CN1425288A - Prometryn weedicide composition - Google Patents

Prometryn weedicide composition Download PDF

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Publication number
CN1425288A
CN1425288A CN 01140288 CN01140288A CN1425288A CN 1425288 A CN1425288 A CN 1425288A CN 01140288 CN01140288 CN 01140288 CN 01140288 A CN01140288 A CN 01140288A CN 1425288 A CN1425288 A CN 1425288A
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chloro
english common
composition according
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CN 01140288
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马韵升
史庆领
温沛宏
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Men Zhen
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Men Zhen
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Abstract

The weedicide composition contains at least weedicide A and a kind of weedicide B. The weedicide A is 4,6-bis(diisopropyl amino)-2-methlthio-1,3,5-triazinyl nicosulfuron, named also prometryne.

Description

Prometryn weedicide composition
The present invention relates to prometryn and have a kind of herbicides compounds B at least, compd B is: B 1, alachlor Chinese adopted name: alachlor; English common name: alachlor; Chemical name: 2-chloro-2 ', 6 '-diethyl-N-methoxy acetanil B 2, Acetochlor Chinese adopted name: Acetochlor; English common name: acetochlor; Chemical name: 2-chloro-N-ethoxymethyl-6 '-acetyl-O-is for aniline B 3, propisochlor Chinese adopted name: propisochlor; English common name: propisochlor; Chemical name: 2-chloro-N-(2-ethyl-6-methylbenzene)-N-[(1-methyl ethoxy)] methylacetamide B 4, isopropyl methoxalamine Chinese adopted name: isopropyl methoxalamine; English common name: metolachlor; Chemical name: 2-chloro-6 '-ethyl-N-(2-methoxyl group-1-Methylethyl) acetyl-neighbour-for aniline B 5, butachlor Chinese adopted name: butachlor; English common name: butachlor; Chemical name: N-fourth oxygen methyl-2-chloro-2 ', 6 '-diethyl acetanil B 6, Oxyfluorfen Chinese adopted name: Oxyfluorfen; English common name: oxyfluorfen; Chemical name: 2-chloro-a, a, a-three fluoro-p-tolyls-3-ethyoxyl-4-nitrobenzophenone ether B 7, Pendimethalin Chinese adopted name: Pendimethalin; English common name: pendimethalin; Chemical name: N-(1-ethyl propyl)-2,6-dinitro-3,4-3,5-dimethylphenyl
At present, corn field herbicide mainly is based on closed soil, mainly carries out closed soil treatment before the seedling with Acetochlor in the weed killer herbicide.Because the agent of Acetochlor list has been used for many years, in the certain areas weeds it is had fixed pesticide resistance, must increase consumption, but bring the problem of poor stability.And that the prometryn complex preparation is used at home is less, especially in corn field and soybean field.Prometryn and alachlor, Acetochlor, propisochlor, isopropyl methoxalamine, butachlor, ethoxy carboxylic grass ether, Pendimethalin are re-dubbed preparation, they can enlarge kill the grass spectrum, improve herbicidal effect, reduce residual activity, reduce poisoning, delay the drug-fast generation of weeds and the succession of community crop, the reduction dosage, reduce environmental pollution; Laborsaving simultaneously, economical, reduce farmer's burdens.
Composition of the present invention can be two combinations, also can be the composition that aforesaid compound forms more than three kinds.
The mechanism of action difference of the various compositions of composition of the present invention, mutually synergy between them, the pesticide resistance of weeds reduces, so the herbicidal effect of composition is obviously high slightly or the suitable herbicidal effect of single time spent of each component, and kills the grass spectrum and broadens.
Composition of the present invention is mainly used in corn field, soybean field, mainly prevents and kill off upland field weeds such as lady's-grass, green foxtail, wild oat, eleusine indica, salsola collina, Amaranthus retroflexus, acalypha copperleaf, kitchen garden, black nightshade, multitude, Siberian cocklebur, meadow pine, chickweed.
Prometryn and alachlor, Acetochlor, propisochlor, isopropyl methoxalamine, butachlor, ethoxy carboxylic grass ether, Pendimethalin weeding ratio are 1: 160 to 80: 1 based on the parts by weight of active component in the present composition, optimal proportion 1: 40 to 40: 1.
Composition of the present invention can also comprise emulsifier, solvent, auxiliary agent, filler, oils (vegetable oil, mineral oil) etc., and the parts by weight of its shared composition are 0.5%~95%.
The best preparation of composition of the present invention has: oil-suspending agent, aqueous suspension agent, suspension emulsion, aqua, also can be other formulations such as missible oil, pulvis, dust agent, granula, microemulsion, wetting powder and granule.
Composition of the present invention also will add surface reactive materials such as emulsifier, dispersant, wetting agent, to increase stability, wetability, the permeability of composition.
The product that the present invention describes can be the finished product preparation form, and promptly material mixes in the product.Yet the composition of composition also can provide with preparation separately, directly mixes in jar before use.
Composition of the present invention can use by common method, as spraying.
The present composition can illustrate with following embodiment:
The preparation of embodiment 1 45% oil-suspending agent
Prometryn 15% (weight)
Alachlor 30% (weight)
Emulsifier 10% (weight)
Surfactant 10% (weight)
Oils 35% (weight)
Various components are mixed, in sand mill, be ground to the active ingredient particle diameter less than 3 μ m.
The preparation of embodiment 2 50% wetting powders
Prometryn 25% (weight)
Propisochlor 25% (weight)
Auxiliary agent 10% (weight)
Filler 40% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed, be crushed to certain fineness.
The preparation of embodiment 3 50% aqueous suspension agents
Prometryn 30% (weight)
Acetochlor 20% (weight)
Emulsifier 10% (weight)
Surfactant 10% (weight)
Water 30% (weight)
Various components are mixed, in sand mill, be ground to the active ingredient particle diameter less than 3 μ m.
The preparation of embodiment 4 42% wetting powders
Prometryn 20% (weight)
Pendimethalin 22% (weight)
Auxiliary agent 10% (weight)
Filler 48% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed.
The preparation of embodiment 5 56% missible oil
Prometryn 20% (weight)
Isopropyl methoxalamine 36% (weight)
Emulsifier 10% (weight)
Auxiliary agent 10% (weight)
Dimethylbenzene 24% (weight)
Various materials are added in the reactor successively, under stirring condition, it is fully mixed
Embodiment 6 prometryns and Acetochlor are formed the test of pesticide effectiveness of preparation
Corn is broadcast the preceding dispenser of back seedling, and 20 days investigation strain preventive effect results are as follows behind the medicine:
The medicament title Consumption (gram/mu) Lady's-grass Eleusine indica The barnyard grass grass Kitchen garden Acalypha copperleaf
Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%)
25% prometryn WP ??240 ??5.7 ??95.4 ??0.3 ??99.4 ??5.1 ??92.9 ??2.2 ??84.8 ??1.4 ??85.9
50% acetochlor ec ??80 ??5.6 ??95.5 ??0.4 ??99.1 ??5.3 ??92.7 ??1.3 ??91.0 ??0.8 ??91.9
50% pounces on second SC ??200 ??8.1 ??93.5 ??0.6 ??98.3 ??5.4 ??92.5 ??1.1 ??92.4 ??0.7 ??92.9
Blank ???- ??125 ??- ??46.7 ??- ??72.4 ??- ??14.5 ??- ??9.9 ??-
Test shows: prometryn and Acetochlor are used with annual gramineous weed suitable with each single agent preventive effect, and slightly height of preventive effect is compared in single agent to broad leaved weed and each, and both have used synergistic effect with.
Embodiment 7 prometryns and alachlor are formed the test of pesticide effectiveness of preparation
Corn is broadcast the preceding dispenser of back seedling, and 20 days investigation strain preventive effect results are as follows behind the medicine
The medicament title Consumption (gram/mu) Lady's-grass Eleusine indica The barnyard grass grass Kitchen garden Acalypha copperleaf
Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%)
25% prometryn WP ??240 ??3.0 ??96.8 ??1.1 ????96.9 ??3.2 ??94.7 ????1.8 ????85.5 ????1.7 ????83.9
48% alachlor EC ??250 ??8.1 ??91.5 ??2.2 ????93.8 ??5.8 ??90.4 ????2.1 ????83.1 ????1.8 ????83.0
45% pounces on the nail polish suspending agent ??400 ??1.4 ??98.5 ??1.2 ????96.6 ??2.3 ??96.2 ????1.7 ????86.3 ????1.4 ????86.8
Blank ??- ??95.8 ??- ??35.6 ????- ??60.5 ??- ????12.4 ????- ????10.6 ????-
The result shows: prometryn and alachlor are used with suitable with each single agent preventive effect, and to crop safety.
Embodiment 8 prometryns and Pendimethalin are formed the test of pesticide effectiveness of preparation
Corn is broadcast the preceding dispenser of back seedling, and 20 days investigation strain preventive effect results are as follows behind the medicine
The medicament title Consumption (gram/mu) Lady's-grass Eleusine indica The barnyard grass grass Kitchen garden Acalypha copperleaf
Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%)
25% prometryn WP ??240 ??5.1 ??93.4 ??4.1 ??92.7 ??5.9 ??91.3 ??1.1 ????89.1 ??1.2 ??85.5
33% Pendimethalin EC ??200 ??6.5 ??91.5 ??5.8 ??89.7 ??6.4 ??90.5 ??1.2 ????8813 ??1.3 ??84.3
42% pounces on diformazan WP ??300 ??5.5 ??92.8 ??4.7 ??91.7 ??6.2 ??90.8 ??1.2 ????88.1 ??1.1 ??86.7
Blank ??- ??76.9 ??- ??56.5 ??- ??67.6 ??- ??10.1 ????- ??8.3
Test shows: prometryn and Pendimethalin are used with suitable with each single agent preventive effect, no antagonism.
Embodiment 9 prometryns and isopropyl methoxalamine are formed the test of pesticide effectiveness of preparation
Corn is broadcast the preceding dispenser of back seedling, and 20 days investigation strain preventive effect results are as follows behind the medicine
The medicament title Consumption (gram/mu) Lady's-grass The barnyard grass grass Lamb's-quarters Kitchen garden Black nightshade
Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%) Strain/m 2 Preventive effect (%)
25% prometryn WP ??240 ??3.3 ??95.6 ??3.0 ??93.5 ??1.2 ??90.5 ????1.7 ??85.7 ??1.2 ??87.4
72% isopropyl methoxalamine EC ??150 ??2.9 ??96.1 ??2 ??96.0 ??1.1 ??91.3 ????1 ??91.3 ??0.9 ??90.5
56% pounces on the different third first EC ??300 ??2.4 ??96.8 ??1.8 ??96.2 ??0.9 ??92.8 ????0.8 ??93.1 ??0.8 ??91.6
Blank ??- ??74.1 ??- ??46.8 ??- ??12.6 ??- ????11.6 ??- ??9.5 ??-
Test shows; Prometryn and isopropyl methoxalamine are used with to enlarge and are killed the grass spectrum, to crop safety.

Claims (6)

1. Herbicidal combinations, it contains and has a kind of herbicides compounds B and another kind of herbicides compounds A at least, and the Chinese adopted name of compd A is: prometryn; English common name is: prometryne; Chemical name is: 4, and the two diisopropylaminoethyls of 6--2-methyl mercapto-1,3,5-triazines nicosulfuron; Compd B is: B 1, alachlor Chinese adopted name: alachlor; English common name: alachlor; Chemical name: 2-chloro-2 ', 6 '-diethyl-N-methoxy acetanil B 2, Acetochlor Chinese adopted name: Acetochlor; English common name: acetochlor; Chemical name: 2-chloro-N-ethoxymethyl-6 '-acetyl-O-is for aniline B 3, propisochlor Chinese adopted name: propisochlor; English common name: propisochlor; Chemical name: 2-chloro-N-(2-ethyl-6-methylbenzene)-N-[(1-methyl ethoxy)] methylacetamide B 4, isopropyl methoxalamine Chinese adopted name: isopropyl methoxalamine; English common name: metolachlor; Chemical name: 2-chloro-6 '-ethyl-N-(2-methoxyl group-1-Methylethyl) acetyl-neighbour-for aniline B 5, butachlor Chinese adopted name: butachlor; English common name: butachlor; Chemical name: N-fourth oxygen methyl-2-chloro-2 ', 6 '-diethyl acetanil B 6, Oxyfluorfen Chinese adopted name: Oxyfluorfen; English common name: oxyfluorfen; Chemical name: 2-chloro-a, a, a-three fluoro-p-tolyls-3-ethyoxyl-4-nitrobenzophenone ether B 7, Pendimethalin Chinese adopted name: Pendimethalin; English common name: pendimethalin; Chemical name: N-(1-ethyl propyl)-2,6-dinitro-3,4-3,5-dimethylphenyl
2. composition according to claim 1, preparation are suspending agent.
3. composition according to claim 1, wherein compd A and compd B weeding ratio are 1: 160 to 80: 1 based on the parts by weight of active component, optimal proportion 1: 40 to 40: 1.
4. composition according to claim 1 also contains other emulsifier, solvent, auxiliary agent, filler, oils (vegetable oil, mineral oil) etc. except that active constituent.
5. composition according to claim 1 also contains other emulsifier, auxiliary agent, surfactant etc. except that active constituent.
6. composition according to claim 1, purposes are that corn field is broadcast the preceding weeding of back seedling.
CN 01140288 2001-12-12 2001-12-12 Prometryn weedicide composition Pending CN1425288A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN 01140288 CN1425288A (en) 2001-12-12 2001-12-12 Prometryn weedicide composition

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311744C (en) * 2004-07-28 2007-04-25 杨卫东 Weed control combination in use for paddy field
CN101971817A (en) * 2010-07-15 2011-02-16 湖北奥士特奥农药产品研发有限公司 Herbicide prepared by binary compounding of oxyfluoyfen and prometryn and preparation method thereof
CN101971818A (en) * 2010-07-14 2011-02-16 湖北奥士特奥农药产品研发有限公司 Herbicide prepared by binary combination of pendimethalin and prometryn and preparation method thereof
CN103478136A (en) * 2013-09-30 2014-01-01 山东滨农科技有限公司 Herbicidal composition for peanut field
CN103493819A (en) * 2013-09-12 2014-01-08 薛列驹 Compounded herbicide
CN101720763B (en) * 2009-12-18 2014-04-30 广东省农业科学院植物保护研究所 Vegetable field herbicide composition and preparation method and use of water emulsion thereof
CN105284825A (en) * 2015-06-29 2016-02-03 新乡市植物化学厂(普通合伙) Weeding composition containing ametryn and oxyfluorfen as well as application of weeding composition
CN105746532A (en) * 2015-12-28 2016-07-13 山东潍坊润丰化工股份有限公司 Acetochlor and prometryn containing weeding composition and preparation method and application thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1311744C (en) * 2004-07-28 2007-04-25 杨卫东 Weed control combination in use for paddy field
CN101720763B (en) * 2009-12-18 2014-04-30 广东省农业科学院植物保护研究所 Vegetable field herbicide composition and preparation method and use of water emulsion thereof
CN101971818A (en) * 2010-07-14 2011-02-16 湖北奥士特奥农药产品研发有限公司 Herbicide prepared by binary combination of pendimethalin and prometryn and preparation method thereof
CN101971817A (en) * 2010-07-15 2011-02-16 湖北奥士特奥农药产品研发有限公司 Herbicide prepared by binary compounding of oxyfluoyfen and prometryn and preparation method thereof
CN103493819A (en) * 2013-09-12 2014-01-08 薛列驹 Compounded herbicide
CN103478136A (en) * 2013-09-30 2014-01-01 山东滨农科技有限公司 Herbicidal composition for peanut field
CN105284825A (en) * 2015-06-29 2016-02-03 新乡市植物化学厂(普通合伙) Weeding composition containing ametryn and oxyfluorfen as well as application of weeding composition
CN105746532A (en) * 2015-12-28 2016-07-13 山东潍坊润丰化工股份有限公司 Acetochlor and prometryn containing weeding composition and preparation method and application thereof
CN105746532B (en) * 2015-12-28 2018-07-13 山东潍坊润丰化工股份有限公司 A kind of Herbicidal combinations and its preparation method and application containing Acetochlor and prometryn

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