CN1425625A - Super long after glow luminous floor jade tile and its preparing method - Google Patents
Super long after glow luminous floor jade tile and its preparing method Download PDFInfo
- Publication number
- CN1425625A CN1425625A CN 02135417 CN02135417A CN1425625A CN 1425625 A CN1425625 A CN 1425625A CN 02135417 CN02135417 CN 02135417 CN 02135417 A CN02135417 A CN 02135417A CN 1425625 A CN1425625 A CN 1425625A
- Authority
- CN
- China
- Prior art keywords
- paste
- cobalt naphthenate
- cyclohexanone peroxide
- jade
- unsaturated polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/807—Luminescent or fluorescent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Floor Finish (AREA)
- Luminescent Compositions (AREA)
Abstract
The floor tile is produced with natural jade powder, glass beads, silica particle, superlong afterglow luminous power, unsaturated polyester resin and other components. The floor tile receives ultraviolet radiation to accumulate light in day time and glow with color light in night. It is soft, high in strength and wear resistant; may be used widely in household, dence hall, hotel, park and other places; and is power saving and charming.
Description
Technical field
The present invention relates to indoor building material area, particularly a kind of super long after glow luminous floor jade tile and preparation method thereof.
Prior art
Prior art is used mostly is indoor porcelain floor tile, and produce this brick and need burn till, the waste fuel energy, and intensity and wear resistance are relatively poor, and color and luster is not attractive in appearance.Also occurred plastic floor brick, solid wooden floor board brick etc. in the market, but its easy warpage is out of shape, costs an arm and a leg.
Summary of the invention
The objective of the invention is in order to overcome above-mentioned defective, a kind of folding strength height of novelty, good, the save energy of wear resistance are provided, receive after the uviolizing luminous floor tile and production method thereof at night self daytime.
The present invention realizes like this, super long after glow luminous floor jade tile is to be base-material with the natural jade powder, is filler with glass microballon and silicon dioxide microparticle, is luminescent material with the overlength afterglow luminescent powder, with the unsaturated polyester resin is tackiness agent, with NNO is diffusant, is initiator with the cyclohexanone peroxide paste, is promotor with the cobalt naphthenate, with organosilane A151 is coupling agent, dibutyl phthalate (DBP) is a softening agent, and other has UV light absorber, refining forming such as film mould agent.
Its weight proportion is:
Silicon dioxide microparticle 10%-12.5%
Natural jade particulate 10%-12.5%
Unsaturated polyester resin 16%-20%
Overlength afterglow luminescent powder 0.5-0.8%
Glass microballon 60%-70%
NNO diffusant 0.1%-0.15%
Cyclohexanone peroxide is stuck with paste 1%-4%
Cobalt naphthenate 1%-3%
Organosilane A151 0.5%-1%
Dibutyl phthalate (DBP) 0.5%-1%
UV light absorber 0.1-0.2%
Other auxiliary material is an amount of
Wherein, the batching for preparing this super long after glow luminous floor jade tile is divided into two kinds of bed material and linings, and wherein the weight proportion of bed material is:
Silicon dioxide microparticle 10%-12.5%
Unsaturated polyester resin 10%-14%
Glass microballon 60%-70%
Cyclohexanone peroxide is stuck with paste 0.5%-2%
Cobalt naphthenate 0.5%-1.5%
NNO diffusant 0.05%-0.1%
Organosilane A151 0.25%-0.5%
Dibutyl phthalate (DBP) 0.3%-0.7%
Other auxiliary material is an amount of
The weight proportion of lining is:
Unsaturated polyester resin 5%-7%
Overlength afterglow luminescent powder 0.5%-0.8%
Natural jade particulate 10%-12.5%
Cyclohexanone peroxide is stuck with paste 0.5%-2%
Cobalt naphthenate 0.5%-1.5%
Organosilane A151 0.25%-0.5%
UV light absorber 0.1%-0.2%
Its production method is
1. in proportion unsaturated polyester resin, natural jade particulate, overlength afterglow luminescent material are mixed and stir, react after 10 minutes, adding cyclohexanone peroxide paste, cobalt naphthenate, organosilane A151, UV light absorber are standby as lining.2. in proportion with unsaturated polyester resin, glass microballon, NNO, cyclohexanone peroxide paste, cobalt naphthenate, that organosilicon A1 51 is mixed with bed material is standby.3. mould is placed on the template, last releasing agent is put lining earlier, and lining adds bed material after doing, compression moulding, and the demoulding after 60-120 minute through maintenance below 40 ° more than 20 ° 6 hours, is finished product again.
The beneficial effect that the present invention produced is: super long after glow luminous floor jade tile receives uviolizing and hold light daytime, can self send colored radiance night, the quality softness, the intensity height, wear resistance is strong, can be widely used in places such as family, dance hall, hotel, park, save energy, other tool is temperament and interest.
