3, be more preferably C
2Aliphatic alcohol.Aliphatic alcohol accounts for about 1% to about 75%, preferred about 10% to about 40%, more preferably from about 15% to about 30%, more preferred about 18% to about 26% of whole composition weight usually.
Viscosity modifier
Compositions of the present invention also can comprise viscosity modifier.The present invention can use any viscosity modifier that is suitable for use in the Haircare composition.Usually, if there is viscosity modifier, then it accounts for about 0.01% to about 10%, more preferably from about 0.05% to about 5%, most preferably from about 0.1% to about 3% of whole composition weight usually.The non-limiting instance of suitable viscosity modifier can see
CTFA (CTFA makes up in the world International Cosmetic Ingredient Dictionary and Handbook Divide dictionary and handbook), the 7th edition, edit (The Cosmetic, Toiletryand Fragrance Association, Inc., Washington, D.C., 1997) by Wenninger and McEwen, the document is introduced the present invention as a reference.
The viscosity modifier that is suitable for use among the present invention comprises shear sensitive viscosity modifier.Terminology used here " to shear sensitive viscosity modifier " means such viscosity modifier, and it can form the compositions that viscosity reduces under low shear rate.Shear rate (second
-1) can be defined as the speed (meter per second) of material and the ratio of its distance (rice) apart from the static target thing.Less than about 250 seconds
-1Shear rate be considered to " low shear rate ".The present invention can use any be applicable to hair conditioning to shear sensitive viscosity modifier.But, be preferred for of the present invention being formed in less than about 100 seconds
-1, more preferably less than 50 seconds
-1Shear rate under the viscosity modifier of the compositions that reduces of viscosity.In addition, preferred was those viscosity modifiers that can form such compositions to shear sensitive viscosity modifier, at 50 seconds
-1Shear rate under described compositions viscosity reduction amount greater than about 30%, be preferably greater than about 50%, more preferably greater than about 70%, be preferably greater than about 80% again.
Being preferred for viscosity modifier of the present invention is those viscosity modifiers that can form such compositions, and the viscosity of said composition also is responsive to the electrolyte concentration that contains aqueous phase, is called " to salt-sensitive viscosity modifier " hereinafter.Relevant background knowledge to salt-sensitive viscosity modifier can see
American Chemical Society Symposium Series(1991), the 462nd volume, the 101-120 page or leaf is introduced the present invention as a reference.The present invention can use any be suitable in the Haircare composition to salt-sensitive viscosity modifier.
The example of suitable viscosity modifier is including but not limited to synthetic li-montmorillonite, carboxylate anion's polymer/copolymer and the crosslinked polymer/copolymer of carboxylate anion.Be preferred for the crosslinked polymer/copolymer of the carboxylate anion of being of the present invention.Carboxylate anion's crosslinked copolymers more preferably.
The synthetic li-montmorillonite that is used for the present invention is synthetic lamellated silicate, as sodium magnesium silicate.The example of suitable synthetic li-montmorillonite comprises those materials of having bought with trade name Laponite from Britain Laporte Plc..
The carboxylate anion's copolymer that is used for the present invention can be the crosslinked copolymers of the hydrophobically modified of carboxylic acid and alkyl carboxylates, and it has amphipathic.These carboxylate anion's copolymers obtain by following material is carried out copolymerization, described material is: 1) carboxylic acid monomer such as acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, fumaric acid .beta.-methylacrylic acid or α-Lv Daibingxisuan, 2) have 1 carboxylate and preferred 3 to the alkyl chain of about 30 carbon atoms) have a cross-linking agent of following general formula:
R wherein
1Be hydrogen or have about 1 alkyl to about 30 carbon atoms; Y
1Be oxygen, CH independently
2O, COO, OCO,
Or
R wherein
2Be hydrogen or have about 1 alkyl to about 30 carbon atoms; Y
2Be selected from (CH
2) m ", (CH
2CH
2O) m " or (CH
2CH
2CH
2O) m ", wherein m " is 1 to about 30 integer.
Being suitable for carboxylate anion's copolymer of the present invention is the acrylic acid/alkyl acrylate copolymer with following general formula:
R wherein
2Be hydrogen independently or have about 1 alkyl, wherein at least one R to about 30 carbon atoms
2Be hydrogen, R
1As hereinbefore defined, n, n ', m and m ' are integers, and wherein n+n '+m+m ' is about 40 to about 100, n, and " be 1 to about 30 integer, the definition of P should make that the molecular weight of copolymer is about 5000 to about 3,000,000.
Can add nertralizer with the carboxylate anion's copolymer of the present invention that neutralizes.The non-limiting instance of this class nertralizer comprises sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine (DIPA), amino methyl propanol, trimethylamine (tromethamine), tetrahydroxypropyl ethylenediamine and composition thereof.
The non-limiting instance of suitable carboxylate anion's viscosity modifier comprises that the details of its preparation method can see United States Patent (USP) 3,940,351,5,288,814,5,349,030,5373,044 and 5,468,797, these patents are incorporated herein by reference.The example of carboxylate anion's viscosity modifier comprises can be from B.F.Goodrich, Cleveland, those that OH, USA obtain with trade name Pemulen TR-1, PemulenTR-2, Carbopol 980, Carbopol 981, Carbopol ETD-2020, CarbopolETD-2050 and Carbopol Ultrez 10.Preferred Carbopol ETD-2020, Carbopol ETD-2050 and Carbopol Ultrez 10, especially Carbopol Ultrez 10.
From improving spreadability, reduce cohesiveness and improving glossy viewpoint, being used for particularly preferred viscosity modifier of the present invention is carboxylate anion's viscosity modifier, as Carbopol Ultrez 10.
The polyethyleneglycol derivative of glyceride
The polyethyleneglycol derivative of suitable glyceride comprises water miscible and is suitable for the polyethyleneglycol derivative of any glyceride in the Haircare composition.The polyethyleneglycol derivative that is suitable for glyceride of the present invention comprises the derivant of monoglyceride, diglyceride and triglyceride and composition thereof.
The polyethyleneglycol derivative that is suitable for a class glyceride of the present invention is the polyethyleneglycol derivative that meets those glyceride of following general formula I:
Wherein, n, ethoxylation degree, for about 4 to about 200, preferred about 5 to about 150, more preferably from about 20 to about 120, and wherein R comprises and has about 5 to about 25 carbon atoms, preferred about 7 aliphatic groups to about 20 carbon atoms.
The polyethyleneglycol derivative of suitable glyceride can be the polyethyleneglycol derivative of hydrogenant Oleum Ricini.For example, the hydrogenant Oleum Ricini of PEG-20, the hydrogenant Oleum Ricini of PEG-30, the hydrogenant Oleum Ricini of PEG-40, the hydrogenant Oleum Ricini of PEG-45, the hydrogenant Oleum Ricini of PEG-50, the hydrogenant Oleum Ricini of PEG-54, the hydrogenant Oleum Ricini of PEG-55, the hydrogenant Oleum Ricini of PEG-60, the hydrogenant Oleum Ricini of PEG-80 and the hydrogenant Oleum Ricini of PEG-100.Be preferred in the compositions of the present invention is the hydrogenant Oleum Ricini of PEG-60.
The polyethyleneglycol derivative of the glyceride that other is suitable can be stearic polyethyleneglycol derivative.For example, PEG-30 stearate, PEG-40 stearate, PEG-50 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate and PEG-150 stearate.Be preferred among the present invention is the PEG-100 stearate.
Cationic surfactant
Used cationic surfactant contains amino or quaternary ammonium part in the compositions of the present invention.Cationic surfactant is preferred, but not necessarily, is insoluble in the compositions of the present invention.Some that are used for those cationic surfactants of the present invention have been done disclosure in following introducing the present invention file as a reference, described file is M.C.Publishing Co., McCutcheon ' s,
Detergents﹠amp; Emulsifiers (surfactant and emulsifying agent), (North America version 1979); People such as Schwartz,
Surface Active Agents, Their Chemisty and Technology (surfactant, its chemical property and skill Art), New York:Interscience Publishers, 1949; Authorized the United States Patent (USP) 3,155,591 of Hilfer on November 3rd, 1964; Decembers in 1975 were authorized people's such as Laughlin United States Patent (USP) 3,929,678 on the 30th; Authorize people's such as Bailey United States Patent (USP) 3,959,461 on May 25th, 1976 and authorize Bolich June 7 nineteen eighty-three, the United States Patent (USP) 4,387,090 of Jr..
Being used for the cationic surfactant material that contains quaternary amine of the present invention is those cationic surfactants with following general formula:
Wherein, R
1-R
4Be independently selected from and have about 1 to the aliphatic group of about 22 carbon atoms or have about 1 aryl, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or alkaryl to about 22 carbon atoms; X is for becoming salt anionic, as is selected from halide ion (as chloride ion, bromide ion), acetate, citrate, lactate, glycolic acid ester group, phosphate radical, nitrate anion, sulfate radical and alkyl sulfate.Aliphatic group de-carbon and hydrogen atom also can comprise ehter bond and other group such as amino outward.Long-chain aliphatic group is those groups of 12 carbon atoms or more a plurality of carbon atoms according to appointment, can be saturated group or unsaturated group.Particularly preferably be mono-long chain (as single C
12-C
22, single C preferably
12-C
18, be more preferably single C
16Aliphatic group, preferably alkyl), two short chains are (as C
1-C
3Alkyl, C preferably
1-C
2Alkyl) quaternary amine.
The primary, the salt of the second month in a season and uncle's fatty amine also is the suitable cationic surfactants material.The alkyl of this class amine preferably has about 12 to about 22 carbon atoms, can be that replace or unsubstituted.This class amine used herein comprises (having 5 moles of ethylene oxide) stearylamine, dihydroxy ethyl stearylamine and the Semen arachidis hypogaeae base docosyl amine of the amino propyl-dimethyl amine of stearoyl, diethyllaminoethyl stearmide, dimethyl stearylamine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, Semen Myristicae amine, tridecyl amine, ethyl stearylamine, N-tallow propane diamidogen, ethoxylation.Suitable amine salt comprises halogen, acetate, phosphate, nitrate, citrate, lactate and alkyl sulfate.This class salt comprises stearic amine hydrochlorate, Semen sojae atricolor amine chloride, stearic amine formates, N-Adeps Bovis seu Bubali propane diamine dichloride, the amino propyl-dimethyl amine citrate of stearoyl, hexadecyltrimethylammonium chloride and two (cetyl) two (methyl) ammonium chloride.Be preferred in the compositions of the present invention is hexadecyltrimethylammonium chloride.The cationic amine surfactant that is included in those cationic surfactants that are used for the present invention is disclosed in the United States Patent (USP) 4,275,055 of authorizing people such as Nachtigal on June 23rd, 1981, and this patent is introduced the present invention as a reference.
The consumption of cationic surfactant preferably composition weight about 0.1% to about 10%, more preferably from about 0.25% to about 5%, most preferably from about 0.3% to about 0.7%.
Aliphatic alcohol
Haircare composition of the present invention also can comprise aliphatic alcohol.Can use any aliphatic alcohol that is suitable for hair conditioning among the present invention.But, C preferably
8-C
22, C more preferably
12-C
18, C further preferably
16Aliphatic alcohol.
The consumption of aliphatic alcohol preferably composition weight about 0.1% to about 20%, more preferably from about 0.25% to about 10%, most preferably from about 0.5% to about 5%.
If have aliphatic alcohol and cationic surfactant simultaneously, the ratio of then described aliphatic alcohol and described surfactant is about 3: 1 to about 6: 1, is more preferably 4: 1.
Water
Compositions of the present invention also comprises water usually.When having water in the compositions, it accounts for about 25% to about 99%, preferred about 50% to about 98%, more preferably from about 65% to about 95% of whole composition weight usually.
Additional component
Compositions of the present invention can comprise multiple being applicable to makes this based composition on making up or aestheticly more make us accepting other optional components that additional use benefit is provided to compositions.The optional member of this class routine is known for those of ordinary skills.
Multiple additional composition can be formulated in the compositions of the present invention.These supplementary elements comprise: other hair conditioning composition such as pantothenylol, pantethine (panthetine), pantetheine (pantotheine), pantoyl benzyl ethyl ether and combination thereof; Other solvent such as hexanediol; Hair keeps those polymer described in polymer such as the WO-A-94/08557, and this document is incorporated herein by reference; Detersive surfactant such as anion, nonionic, both sexes and zwitterionic surfactant; Additional viscosity modifier and suspending agent such as xanthan gum, guar gum, hydroxyethyl-cellulose, triethanolamine, methylcellulose, starch and starch derivatives; The methanol amide such as the coconut monoethanol amide of viscosity modifier such as long-chain fatty acid; The crystal suspending agent; Pearlescent additive such as diglycol stearate; Opacifier such as polystyrene; Antiseptic such as phenyl phenol, benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea and hydantoin; Polyvinyl alcohol; Ethanol; PH regulator agent such as lactic acid, citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt, generally for example potassium acetate and sodium chloride; Coloring agent such as FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; Hair Reducing agent such as thioglycolate salt; Spice; Sequestering agent such as tetrasodium ethylenediamine tetraacetate; Antidandruff agent such as 2-mercaptopyridine zinc oxide (ZPT), sulfur, selenium sulfide, coal tar, Octopirox ethanolamine (piroctone olamine), ketoconazole, Climbazole and salicylic acid; Antioxidant/UV filters agent such as octyl methoxycinnamate, benzophenone-3 and DL-alpha tocopherol acetas and polymeric plasticizer such as glycerol, diisobutyl adipate, butyl stearate and propylene glycol.Usually these selectivity compositions use amount separately is about 0.001% to about 10.0%, preferred about 0.01% to about 5.0% of a composition weight.
Product form
Compositions of the present invention can be mixed with various product forms, includes, but are not limited to cream, gel, aerosol or non-aerosol foam, mousse and hair spray.The propellant (using air as propellant in pumping hair spray or pumping bubble wrap) of can be with propellant or not needing to add is especially prepared mousse, foam and hair spray, described propellant such as propane, butane, pentane, dimethyl ether, fluorohydrocarbon, carbon dioxide and nitrous oxide.
Using method
Use Haircare composition of the present invention to come the hair of caregiver with conventional method.With the compositions of effective dose, normally about 1-50 restrains, preferably about 1-20 gram compositions is coated on the hair.The coating of compositions generally includes and with hands and finger or with proper tools such as comb or brush compositions is applied in the whole hair fully usually.Then compositions is stayed on the hair, usually up to consumer wash hair next time send out till.
The method for optimizing of treatment of hair comprises the following steps:
(a) Haircare composition with effective dose is coated on wet, moist or the exsiccant hair,
(b) with hands and finger or with proper tools compositions is applied in the whole hair fully.
This method can be chosen wantonly and comprise further step with the water rinse hair.
Embodiment
The following examples are further set forth and the interior preferred embodiment of the explanation scope of the invention.These embodiment only are in order to set forth the present invention, are not limitation of the present invention, because multiple variation can be arranged not breaking away under spirit of the present invention and the category.All the components is represented with the percetage by weight of active component.
Example I (% weight)
| I (hair spray) | |
| Water | In right amount |
| The cationic polymer of hydroxyethyl-cellulose 1 | 0.075 |
| Trisodium citrate | 0.70 |
| PEG 60 hydrogenant Oleum Ricini 2 | 0.80 |
| Lactic acid | 0.10 |
| Phenyl phenol | 0.20 |
| CI 42045 (Blue VRS) | 0.0001 |
| Spice | 0.1 |
1) charge density is that 1.93meq/g and weight average mole are 1,250,000 polymer, available from Amerchol.
2) the Cremophor RH-60 that supplies by BASF.
Cationic polymer and trisodium citrate are added in the entry, and thoroughly stir at ambient temperature up to obtaining homogeneous solution.Other component mixes with all then, and adds in the above-mentioned homogeneous phase solution.Then with the gained solution stirring till homogeneous phase.
Example II (% weight)
| II (mousse) | |
| Water | In right amount |
| The cationic polymer of hydroxyethyl-cellulose 1 | 0.30 |
| Trisodium citrate | 0.10 |
| PEG 60 hydrogenant Oleum Ricini 2 | 0.10 |
| CAPB 3 | 0.30 |
| Lactic acid | 0.02 |
| Phenyl phenol | 0.30 |
| Spice | 0.25 |
1) charge density is that 1.93meq/g and weight average mole are 1,250,000 polymer, available from Amerchol.
2) the Cremophor RH-60 that supplies by BASF.
3) the Tegobetaine F that supplies by Goldschmidt.
