CN1386814A - Composite rubber strip for hollow glass and its preparing process - Google Patents
Composite rubber strip for hollow glass and its preparing process Download PDFInfo
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- CN1386814A CN1386814A CN 01134332 CN01134332A CN1386814A CN 1386814 A CN1386814 A CN 1386814A CN 01134332 CN01134332 CN 01134332 CN 01134332 A CN01134332 A CN 01134332A CN 1386814 A CN1386814 A CN 1386814A
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Abstract
A composite rubber strip for dual-layer of glass is prepared from butyl rubber, liquid rubber, viscosity increasing resin, anti-ageing agent, talc powder, molecular sieve, silica white and carbon black through proportioning, plasticizing, milling, kneading, filtering, extruding, cooling and coiling.
Description
The present invention relates to a kind of double glazing composite rubber strip and manufacture method thereof.
Along with improving constantly of constant development of economy and living standards of the people, people are to the environment of office and inhabitation, condition to each side such as traffic and lives has all had higher requirement, high-riser miscellaneous and residence building are rised sheer from level ground, air-conditioned train and automobile increase sharply fast, and be also more and more higher to the requirement of various electrical equipments simultaneously.For seal, be incubated, moistureproof, prevent the pollution of the environment and for attractive in appearance, many buildingss, the vehicles and electrical equipment etc. have all used double glazing unit.The consequent is to need a large amount of double glazing Composite sealing adhesive tapes.
The existing at present report of producing the glass capsulation adhesive tape.For example, introduced a kind of binder composition and production method thereof among the CN87107676A, but the prescription complexity of the binder composition of being introduced there is not to introduce in detail the method for producing joint strip yet.Introduced a kind of laminate of composite structure among the CN1216948A, but it there be not concrete prescription and the preparation embodiment of place of matchmakers with seal gum.Introduced a kind of Composite sealing adhesive tape among the CN2261429Y, but it does not introduce the raw materials used prescription of this Composite sealing adhesive tape and its concrete preparation method yet.
The invention provides a kind of double glazing composite rubber strip, a kind of method of making the double glazing composite rubber strip also is provided.Double glazing composite rubber strip prescription of the present invention is simple, and handiness is big, and product hermeticity can be good, and suction is strong, and smooth and beautiful appearance is ageing-resistant, and never degenerate decades.The method technology simple and flexible of manufacturing double glazing composite rubber strip of the present invention, equipment is simple, easily operation.
Introduce below and make used raw material and the proportionlity thereof of double glazing composite rubber strip of the present invention.
The used raw material of double glazing composite rubber strip of the present invention is divided into four classes: the first kind is a polyisobutylene rubber; Second class is an organic additive; The 3rd class is an inorganic assistant agent; The 4th class is a carbon black.
With raw materials used gross weight is 100% to calculate as benchmark, and wherein, first kind polyisobutylene rubber is 25-58%, preferred 35-50%; The second class organic additive is 2-8%, preferred 3-6%; The 3rd class inorganic assistant agent is 15-36%, preferred 16-25%; The 4th class carbon black is 24-50%, preferred 30-40%.
Introduce double glazing composite rubber strip of the present invention used raw material and proportioning thereof below in detail.
With raw materials used gross weight is 100% to calculate as benchmark, wherein:
First kind polyisobutylene rubber, it mainly acts on is to regulate the soft or hard of adhesive tape and viscosity etc., this type of material comprises three kinds of materials: 1. butyl rubber: it can be selected from brominated butyl rubber, chlorinated butyl rubber, common butyl rubber as 268,301 etc.The molecular weight of used butyl rubber should be greater than 250,000, and its consumption can be regulated according to the size of molecular weight, is generally 10-20%, and it also can increase and decrease mutually with other material in this class material, reaches required total amount; 2. liquid glue: it also claims low molecular polyisobutylene, and the molecular weight of used polyisobutene is generally greater than 1800, and consumption is 10-25%, also can increase and decrease mutually with other material in this class material, reaches required total amount; 3. tackifying resin: it mainly is to cooperate liquid glue that adhesive tape is played viscosifying action.It can be selected from model is chemical industry resins such as E-1102, E-1102F, E-1202, E-1265, E-1304, E-1310, E-1401, also can select common natural resin, terpine resin etc. for use.Wherein chemical industry resin and natural resin can mix use, also can use separately.Its usage quantity is 5-15%;
The second class organic additive, it mainly acts on is to prevent to take place in the use of adhesive tape finished product to wear out.This type of material comprises three kinds of materials: 1. dicumyl peroxide (DCP), and its consumption is 0.5-3%; 2. anti-aging agent RD, its consumption is 1-2%; 3. antioxidant 4010NA, its consumption is 0.5-3%.It also can replace with other like product.
The 3rd class inorganic assistant agent, this type of material comprise three class materials: 1. talcum powder and/or lime carbonate, and mainly as weighting material, its grain diameter is more than 250 orders, and the high more adhesive tape luminance brightness of making of order number is good more certainly, and consumption is 8-12%.Talcum powder and lime carbonate can use with any mixed, also can use separately; 2. potter's clay mainly also is that it is bigger than talcous viscosity as weighting material, and a piece of wood serving as a brake to halt a carriage of adhesive tape is had good effect, and consumption is 2-4%.Two kinds of materials of talcum powder or lime carbonate and potter's clay can use separately, also can use with any mixed, reach required total amount; 3. molecular sieve, it is as hygroscopic agent, consumption is 5-20%.Can be selected from 3A, 4A, 5A equimolecular sieve, 3A, 4A, 5A equimolecular sieve can use separately, also can use with any mixed, and preferred the mixing uses.It can guarantee exhaust moisture between the layer glass of adhesive tape after making the double glazing adhesive tape.
The 4th class carbon black, carbon black is mainly as weighting material.This type of material comprises four class materials: 1. white carbon black, and it can increase the intensity of glue, reduces proportion, and consumption is at 4-10%.2. the high abrasion carbon black is good as weighting material hardness, can be selected from the high abrasion carbon black 220, No. 330, and consumption is 5-10%.3. extrude carbon black soon, as weighting material, it can make glue smooth, and adhesive tape is extruded smooth and easy, can be selected from the fast carbon black that extrudes 539,550, No. 660, and the fast extrusion carbon black of these models can use separately, also can use with any mixed, and consumption is 5-10%.4. partly go on foot strong carbon black, it makes the adhesive tape of making not have bounce-back, can be selected from 660 or No. 774, and consumption is 10-20%.
Four kinds of above-mentioned carbon blacks generally are to mix to use, and also can be used alone or two kinds, and the quantity between them can be complementary, reaches required total amount.
Make the used material of double glazing composite rubber strip of the present invention and all be the known products that the external import that can buy on the market or domestic manufacturer produce.
Below introduce in detail the method for making double glazing composite rubber strip of the present invention.
The manufacturing step of double glazing composite rubber strip of the present invention is as follows:
1. batching:, take by weighing various materials separately according to the ratio of the required various materials of described prescription according to the composite rubber strip (by 100% weight) of preproduction amount;
2. plasticate: use the mill of gap less than 2mm, butyl rubber is joined in the mill, after plasticating 10-20 minute under 80-90 ℃ the temperature, add organic additive (three kinds of anti-aging agent), reclaiming by plastification 10-20 minute, obtain a kind of butyl rubber of plasticating uniformly;
3. mixing: as in above-mentioned 2 resulting butyl rubbers of plasticating, to add carbon black, 50% weight that adds required talcum powder, lime carbonate and potter's clay amount again, the liquid glue that adds 65% weight then, the mixture that obtains joined open refining in the mill, under 80-95 ℃ temperature mixing about 10-20 minute, make its uniform mixing, be squeezed into the shinny film that thickness is no more than 10mm again, the film that obtains is cut into small pieces, so that next step processing;
4. mediate: kneader is preheating to 80-90 ℃, the above-mentioned 3 block films that obtain are joined continuously in the kneader of preheating and mediate, when film reaches 110 ℃ of deliquescing and sticks together, add remaining 35% liquid glue, whole resin and all the other talcum powder of 50%, lime carbonate and potter's clay.The mixture that obtains is further mediated in this kneader, more all molecular sieves is added after the kneading evenly, further mediates again, obtains a kind of uniform kneaded material at last;
5. filter: the above-mentioned 4 even kneaded materials that obtain are joined in the extrusion machine, install one deck 40 orders and one deck 60 purpose woven wires in the outlet of extrusion machine.When extruding this kneaded material, extrusion machine removes by filter foreign material and granular solids by two-layer woven wire.Then, be extruded into thick adhesive tape doubly with a forcing machine again than the coarse 4-5 of finished product adhesive tape;
