CN1443837A - Detergent composition - Google Patents
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- CN1443837A CN1443837A CN 03119455 CN03119455A CN1443837A CN 1443837 A CN1443837 A CN 1443837A CN 03119455 CN03119455 CN 03119455 CN 03119455 A CN03119455 A CN 03119455A CN 1443837 A CN1443837 A CN 1443837A
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Abstract
A detergent composition is comprised by the following component (A), (B) and (C): (A) a phosphoric ester surfactant being a mixture of (a<SB>1</SB>) a phosphoric monoester represented by formula (1) with (a<SB>2</SB>) a phosphoric diester represented by formula (2) in an (a<SB>1</SB>)/(a<SB>2</SB>) weight ratio of 85/15 to 50/50, (B) a higher fatty acid represented by formula (3): R<SP>4</SP>-COOM or a salt thereof; and (C) a sulfobetaine represented by formula (4). The detergent composition is lowly irritating to the skin, excellent in foamability, capable of giving creamy foam quality and good application texture, excellent in low-temperature stability, and easy to formulate in production.
Description
Technical field
The present invention relates to the cleansing composition little to pungencys such as skins, that low-temperature stability good, whipability good, alveolar substance is satiny and usability is good.
Background technology
The phosphoric acid ester tensio-active agent is compared with soap, alkyl ether sulphate, alkyl sulfuric ester etc., since low to the pungency of skin or hair, so be widely used as the composition of skin cleaning agent.Just because this feature, so be widely used in the mixed stocker that other anion surfactant inclusive NAND ionic surface active agent mixes mutually etc.
, the phosphoric acid ester tensio-active agent is generally obtained by monoesters and two ester mixtures, then is mixed with the also poor dialkyl group phosphoric acid of poorly water-soluble, foaming power in the alkyl phosphate.When the main component that they is used alone as detergent is used,, therefore there is the people to propose the method for other compounding aid owing to generally can have problems at aspects such as foaming power, low-temperature stabilities.To have the method (with reference to spy open clear 62-138594 communique) of the hydroxyl sulfo betaine of ad hoc structure as auxiliary agent, be a kind ofly to strengthen whipability, improving aspect the low-temperature stability, but do not satisfy the requirement of foaming power, alveolar substance two aspects simultaneously than more excellent method.In addition, with the method (with reference to spy open clear 53-26808 communique) of amino third sultaine of trialkyl Padil trimethyl-glycine or trialkyl, improved foaming power and water-soluble, but also do not satisfied the requirement of foaming power and alveolar substance two aspects simultaneously as auxiliary agent.
On the other hand, use amine oxide and higher fatty acid salt method (opening clear 58-103598 communique) with reference to the spy as auxiliary agent, when using alkylphosphonate, improving the effect that has aspect foaming power, the alveolar substance to a certain degree, if but the ratio of alkylphosphonate/dialkyl phosphate salt is difficult to satisfy the requirement of foaming power and alveolar substance two aspects less than 90/10.
Therefore, the purpose of this invention is to provide little to stimulations such as skins, whipability good, alveolar substance is satiny, usability is good, low-temperature stability is good, the cleansing composition that is easy to allocate when making.
Summary of the invention
The inventor etc. are for the cleansing composition that uses the phosphoric acid ester tensio-active agent, be used with specific sultaine by higher fatty acid or its salt, discovery can make the cleansing composition little to skin irritation, that low-temperature stability good, whipability good, alveolar substance is satiny and usability is good.And, because it is the composition of this composition, so be easy to allotment when making.
That is, the invention provides and contain following composition (A), (B) and cleansing composition (C) and manufacture method thereof:
(A) phosphoric acid ester tensio-active agent, it is
(a
1) with the phosphate monoester of general formula (1) expression and
(a
2) with the mixture of the phosphodiester of general formula (2) expression, its weight ratio that contains ratio is (a
1)/(a
2)=85/15～50/50
(R in the formula
1, R
2And R
3Represent that respectively carbonatoms is 8～18 straight or branched alkyl or alkenyl, X
1, X
2And Y represents hydrogen atom, alkali metal atom, alkaline earth metal atom, alkanolamine or ammonium respectively, and on average additional mole number k, m, n represent 0～10 numeral respectively);
(B) with general formula (3)
R
4-COOM (3) (R in the formula
4The expression carbonatoms is 7～17 saturated or unsaturated fatty hydrocarbons base, and M represents hydrogen atom, alkali metal atom, alkanolamine or ammonium) higher fatty acid or its salt of expression;
(C) with general formula (4)
(R in the formula
5The expression carbonatoms is 8～18 saturated or unsaturated alkyl, R
6And R
7Represent that respectively methyl, Z represent hydrogen atom or hydroxyl) expression sultaine.
Embodiment
Be used for the phosphoric acid ester with general formula (1) and (2) expression of the present invention, R at composition (A) as the low irritant base
1, R
2And R
3Be preferably carbonatoms 10～16, be preferably the alkyl of carbonatoms 12～14 especially; X
1, X
2And Y is preferably potassium or such alkali metal atom or the trolamine of sodium, from water-soluble aspect, is preferably potassium especially.From the viewpoint of foaming power, oxyethane on average additional mole number k, m and n are preferably 0～4 mole, preferred especially 0～2 mole.
The viewpoint that alkyl phosphate monoester (a1) in the composition (A) and alkylphosphonic acid carboxylic acid diester (a2) are easy to allocate when containing ratio from manufacturing, weight ratio is (a1)/(a2)=85/15～50/50, is preferably 80/20～70/30.Alkyl phosphate monoester (a1) contain rate when low, whipability is poor; Contain rate when high, the fusing point height of the mixture of alkyl phosphate is difficult to preparation.
The content of the phosphoric acid ester tensio-active agent of composition (A) sees that by whipability, clearing power and the viewpoint that is easy to allocate cleansing composition of the present invention is preferably 5～40 weight %, is preferably 8～30 weight % especially.
In the higher fatty acid or its salt with general formula (3) expression of composition (B), R
4Be preferably carbonatoms 9～17, more preferably carbonatoms 11～17, are preferably the alkyl of carbonatoms 11～13 especially; M is preferably alkali metal atom, alkanolamine or ammonium, is preferably the such alkali metal atom of potassium or sodium especially.
This higher fatty acid salt also can modulate higher fatty acid and alkali generation neutralization reaction by in the matching piece of making cleansing composition.And the part of higher fatty acid salt also can be carried out the salt displacement with the counterion of phosphate ester salt, and does not hinder effect of the present invention.
Composition (B) can cause the not available effect of improving alveolar substance of composition (C),, causes clammy alveolar substance that is, has also improved whipability in addition.
Can separately or mix higher fatty acid or its salt that ground uses composition (B) more than 2 kinds.The content of composition (B) is preferably 1～20 weight % from giving the aspect of cleansing composition detergency of the present invention, whipability, and more preferably 1～10 weight % is preferably 2～8 weight % especially.
In cleansing composition of the present invention, although the preferred content of composition (A) and composition (B) can be as mentioned above, but, from the sense of touch of clearing power, foaming power, bubble and to the pungency aspect of skin, composition (A) and composition (B) contain ratio, preferred weight ratio is 95/5～50/50, is preferably 90/10～70/30 especially.
The sultaine of composition (C) is represented with above-mentioned general formula (4).In formula (4), Z is preferably hydroxyl, R
5The alkyl or the alkenyl of preferred carbonatoms 10～16, more preferably Z is hydroxyl and R
5Alkyl or alkenyl, particularly R for carbonatoms 10～16
5Be lauryl or myristyl, promptly be preferably lauryl dimethyl hydroxyl sulfo betaine and myristyl dimethyl hydroxyl sultaine.
Composition (C) has the effect of keeping low-temperature stability, improving foaming power.
The content of composition (C) is preferably 0.1～20 weight % of cleansing composition of the present invention, and more preferably 1～15 weight % is preferably 2～12 weight % especially.
With respect to composition (A) and total content (B), the ratio of the content of composition (C), from improving the viewpoint of low-temperature stability and foaming power, preferred weight ratio is [(A)+(B)]/(C)=40/2～10/7, is preferably 30/2～20/7 especially.
By also reaching (C), when having kept phosphoric acid ester tensio-active agent inherent low irritant, also improved the shortcoming of phosphoric acid ester tensio-active agent aspect whipability and alveolar substance with composition (A), (B).Alveolar substance is preferably clammy.And, also have the peculiar usability of phosphoric acid ester tensio-active agent, promptly the skin of Gong Rening does not have tight sense, and usability is good.In addition, because the present invention adopts above-mentioned composition,, be easy to allotment during manufacturing so viscosity can not rise when making.
Corresponding to application target, in the scope of harmless effect of the present invention, cleansing composition of the present invention can also cooperate pigment, spices, sterilant, antiphlogistic, sequestrant, suds booster, thickening material, viscosity modifier, pearling agent, sanitas, wetting agent, pH value conditioning agent and other tensio-active agent etc.
Formulation for cleansing composition of the present invention has no particular limits, and according to existing known various formulations, can be assumed to be for example liquid shampoo, butteriness Cleansing Foam, bathing agents etc.
The manufacture method of cleansing composition of the present invention comprises following operation:
1) modulation contains composition (A), (B) and mixture (C);
2) container of then this mixture being packed into.
When composition (A), (B) are reached (C) mixing, needn't consider their order, also can mix simultaneously.Because viscosity can increase during known cooperation composition (A), therefore preferably under 40～80 ℃, carry out heated and stirred.
By having the cleansing composition that the present invention forms,, therefore can below 10000mPas, make owing to when mixing, do not produce violent tackified phenomenon.
Embodiment
Embodiment 1～12 and comparative example 1～6
Mix each composition down at 70 ℃ and make the cleansing composition (pH is adjusted into 7～8) shown in table 1～3, state, foaming power, whipability, alveolar substance, usability and low-temperature stability during to manufacturing are estimated.The result is shown in table 1～3.
State when (1) making
State when cleansing composition is made by following standard, is with the naked eye estimated.
Zero: be easy to allotment
*: viscosity rises and can not allocate
(2) foaming power experiment
Add lanolin 0.5% 3% (4 of cleansing composition to as artificial dirt.Hard water) in the aqueous solution.Under 40 ℃, revolution 1000rpm made under the condition of turning direction counter-rotating in per 10 seconds, stirred 5 minutes in tube, estimated according to the bubble amount that stirs after finishing with the flat pattern blade.
(3) whipability, alveolar substance and usability
Whipability and alveolar substance when estimating clean hand, wrist by 10 special members according to following judgement criteria will be coated on the palm according to the synthetic cleansing composition 1g of ordinary method.
(whipability)
A: the bubble amount is very many.
B: the bubble amount is many.
C: the bubble amount is few slightly.
D: the bubble amount is few.
(alveolar substance)
A: fine and smooth and very clammy good alveolar substance.
B: clammy good alveolar substance.
C: clammy slightly alveolar substance.
D: slight coarse alveolar substance.
(usability)
A: usability is good.
B: usability is good slightly.
C: usability is poor.
(4) low-temperature stability experiment
Cleansing composition is packed in the vial, 5 ℃ preserve 10 days down after, take out down from 5 ℃, at room temperature (25 ℃) were placed 1 hour, by following standard, with the naked eye estimated outward appearance.
◎: transparent.
Zero: muddy a little.
△: slight haze.
*: precipitate and separate takes place.