Embodiment:
6 kilograms of unsaturated polyester resins, 11 kilograms of natural jade particulates, 0.065 kilogram of overlength afterglow luminescent powder are mixed stirring, react after 10 minutes, it is standby as lining to add 0.0125 kg peroxygen pimelinketone paste, 0.01 kilogram of cobalt naphthenate, 0.038 kilogram of organosilicon A151,0.015 kilogram of UV light absorber.With 12 kilograms of silicon dioxide microparticles, 12 kilograms of unsaturated polyester resins, 65 kilograms of glass microballons, 0.075 kilogram of dispersing agent NNO, 0.0125 kg peroxygen pimelinketone stick with paste, 0.01 kilogram of cobalt naphthenate, that 0.038 kilogram of organosilane A151 is mixed with bed material is standby.Mould is placed on the template, last releasing agent, first paving material, lining is done the back and is gone up bed material, compression moulding, the demoulding after 60-120 minute, maintenance 6 hours under 20 ℃ of-40 ℃ of temperature again is finished product.
In addition, can make various artworks such as noctilucence sculpture, all belong in the protection domain of the present invention according to the variation of mould.
Claims (3)
1, a kind of super long after glow luminous floor jade tile, it is characterized in that with the natural jade particulate be base-material, with the unsaturated polyester resin is tackiness agent, with the cyclohexanone peroxide paste is initiator, with the cobalt naphthenate is promotor, is aggregate with the glass microballon, is luminescent material with the overlength afterglow luminescent powder, interpolation diffusant, softening agent, UV light absorber are made with extra care and are formed, and its weight proportion is:
Natural jade particulate 10%-10.5%
Silicon dioxide microparticle 10%-10.5%
Unsaturated polyester resin 16%-20%
Overlength afterglow luminescent powder 0.5%-0.8%
Glass microballon 60%-70%
Dispersing agent NNO 0.1%-0.15%
Cyclohexanone peroxide is stuck with paste 1%-4%
Cobalt naphthenate 1%-3%
Organo-silicon coupling agent 0.5%-1%
Softening agent 0.5%-1%
UV light absorber 0.1%-0.2%
Other subsidiary material are an amount of
Wherein the weight proportion of bed material is:
Silicon dioxide microparticle 10%-12.5%
Unsaturated polyester resin 10%-14%
Glass microballon 60%-70%
Cyclohexanone peroxide is stuck with paste 0.5%-2%
Cobalt naphthenate 0.5%-1.5%
NNO 0.05％-0.1％
Organosilane A151 0.25%-0.5%
Dibutyl phthalate (DBP) 0.3%-0.7%
Other auxiliary material is an amount of
The weight proportion of lining is:
Unsaturated polyester resin 5%-7%
Overlength afterglow luminescent powder 0.5%-0.8%
Natural jade particulate 10%-12.5%
Cyclohexanone peroxide is stuck with paste 0.5%-2%
Cobalt naphthenate 0.5%-1.5%
Organosilane A151 0.25%-0.5%
UV light absorber 0.1%-0.2%
2, the production method of super long after glow luminous floor jade tile as claimed in claim 1 is characterized in that adopting following technology and step:
1. in proportion with tackiness agent.Natural jade particulate, overlength afterglow luminescent material mix and to stir material, reacts after 10 minutes, and adding cyclohexanone peroxide paste, cobalt naphthenate, organosilane A151, that UV light absorber is made lining is standby.2. in proportion with tackiness agent, glass microballon, NNO diffusant, cyclohexanone peroxide paste, cobalt naphthenate, that organosilicon A is mixed with bed material is standby.3. mould is placed on the template, the first paving of last releasing agent material, lining is done the back and is gone up bed material, and the demoulding after compression moulding 60-120 minute was finished product in 6 hours through 20 ° of-40 ° of following temperature maintenances again.
3,, it is characterized in that to cause various luminous artistic articles according to tool change with its batching and production technique and step as the described jade excusing from death of claim 1 and claim 2 twilight sunset noctilucence floor tile batching and production method thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135417 CN1425625A (en) | 2002-08-12 | 2002-08-12 | Super long after glow luminous floor jade tile and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135417 CN1425625A (en) | 2002-08-12 | 2002-08-12 | Super long after glow luminous floor jade tile and its preparing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1425625A true CN1425625A (en) | 2003-06-25 |
Family
ID=4748190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02135417 Pending CN1425625A (en) | 2002-08-12 | 2002-08-12 | Super long after glow luminous floor jade tile and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1425625A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100560345C (en) * | 2006-12-27 | 2009-11-18 | 江阴市华宏橡塑厂 | The preparation method of floor covering with illuminant colorful spots |
| CN102029718A (en) * | 2009-09-28 | 2011-04-27 | 哈尔滨赛玉科技发展有限责任公司 | Agate-jade artificial composite material decorating plate and processing method |
| CN101403475B (en) * | 2008-11-13 | 2011-08-17 | 北京航空航天大学 | Energy accumulation luminous stone and its production method |
-
2002
- 2002-08-12 CN CN 02135417 patent/CN1425625A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100560345C (en) * | 2006-12-27 | 2009-11-18 | 江阴市华宏橡塑厂 | The preparation method of floor covering with illuminant colorful spots |
| CN101403475B (en) * | 2008-11-13 | 2011-08-17 | 北京航空航天大学 | Energy accumulation luminous stone and its production method |
| CN102029718A (en) * | 2009-09-28 | 2011-04-27 | 哈尔滨赛玉科技发展有限责任公司 | Agate-jade artificial composite material decorating plate and processing method |
| CN102029718B (en) * | 2009-09-28 | 2015-04-08 | 哈尔滨赛玉科技发展有限责任公司 | Agate-jade artificial composite material decorating plate and processing method |
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| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |