CN1399882A - Plant bactericide containing diniconazole and prochloraz zinc salt - Google Patents

Plant bactericide containing diniconazole and prochloraz zinc salt Download PDF

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Publication number
CN1399882A
CN1399882A CN 01123807 CN01123807A CN1399882A CN 1399882 A CN1399882 A CN 1399882A CN 01123807 CN01123807 CN 01123807 CN 01123807 A CN01123807 A CN 01123807A CN 1399882 A CN1399882 A CN 1399882A
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CN
China
Prior art keywords
zinc salt
diniconazole
prochloraz zinc
prochloraz
bactericide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 01123807
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Chinese (zh)
Inventor
仲汉根
陈晓东
季自珍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Huifeng Agrochemical Co Ltd
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Jiangsu Huifeng Agrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Huifeng Agrochemical Co Ltd filed Critical Jiangsu Huifeng Agrochemical Co Ltd
Priority to CN 01123807 priority Critical patent/CN1399882A/en
Publication of CN1399882A publication Critical patent/CN1399882A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a plant bactericide containing diniconazole and prochloraz zinc salt, which is characterized in that the diniconazole and prochloraz zinc salt and conventional additives and excipients are compounded into common formulations including powder, wettable powder, emulsifiable concentrate, suspending emulsion and granules. The bactericide of the present invention has low active component amount, wide control spectrum, synergistic effect and high yield, and is especially suitable for preventing and treating pseudocercospora, coracoid spore, ascomycete, basidiomycete and nucleoporidia.

Description

A kind of bactericide that contains diniconazole and prochloraz zinc salt
Technical field
The present invention relates to bactericide, a kind of bactericide that contains diniconazole and prochloraz zinc salt of more specifically saying so.
Background technology
Alkene azoles alcohol is a kind of high-effective broad-spectrum fungicide; have protection, treat, root out three effects greatly; it is a kind of brand-new compound; in thalline, work by the biosynthesis that suppresses ergosterol in the thalline; similar to other bactericide mechanism of action, therefore can there be transreactance with mutual the mixing of other bactericide.Foliage applying can be prevented and treated white powder germ and the black star germ on grape, cereal crop and the fruit, is used for the bunt bacterium that seed treatment can be prevented and treated the cereal class.For example can prevent and treat powdery mildew, leaf rust, the yellow rust of cereal with the 50-125gAI/ha foliage-spray; The 5-10g/100kg seed is dressed seed, and can prevent and treat smut, bunt; The 6-10g/100kg seed is dressed seed, and can prevent and treat stripe disease; 25-40ppm can prevent and treat grape powdery mildew and black rot; 25-50ppm can prevent and treat apple mildew and scab.
Prochloraz zinc salt is that various crop is all had the protective fungicide effect, is the protective fungicide that is used for leaf portion, and general plant-less toxicity is mainly used in anti-smelting to various crop disease such as wheat class, paddy rice, fruit tree, vegetables and tobacco such as wheat rust, head blight; Rice blast, line disease; The corn northern leaf blight; The rust of apple and pears etc. are to work by the biosynthesis that suppresses ergosterol in the thalline.112g mu, foliage-spray can be prevented and treated cucumber anthracnose; 0.8-1.2g commodity amount is dissolved in 1 premium on currency, sprays on 1 square metre the field, can be used to prevent and treat cucumber downy mildew, cercospora leaf spot of sugar beet; 120-200ppm is used for citrus and adopts the back anti-corrosive fresh-keeping, can prevent and treat green mold of citrus, anthracnose, blossom-end rot.But, these two kinds of prescriptions are solely used, to pears and apple and scab, potato late blight, black swollen sick, dehiscence is sick, the preventive effect of soft rot, black spot and withered rust such as Chinese cabbage, radish, turnip, cucumber bacterial angular leaf spot, celery leaf spot, eqpidemic disease is not good.
Summary of the invention
The purpose of this invention is to provide and a kind of disease is had the bactericide that the active component total amount is used in improved action effect and reduction.
Technical scheme of the present invention: with diniconazole and prochloraz zinc salt and known auxiliary agent, the compound regular dosage form of making of excipients.
Bactericide of the present invention is the preparation that comprises pulvis, wetting powder, suspension emulsion, emulsifiable concentrate, granule that contains the diniconazole and prochloraz zinc salt of the heavy % of 0.1-95 (the heavy % of best 0.5-90), described diniconazole and prochloraz zinc salt mixed weight ratio is 1: 1-100, the best is 1: 1-40.
Described preparation is that routinely preparation method promptly adds known solvent and/or carrier, emulsifier, dispersant in diniconazole and prochloraz zinc salt, makes required formulation.
The surfactant materials that preparation of the present invention is used comprises alkali metal, the alkali salt of lauryl ether sulfuric acid and fatty alcohol sulphuric acid, ethoxylated castor oil, polyoxyethylene or polyoxypropylene alkyl ether laruyl alcohol, the polyglycol ether acetic acid esters, sorbitan ester, methylcellulose, naphthalene or naphthalene sulfonic acids and phenol or with iso-octyl, octyl group or nonyl phenol, alkylphenol or the tributyl phenyl polyglycol ether of the condensation product of formaldehyde, polyoxyethylene octylphenol ether, ethyoxyl alkylization, alkyl aryl polyether alcohol, different three decyl alcohol, fatty alcohol ethylene oxide condensate etc.
Described pulvis can be mixed together with solid carrier by the mixture with diniconazole and prochloraz zinc salt, abradant surface becomes.
Described granule is diniconazole and prochloraz zinc salt mixture etc. is adhered on the solid carrier and makes.
Described solid carrier comprises silica gel, silica, silicate, lime, lime stone, kaolin, chalk, diatomite, loess, bark powder, potter's clay, calcium sulphate and magnesium sulfate, magnesia, molding powder, chemical fertilizer.
Above-mentioned surfactant and carrier are the commercially available prod.
Advantage of the present invention:
Bactericide of the present invention can reduce formulation rate, improve the bactericidal action spectrum of using diniconazole and prochloraz zinc salt separately, the expanding prevention spectrum, Synergistic, increase income, be applicable to the disease of crops such as control pears, apple, banana, pineapple, grape, melon, citrus, mango, mushroom, particularly prevent and treat pseudo-cercospora, Rhynchosporium spp, Saccharomyces, Basidiomycotina, Pyrenophora, as the green mould of the scab of pears, citrus, mango anthracnose, mushroom white rot etc.; Bactericide of the present invention can mix use with other composition such as weed killer herbicide, insecticide or other bactericide.
Embodiment
Further specify characteristics of the present invention below by instantiation.
Example 1
Alkene azoles alcohol 6%, prochloraz zinc salt 24%, emulsifier farming breast 0,210 5%, solvent xylene 65% are mixed into homogeneous phase liquid, obtain missible oil.
Example 2
With alkene azoles alcohol 2.5%, prochloraz zinc salt 30%, draw back powder LS (alkylnaphthalene sulfonate) 4%, carboxymethyl cellulose 6%, dispersing agent NNO (two naphthalene sulfonic acid-formaldehyde condensation product) 10%, lightweight charcoal acid calcium 47.5% and mix, mixture makes wetting powder through grinding.
Example 3
Alkene azoles alcohol 12%, prochloraz zinc salt 25%, emulsifier farming breast 0,210 15%, water 48% are stirred, obtain aqua.
Example 4
With alkene azoles alcohol 0.5%, prochloraz zinc salt 0.5%, emulsifier farming breast 0,210 10%, all the other are the dimethylbenzene mixing, get missible oil.
Example 5
With alkene azoles alcohol 0.5%, prochloraz zinc salt 50%, draw back powder LS 5% carboxymethyl cellulose 5%, dispersing agent NNO 10%, precipitated calcium carbonate 29.5%, wetting powder.
Example 6
Triethanolamine salt 15%, co-emulsifier dodecanol-15% with alkene azoles alcohol 12%, prochloraz zinc salt 25%, emulsifier 2,4, poly-(20) the glycol ether phosphate monoester of 6-three (1-phenethyl) phenol or dibasic acid esters and monoesters mixture, antimicrobial benzoic acid 2%, the NaCl aqueous solution 41% stirs, and obtains aqueous emulsion.
Example 7
With alkene azoles alcohol 45%, prochloraz zinc salt 45%, filler white carbon 8%, other auxiliary agent 2% (wherein surfactant lignin sulfonic acid sodium salt 0.5%, dispersant alkyl sulfonic acid sylvite 0.5%, stabilizing agent heptadecanol 1%), mixing grinds and obtains soluble powder.
Example 8
This example is an application example.
Adopt the missible oil of example 1 preparation to prevent and treat fragrant burnt leaf spot test.Experimental condition and result such as following table:
The medicine product claim Extension rate Before the medicine, % Behind the medicine 15 days, % Behind the medicine 25 days, %
The incidence of disease Disease refers to The incidence of disease Disease refers to Preventive effect The incidence of disease Disease refers to Preventive effect
Example 1 missible oil 1000 ?9.0 ?3.5 ?16.3 ?8.7 ?81.0 ?20.8 ?12.5 ?81.3
Example 1 missible oil 800 ?11.3 ?5.5 ?18.5 ?10.5 ?85.4 ?22.5 ?13.2 ?87.4
Example 1 missible oil 500 ?10.2 ?3.6 ?17.2 ?4.5 ?90.4 ?22.2 ?6.7 ?90.2
25% makes hectogram missible oil 1000 ?11.0 ?4.5 ?18.1 ?9.2 ?84.4 ?23.4 ?11.9 ?86.1
12.5% alkene azoles alcohol wetting powder 1000 ?9.5 ?3.6 ?17.5 ?5.0 ?88.5 ?23.5 ?10.8 ?85.6