Table 1
| Composition (%) | Embodiment | ||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ????6 | ||
| (A) | / ( /＝75/25 ) / ( /＝80/20 ) / ( /＝ 70/30 ) ( 2 ) / ( 2 ) ( /＝75/25 ) ( 2 ) / ( 2 ) ( /＝75/25 ) ( 1 ) / ( 1 ) ( /＝75/25 ) ( 3 ) / ( 3 ) ( /＝80/20 ) | ????14 ????- ????- ????- ????- ????- ????- | ????14 ????- ????- ????- ????- ????- ????- | ????14 ????- ????- ????- ????- ????- ????- | ????28 ????- ????- ????- ????- ????- ????- | ????- ????14 ????- ????- ????- ????- ????- | ????- ????- ????28 ????- ????- ????- ????- |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay body/two bay body=100/0) lauryl nitranol salt/dilauryl nitranol salt (single bay body/two bay body=35/65) | ????- ????- | ????- ????- | ????- ????- | ????- ????- | ????- ????- | ????- ????- | |
| (B) | Potassium laurate potassium myristate sodium laurate Sodium myristate potassium palmitate potassium stearate palmitic acid triethanolamine myristic acid triethanolamine | ????3 ????2 ????- ????- ????- ????- ????- ????- | ????- ????- ????5 ????2 ????- ????- ????- ????- | ????5 ????2 ????- ????- ????- ????- ????- ????- | ????2.5 ????2.5 ????- ????- ????- ????- ????- ????- | ????5 ????- ????- ????- ????- ????- ????- ????- | ????2.5 ????2.5 ????- ????- ????- ????- ????- ????- |
| (C) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine | ????- ????- | ????3 ????- | ????- ????7 | ????3 ????- | ????2 ????- | ????10 ????- |
| Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| State during manufacturing | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | |
| Foaming power (ml) | ????210 | ????205 | ????210 | ????250 | ????215 | ????210 | |
| Whipability alveolar substance usability low-temperature stability | ????B ????A ????A ????○ | ????B ????A ????A ????○ | ????B ????A ????A ????◎ | ????A ????A ????A ????○ | ????B ????A ????A ????○ | ????A ????A ????A ????◎ | |
Table 2
| Composition (%) | Embodiment | ||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ????6 | ||
| (A) | / ( /＝75/25 ) / ( /＝80/20 ) / ( /＝70/30 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 2 ) / ( 2 ) ( /＝75/25 ) ( 1 ) / ( 1 ) ( / ＝75/25 ) ( 3 ) / ( 3 ) ( / ＝80/20 ) | ????14 ????- ????- ????- ????- ????- ????- | ????14 ????- ????- ????- ????- ????- ????- | ????- ????- ????- ????14 ????- ????- ????- | ????- ????- ????- ????10.5 ????3.5 ????- ????- | ????- ????- ????- ????- ????- ????14 ????- | ????- ????- ????- ????- ????- ????- ????14 |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay body/two bay body=100/0) lauryl nitranol salt/dilauryl nitranol salt (single bay body/two bay body=35/65) | ????- ????- | ????- ????- | ????- ????- | ????- ????- | ????- ????- | ????- ????- | |
| (B) | Potassium laurate potassium myristate sodium laurate Sodium myristate potassium palmitate potassium stearate palmitic acid triethanolamine Rou Dou guan triethylenetetraminehexaacetic acid hydramine | ????3.5 ????1.5 ????- ????- ????0.6 ????0.4 ????- ????- | ????- ????- ????- ????- ????- ????- ????5 ????2 | ????3 ????2 ????- ????- ????- ????- ????- ????- | ????3 ????2 ????- ????- ????- ????- ????- ????- | ????2.5 ????2.5 ????- ????- ????- ????- ????- ????- | ????3 ????2 ????- ????- ????- ????- ????- ????- |
| (C) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine | ????5 ????- | ????5 ????- | ????5 ????- | ????7 ????- | ????5 ????- | ????5 ????- |
| Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| State during manufacturing | ????○ | ????○ | ????○ | ????○ | ????○ | ????○ | |
| Foaming power (ml) | ????205 | ????215 | ????212 | ????220 | ????211 | ????200 | |
| Whipability alveolar substance usability low-temperature stability | ????B ????A ????A ????○ | ????B ????A ????A ????◎ | ????B ????A ????A ????○ | ????A ????A ????A ????○ | ????A ????A ????A ????○ | ????B ????A ????A ????○ | |
Table 3
Embodiment 13 (bathing agents)
| Composition (%) | Embodiment | ||||||
| ????1 | ????2 | ????3 | ????4 | ????5 | ????6 | ||
| (A) | / ( /＝75/25 ) / ( /＝80/20 ) / ( /＝70/30 ) ( 2 ) / ( 2 ) ( /＝ 75/25 ) ( 2 ) / ( 2 ) ( / ＝75/25 ) ( 1 ) / ( 1 ) ( /＝ 75/25 ) ( 3 ) / ( 3 ) ( /＝ 80/20 ) | ????14 ????- ????- ????- ????- ????- ????- | ????14 ????- ????- ????- ????- ????- ????- | ????- ????- ????- ????- ????- ????- ????- | ?????- ?????- ?????- ?????- ?????- ?????- ?????- | ????- ????- ????- ????14 ????- ????- ????- | ????- ????- ????- ????14 ????- ????- ????- |
| Lauryl potassium phosphate salt/dilauryl potassium phosphate salt (single bay body/two bay body=100/0) lauryl nitranol salt/dilauryl nitranol salt (single bay body/two bay body=35/65) | ????- ????- | ????- ????- | ????- ????14 | ????28 ????- | ????- ????- | ????- ????- | |
| (B) | Potassium laurate potassium myristate sodium laurate Sodium myristate potassium palmitate potassium stearate palmitic acid triethanolamine myristic acid triethanolamine | ????- ????- ????- ????- ????- ????- ????- ????- | ????3 ????2 ????- ????- ????- ????- ????- | ????5 ????2 ????- ????- ????- ????- ????- ????- | ????2.5 ????2.5 ????- ????- ????- ????- ????- ????- | ????- ????- ????- ????- ????- ????- ????- ????- | ????3 ????2 ????- ????- ????- ????- ????- ????- |
| (C) | Lauryl hydroxyl sulfo betaine myristyl hydroxyl sulfo betaine | ????5 ????- | ????- ????- | ????- ????7 | ????3 ????- | ????5 ????- | ????- ????- |
| Pure water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | |
| State during manufacturing | ????○ | ????○ | ????○ | ????× | ????○ | ????○ | |
| Foaming power (ml) | ????150 | ????165 | ????85 | ?????- | ????135 | ????150 | |
| Whipability alveolar substance usability low-temperature stability | ????C ????D ????A ????○ | ????C ????B ????C ????× | ????D ????D ????A ????○ | ?????- ?????- ?????- ?????- | ????C ????D ????A ????○ | ????C ????B ????C ????× | |
Make bathing agents with following prescription.
(weight portion)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 15
(single bay body/two bay body=75/25)
Potassium laurate 2.5
Potassium myristate 2.5
Propylene glycol 5
Cationic cellulose [Port イ ズ C-150L; Flower king (strain) system] 0.3
Lauryl hydroxyl sulfo betaine 5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT??????????????????????????????????????????????????0.2
Spices 0.05
The pure water surplus
100.00
Embodiment 14 (bathing agents)
Make bathing agents with following prescription.
(weight portion)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 20
(single bay body/two bay body=75/25)
Potassium laurate 7
Dipropylene glycol 2
Polyethylene oxide alkyl ethers potassium salt 2
Glycerine 3
Vinylformic acid-alkyl methacrylate multipolymer
A)0.2
Lauryl hydroxyl sulfo betaine 8
Diglycol stearate 2
Whitfield's ointment 0.2
BHT??????????????????????????????????????????????????0.2
Spices 0.05
The pure water surplus
100.00
A)Power-ボ Port-Le ETD2020; The BFGoodrich corporate system
Embodiment 13 and 14 bathing agents whipability are good, alveolar substance is satiny, the usability when cleaning is good, to the blandness of skin.
Embodiment 15 (Cleansing Foam)
Make Cleansing Foam with following prescription.
(weight portion)
Lauryl potassium phosphate salt/dilauryl potassium phosphate salt 19
(single bay body/two bay body=75/25)
Coco-nut oil fatty acid sylvite 5
Dipropylene glycol 1.5
Propylene glycol 5
Sorbitol Powder 5
Polyethylene oxide alkyl ethers potassium salt 1.8
(alkyl: C
12/ C
14=75/25, EO:10)
Three iso stearate polyoxyethylene shrink sorbitol esters 2
(EO：160)
Poise C-80M [Port イ ズ C-150L; Flower king (strain) system] 0.3
Vinylformic acid-alkyl methacrylate multipolymer
B)0.5
Lauryl hydroxyl sulfo betaine 5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT??????????????????????????????????????????????????0.2
Spices 0.05
The pure water surplus
100.00
B)Power-ボ Port-Le ETD2020; BFGoodrich corporate system embodiment 16 (Cleansing Foam)
Make Cleansing Foam with following prescription.
(weight portion)
Lauryl nitranol salt/dilauryl phosphoric acid
Triethanolamine salt (single bay body/two bay body=73/27) 19
Lauric acid triethanolamine salt 2.5
Tetradecanoic acid triethanolamine salt 2.5
Glycerine 16
Three iso stearate polyoxyethylene shrink sorbitol esters 2
(EO：160)
Poise C-80M [Port イ ズ C-150L; Flower king (strain) system] 0.5
Vinylformic acid-methacrylic acid alkyl copolymer
C)0.5
Lauryl hydroxyl sulfo betaine 5.0
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT????????????????????????????????????????????????????0.2
The pure water surplus
100.00
C)Power-ボ Port-Le ETD2020; The BFGoodrich corporate system
Embodiment 15 and 16 Cleansing Foam whipability are good, alveolar substance is satiny, the usability when cleaning is good, to the blandness of skin.
Embodiment 17 (bathing agents)
Make bathing agents with following prescription.
(weight portion)
Polyoxyethylene (2) lauryl potassium phosphate salt/
Polyoxyethylene (2) dilauryl potassium phosphate salt
(single bay body/two bay body=75/25) 15
Potassium laurate 2.5
Potassium myristate 2.5
Propylene glycol 5
Poise C-80M [Port イ ズ C-150L; Flower king (strain) system] 0.3
Lauryl hydroxyl sulfo betaine 5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT????????????????????????????????????????????????????0.2
Spices 0.05
The pure water surplus
100.00
The bathing agents whipability of embodiment 17 is good, alveolar substance is satiny, the usability when cleaning is good, to the blandness of skin.
Embodiment 18 (Cleansing Foam)
Make Cleansing Foam with following method.
(weight portion)
Polyoxyethylene (2) lauryl potassium phosphate salt/
Polyoxyethylene (2) dilauryl potassium phosphate salt
(single bay body/two bay body=75/25) 15
Polyoxyethylene (2) myristyl potassium phosphate salt/
Polyoxyethylene (2) myristyl potassium phosphate salt
(single Semen Myristicae matrix/myristyl body=75/25) 5
Coco-nut oil fatty acid sylvite 5
Dipropylene glycol 1.5
Propylene glycol 5
Sorbitol Powder 5
Polyethylene oxide alkyl ethers potassium salt 1.8
(alkyl: C
12/ C
14=75/25, EO:10)
Three iso stearate polyoxyethylene shrink sorbitol esters 2
(EO：160)
Poise C-80M [Port イ ズ C-150L; Flower king (strain) system] 0.3
Vinylformic acid-methacrylic acid alkyl copolymer
D)0.5
Lauryl hydroxyl sulfo betaine 5
Diglycol stearate 2
Methyl p-hydroxybenzoate 0.2
Propylparaben 0.1
BHT????????????????????????????????????????????????????0.2
Spices 0.05
The pure water surplus
100.00
D): power-ボ Port-Le ETD2020; The BFGoodrich corporate system
The Cleansing Foam whipability of embodiment 18 is good, alveolar substance is satiny, the usability when cleaning is good, to the blandness of skin.
Industrial applicability
Cleansing composition of the present invention is little to skin irritation, whipability good, alveolar substance is satiny and usability is good when clean, low-temperature stability good, be easy to allotment when making.
Claims (7)
1. cleansing composition is characterized in that: contain following composition (A), (B) and (C),
(A) phosphoric acid ester tensio-active agent, it is
(a
1) with general formula (1) expression phosphate monoester and
(a
2) with the mixture of phosphodiester of general formula (2) expression, their weight ratio that contains ratio is: (a
1)/(a
2)=85/15～50/50
(R in the formula
1, R
2And R
3Represent that respectively carbonatoms is 8～18 straight or branched alkyl or alkenyl, X
1, X
2And Y represents hydrogen atom, alkali metal atom, alkaline earth metal atom, alkanolamine or ammonium respectively, and on average additional mole number k, m, n represent 0～10 numeral respectively);
(B) be with general formula (3)
R
4-COOM??????????(3)
(R in the formula
4The expression carbonatoms is 7～17 saturated or unsaturated fatty hydrocarbons base, and M represents hydrogen atom, alkali metal atom, alkanolamine or ammonium) higher fatty acid or its salt of expression;
(C) be with general formula (4)
(R in the formula
5The expression carbonatoms is 8～18 saturated or unsaturated alkyl, R
6And R
7Represent that respectively methyl, Z represent hydrogen atom or hydroxyl) expression sultaine.
2. cleansing composition as claimed in claim 1 is characterized in that: composition (A) and weight ratio (B) are (A)/(B)=95/5～50/50.
3. cleansing composition as claimed in claim 1 or 2 is characterized in that: the weight ratio of the ratio of composition (A) and total amount (B) and composition (C) is [(A)+(B)]/(C)=40/2～10/7.
4. cleansing composition as claimed in claim 1 or 2 is characterized in that: the content of composition (A) is 5～40 weight %.
5. cleansing composition as claimed in claim 1 or 2 is characterized in that: the content of composition (B) is 1～20 weight %.
6. cleansing composition as claimed in claim 1 or 2 is characterized in that: the content of composition (C) is 0.1～20 weight %.
7. the manufacture method of cleansing composition as claimed in claim 1 is characterized in that: have with composition (A), (B) and (C) mixing, in the operation of 40～80 ℃ of following heated and stirred.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002066686 | 2002-03-12 | ||
| JP2002066686 | 2002-03-12 | ||
| JP2002292353A JP3813563B2 (en) | 2002-03-12 | 2002-10-04 | Cleaning composition |
| JP2002292353 | 2002-10-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1443837A true CN1443837A (en) | 2003-09-24 |
| CN100400632C CN100400632C (en) | 2008-07-09 |
Family
ID=28043688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031194559A Expired - Lifetime CN100400632C (en) | 2002-03-12 | 2003-03-12 | Detergent composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3813563B2 (en) |
| CN (1) | CN100400632C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101415810B (en) * | 2006-04-07 | 2011-06-22 | 花王株式会社 | Cleanser composition |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060142174A1 (en) * | 2003-04-14 | 2006-06-29 | Kao Corporation | Cleaning agent composition |
| JP5592051B2 (en) * | 2007-11-09 | 2014-09-17 | 花王株式会社 | Liquid detergent composition |
| JP2009275010A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
| JP2009275012A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
| JP2009275009A (en) * | 2008-05-16 | 2009-11-26 | Kao Corp | Skin cleanser composition |
| JP6482181B2 (en) * | 2014-03-31 | 2019-03-13 | ミヨシ油脂株式会社 | Transparent liquid detergent composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943517B2 (en) * | 1981-12-14 | 1984-10-22 | 花王株式会社 | liquid cleaning composition |
| JPH0246639B2 (en) * | 1985-12-12 | 1990-10-16 | Kao Corp | SENJOZAISOSEIBUTSU |
| JP3327889B2 (en) * | 1999-12-24 | 2002-09-24 | 花王株式会社 | Detergent composition |
-
2002
- 2002-10-04 JP JP2002292353A patent/JP3813563B2/en not_active Expired - Fee Related
-
2003
- 2003-03-12 CN CNB031194559A patent/CN100400632C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101415810B (en) * | 2006-04-07 | 2011-06-22 | 花王株式会社 | Cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3813563B2 (en) | 2006-08-23 |
| JP2003336091A (en) | 2003-11-28 |
| CN100400632C (en) | 2008-07-09 |
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