Cationic polymer and trisodium citrate are added in the entry, and thoroughly stir at ambient temperature up to obtaining homogeneous solution.Other component mixes with all then, and adds in the above-mentioned homogeneous solution.Then with the gained solution stirring till evenly.Filling ratio with 10-15 part concentrate and 1 part of propellant is packaged in products obtained therefrom in the aerosol container of the pressurization that contains volatile propellant (as propane, butane etc.) then.
EXAMPLE III-IV (% weight)
| III (cream) | IV (cream) | ||
| Water | In right amount | In right amount | - |
| Carbomer 1 | 1.00 | - | A |
| Acrylate/C 10-30Alkyl acrylate cross-linked polymer 2 | - | 0.60 | A |
| The cationic polymer of hydroxyethyl-cellulose 11 | 1.00 | 0.10 | B |
| Methyl parahydroxybenzoate | 0.08 | - | C |
| Propyl p-hydroxybenzoate | 0.04 | - | C |
| Cetyl alcohol 3 | 2.40 | 1.00 | C |
| Stearyl alcohol | 0.50 | C | |
| Hexadecyltrimethylammonium chloride 4 | 0.60 | - | C |
| PEG 60 hydrogenant Oleum Ricini 5 | 0.05 | - | C |
| Ammonium lauryl sulfate 6 | 0.10 | - | C |
| PEG 100 stearates 7 | - | 0.13 | C |
| Ethanol (degeneration) | - | 30.00 | D |
| Camphora | 0.10 | - | D |
| The different pulegol of 1- 8 | - | 0.50 | D |
| Polyquatemium 4 9 | 0.10 | - | D |
| 2-phenyl propyl M ' Q resin 10 | - | 0.50 | D |
| Lactic acid | - | 0.15 | D |
| Phenyl phenol | 0.20 | 0.20 | D |
| EDTA four sodium | 0.01 | - | D |
| Citric acid | 0.10 | - | D |
| Spice | 0.60 | 1.00 | D |
| Triethanolamine | 0.40 | 0.40 | E |
1) the Carbopol Ultrez 10 that supplies by BF Goodrich;
2) the Pemulen TR2 that supplies by BF Goodrich;
3) the Crodacol C-95 that supplies by Croda Inc.;
4) the Dehyquat A that supplies by Henkel;
5) the Cremophor RH-60 that supplies by BASF;
6) by Albright.﹠amp; The Empicol AL 30/T of Wilson supply;
7) Myrj 59 that supplies by ICI Surfactants;
8) the Coolact P that supplies by Takasago;
9) the Celquat L200 that supplies by National Starch;
10) according to GB-A-2,297,775 is prepared;
11) charge density is that 1.93meq/g and weight average mole are 1,250,000 polymer, available from Amerchol.
Component A is dissolved in the water, is heated to 80 ℃ then.Add all the components C then, by carrying out high shear mixing simultaneously by heat-exchangers of the plate type with mixture reflux cooling to 30 ℃.To criticize cooldown rate and remain on 1.0-1.5 ℃/minute.The composition E that adds all the components D and 50% then, i.e. triethanolamine.Then this mixture is stirred till homogeneous phase.Be dissolved in B component in the water then and add to become owner of and mix in the thing.Then this mixture is carried out high shear mixing till obtaining uniform particle size distribution.Stop then circulating to prevent that the shear stress to product damages in finishing neutral process.Add remaining component E up to pH that reaches regulation and viscosity.
EXAMPLE V (% weight)
| V (emulsion, Lotion) | ||
| Water | In right amount | - |
| Methyl parahydroxybenzoate | 0.50 | A |
| Propyl p-hydroxybenzoate | 0.40 | A |
| Cetyl alcohol 1 | 1.60 | A |
| Hexadecyltrimethylammonium chloride 2 | 0.40 | A |
| PEG 60 hydrogenant Oleum Ricini 3 | 0.10 | A |
| The cationic polymer of hydroxyethyl-cellulose 5 | 0.20 | B |
| The poly dimethyl polysiloxanes 4 | 0.20 | C |
| Styryl M ' Q resin | 0.20 | C |
| The 2-mercaptopyridine zinc oxide | 0.03 | C |
| Octyl methoxycinnamate | 0.10 | C |
| Benzophenone-3 | 0.02 | C |
| DL-alpha tocopherol acetas | 0.03 | C |
| DMDM Hydantoin | 0.05 | C |
| EDTA four sodium | 0.30 | C |
| Citric acid | 0.20 | C |
| Spice | 0.40 | C |
1) the Crodacol C-95 that supplies by Croda Inc.;
2) the Dehyquat A that supplies by Henkel;
3) the Cremophor RH-60 that supplies by BASF;
4) DC200 that supplies by Dow Corning;
5) charge density is that 1.93meq/g and weight average mole are 1,250,000 polymer, available from Amerchol.