Claims (3)

1. bactericide that contains diniconazole and prochloraz zinc salt, it is characterized in that being re-dubbed the preparation that comprises pulvis, wetting powder, suspension emulsion, emulsifiable concentrate, granule by diniconazole and prochloraz zinc salt and auxiliary agent, excipients, described diniconazole and prochloraz zinc salt mixture accounts for the 0.1-95% of weight of formulation, and described alkene azoles alcohol is 1 with the mixed weight ratio of prochloraz zinc salt: 1-100.
2. according to the described bactericide of claim 1, it is characterized in that described diniconazole and prochloraz zinc salt mixture accounts for the 0.5-90% of weight of formulation, diniconazole and prochloraz zinc salt mixed weight ratio is 1: 1-40.
3. the purposes of the described bactericide of claim 1 is characterized in that being applicable to control pseudo-cercospora, Rhynchosporium spp, Saccharomyces, Basidiomycotina, nuclear cavity Pseudomonas germ.
CN 01123807 2001-07-30 2001-07-30 Plant bactericide containing diniconazole and prochloraz zinc salt Pending CN1399882A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 01123807 CN1399882A (en) 2001-07-30 2001-07-30 Plant bactericide containing diniconazole and prochloraz zinc salt

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 01123807 CN1399882A (en) 2001-07-30 2001-07-30 Plant bactericide containing diniconazole and prochloraz zinc salt

Publications (1)

Publication Number Publication Date
CN1399882A true CN1399882A (en) 2003-03-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 01123807 Pending CN1399882A (en) 2001-07-30 2001-07-30 Plant bactericide containing diniconazole and prochloraz zinc salt

Country Status (1)

Country Link
CN (1) CN1399882A (en)

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