CN1410626A - Production technology of pure natural antibacterial bamboo paste - Google Patents

Production technology of pure natural antibacterial bamboo paste Download PDF

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Publication number
CN1410626A
CN1410626A CN 02133752 CN02133752A CN1410626A CN 1410626 A CN1410626 A CN 1410626A CN 02133752 CN02133752 CN 02133752 CN 02133752 A CN02133752 A CN 02133752A CN 1410626 A CN1410626 A CN 1410626A
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bamboo
slurry
machine
pulp
desanding
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CN 02133752
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CN1184374C (en
Inventor
贺世福
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Yibin Grace Group Co Ltd
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Chuntian Green Bamboo Source Development Co Ltd Chengdu
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Abstract

The invention relates to the technique of preparing bamboo pulp by using the raw materials as following natural bamboo; whangee, fishscale bamboo, bitter bamboo, square bamboo etc. The preparation procedures include stocking, cooking discharging, washing, desanding, chloridizing, alkaline treatment, blanching etc. The character is that the preprocessing working procedure is added between the stocking and cooking procedures. The technical conditions of the preprocessing working procedure are as following: liquor ratio 1:1.0-5.0, from the room temperature to rise to 120-140 deg.C within 45-75 minutes; exhausting gas 5-20 minutes, then heating up again to 120-140 deg.C; heat preservation for 4-6 hours, then exhausting treating liquid.

Description

The production technology of pure natural antibacterial bamboo paste
Technical field:
The present invention relates to a kind of production technology of pure natural antibacterial bamboo paste
Background technology:
Along with development, the human civilization advance of society, people are more and more higher to self Health and Living environment requirement, and uphold nature is pursued environment-protecting articles nuisanceless, that have no side effect and come into fashion.And now, many commodity, the product closely bound up such as packaging for foodstuff articles for use particularly with the human lives, for reaching the purpose of antibacterial and mouldproof, often realize by adding synthetic additive, and these synthetic additives all are the synthetic to the human body toxic side effect basically, if use for a long time, contact, health and environment are all had serious harm.How to utilize natural resources, particularly utilize bamboo resource, produce pure natural antibacterial bamboo paste, among people's consideration.
China's bamboo resource is abundant, and output is big, wide in variety,, has extensively carried out " wood substituted by bamboo " production bamboo pulp at southern area, is used for papermaking.Its bamboo pulp and paper product do not have the natural antibacterial function, only do general in, low-grade package paper and cultural paper, product purpose is narrower, added value is not high.The present bamboo pulp technological process of production is for getting the raw materials ready-boiling-blowing-washing-desanding-concentrate-chlorination-alkali treatment-hypochlorite bleaching-washing-concentrate-manufacture paper with pulp.By the common bamboo pulp of this explained hereafter, its alpha-cellulose content is 75-85%, pentosan 12-18%, ash 1-2%.Because its alpha-cellulose content is low, impurity contents such as pentosan, ash are higher, so this bamboo pulp does not have the natural antibacterial function.
Summary of the invention:
The objective of the invention is to make full use of natural bamboo resource, design a kind of alpha-cellulose content height, impurity contents such as pentosan, ash are lower, have the bamboo pulp production technology of natural antibacterial function.
Production technology of the present invention has reached above-mentioned purpose of design, and it is to improve on the basis of existing bamboo pulp production technology, and its concrete technological process is as follows:
The production technology of this pure natural antibacterial bamboo paste, comprise and get the raw materials ready, boiling, blowing, washing, desanding, concentrate, chlorination, alkali treatment, hypochlorite bleaching, washing, concentrate, manufacture paper with pulp, it is characterized in that having increased pretreatment process between procedure for preparation and cooking process, its specific operation process is as follows: (one), get the raw materials ready:
The bamboo material is cut into the bamboo chip of required specification; (2), preliminary treatment:
Carry out in boiling vessel, its technical conditions are: liquor ratio=1: 1.0-5.0, intensification condition: be warming up to 120-140 ℃ by normal temperature, heating-up time is 45-75 minute, exhaust 5-20 minute, is warming up to 120-140 ℃ again, be incubated 4-6 hour, insulation finishes, and gets rid of treatment fluid; (3), ammonium sulfite boiling:
Always use the ammonium amount: with (NH 4) 2SO 3Meter is the 20-25% of over dry bamboo material, liquor ratio=1: 2-5, buffer is 3.0-5.0%, and buffer is a kind of in urea, ammoniacal liquor, the NaOH, according to above-mentioned technical conditions, in boiling vessel, carry out the ammonium sulfite boiling, the intensification condition: rise to 110-120 ℃ by room temperature, 60 minutes heating-up times, be incubated 1 hour, float gas 5-10 minute is warming up to 140-150 ℃ again, be incubated 3 hours, exhaust is 10 minutes again, is warming up to 160-170 ℃ again, be incubated 2-4 hour, insulation finishes, blowing; (4), washing;
Slurry squeezes out black digestion liquid in the slurry through acroll press washer, washs to pH value=9.5-8.0 through wash engine again; (5), screening:
Shake frame sieve of employing sifts out not steam and separates thing and big impurity, screens through pressurized screen again; (6), desanding:
Slurry carries out in desander, adopts three sections desanding, removes chiltern and heavy seeds; (7), concentrate:
In thickener, slough the part moisture in the slurry, make slurry concentration reach 3.5-5.0%; (8), chlorination:
Technical conditions: chlorine dosage is the 60-70% of totally applied chlorine, and starching dense is 3.0-5.0%, under normal temperature condition, floats at chlorination tower or pipe and to carry out chloridized in the machine, time of chlorinating: in the chlorination tower 40-60 minute, floating in the machine at pipe was 5 minutes; (9), alkali treatment::
Technical conditions: starch dense: 3.0-5.0%, with alkali is NaOH, consumption is 2.0-5.0% to the oven dry stock amount, temperature 50-90 ℃, time 60-90 minute, in alkalization tower or bleaching machine or stock tank, slurry is carried out alkali treatment, if select for use pipe to float machine, then can directly float and carry out alkali treatment in the machine, and then slurry is put in the stock tank at pipe; (10), hypochlorite bleaching, washing:
Technical conditions: chlorine dosage is the 30-40% of totally applied chlorine, and temperature is 35-45 ℃, and time 120-260 minute, pH value=9.5-11 bleached in bleaching machine, and bleaching finishes, and can wash in bleaching machine; (11), desanding, concentrate and manufacture paper with pulp:
In desander, carry out desanding, dense for 3.0-5.0% through the thickener dehydration to starching, send pulp machine to manufacture paper with pulp then.
This technology is raw materials used to be cizu, bambusa textile, huge bamboo, fishscale bamboo, Xifeng Bamboo, sweet bamboo, bitter bamboo, support green bamboo, Fang Zhu.
According to above-mentioned technological process operation, can produce pure bamboo pulp with natural antibacterial function.The main cane part of using of bamboo material, the cane part of bamboo material mainly is made up of cellulose, hemicellulose, lignin and pectin, starch etc.Its holocellulose content is about 40-50%, and pentosan content is up to 16-22%, bamboo pulp fiber form and physics, chemical index are between needle and broad-leaved wood fiber, but it has particular structure again, different with fibers such as wood, grass, cotton, fiber crops, after particularly handling, when fiber fineness reaches higher level through special process, just possessed the exceptional function that fibers such as wood, grass, cotton, fiber crops do not have, i.e. natural antibacterial effect.Because the present invention has increased pretreatment process in existing traditional bamboo pulp technology, remove hemicellulose and other impurity in the bamboo material, the purification cellulose reaches more than 93% alpha-cellulose content, therefore, makes bamboo pulp have the natural antibacterial function.Utilize the bamboo pulp of explained hereafter of the present invention to make Related product, do not need to add artificial synthetic Fungicidal substance, can reach sterilization, sterilisation purpose, can be used for producing products such as antiseptic gauze, sanitary napkin, disinfecting paper, food wrapper, disposable container.Because the natural bamboo resource of China is inexhaustible, therefore, the present invention is a kind of suitable China's actual conditions, have the production technology of the ideal green environment-friendly products of general promotional value.
The specific embodiment: embodiment 1 (one), get the raw materials ready:
1000 kilograms of over dry bamboo material are cut into the bamboo chip of required specification; (2), preliminary treatment:
Carry out in boiling vessel, its technical conditions are: liquor ratio=1: 1, and the intensification condition: be warming up to 120 ℃ by room temperature, the heating-up time is 60 minutes, exhaust 5-20 minute, be warming up to 120 ℃ again, be incubated 6 hours, insulation finishes, and gets rid of treatment fluid; (3), ammonium sulfite boiling:
Always use the ammonium amount: with (NH 4) 2SO 3Meter is 20% of over dry bamboo material, and the boiling buffer is a urea, consumption is 3% of over dry bamboo material, and liquor ratio=1: 2.0 is according to above-mentioned technical conditions, in boiling vessel, the bamboo material is carried out the ammonium sulfite boiling, rise to 110 ℃ by room temperature, 60 minutes heating-up times, float gas 10 minutes is warming up to 150 ℃ again, is incubated 3 hours, exhaust is 10 minutes again, is warming up to 170 ℃ again, is incubated 4 hours, insulation finishes, blowing; (4), washing;
Slurry squeezes out black digestion liquid in the slurry through acroll press washer, washs to pH value=8.0 through wash engine again; (5), screening:
Shake frame sieve of employing sifts out not steam and separates thing and big impurity, screens through pressurized screen again; (6), desanding:
Slurry carries out in desander, adopts three sections desanding, removes chiltern and heavy seeds; (7), concentrate:
In thickener, slough the part moisture in the slurry, make slurry concentration reach 3.5%; (8), chlorination:
Technical conditions: chlorine dosage is 40%, and starching dense is 3.5%, floats at chlorination tower or pipe under normal temperature condition and carries out chloridized in the machine, time of chlorinating: floating in the machine at pipe in 40 minutes in the chlorination tower is 5 minutes; (9), alkali treatment::
Technical conditions: starch dense: 5.0%, be NaOH with alkali, consumption is 5.0% to the oven dry stock amount, 50 ℃ of temperature, are carried out alkali treatment to slurry at 60 minutes time in the alkalization tower; (10), hypochlorite bleaching, washing:
Technical conditions: chlorine dosage is 40% of a totally applied chlorine, and temperature is 35 ℃, and the time is 120 minutes, and bleach in bleaching machine pH value=9.5, and bleaching finishes, and washs in bleaching machine; (11), desanding, concentrate and manufacture paper with pulp:
Carrying out desanding in desander, is 3.0% through the thickener dehydration to starching dense, send pulp machine to manufacture paper with pulp then.
In the present embodiment.Unscreened yield is 30-35, and the slurry bleachability is 9-13%, degree of bleaching 60-70%.
Embodiment 2 (one), get the raw materials ready:
1000 kilograms of bamboo material are cut into required specification: (two), preliminary treatment:
Carry out in boiling vessel, its technical conditions are: liquor ratio=1: 3.0, and Jiang Shui, bamboo expect, mix temperature conditions in boiling vessels: be warming up to 130 ℃ by room temperature, heating-up time is 60 minutes, and exhaust 10 minutes is warming up to 130 ℃ again, be incubated 5 hours, insulation finishes, and gets rid of treatment fluid.(3), ammonium sulfite boiling:
Always use the ammonium amount: with (NH 4) 2SO 3Meter is 25% of over dry bamboo material, and buffer is an ammoniacal liquor, consumption is 3% of over dry bamboo material, according to above-mentioned technical conditions, in boiling vessel, carry out the ammonium sulfite boiling, the intensification condition: rise to 120 ℃ by room temperature, 1 hour heating-up time, float gas 8 minutes is warming up to 170 ℃ again, is incubated 4 hours, insulation finishes, blowing; (4), washing;
Slurry squeezes out black digestion liquid in the slurry through acroll press washer, washs to pH value=9 through wash engine again; (5), screening:
Shake frame sieve of employing sifts out not steam and separates thing and big impurity, screens through pressurized screen again; (6), desanding:
Slurry carries out in desander, adopts three sections desanding, removes chiltern and heavy seeds; (7), concentrate:
In thickener, slough the part moisture in the slurry, make slurry concentration reach 4%; (8), chlorination:
Technical conditions: chlorine dosage is 60% of a totally applied chlorine, and starching dense is 4.0%, under normal temperature condition, floats at pipe and to carry out chloridized in the machine, and time of chlorinating is 5 minutes; (9), alkali treatment::
Technical conditions: starch dense: being 4.0%, is NaOH with alkali, and consumption is 3.5% to the oven dry stock amount, and 70 ℃ of temperature, are carried out alkali treatment to slurry at 75 minutes time in bleaching machine; (10), hypochlorite bleaching, washing:
Technical conditions: chlorine dosage is 40% of a totally applied chlorine, and temperature is 40 ℃, and the time is 3 hours, and bleach in bleaching machine pH value=10, and bleaching finishes, and washs in floating machine; (11), desanding, concentrate and manufacture paper with pulp:
Carrying out desanding in desander, is 4.0% through the thickener dehydration to starching dense, send pulp machine to manufacture paper with pulp then.
The unscreened yield of present embodiment is 30-35, bleachability 9-13%, whiteness 60-70%.
Embodiment 3 (one), get the raw materials ready:
With the required specification of bamboo material cutting growth; (2), preliminary treatment:
Carry out in boiling vessel, its technical conditions are: liquor ratio=1: 5.0, and Jiang Shui, bamboo material mix the intensification condition in boiling vessel: be warming up to 140 ℃ by room temperature, time is 75 minutes, and exhaust 20 minutes is warming up to 140 ℃ again, be incubated 6 hours, insulation finishes, and gets rid of treatment fluid; (3), ammonium sulfite boiling:
Always use the ammonium amount: with (NH 4) 2SO 3Meter is 25% of over dry bamboo material, and buffer is a caustic soda, consumption is 2% of over dry bamboo material, and liquor ratio=1: 3.0 is according to above-mentioned technical conditions, in boiling vessel, carry out the ammonium sulfite boiling, rise to 110 ℃, 60 minutes heating-up times by room temperature, float gas 10 minutes is warming up to 110 ℃ again, 80 minutes heating-up times, exhaust is 10 minutes again, is warming up to 170 ℃ again, is incubated 4 hours, insulation finishes, blowing; (4), washing;
Slurry squeezes out black digestion liquid in the slurry through acroll press washer, washs to pH value=9.5 through wash engine again; (5), screening:
Shake frame sieve of employing sifts out not steam and separates thing and big impurity, screens through pressurized screen again; (6), desanding:
Slurry carries out in desander, adopts three sections desanding, removes chiltern and heavy seeds; (7), concentrate:
In thickener, slough the part moisture in the slurry, make slurry concentration reach 5%; (8), chlorination:
Technical conditions: chlorine dosage is 60% of a totally applied chlorine, and slurry concentration is 5.0%, under normal temperature condition, carries out chloridized in the chlorination tower, time of chlorinating: 60 minutes; (9), alkali treatment:
Technical conditions: starch dense: 5.0%, be NaOH with alkali, consumption is 5.0% to the oven dry stock amount, 90 ℃ of temperature, are carried out alkali treatment to slurry at 90 minutes time in the alkalization tower; (10), hypochlorite bleaching, washing:
Technical conditions: chlorine dosage is 40% of a totally applied chlorine, and temperature is 45 ℃, and 260 minutes time, bleach in bleaching machine pH value=11, and bleaching finishes, and washs in bleaching machine; (11), desanding, concentrate and manufacture paper with pulp:
Carrying out desanding in desander, is 5.0% through the thickener dehydration to starching dense, send pulp machine to manufacture paper with pulp then.
The unscreened yield of present embodiment is 30-35, slurry bleachability 9-13%, whiteness 60-70.

Claims (1)

1, the production technology of pure natural antibacterial bamboo paste, comprise and get the raw materials ready, boiling, blowing, washing, desanding, concentrate, chlorination, alkali treatment, hypochlorite bleach, washing, concentrate, manufacture paper with pulp, it is characterized in that having increased pretreatment process between procedure for preparation and cooking process, its specific operation process is as follows: (one), get the raw materials ready:
The bamboo material is cut into required specification; (2), preliminary treatment:
Carry out in boiling vessel, its technical conditions are: liquor ratio=1: 1.0-5.0, intensification condition: be warming up to 120-140 ℃ by normal temperature, heating-up time is 45-75 minute, exhaust 5-20 minute, is warming up to 120-140 ℃ again, be incubated 4-6 hour, insulation finishes, and gets rid of treatment fluid; (3), ammonium sulfite boiling:
Always use the ammonium amount: with (NH 4) 2SO 3Meter is the 20-25% of over dry bamboo material, buffer 3.0-5.0%, liquor ratio=1: 2.0-5.0 according to above-mentioned technical conditions, carries out the ammonium sulfite boiling in boiling vessel, intensification condition: rise to 110-120 ℃ by room temperature, 60 minutes heating-up times, be incubated 1 hour, float gas 5-10 minute is warming up to 140-150 ℃ again, is incubated 1-3 hour, exhaust is 10 minutes again, is warming up to 160-170 ℃ again, is incubated 2-4 hour, insulation finishes, blowing; (4), washing;
Slurry squeezes out black digestion liquid in the slurry through acroll press washer, washs to pH value=9.5-8.0 through wash engine again; (5), screening:
Shake frame sieve of employing sifts out not steam and separates thing and big impurity, screens through pressurized screen again; (6), desanding:
Slurry carries out in desander, adopts three sections desanding, removes chiltern and heavy seeds; (7), concentrate:
In thickener, slough the part moisture in the slurry, make slurry concentration reach 3.5-5.0%; (8), chlorination:
Technical conditions: chlorine dosage is the 60-70% of totally applied chlorine, and starching dense is 3.0-5.0%, under normal temperature condition, floats at chlorination tower or pipe and to carry out chloridized in the machine, time of chlorinating: in the chlorination tower 40-60 minute, floating in the machine at pipe was 5 minutes; (9), alkali treatment::
Technical conditions: starch dense: 3.5-5.0%, with alkali is NaOH, consumption is 2.0-5.0% to the oven dry stock amount, temperature 50-90 ℃, time 60-90 minute, in alkalization tower or bleaching machine or stock tank, slurry is carried out alkali treatment, if select for use pipe to float machine, then can directly float and carry out alkali treatment in the machine, and then slurry is put in the stock tank at pipe; (10), hypochlorite bleaching, washing:
Technical conditions: chlorine dosage is the 30-40% of totally applied chlorine, and temperature is 35-45 ℃, and time 120-260 minute, pH value=9.5-11 bleached in bleaching machine, and bleaching finishes, and can wash in bleaching machine; (11), desanding, concentrate and manufacture paper with pulp:
In desander, carry out desanding, dense for 3-5.0% through the thickener dehydration to starching, send pulp machine to manufacture paper with pulp then.
According to above-mentioned technological process operation, can produce pure bamboo pulp with natural antibacterial function.
This technology is raw materials used to be cizu, bambusa textile, huge bamboo, fishscale bamboo, Xifeng Bamboo, sweet bamboo, bitter bamboo, support green bamboo, Fang Zhu.
CN 02133752 2002-09-16 2002-09-16 Production technology of pure natural antibacterial bamboo paste Expired - Fee Related CN1184374C (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008074220A1 (en) * 2006-12-18 2008-06-26 Hebei Jigao Chemical Fiber Co., Ltd. A preparation method of a bamboo pulp
CN101880981A (en) * 2010-07-09 2010-11-10 延边石岘白麓纸业股份有限公司 Method for making pulp
CN101298700B (en) * 2007-04-30 2010-11-10 河北吉藁化纤有限责任公司 Method for preparing bamboo pulp for cellulose viscose and products thereof
CN101158123B (en) * 2007-11-15 2011-07-20 宜宾纸业股份有限公司 High-strength bamboo pulp manufacturing technique
CN102174765A (en) * 2010-12-01 2011-09-07 江西含珠实业有限公司 Technological process for making Lian-si paper by using moso bamboo
CN104141256A (en) * 2014-07-24 2014-11-12 四川省西龙生物质材料科技有限公司 Uncolored bamboo fiber with high antibacterial activity and processing method thereof
CN105064136A (en) * 2015-08-13 2015-11-18 合肥龙发包装有限公司 Antibacterial packing paper
CN105730841A (en) * 2016-04-29 2016-07-06 洪帅 Portable lifting handle and manufacturing method of portable lifting handle
CN107814069A (en) * 2017-11-05 2018-03-20 佛山神航科技有限公司 A kind of papery bag containing mao bamboon paper pulp