Component A is dissolved in the water, is heated to 80 ℃ then.By the mixture to 30 that carries out high shear mixing cooling gained by board-like thermal converter simultaneously ℃.Cooldown rate is remained on 1.0-1.5 ℃/minute.Add all the components C then.Then this mixture is stirred till homogeneous phase.Be dissolved in B component in the water then and add to become owner of and mix in the thing.Then this mixture is carried out high shear mixing till obtaining uniform particle size distribution.
Claims (16)
1. Wo 2008069000 that is used for disposable use, it comprises:
(a) 0.01% to 2% weight, cationic charge density is greater than 1.5meq/g and less than the Onamer M 0 of 3.5meq/g;
(b) less than the anion surfactant of 2% weight; With
(c) C of 10% to 40% weight
2-C
3Aliphatic alcohol.
2. Wo 2008069000 according to claim 1, wherein said compositions comprises the anion surfactant of 0% weight.
3. Wo 2008069000 according to claim 1, the charge density of wherein said Onamer M 0 is less than 2.5meq/g.
4. Wo 2008069000 according to claim 3, the charge density of wherein said Onamer M 0 is less than 2.2meq/g.
5. Wo 2008069000 according to claim 1, wherein said Onamer M 0 accounts for 0.05% to 1% of whole composition weight.
6. Wo 2008069000 according to claim 1, wherein said aliphatic alcohol are C
2Aliphatic alcohol.
7. according to any one described Wo 2008069000 among the claim 1-6, the mean molecule quantity of wherein said Onamer M 0 is 5000 to 10,000,000.
8. Wo 2008069000 according to claim 7, the mean molecule quantity of wherein said Onamer M 0 is 1,000,000 to 1,500,000.
9. Wo 2008069000 according to claim 1, it also comprises the polysiloxanes conditioner.
10. Wo 2008069000 according to claim 9, wherein the polysiloxanes conditioner is the polysiloxanes of aryl, alkaryl or aralkyl modification.
11. Wo 2008069000 according to claim 10, wherein the polysiloxanes conditioner is the polysiloxanes of aralkyl modification.
12. according to each described Wo 2008069000 among the claim 9-11, wherein the polysiloxanes conditioner is a polyorganosiloxane resin.
13. Wo 2008069000 according to claim 12, wherein polyorganosiloxane resin accounts for 0.001% to 10% of whole composition weight.
14. Wo 2008069000 according to claim 12, wherein the viscosity of polyorganosiloxane resin is less than 5000mm
2s
-1
15. Wo 2008069000 according to claim 14, wherein the viscosity of polyorganosiloxane resin is less than 1000mm
2s
-1
16. Wo 2008069000 according to claim 15, wherein the viscosity of polyorganosiloxane resin is less than 600mm
2s
-1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1998/015749 WO2000006093A1 (en) | 1998-07-30 | 1998-07-30 | Hair care compositions |
| USPCT/US98/15749 | 1998-07-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1310606A CN1310606A (en) | 2001-08-29 |
| CN1194658C true CN1194658C (en) | 2005-03-30 |
Family
ID=22267578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB998089745A Expired - Fee Related CN1194658C (en) | 1998-07-30 | 1999-03-26 | Hair care compositions |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1100438A1 (en) |
| JP (1) | JP4007479B2 (en) |
| CN (1) | CN1194658C (en) |
| AU (2) | AU8760598A (en) |
| BR (1) | BR9912540A (en) |
| CA (1) | CA2337165C (en) |
| WO (2) | WO2000006093A1 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6627183B1 (en) | 1998-07-30 | 2003-09-30 | The Procter & Gamble Company | Hair care compositions |
| BR0008335A (en) * | 1999-02-19 | 2002-01-29 | Procter & Gamble | Leave-in cosmetic composition, treatment process, use of a polymer containing cations and use of a composition |
| US7939601B1 (en) | 1999-05-26 | 2011-05-10 | Rhodia Inc. | Polymers, compositions and methods of use for foams, laundry detergents, shower rinses, and coagulants |
| ES2317838T3 (en) | 1999-05-26 | 2009-05-01 | Rhodia Inc. | BLOCK POLYMERS, COMPOSITIONS AND METHODS OF USING FOAMS, DETERGENTS FOR LAUNDRY, CLEARING AGENTS FOR SHOWER AND COAGULANTS. |
| US7405188B2 (en) * | 2001-12-12 | 2008-07-29 | Wsp Chemicals & Technology, Llc | Polymeric gel system and compositions for treating keratin substrates containing same |
| US8273693B2 (en) * | 2001-12-12 | 2012-09-25 | Clearwater International Llc | Polymeric gel system and methods for making and using same in hydrocarbon recovery |
| US20030114315A1 (en) * | 2001-12-12 | 2003-06-19 | Clearwater, Inc. | Polymeric gel system and use in hydrocarbon recovery |
| CN106420398A (en) * | 2016-11-22 | 2017-02-22 | 郑州兰茜生物工程有限公司 | Leave-on waterborne spraying type hair conditioner and preparation method thereof |
| MX2023014888A (en) | 2021-06-30 | 2024-02-12 | Unilever Ip Holdings B V | Transparent cosmetic and personal care compositions. |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5883058A (en) * | 1995-08-29 | 1999-03-16 | The Procter & Gamble Company | High lather styling shampoos |
| JP3395488B2 (en) * | 1995-11-15 | 2003-04-14 | 味の素株式会社 | Hair cosmetics |
| US5681546A (en) * | 1996-03-18 | 1997-10-28 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Hair styling mousse |
| US5932202A (en) * | 1996-03-27 | 1999-08-03 | The Procter & Gamble Company | Conditioning shampoo composition |
| WO1997035542A1 (en) * | 1996-03-27 | 1997-10-02 | The Procter & Gamble Company | Conditioning shampoo compositions containing polyalphaolefin conditioner |
| US6221817B1 (en) * | 1996-03-27 | 2001-04-24 | The Procter & Gamble Company | Conditioning shampoo composition |
| GB9616411D0 (en) * | 1996-08-05 | 1996-09-25 | Unilever Plc | Shampoo compositions and method |
| US6248317B1 (en) * | 1996-10-25 | 2001-06-19 | The Procter & Gamble Company | Styling shampoo compositions with improved styling polymer deposition |
| AU4918597A (en) * | 1996-10-25 | 1998-05-22 | Procter & Gamble Company, The | Conditioning shampoo compositions containing emulsion polymerized polymer |
| EP0948315A1 (en) * | 1996-12-30 | 1999-10-13 | The Procter & Gamble Company | Conditioning shampoo compositions |
-
1998
- 1998-07-30 WO PCT/US1998/015749 patent/WO2000006093A1/en active Application Filing
- 1998-07-30 AU AU87605/98A patent/AU8760598A/en not_active Abandoned
-
1999
- 1999-03-26 CA CA002337165A patent/CA2337165C/en not_active Expired - Fee Related
- 1999-03-26 EP EP99914962A patent/EP1100438A1/en not_active Ceased
- 1999-03-26 CN CNB998089745A patent/CN1194658C/en not_active Expired - Fee Related
- 1999-03-26 JP JP2000561959A patent/JP4007479B2/en not_active Expired - Fee Related
- 1999-03-26 AU AU33591/99A patent/AU3359199A/en not_active Abandoned
- 1999-03-26 WO PCT/US1999/006114 patent/WO2000006102A1/en active Application Filing
- 1999-03-26 BR BR9912540-4A patent/BR9912540A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000006102A1 (en) | 2000-02-10 |
| AU3359199A (en) | 2000-02-21 |
| BR9912540A (en) | 2001-05-02 |
| WO2000006093A1 (en) | 2000-02-10 |
| CN1310606A (en) | 2001-08-29 |
| JP4007479B2 (en) | 2007-11-14 |
| EP1100438A1 (en) | 2001-05-23 |
| AU8760598A (en) | 2000-02-21 |
| CA2337165A1 (en) | 2000-02-10 |
| JP2003524596A (en) | 2003-08-19 |
| CA2337165C (en) | 2003-05-27 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050330 |