CN1429468A - Method of increasing length of life of heating elements at low temperatures - Google Patents
Method of increasing length of life of heating elements at low temperatures Download PDFInfo
- Publication number
- CN1429468A CN1429468A CN01809573A CN01809573A CN1429468A CN 1429468 A CN1429468 A CN 1429468A CN 01809573 A CN01809573 A CN 01809573A CN 01809573 A CN01809573 A CN 01809573A CN 1429468 A CN1429468 A CN 1429468A
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- CN
- China
- Prior art keywords
- water content
- volume
- atmosphere
- temperature
- heating elements
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000010438 heat treatment Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 7
- 229910021344 molybdenum silicide Inorganic materials 0.000 claims abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 229910001182 Mo alloy Inorganic materials 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 3
- 239000000956 alloy Substances 0.000 abstract description 3
- MGRWKWACZDFZJT-UHFFFAOYSA-N molybdenum tungsten Chemical compound [Mo].[W] MGRWKWACZDFZJT-UHFFFAOYSA-N 0.000 abstract 1
- 229910021342 tungsten silicide Inorganic materials 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910016006 MoSi Inorganic materials 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/148—Silicon, e.g. silicon carbide, magnesium silicide, heating transistors or diodes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/018—Heaters using heating elements comprising mosi2
Landscapes
- Resistance Heating (AREA)
- Ceramic Products (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Silicon Compounds (AREA)
Abstract
A method of lengthening the useful life of heating elements that are essentially comprised of molybdenum silicide and molybdenum tungsten silicide and different alloys of these basic materials, when the elements are operated at a relatively low temperature, such as a temperature in the range of 400-800 DEG C, The invention is characterised in that the atmosphere surrounding the elements as they operate is caused to have a water content that is less than about one percent by volume.
Description
Invention field
The present invention relates to prolong heating element (heating elements) method in useful life at low temperatures, more specifically, prolong and to contain molybdenum silicide and molybdenum silicide tungsten, comprise useful life of element of the various alloys of these base materials.This element is to be prepared in a large amount of applications by the applicant.
Background of invention
When this element under low relatively temperature, when under about 400-500 ℃ temperature, operating, will can not generate the silica shell (scale) (so-called glassy layer) of protectiveness, this is opposite when at high temperature element being operated.On the contrary, element can suffer from so-called harmful substance (pest), and the meaning is the MoO that can form non-protective on the surface of element
3And SiO
2Layer.This mixture be porous and be easy to decompose, thereby obviously shortened the useful life of element.
But, however, some application scenario also this element as best choice.When an example in this respect is the heating of LPCVD chamber (low pressure chemical vapor deposition) in making electronic circuit.
The cryogenic properties of this heating element can by under about 1500 ℃ or higher temperature with element pre-oxidation to form SiO
2Top layer (skin) and being improved.The formation of harmful substance will be slowed down in this top layer.
The method that is proposed can prolong the useful life of this heating element greatly.
Technical scheme
Therefore, the present invention relates to a kind of heating element that prolongs the various alloys that mainly contain molybdenum silicide and molybdenum silicide tungsten and these base materials at low temperatures, method as useful life in when operation under 400-800 ℃ the temperature, wherein said method is characterised in that when described element is operated, and makes the water content of component ambient atmosphere be lower than about 1 volume %.
The present invention is based on a wonderful discovery, that is, even oxygen content is very high in the gas, but water content remains on low-level the time in the component ambient gas, the MoO of formation
3And SiO
2The amount of oxide products can be few.
The accompanying drawing summary
Referring now to accompanying drawing the present invention is explained in detail, wherein:
Fig. 1 shows for gas with various, oxide thickness and time relation figure and
Fig. 2 shows the weightening finish that caused by oxidation and the graph of a relation of ambient gas water content.
Detailed Description Of The Invention
The present invention relates to a kind of prolong mainly contain the molybdenum silicide and the various alloys of molybdenum silicide tungsten and these base materials heating element under relative low temperature, as the method in useful life in when operation under 400-800 ℃ the temperature.In this temperature range, this element suffers from so-called harmful substance.On the one hand, the operating temperature of element is along with the using method of element changes, and on the other hand, it is also formed along with the material of element and changes.
Harmful substance is by MoSi
2And O
2Form MoO
3And SiO
2Therefore the relative porous of this oxide mixture can not provide any protection to avoid continuing oxidation.
According to the present invention, the vapour content of surrounding atmosphere is lower than about 1 volume % in the time of making element operation, and this can make the growth of harmful substance significantly reduce.