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100441772C (en) * 2007-02-06 2008-12-10 新邵县广信有限责任公司 Production technology of thermomechanical bamboo pulp

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008074220A1 (en) * 2006-12-18 2008-06-26 Hebei Jigao Chemical Fiber Co., Ltd. A preparation method of a bamboo pulp
CN101298700B (en) * 2007-04-30 2010-11-10 河北吉藁化纤有限责任公司 Method for preparing bamboo pulp for cellulose viscose and products thereof
CN101158123B (en) * 2007-11-15 2011-07-20 宜宾纸业股份有限公司 High-strength bamboo pulp manufacturing technique
CN101880981A (en) * 2010-07-09 2010-11-10 延边石岘白麓纸业股份有限公司 Method for making pulp
CN101880981B (en) * 2010-07-09 2013-11-27 延边石岘白麓纸业股份有限公司 Method for making pulp
CN102174765A (en) * 2010-12-01 2011-09-07 江西含珠实业有限公司 Technological process for making Lian-si paper by using moso bamboo
CN104141256A (en) * 2014-07-24 2014-11-12 四川省西龙生物质材料科技有限公司 Uncolored bamboo fiber with high antibacterial activity and processing method thereof
CN104141256B (en) * 2014-07-24 2017-01-18 四川环龙新材料有限公司 Uncolored bamboo fiber with high antibacterial activity and processing method thereof
CN105064136A (en) * 2015-08-13 2015-11-18 合肥龙发包装有限公司 Antibacterial packing paper
CN105730841A (en) * 2016-04-29 2016-07-06 洪帅 Portable lifting handle and manufacturing method of portable lifting handle
CN107814069A (en) * 2017-11-05 2018-03-20 佛山神航科技有限公司 A kind of papery bag containing mao bamboon paper pulp

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