6. jewelling band: the certain size one-tenth dish aluminium strip of having bought on the market is cut into desired aluminum strip with aluminium belt cutting machine, is cut into the waviness aluminium strip of the required gradient again with the waviness aluminium strip shaper of lower gear interlock on the platform;
7. with adhesive tape forcing machine extrusion molding adhesive tape: this adhesive tape cross-head has the gel feed of a connection forcing machine, an aluminium strip import and a finished product adhesive tape outlet.Import becomes an angle of 90 degrees to gel feed with aluminium strip.The adhesive tape temperature out is about 90 ℃.Glue and aluminium strip obtain the adhesive tape of glue and aluminium strip one simultaneously through the forcing machine extruding;
8. transmit cooling: above-mentioned 7 the finished product adhesive tape of being extruded by forcing machine is served constantly mobile travelling belt, and this travelling belt length can not be too short, and general requirement is more than 12 meters.Generally will there be the cooling blower air-supply travelling belt top, the back difficult deformation so that adhesive tape is fully lowered the temperature;
9. adhesive tape dish dish: the above-mentioned 8 cooling adhesive tape use dish dish device dish dishes that obtain.When adhesive tape dish dish, must separate with two-sided separate paper between every layer of adhesive tape, can not contact with each other between the adhesive tape, can obtain the plate-like adhesive tape like this;
10. pack: the above-mentioned 9 adhesive tape dishes that obtain are packed with the plastic-aluminum vacuum packaging bag, be noted that and separate adhesive tape with separate paper, in case adhesive tape is sticked together, and add the molecular sieve hygroscopic agent in bag, sealed after being vacuumized just can be used as production marketing, use.
Making the used equipment of double glazing composite rubber strip of the present invention all is the general equipment in this area.
With embodiment double glazing composite rubber strip of the present invention and manufacture method thereof are described further below, but the present invention is not subjected to the restriction of embodiment.
Embodiment 1
With the thick adhesive tape of making 100 kilograms of no wave aluminium strips is benchmark, takes by weighing various materials according to following weight:
Get 42 kilograms of first kind material polyisobutylene rubbers, wherein 16 kilograms of chlorinated butyl rubbers, molecular weight are 2000 16 kilograms of polyisobutene, 10 kilograms of tackifying resin E-1102;
Get 5 kilograms of the second class material organic additives, wherein 2 kilograms of dicumyl peroxides (DCP), 1 kilogram of anti-aging agent RD, 2 kilograms of antioxidant 4010NAs;
Get 18 kilograms of the 3rd class material inorganic assistant agents, wherein particle diameter is 6 kilograms of 280 purpose talcum powder and 3 kilograms in lime carbonate, 4 kilograms in potter's clay, 5 kilograms in 3A molecular sieve;
Get 35 kilograms of the 4th class material carbon blacks, wherein white 5 kilograms, No. 220 high abrasion carbon blacks of carbon black 10 kilograms, No. 550 are fast to extrude 10 kilograms of carbon blacks, partly go on foot 10 kilograms of No. 660, strong carbon blacks.
Make required adhesive tape according to the methods below:
1. use the mill of gap less than 2mm, the chlorinated butyl rubber of above-mentioned first kind material is joined in the mill for 16 kilograms, after plasticating 10 minutes under 80 ℃ of temperature, add 5 kilograms of the above-mentioned second class material organic additives, reclaiming by plastification 20 minutes obtains a kind of butyl rubber of plasticating uniformly;
2. in above-mentioned 1 resulting butyl rubber of plasticating, add 35 kilograms of above-mentioned the 4th class material carbon blacks, add 50% of above-mentioned the 3rd class material inorganic assistant agent talcum powder, lime carbonate and potter's clay again, promptly 6.5 kilograms, add 65% of polyisobutene liquid glue then, promptly 10.4 kilograms, the mixture that obtains joined open refining in the mill, under 80 ℃ of temperature mixing about 10 minutes, make its uniform mixing, be squeezed into the shinny film of thickness 10mm again, and the film that obtains is cut into small pieces.
3. kneader is preheating to about 80 ℃, the above-mentioned 2 block films that obtain are joined continuously in the kneader of preheating and mediate, when film reaches 110 ℃ of deliquescing and sticks together, top remaining 35% liquid glue, promptly 5.6 kilograms, 10 kilograms of above-mentioned whole tackifying resins and all the other talcum powder of 50%, lime carbonate and potter's clay join in the kneader for 6.5 kilograms, the mixture that obtains is further mediated in this kneader, after mediating evenly again 5 kilograms of addings of above-mentioned all 3A molecular sieves, further mediate again, obtain a kind of uniform kneaded material at last;
4. the above-mentioned 3 even kneaded materials that obtain are joined in the extrusion machine, install one deck 40 orders and one deck 60 purpose woven wires in the outlet of extrusion machine.When extruding this kneaded material, extrusion machine removes by filter foreign material and granular solids by two-layer woven wire.Then, be extruded into than the coarse about 4 times thick adhesive tape of finished product adhesive tape with a forcing machine again;
5. jewelling band: the one-tenth dish aluminium strip of having bought on the market is cut into desired aluminum strip with aluminium belt cutting machine, is cut into the waviness aluminium strip of the required gradient again with the waviness aluminium strip shaper of lower gear interlock on the platform;
6. use the gel feed that a connection forcing machine is arranged on extruder head, the adhesive tape forcing machine of an aluminium strip import and a finished product adhesive tape outlet pushes above-mentioned 4 thick adhesive tape and above-mentioned 5 aluminium strips that obtain together.Import becomes an angle of 90 degrees with aluminium strip in thick adhesive tape import.The adhesive tape temperature out is 90 ℃.Adhesive tape and aluminium strip obtain the adhesive tape of glue and aluminium strip one simultaneously through the forcing machine extruding;
7. above-mentioned 6 adhesive tape that obtain are served the travelling belt that constantly moves, about 13 meters of this travelling belt length.There is the cooling blower air-supply travelling belt top, makes the adhesive tape cooling;
8. use dish dish device is the above-mentioned 7 adhesive tape dish dishes that obtain.When adhesive tape dish dish, separate with the two-sided separate paper of having bought on the market between every layer of adhesive tape, can not contact with each other between the adhesive tape, obtain the plate-like adhesive tape like this;
9. the above-mentioned 8 adhesive tape dishes that obtain are packed with the plastic-aluminum vacuum packaging bag, with separate paper adhesive tape is separated during packing,, and in bag, add 3A molecular sieve hygroscopic agent in case adhesive tape is sticked together, sealed after being vacuumized obtains the finished product double glazing composite rubber strip of specifications and models 9mm.
The product of this embodiment in July calendar year 2001 through Ministry of Chemical Industry rubber sundry goods quality supervision and test center, detect according to Q/TXHLJ002-2001 double glazing composite rubber strip standard, think 8 all conformance with standard requirements such as project sag, low temperature flexibility, density, anti-ozone ageing of examining.Concrete assay is listed in the table below:
| Test item | Standard-required | Measured value | Individual event is judged | Testing standard |
| Density Mg/m 3 | ??≥1.2-1.4 | ?1.3 | Qualified | GB/T533 |
| (80 ℃ * 2h) mm of sags | ??0 | ?0 | Qualified | GB/T13477 |
| Low temperature flexibility (40 ℃ * 8h) | Flawless | Flawless | Qualified | GB/T13477 |
| Total cross section tensile strength N | ??≥140 | ??190 | Qualified | GB/T3686 |
| Total cross section tensile yield % | ??≤12 | ??9 | Qualified | GB/T3686 |
| Bonding tensile shear strength (with metal) MPa | ??≥0.10 | ??0.15 | Qualified | GB/T13936 |
| Anti-ozone ageing (50pphm * 48h) | There is not be full of cracks | There is not be full of cracks | Qualified | GB/T7762 |
| Specification: adhesive tape external form width mm | ??12.3±0.2 | ??12.1 | Qualified | Q/TXHLJ002 |
| Specification: adhesive tape external form thickness mm | ??6.1±0.2 | ??6.1 | Qualified | Q/TXHLJ002 |
Embodiment 2
In this embodiment, take by weighing various materials,, make the double glazing composite rubber strip according to the identical manufacture method of the foregoing description 1 by following weight.
Get 45 kilograms of first kind material polyisobutylene rubbers, wherein 18 kilograms of No. 301 butyl rubbers, molecular weight are 2400 17 kilograms of polyisobutene, 10 kilograms of tackifying resin E-1102;
Get 4 kilograms of the second class material organic additives, wherein 1 kilogram of dicumyl peroxide (DCP), 1 kilogram of anti-aging agent RD, 2 kilograms of antioxidant 4010NAs;
Get 20 kilograms of the 3rd class material inorganic assistant agents, wherein particle diameter is 6 kilograms of 300 purpose talcum powder and 2 kilograms in lime carbonate, 6 kilograms in potter's clay, 6 kilograms in 4A molecular sieve;
Get 31 kilograms of the 4th class material carbon blacks, wherein white 4 kilograms, No. 330 high abrasion carbon blacks of carbon black 8 kilograms, No. 550 are fast to extrude 8 kilograms of carbon blacks, partly go on foot 11 kilograms of No. 660, strong carbon blacks.
Embodiment 3
In this embodiment, take by weighing various materials,, make the double glazing composite rubber strip according to the identical manufacture method of the foregoing description 1 by following weight.
Get 50 kilograms of first kind material polyisobutylene rubbers, wherein 15 kilograms of chlorinated butyl rubbers, molecular weight are 2400 20 kilograms of polyisobutene, 15 kilograms of tackifying resin E-1102;
Get 4 kilograms of the second class material organic additives, wherein 2 kilograms of dicumyl peroxides (DCP), 1 kilogram of anti-aging agent RD, 1 kilogram of antioxidant 4010NA;
Get 22 kilograms of the 3rd class material inorganic assistant agents, wherein particle diameter is 6 kilograms of 280 purpose talcum powder and 4 kilograms in lime carbonate, 4 kilograms in potter's clay, 8 kilograms in 3A molecular sieve;
Get 24 kilograms of the 4th class material carbon blacks, wherein white 4 kilograms, No. 220 high abrasion carbon blacks of carbon black 5 kilograms, No. 660 are fast to extrude 5 kilograms of carbon blacks, partly go on foot 10 kilograms of No. 660, strong carbon blacks.
Claims (4)
1. double glazing composite rubber strip, it is made by following material:
With gross weight is 100% to calculate as benchmark, and polyisobutylene rubber is 25-58%, and organic additive is 2-8%, and inorganic assistant agent is 15-36%, and carbon black is 24-50%;
Wherein said polyisobutylene rubber comprises three kinds of following materials:
(1). molecular weight is greater than 250,000 the butyl rubber that is selected from brominated butyl rubber, chlorinated butyl rubber, common butyl rubber 268 or 301, and its consumption is 10-20%;
(2). molecular weight is greater than 1800 polyisobutene liquid glue, and its consumption is 10-25%;
(3). being selected from model is the tackifying resin of the chemical industry resin of E-1102, E-1102F, E-1202, E-1265, E-1304, E-1310, E-1401, common natural resin or terpine resin, and its consumption is 5-15%;
Wherein said organic additive comprises three kinds of following materials:
(1). dicumyl peroxide (DCP), its consumption are 0.5-3%;
(2). anti-aging agent RD, its consumption are 1-2%;
(3). antioxidant 4010NA, its consumption are 0.5-3%;
Wherein said inorganic assistant agent comprises three following class materials:
(1). talcum powder or the lime carbonate of particle diameter more than 250 orders, its consumption is 8-12%;
(2). potter's clay, its consumption are 2-4%;
(3). be selected from the molecular sieve of 3A, 4A or 5A, its consumption is 5-20%;
Wherein said carbon black comprises four following class materials:
(1). white carbon black, consumption is at 4-10%;
(2). be selected from 220 or No. 330 high abrasion carbon black, its consumption is 5-10%;
(3). be selected from 539,550 or No. 660 fast extrusion carbon black, its consumption is 5-10%;
(4). be selected from 660 or No. 774 partly go on foot strong carbon black, consumption is 10-20%;
The gross weight of above-mentioned material therefor is 100%.
2. according to the double glazing composite rubber strip of claim 1, wherein
With gross weight is 100% to calculate as benchmark, and polyisobutylene rubber is 35-50%; Organic additive is 3-6%; Inorganic assistant agent is 16-25%; Carbon black is 30-40%.
3. according to the double glazing composite rubber strip of claim 1 or 2, wherein
With gross weight is 100% to calculate as benchmark, and polyisobutylene rubber is 42%; Organic additive is 5%; Inorganic assistant agent is 18%; Carbon black is 35%.
4. the manufacture method of claim 1 or 2 or 3 double glazing composite rubber strip, it comprises following step:
(1). batching:, take by weighing various materials separately according to the ratio of the required various materials of described prescription according to the composite rubber strip (by 100% weight) of preproduction amount;
(2). plasticate: use the mill of gap, butyl rubber is joined in the mill, after plasticating 10-20 minute under 80-90 ℃ the temperature, add organic additive, reclaiming by plastification 10-20 minute, obtain a kind of butyl rubber of plasticating uniformly less than 2mm;
(3). mixing: as in above-mentioned (2) resulting butyl rubber of plasticating, to add carbon black, 50% weight that adds required talcum powder, lime carbonate and potter's clay amount again, the liquid glue that adds 65% weight then, the mixture that obtains joined open refining in the mill, under 80-95 ℃ temperature mixing 10-20 minute, make its uniform mixing, be squeezed into the shinny film that thickness is no more than 10mm again, the film that obtains is cut into small pieces, so that next step processing;
(4). mediate: kneader is preheating to 80-90 ℃, the block film that above-mentioned (3) are obtained joins continuously in the kneader of preheating and mediates, when film reaches 110 ℃ of deliquescing and sticks together, add remaining 35% liquid glue, whole resin and all the other talcum powder of 50%, lime carbonate and potter's clay, the mixture that obtains is further mediated in this kneader, again all molecular sieves are added after mediating evenly, further mediate again, obtain a kind of uniform kneaded material at last;
(5). filter: the even kneaded material that above-mentioned (4) are obtained joins in the extrusion machine, install one deck 40 orders and one deck 60 purpose woven wires in the outlet of extrusion machine, when extruding this kneaded material, extrusion machine removes by filter foreign material and granular solids by two-layer woven wire, then, be extruded into thick adhesive tape doubly with a forcing machine again than the coarse 4-5 of finished product adhesive tape;
(6). jewelling band: the certain size one-tenth dish aluminium strip of having bought on the market is cut into desired aluminum strip with aluminium belt cutting machine, is cut into the waviness aluminium strip of the required gradient again with the waviness aluminium strip shaper of lower gear interlock on the platform;
(7). with adhesive tape forcing machine extrusion molding adhesive tape: this adhesive tape cross-head has the gel feed of a connection forcing machine, an aluminium strip import and a finished product adhesive tape outlet, import becomes an angle of 90 degrees to gel feed with aluminium strip, the adhesive tape temperature out is about 90 ℃, glue and aluminium strip obtain the adhesive tape of glue and aluminium strip one simultaneously through the forcing machine extruding;
(8). the travelling belt cooling: the finished product adhesive tape that above-mentioned (7) obtain is served the travelling belt that constantly moves, and this travelling belt length is general more than 12 meters, and there is the cooling blower air-supply travelling belt top, so that adhesive tape is fully lowered the temperature;
(9). adhesive tape dish dish: the adhesive tape dish dish that use dish dish device obtains above-mentioned (8), when adhesive tape dish dish, must separate with two-sided separate paper between every layer of adhesive tape, can not contact with each other between the adhesive tape, obtain the plate-like adhesive tape;
(10). packing: the adhesive tape dish that above-mentioned (9) obtain is packed with the plastic-aluminum vacuum packaging bag, to separate adhesive tape with separate paper during packing,, and will in bag, add the molecular sieve hygroscopic agent in case adhesive tape is sticked together, sealed after being vacuumized just obtains packaged product adhesive tape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01134332 CN1386814A (en) | 2001-10-31 | 2001-10-31 | Composite rubber strip for hollow glass and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01134332 CN1386814A (en) | 2001-10-31 | 2001-10-31 | Composite rubber strip for hollow glass and its preparing process |
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| CN1386814A true CN1386814A (en) | 2002-12-25 |
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| CN 01134332 Pending CN1386814A (en) | 2001-10-31 | 2001-10-31 | Composite rubber strip for hollow glass and its preparing process |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399521A (en) * | 2010-09-17 | 2012-04-04 | 成都硅宝科技股份有限公司 | Hot melt butyl sealant for hollow glass and manufacture method thereof |
| CN102504709A (en) * | 2011-10-24 | 2012-06-20 | 杜德升 | Sealing rubber sheet for cavity of hollow glass and processing method thereof |
| CN102601884A (en) * | 2012-03-07 | 2012-07-25 | 辽宁双强塑胶科技开发有限公司 | Method for preparing composite rubber strip for hollow glass |
| CN102911625A (en) * | 2012-11-19 | 2013-02-06 | 郑州中原应用技术研究开发有限公司 | Thermoplastic spacing bar and preparation method thereof |
| CN104204631A (en) * | 2012-03-24 | 2014-12-10 | 日本华尔卡工业株式会社 | Fluorine resin gasket for pipe seal |
| CN107720772A (en) * | 2017-09-26 | 2018-02-23 | 郑州雪山实业股份有限公司 | Special 3A G activation powder of double glazing adhesive tape and preparation method thereof |
| CN108424008A (en) * | 2018-04-28 | 2018-08-21 | 揭阳市东信智能门窗科技有限公司 | A kind of sound insulation hollow glass and preparation method thereof |
| CN109913151A (en) * | 2019-03-25 | 2019-06-21 | 河南连邦有机硅科技有限公司 | A kind of hollow glass special environment protection butyl rubber |
-
2001
- 2001-10-31 CN CN 01134332 patent/CN1386814A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399521A (en) * | 2010-09-17 | 2012-04-04 | 成都硅宝科技股份有限公司 | Hot melt butyl sealant for hollow glass and manufacture method thereof |
| CN102399521B (en) * | 2010-09-17 | 2013-04-03 | 成都硅宝科技股份有限公司 | Hot melt butyl sealant for hollow glass and manufacture method thereof |
| CN102504709A (en) * | 2011-10-24 | 2012-06-20 | 杜德升 | Sealing rubber sheet for cavity of hollow glass and processing method thereof |
| CN102601884A (en) * | 2012-03-07 | 2012-07-25 | 辽宁双强塑胶科技开发有限公司 | Method for preparing composite rubber strip for hollow glass |
| CN102601884B (en) * | 2012-03-07 | 2015-03-04 | 辽宁双强塑胶科技发展股份有限公司 | Method for preparing composite rubber strip for hollow glass |
| CN104204631A (en) * | 2012-03-24 | 2014-12-10 | 日本华尔卡工业株式会社 | Fluorine resin gasket for pipe seal |
| CN102911625A (en) * | 2012-11-19 | 2013-02-06 | 郑州中原应用技术研究开发有限公司 | Thermoplastic spacing bar and preparation method thereof |
| CN102911625B (en) * | 2012-11-19 | 2015-03-11 | 郑州中原应用技术研究开发有限公司 | Thermoplastic spacing bar and preparation method thereof |
| CN107720772A (en) * | 2017-09-26 | 2018-02-23 | 郑州雪山实业股份有限公司 | Special 3A G activation powder of double glazing adhesive tape and preparation method thereof |
| CN108424008A (en) * | 2018-04-28 | 2018-08-21 | 揭阳市东信智能门窗科技有限公司 | A kind of sound insulation hollow glass and preparation method thereof |
| CN108424008B (en) * | 2018-04-28 | 2020-12-29 | 揭阳市东信智能门窗科技有限公司 | Sound-insulation hollow glass and preparation method thereof |
| CN109913151A (en) * | 2019-03-25 | 2019-06-21 | 河南连邦有机硅科技有限公司 | A kind of hollow glass special environment protection butyl rubber |
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