CN1410401A - Complex fertilizer for killing insect and bacteria and its production method - Google Patents
Complex fertilizer for killing insect and bacteria and its production method Download PDFInfo
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- CN1410401A CN1410401A CN01133532A CN01133532A CN1410401A CN 1410401 A CN1410401 A CN 1410401A CN 01133532 A CN01133532 A CN 01133532A CN 01133532 A CN01133532 A CN 01133532A CN 1410401 A CN1410401 A CN 1410401A
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Abstract
An insecticiding bactericiding coordinated fertilizer is prepared through coordination reactions between protocatechuic acid and ferrous sulfate, between protocatechuic acid and zinc sulfate, between manganese sulfate and uncarine, and between copper sulfate and thevetoside, and mixing the resultant mating members with magnesium sulfate, RE nitrate, ammonium molybdate and boric acid. Its advantages are high fertility and high insecticiding and bactericiding power.
Description
The invention belongs to the mixture and the production method of one or more fertilizer and no special fertilizer efficiency component.Relate in particular to a kind of fertilizer and production method that contains sterilant.
Agricultural chemicals of existing trace element fertilizer and preparation method thereof and Pesticidal and sterilizing and preparation method thereof, the product that the former obtains are little fertilizer, and the product that the latter obtains is an agricultural chemicals.Little fertilizer can not Pesticidal and sterilizing, and agricultural chemicals can not produce fertilizer efficiency.Once the little fertilizer of handlebar, agricultural chemicals were mixed in document announcement together, attempt to solve the problem that can Pesticidal and sterilizing can produce fertilizer efficiency again, but this mixes two kinds of products and composition mixture (Aqueous pesticidaland fertilizer composition comprising triticumspeltaextract.DE19757522 just simply; Fertilizer composition with pesticicd US5016045; Combined fertilizer applicator for plant US0254591; Insecticidiafertilizer mixcuves US5783203), but can not become and promptly produce the title complex that fertilizer efficiency again can Pesticidal and sterilizing.This mixing can make emulsion be damaged, produce precipitation sometimes, the ability that makes the fat-soluble of medicine and see through cell reduces, drug effect and fertilizer efficiency have been influenced, and sterilant and mixing of fertilizer are restricted, especially the internal-suction type agricultural chemicals generally can not mix use with fertilizer, makes it not have versatility.
Task of the present invention provide a kind of can strengthen the Pesticidal and sterilizing ability, again can strengthen fertilizer efficiency, also can improve the fat-soluble of fertilizer and see through the ability of cell and can make Pesticidal and sterilizing composition and trace element extensively coordinate complex fertilizer and production method.
For finishing above-mentioned task, the technical solution adopted in the present invention is made up of Protocatechuic Acid, uncarine, the thevetin of Liu Suan Copper, zinc sulfate, manganous sulfate, sal epsom, ferrous sulfate, nitric acid mishmetal, Molybdenum acid ammonium, boric acid and Pesticidal and sterilizing effective constituent.
Wherein Liu Suan Copper is 4～7%, zinc sulfate is 2～5%, manganous sulfate is 1～3%, sal epsom is 1.5～3.0%, ferrous sulfate is 1.5～1.8%, the nitric acid mishmetal is that 0.5～0.9%, Molybdenum acid ammonium is 0.5～0.7%, boric acid is 2～4%, Protocatechuic Acid is 8～10%, uncarine is 6～9%, thevetin is 3～5%.
Production method of the present invention is, Protocatechuic Acid and ferric sulfate carried out coordination reaction, Protocatechuic Acid and zinc sulfate carry out coordination reaction, and manganous sulfate and uncarine carry out coordination reaction, and Liu Suan Copper and thevetin carry out coordination reaction.
Then the reaction that is mixed again of the resulting title complex of above-mentioned reaction and sal epsom, sulfuric acid mishmetal, Molybdenum acid ammonium, boric acid.
The condition of coordination reaction is: 80～120 ℃ of temperature, 30～60 minutes time, pH2～6.
Owing to adopt technique scheme, the present invention can make multiple Pesticidal and sterilizing effective constituent and various trace element carry out coordination reaction widely, formed complex fertilizer can improve fat-soluble and see through the ability of cell, the drug effect of the energy force rate monomer agricultural chemicals of Pesticidal and sterilizing is stronger, the fertilizer efficiency also little fertilizer than general is higher, also is higher than simple mixtures
The invention will be further described below in conjunction with embodiment.
Embodiment preparation of the present invention can be divided into following step and carry out:
The preparation of the first step raw material
The making of 1 Protocatechuic Acid.
Folium ilicis chinensis (Aquifoliaceae Chinese ilex plant) cured leaf 4～5kg, with 2～4 times of water loggings, heated 30～70 minutes, get leaching liquid after the filtration, being concentrated into volume is 500～1000 milliliters, regulate pH=1～3 with hydrochloric acid, add ethyl acetate cascade extraction (compare 1～3, progression 3～5) then, add 5%NaHCo again
3Back extraction (compare 1～3, progression 2～4) is made.The strip liquor that obtains (main component is a Protocatechuic Acid) is standby.
The making of 2 uncarines
It is that branch, root by yncaria stem with hooks dries abrasive dust that uncarine is made, and hook taking rattan meal 5～kilogram is used NH
4OH, water, alcohol mixeding liquid (9: 30: 16) are wetting, and again with ether leaching (solid-to-liquid ratio 1: 2～4), after 1～4% hydrochloric acid carried out cascade extraction (compare 1～3, progression 4～6) extraction then, ether reclaimed and returns use, and hcl as extraction agent liquid adds uses NH
4OH pH=8～11 of alkalizing.Use ether back extraction (compare 1～3, progression 4～6) again.Strip liquor concentrates the back and reclaims ether, promptly gets uncarine.Standby in the vitriolization.
The making of 3 thevetins
The making of thevetin is that 5～7 kilograms of Semen Thevetiae benevolence are pulverized back benzene (solid-to-liquid ratio 1: 1～2) degreasing, add then 3～5 times the amount 40～60 ℃ water, mix, add again 2～5% toluene thoroughly, placed 20～30 hours down at 30～50 ℃, add 2～4 liters of 95% ethanol again, get effusion, concentrate the back to 800～1000 milliliters, the water that adds 3～5 times of amounts is standby, and ingredient is mainly thevetin.
Second step got the raw materials ready
Protocatechuic Acid, uncarine, the thevetin getting Liu Suan Copper 300 grams, zinc sulfate 300 grams, manganous sulfate 100 grams, sal epsom 100 grams, ferrous sulfate 1000 grams, nitric acid mishmetal 20 Ke, Molybdenum acid ammonium 20 grams, boric acid 200 grams and prepared.
The 3rd step coordination reaction
Protocatechuic Acid and 1 premium on currency dissolved ferrous sulfate are carried out coordination reaction, 80～110 ℃ of temperature, time 30～50min, pH2～4; Protocatechuic Acid and 0.5 premium on currency dissolved zinc sulfate carry out coordination reaction, 90～120 ℃ of temperature, time 40～60min, pH3～5; 0.5 premium on currency dissolved manganous sulfate and uncarine carry out coordination reaction, 70～100 ℃ of temperature, time 30～50min, PH2～4; 0.5 premium on currency dissolved Liu Suan Copper and thevetin carry out coordination reaction, 80～100 ℃ of temperature, time 30～50min, pH3～5.
Then above-mentioned reaction gained is joined with thing and add the reaction that is mixed again of sal epsom, nitric acid mishmetal, Molybdenum acid ammonium, boric acid again.The condition of its coordination reaction is: 90～110 ℃ of temperature, time 30～60min, pH4～6.
Claims (8)
1. the production method of the multielement organic coordination fertilizer of a Pesticidal and sterilizing is characterized in that being made up of sulphur acid Copper, zinc sulfate, manganous sulfate, sal epsom, ferrous sulfate, sulfuric acid mishmetal, Molybdenum acid ammonium, boric acid, Protocatechuic Acid, uncarine, thevetin.
2. the production method of the multielement organic coordination fertilizer of Pesticidal and sterilizing according to claim 1 is characterized in that described Liu Suan Copper is 4～7%, zinc sulfate is 2～5%, manganous sulfate is 1～3%, sal epsom is 1.5～3.0%, ferrous sulfate is 1.5～1.8%, the nitric acid mishmetal is that 0.5～0.9%, Molybdenum acid ammonium is 0.5～0.7%, boric acid is 2～4%, Protocatechuic Acid is 8～10%, uncarine is 6～9%, thevetin is 3～5%.
3. according to the production method of the multielement organic coordination fertilizer of claim 1,2 described Pesticidal and sterilizings, it is characterized in that described Protocatechuic Acid and ferrous sulfate, Protocatechuic Acid and zinc sulfate, manganous sulfate and uncarine, Liu Suan Copper and thevetin carry out coordination reaction respectively; Reaction more again is mixed its title complex adding sal epsom, nitric acid mishmetal, Molybdenum acid ammonium, boric acid.
4. the production method of the multielement organic coordination fertilizer of Pesticidal and sterilizing according to claim 3 is characterized in that described coordination reaction condition is: 80～120 ℃ of temperature, 30～60 minutes time, pH2～6.
5. the fertile method of producing of the multielement organic coordination of Pesticidal and sterilizing according to claim 1, the making that it is characterized in that described Protocatechuic Acid is the water logging of folium ilicis chinensis cured leaf, heating, filtration, concentrates, regulate pH=1～3 with hydrochloric acid, add the ethyl acetate cascade extraction then, add NaHCO again
3Back extraction is made.
6. the production method of the multielement organic coordination fertilizer of Pesticidal and sterilizing according to claim 1 is characterized in that it is that branch, root by yncaria stem with hooks dries abrasive dust that described uncarine is made, and uses NH
4OH, water, alcohol mixeding liquid are wetting, with the ether leaching, carry out cascade extraction with hydrochloric acid then again, and the hcl as extraction agent liquid after the extraction adds uses NH
4The OH pH=8-11 that alkalizes.Use the ether back extraction again.Strip liquor concentrates, behind the recovery ether, in its vitriolization.
7. the production method of the multielement organic coordination fertilizer of Pesticidal and sterilizing according to claim 1 is characterized in that it is Semen Thevetiae benevolence to be pulverized the back use the benzene degreasing that described thevetin is made, and adds water, ethanol then, gets percolating water and concentrates.
8. according to the production method of the multielement organic coordination fertilizer of claim 1,2,3,4 described Pesticidal and sterilizings, it is characterized in that complex fertilizer with described production method made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011335327A CN1182083C (en) | 2001-10-08 | 2001-10-08 | Complex fertilizer for killing insect and bacteria and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011335327A CN1182083C (en) | 2001-10-08 | 2001-10-08 | Complex fertilizer for killing insect and bacteria and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1410401A true CN1410401A (en) | 2003-04-16 |
| CN1182083C CN1182083C (en) | 2004-12-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011335327A Expired - Fee Related CN1182083C (en) | 2001-10-08 | 2001-10-08 | Complex fertilizer for killing insect and bacteria and its production method |
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| Country | Link |
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| CN (1) | CN1182083C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7737174B2 (en) | 2006-08-30 | 2010-06-15 | The Regents Of The University Of Michigan | Indole inhibitors of MDM2 and the uses thereof |
| US7759383B2 (en) | 2005-02-22 | 2010-07-20 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| EA014445B1 (en) * | 2005-02-22 | 2010-12-30 | Дзе Риджентс Оф Дзе Юниверсити Оф Мичиган | Small molecule inhibitors of mdm2 and uses thereof |
| US8222288B2 (en) | 2006-08-30 | 2012-07-17 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| US8518984B2 (en) | 2009-11-12 | 2013-08-27 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8629141B2 (en) | 2011-05-11 | 2014-01-14 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8680132B2 (en) | 2010-11-12 | 2014-03-25 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| CN106047360A (en) * | 2016-05-31 | 2016-10-26 | 山东胜伟园林科技有限公司 | Anti-seepage sand containing catechin and method for planting salix matsudana in saline-alkali soil by utilizing same |
| CN115572200A (en) * | 2022-11-15 | 2023-01-06 | 湖北中烟工业有限责任公司 | Preparation method of tobacco stem organic fertilizer for preventing and treating bacterial wilt |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210371353A1 (en) * | 2020-06-02 | 2021-12-02 | Lanny L. Johnson | Fertilizer compositions and plants containing protocatechuic acid, and uses thereof |
-
2001
- 2001-10-08 CN CNB011335327A patent/CN1182083C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8742121B2 (en) | 2005-02-22 | 2014-06-03 | The Regents Of The University Of Michigan | Process for the preparation of small molecule inhibitors of MDM2 and intermediates used therein |
| US7759383B2 (en) | 2005-02-22 | 2010-07-20 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| EA014445B1 (en) * | 2005-02-22 | 2010-12-30 | Дзе Риджентс Оф Дзе Юниверсити Оф Мичиган | Small molecule inhibitors of mdm2 and uses thereof |
| US8088931B2 (en) | 2005-02-22 | 2012-01-03 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| US8901117B2 (en) | 2005-02-22 | 2014-12-02 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| US8222288B2 (en) | 2006-08-30 | 2012-07-17 | The Regents Of The University Of Michigan | Small molecule inhibitors of MDM2 and the uses thereof |
| US7737174B2 (en) | 2006-08-30 | 2010-06-15 | The Regents Of The University Of Michigan | Indole inhibitors of MDM2 and the uses thereof |
| US8877796B2 (en) | 2009-11-12 | 2014-11-04 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8518984B2 (en) | 2009-11-12 | 2013-08-27 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US9079913B2 (en) | 2009-11-12 | 2015-07-14 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8680132B2 (en) | 2010-11-12 | 2014-03-25 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US9302120B2 (en) | 2010-11-12 | 2016-04-05 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| US8629141B2 (en) | 2011-05-11 | 2014-01-14 | The Regents Of The University Of Michigan | Spiro-oxindole MDM2 antagonists |
| CN106047360A (en) * | 2016-05-31 | 2016-10-26 | 山东胜伟园林科技有限公司 | Anti-seepage sand containing catechin and method for planting salix matsudana in saline-alkali soil by utilizing same |
| CN115572200A (en) * | 2022-11-15 | 2023-01-06 | 湖北中烟工业有限责任公司 | Preparation method of tobacco stem organic fertilizer for preventing and treating bacterial wilt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1182083C (en) | 2004-12-29 |
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Granted publication date: 20041229 Termination date: 20111008 |