MoO under different atmosphere when Fig. 1 illustrates 450 ℃
3And SiO
2Oxide thickness.In Fig. 1, the water content that dry air means air is 0.0005 volume %.Oxygen (O
2) be meant quite dry oxygen, O
2+ 10% H
2O means the oxygen that has 10 volume % water.
Can find out significantly that from Fig. 1 oxide growth has obtained great restriction, and basic identical concerning dry air and dry oxygen, and when surrounding atmosphere contained 10 volume % water, it is fast more than 10 times that oxide growth rate is wanted.
When Fig. 2 illustrates component temperature and is 450 ℃, owing to the relation between the volume % that forms water content in material weightening finish that described oxide takes place and the heating element surrounding atmosphere.
Can clearly find out from Fig. 2, oxidation, the formation of harmful substance is along with the increase of water content is linearly risen.
Confirmed already that the water content of atmosphere can form different oxide structures not simultaneously around.
Under 450 ℃, after 72 hours and 210 hours, can form respectively by being embedded into amorphous Si O
2In MoO
3The oxide that-crystal is formed, the ratio of these two kinds of oxides seems to be maintained fixed constant.
In the oxygen atmosphere that contains 10 volume % water, after 72 hours and 210 hours, can form more MoO respectively
3-crystal.With respect to MoO
3Ratio, seem SiO
2The ratio regular meeting constantly reduce along with the time.
Therefore, the water content of surrounding atmosphere can influence the structure and the quantity of the oxide that forms.The structure of the oxide that forms and quantitative proportion can be used for explaining discussed above, with respect to the water content of ambient gas, and the very big difference that growth took place of oxide.
Can show that also the amount of oxygen is for the not significantly influence of growth of oxide in the surrounding atmosphere.
As what mention in introduction, in some industrial process, aforementioned components is used under described temperature.
As previously mentioned, the invention is characterized in and make that water content is lower than about 1 volume % in the surrounding atmosphere.Fig. 2 shows, in this case, oxide growth is big a little during only than the atmosphere that uses white drying.
But, preferably water content is controlled at and is lower than about 0.5 volume %.
According to the preferred embodiments of the invention, the atmosphere of component ambient is made up of the air with aforementioned water content, and the air of this aridity can also can obtain dry air by air cylinder by being purchased device or equipment is produced.
According to another preferred embodiment, atmosphere is made up of the oxygen with aforementioned water content, and bottled dry oxygen can be used for this purpose.
The selection of atmosphere will depend on the using method of heating element.
Aspect the formation oxide, the atmosphere that is different from air and oxygen also may produce corresponding results, and condition is that described atmosphere has water content of the present invention.For example can use nitrogen or inert gas.
Therefore, will be understood that the present invention will be not limited to aforesaid component ambient atmosphere.
Claims (4)
1. a prolongation mainly contains the heating element of the molybdenum silicide and the various alloys of molybdenum silicide tungsten and these base materials under relative low temperature, method as useful life in when operation under 400-800 ℃ the temperature, it is characterized in that when described element is operated, make the water content of component ambient atmosphere be lower than about 1 volume %.
2. according to the method for claim 1, it is characterized in that atmosphere is made up of the air that water content is lower than about 1 volume %.
3. according to the method for claim 1, it is characterized in that atmosphere is made up of the oxygen that water content is lower than about 1 volume %.
4. according to claim 1,2 or 3 method, it is characterized in that making water content to be lower than about 0.5 volume %.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE00018465 | 2000-05-18 | ||
| SE0001846A SE519027C2 (en) | 2000-05-18 | 2000-05-18 | A method for increasing the life of heating elements at lower temperatures |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1429468A true CN1429468A (en) | 2003-07-09 |
| CN1173600C CN1173600C (en) | 2004-10-27 |
Family
ID=20279729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018095739A Expired - Fee Related CN1173600C (en) | 2000-05-18 | 2001-05-16 | Method of increasing length of life of heating elements at low temperatures |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6707016B2 (en) |
| EP (1) | EP1283004A1 (en) |
| JP (1) | JP3761817B2 (en) |
| KR (1) | KR100510949B1 (en) |
| CN (1) | CN1173600C (en) |
| AU (1) | AU2001260896A1 (en) |
| SE (1) | SE519027C2 (en) |
| WO (1) | WO2001089266A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7770045B2 (en) | 2003-12-09 | 2010-08-03 | Kuka Roboter Gmbh | Method and apparatus for operating cooperating, differing devices |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE520149C2 (en) * | 2000-09-29 | 2003-06-03 | Sandvik Ab | Method for increasing the life of lower temperature molybdenum silicide type heaters |
| SE521794C2 (en) * | 2002-04-05 | 2003-12-09 | Sandvik Ab | Manufacturing process for a molybdenum silicon type heating element, as well as a heating element |
| SE521796C2 (en) * | 2002-04-05 | 2003-12-09 | Sandvik Ab | Process for manufacturing a molybdenum silicon type heating element and a heating element |
| ES2291624T3 (en) * | 2002-04-05 | 2008-03-01 | Sandvik Intellectual Property Ab | METHOD FOR THE MANUFACTURE OF A THERMAL ELEMENT OF MOLIBDENE SILICON TYPE. |
| PL2344428T3 (en) * | 2008-10-22 | 2014-05-30 | Sandvik Intellectual Property | Molybdenum silicide composite material |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH088140B2 (en) * | 1992-05-08 | 1996-01-29 | 株式会社リケン | Method for manufacturing molybdenum disilicide heater |
| SE504235C2 (en) * | 1995-04-11 | 1996-12-09 | Kanthal Ab | Electrical resistance element of molybdenum silicide type |
| WO1996032358A1 (en) | 1995-04-11 | 1996-10-17 | Micropyretics Heaters International | Ceramic, intermetallic or metal ceramic composites with a reduced susceptibility to pesting |
| JPH10104067A (en) | 1996-09-27 | 1998-04-24 | Fuji Electric Co Ltd | Infrared light source of molybdenum disilicide composite ceramics or heating source |
| JPH10324571A (en) | 1997-05-23 | 1998-12-08 | Riken Corp | Molybdenum disilicide ceramic heat generating body and its production |
| JP3657800B2 (en) * | 1998-02-20 | 2005-06-08 | 株式会社リケン | Molybdenum disilicide-based composite ceramic heating element and manufacturing method thereof |
| US6143206A (en) * | 1998-06-24 | 2000-11-07 | Tdk Corporation | Organic positive temperature coefficient thermistor and manufacturing method therefor |
| JP3001857B1 (en) * | 1998-07-31 | 2000-01-24 | 株式会社ジャパンエナジー | Heat generation material mainly composed of MoSi2 having an electrode part excellent in low-temperature oxidation resistance |
| SE520251C2 (en) * | 1999-05-20 | 2003-06-17 | Sandvik Ab | Molybdenum silicon type resistance elements for metal powder sintering |
| SE513990C2 (en) * | 1999-11-18 | 2000-12-11 | Sandvik Ab | High strength molybdenum silicide material |
-
2000
- 2000-05-18 SE SE0001846A patent/SE519027C2/en not_active IP Right Cessation
-
2001
- 2001-05-16 AU AU2001260896A patent/AU2001260896A1/en not_active Abandoned
- 2001-05-16 KR KR10-2002-7015271A patent/KR100510949B1/en not_active IP Right Cessation
- 2001-05-16 CN CNB018095739A patent/CN1173600C/en not_active Expired - Fee Related
- 2001-05-16 EP EP01934742A patent/EP1283004A1/en not_active Withdrawn
- 2001-05-16 JP JP2001585126A patent/JP3761817B2/en not_active Expired - Fee Related
- 2001-05-16 US US10/275,168 patent/US6707016B2/en not_active Expired - Fee Related
- 2001-05-16 WO PCT/SE2001/001081 patent/WO2001089266A1/en not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7770045B2 (en) | 2003-12-09 | 2010-08-03 | Kuka Roboter Gmbh | Method and apparatus for operating cooperating, differing devices |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030020279A (en) | 2003-03-08 |
| SE0001846D0 (en) | 2000-05-18 |
| KR100510949B1 (en) | 2005-10-10 |
| JP2003533858A (en) | 2003-11-11 |
| SE519027C2 (en) | 2002-12-23 |
| WO2001089266A1 (en) | 2001-11-22 |
| US6707016B2 (en) | 2004-03-16 |
| JP3761817B2 (en) | 2006-03-29 |
| SE0001846L (en) | 2001-11-19 |
| US20030150851A1 (en) | 2003-08-14 |
| AU2001260896A1 (en) | 2001-11-26 |
| CN1173600C (en) | 2004-10-27 |
| EP1283004A1 (en) | 2003-02-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20050701 Address after: Sandviken Patentee after: Sandvik AB Address before: Sandviken Patentee before: Sandvik AB |
|
| ASS | Succession or assignment of patent right |
Owner name: EUROPEAN SOLAR CO., LTD. Free format text: FORMER OWNER: SANDVIK AB Effective date: 20060127 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20060127 Address after: Sandviken Patentee after: Sandvik Intellectual Property Address before: Sandviken Patentee before: Sandvik AB |
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| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |