CN110408223A - A kind of Moisture-proof corrosion-proof wood plastic composite and preparation method thereof - Google Patents

A kind of Moisture-proof corrosion-proof wood plastic composite and preparation method thereof Download PDF

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CN110408223A
CN110408223A CN201910531568.9A CN201910531568A CN110408223A CN 110408223 A CN110408223 A CN 110408223A CN 201910531568 A CN201910531568 A CN 201910531568A CN 110408223 A CN110408223 A CN 110408223A
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parts
proof
plastic composite
moisture
wood plastic
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张继兵
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Anhui Huaishu Building Materials Co Ltd
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Anhui Huaishu Building Materials Co Ltd
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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    • B32B27/00—Layered products comprising a layer of synthetic resin
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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Abstract

The invention discloses a kind of Moisture-proof corrosion-proof wood plastic composites and preparation method thereof, belong to wood plastic composite technical field, each raw material composition parts by weight are as follows: 30-50 parts of wood powder, 20-40 parts of vinyon, 15-35 parts of degradable thermoplastic resin, 2-5 parts of activated Calcium carbonate, 10-20 parts of ceramic powder；5-15 parts of polypropene staple, 5-15 parts of polyester fiber, 15-25 parts of glass powdered steel, 5-10 parts of silicon carbide, 10-15 parts of Nano-sized Alumina Powder, 3-8 parts of adhesive, 2-7 parts of adjuvant, 2-10 parts of foaming agent, 4-10 parts of coupling agent.The present invention is by increasing glass powdered steel, ceramic powder, polypropene staple and polyester fiber, enhance the structural rigidity and wearability of wood plastic composite, durability, weatherability, corrosion resistance and the chemical resistance of composite material are mentioned simultaneously, the moisture content of wood plastic composite is effectively reduced, moisture protection is improved.

Description

A kind of Moisture-proof corrosion-proof wood plastic composite and preparation method thereof
Technical field
The present invention relates to a kind of wood plastic composites and preparation method thereof, multiple more particularly to a kind of Moisture-proof corrosion-proof wood moulding Condensation material and preparation method thereof belongs to wood plastic composite technical field.
Background technique
Wood plastic composite is a kind of advanced composite material (ACM) being surging forward in recent years both at home and abroad, refers to and utilizes polyethylene, poly- third Alkene and polyvinyl chloride etc., it is fine with the useless plant such as wood powder, rice husk, stalk more than 50% or more instead of common resin adhesive Dimension is mixed into new wood materials, then through plastic processings such as extruding, molding, injection mouldings, the plate or profile produced. It is mainly used for the industries such as building materials, furniture, logistics packaging.Through hot extrusion molding after plastics and wooden powder are mixed in a certain ratio Plate, referred to as extruding wood-plastic composite panel.With the research and development to wood plastic composite, the plastics of wood plastic composite are produced Raw material, other than having high density polyethylene (HDPE) or polypropylene, there are also polyvinyl chloride and PS.Technique is also squeezed out by earliest single screw rod Machine develops into second generation conical double screw extruder, then arrives and squeeze by parallel double-screw extruder preliminary granulation, then by conical screw It forms out, can make up and be difficult to be plasticized, ageing resistance is poor, creep resistance is poor, the consistency of color and persistence difference and stretches strong Degree etc..
Existing wood plastic composite is in production group for some other components are added to improve wood plastic composite in composition Performance, but ineffective, the moisture resistance and poor corrosion resistance of wood plastic composite have the use of wood plastic composite Very big influence.
Summary of the invention
The main object of the present invention is to provide for a kind of Moisture-proof corrosion-proof wood plastic composite and preparation method thereof, with solution Certainly above-mentioned technical problem.
The purpose of the present invention can reach by using following technical solution:
A kind of Moisture-proof corrosion-proof wood plastic composite, each raw material composition parts by weight are as follows: 30-50 parts of wood powder, polyethylene 20-40 parts of plastics, 15-35 parts of degradable thermoplastic resin, 2-5 parts of activated Calcium carbonate, 10-20 parts of ceramic powder；Polypropylene is short 5-15 parts of fiber, 5-15 parts of polyester fiber, 15-25 parts of glass powdered steel, 5-10 parts of silicon carbide, Nano-sized Alumina Powder 10-15 Part, 3-8 parts of adhesive, 2-7 parts of adjuvant, 2-10 parts of foaming agent, 4-10 parts of coupling agent.
Preferably, described adhesive is synthetic resin adhesive.
Preferably, the adjuvant is the mixture of antioxidant, plasticizer, colorant and paraffin.
Preferably, the foaming agent is polyurethane foams.
Preferably, the coupling agent is silane coupling agent or titanate coupling agent.
A kind of preparation method of Moisture-proof corrosion-proof wood plastic composite, includes the following steps:
Step 1: vinyon being put into kneader molten plastic mixture, is ground into partial size in 1mm or less after cooling Particle or powder it is stand-by；
Step 2: and then raw material is weighed according to each component parts by weight, and weighed wood powder raw material is placed in heat-treating machine Stir process, until the moisture content in wood powder raw material is 0.5%-3%, the temperature for controlling raw material is 100-180 DEG C；
Step 3: by the wood powder handled well in step 2 put into high-speed mixer in, be added coupling agent, 80 DEG C -110 DEG C with It is interior, it stirs evenly, coupling agent is made sufficiently to wrap up wood powder；
Step 4: and then by ceramic powder, polypropene staple, polyester fiber, glass powdered steel, silicon carbide, nano aluminium oxide The vinyon particle or powder handled well in powder and step 1 are placed in high-speed mixer, are then sequentially added degradable Thermoplastic resin, activated Calcium carbonate, adhesive, adjuvant and foaming agent, mix 5- under the conditions of 75-120 DEG C of temperature 10min, then stirring is cooled to 20-50 DEG C, can obtain premix；
Step 5: the resulting premix of step 4 is placed in temperature is 130-190 DEG C, twin-screw revolving speed is 30-50r/min's It carries out melting in screw extruder and compound wood plastic composite melt can be obtained；
Step 6: wood plastic composite melt obtains Moisture-proof corrosion-proof by squeezing out, after injection, hot pressing or compression molding Wood plastic composite.
Preferably, in step 6, wood plastic composite melt extrusion is formed using conical double screw extruder one-step method, Barrel temperature is 140 DEG C~190 DEG C, and 165 DEG C~195 DEG C of die temperature, die end water flowing is cooling.
Preferably, in step 6, compound, single-screw machine is melted using parallel double-screw extruder or conical double-screw squeezes out Double rank unit one-step method extrusion moldings that machine squeezes out, die temperature are 160~195 DEG C, and die end water flowing is cooling.
Preferably, the Moisture-proof corrosion-proof wood moulding prepared by the preparation method of the Moisture-proof corrosion-proof wood plastic composite is multiple Condensation material includes composite layer, the upper erosion resistant coating for being separately positioned on the composite layer two sides and lower erosion resistant coating, top layer is arranged in Waterproof layer and setting are in undermost frosted layer, the composite layer, the upper erosion resistant coating, the waterproof layer, the lower anti-corrosion It is connected by adhesive bonding between layer and the frosted layer.
Preferably, the composite layer includes wood powder, vinyon, activated Calcium carbonate, degradable thermoplastic resin, hair Infusion and coupling agent, the upper erosion resistant coating and the lower erosion resistant coating include ceramic powder, glass powdered steel, adjuvant and bonding Agent, the waterproof layer include wood powder, vinyon, polypropene staple, polyester fiber, glass powdered steel, adjuvant and idol Join agent, the frosted layer includes wood powder, vinyon, silicon carbide, Nano-sized Alumina Powder and adjuvant.
Advantageous effects of the invention:
1, glass powdered steel high-strength light, corrosion resistance and good, designability are good, and ceramic powder is made of inert component, change It is high to learn ingredient stability, intensity, enhances hardness, wash-resistant property and the wearability of wood plastic composite, at the same with glass powdered steel The durability for effectively improving wood plastic composite, weatherability, corrosion resistance and chemical resistance is used in combination.
2, polypropene staple has cracking resistance anti-permeability performance, and polyester fiber moisture content is low, polypropene staple, polyester fiber The moisture content that can effectively reduce wood plastic composite is used in combination with glass powdered steel, improves the impermeability of wood plastic composite Can, moisture protection is effectively improved, while polyester fiber has good wrinkle resistance and conformality, can protect wood plastic composite It is indeformable.
3, silicon carbide and nano oxidized reactive aluminum generate graininess, increase the frictional force on wood plastic composite patch ground.
Detailed description of the invention
Fig. 1 is the Moisture-proof corrosion-proof wood moulding of a preferred embodiment of Moisture-proof corrosion-proof wood plastic composite according to the invention The cross-sectional view of composite material.
In figure: 1- composite layer, the upper erosion resistant coating of 2-, 3- waterproof layer, erosion resistant coating under 4-, 5- frosted layer.
Specific embodiment
To make the more clear and clear technical solution of the present invention of those skilled in the art, below with reference to embodiment to this hair Bright to be described in further detail, embodiments of the present invention are not limited thereto.
Moisture-proof corrosion-proof wood plastic composite provided in this embodiment, each raw material composition parts by weight are as follows: wood powder 30-50 Part, 20-40 parts of vinyon, 15-35 parts of degradable thermoplastic resin, 2-5 parts of activated Calcium carbonate, 10-20 parts of ceramic powder； 5-15 parts of polypropene staple, 5-15 parts of polyester fiber, 15-25 parts of glass powdered steel, 5-10 parts of silicon carbide, nano alumina powder 10-15 parts last, 3-8 parts of adhesive, 2-7 parts of adjuvant, 2-10 parts of foaming agent, 4-10 parts of coupling agent, adhesive is synthetic resin Adhesive, adjuvant are the mixture of antioxidant, plasticizer, colorant and paraffin, and foaming agent is polyurethane foams, coupling agent For silane coupling agent or titanate coupling agent, glass powdered steel high-strength light, corrosion resistance and good, designability are good, ceramic powder It being made of inert component, chemical analysis is stable, intensity is high, enhance hardness, wash-resistant property and the wearability of wood plastic composite, Simultaneously and the durability for effectively improving wood plastic composite, weatherability, corrosion resistance and anti-chemistry is used in combination in glass powdered steel Performance；Polypropene staple has cracking resistance anti-permeability performance, and polyester fiber moisture content is low, polypropene staple, polyester fiber and glass The moisture content that can effectively reduce wood plastic composite is used in combination in glass powdered steel, improves the anti-permeability performance of wood plastic composite, Moisture protection is effectively improved, while polyester fiber has good wrinkle resistance and conformality, can protect wood plastic composite not Deformation；Silicon carbide and nano oxidized reactive aluminum generate graininess, increase the frictional force on wood plastic composite patch ground.
Embodiment one:
Each raw material composition parts by weight are as follows: 35 parts of wood powder, 25 parts of vinyon, and degradable thermoplastic resin 20 Part, 3 parts of activated Calcium carbonate, 10 parts of ceramic powder, 10 parts of polypropene staple, 10 parts of polyester fiber, 15 parts of glass powdered steel, carbonization 5 parts of silicon, 10 parts of Nano-sized Alumina Powder, 4 parts of adhesive, 3 parts of adjuvant, 4 parts of foaming agent, 5 parts of coupling agent, Moisture-proof corrosion-proof wood Plastic composite materials are prepared according to the following steps:
Step 1: vinyon being put into kneader molten plastic mixture, is ground into partial size in 1mm or less after cooling Particle or powder it is stand-by；
Step 2: and then raw material is weighed according to each component parts by weight, and weighed wood powder raw material is placed in heat-treating machine Stir process, until the moisture content in wood powder raw material is 0.5%-3%, the temperature for controlling raw material is 100-180 DEG C；
Step 3: by the wood powder handled well in step 2 put into high-speed mixer in, be added coupling agent, 80 DEG C -110 DEG C with It is interior, it stirs evenly, coupling agent is made sufficiently to wrap up wood powder；
Step 4: and then by ceramic powder, polypropene staple, polyester fiber, glass powdered steel, silicon carbide, nano aluminium oxide The vinyon particle or powder handled well in powder and step 1 are placed in high-speed mixer, are then sequentially added degradable Thermoplastic resin, activated Calcium carbonate, adhesive, adjuvant and foaming agent, mix 5- under the conditions of 75-120 DEG C of temperature 10min, then stirring is cooled to 20-50 DEG C, can obtain premix；
Step 5: the resulting premix of step 4 is placed in temperature is 130-190 DEG C, twin-screw revolving speed is 30-50r/min's It carries out melting in screw extruder and compound wood plastic composite melt can be obtained；
Step 6: wood plastic composite melt obtains Moisture-proof corrosion-proof by squeezing out, after injection, hot pressing or compression molding Wood plastic composite.
The present embodiment is prepared into wood plastic composite using normal components material, has good moisture-proof and anticorrosive property Can, while the wearability and durability of wood plastic composite are improved, there is good conformality.
Embodiment two:
Each raw material composition parts by weight are as follows: 40 parts of wood powder, 30 parts of vinyon, and degradable thermoplastic resin 25 Part, 4 parts of activated Calcium carbonate, 15 parts of ceramic powder, 8 parts of polypropene staple, 8 parts of polyester fiber, 20 parts of glass powdered steel, silicon carbide 7 parts, 12 parts of Nano-sized Alumina Powder, 5 parts of adhesive, 4 parts of adjuvant, 4 parts of foaming agent, 7 parts of coupling agent, Moisture-proof corrosion-proof wood moulding Composite material is prepared according to the following steps:
Step 1: vinyon being put into kneader molten plastic mixture, is ground into partial size in 1mm or less after cooling Particle or powder it is stand-by；
Step 2: and then raw material is weighed according to each component parts by weight, and weighed wood powder raw material is placed in heat-treating machine Stir process, until the moisture content in wood powder raw material is 0.5%-3%, the temperature for controlling raw material is 100-180 DEG C；
Step 3: by the wood powder handled well in step 2 put into high-speed mixer in, be added coupling agent, 80 DEG C -110 DEG C with It is interior, it stirs evenly, coupling agent is made sufficiently to wrap up wood powder；
Step 4: and then by ceramic powder, polypropene staple, polyester fiber, glass powdered steel, silicon carbide, nano aluminium oxide The vinyon particle or powder handled well in powder and step 1 are placed in high-speed mixer, are then sequentially added degradable Thermoplastic resin, activated Calcium carbonate, adhesive, adjuvant and foaming agent, mix 5- under the conditions of 75-120 DEG C of temperature 10min, then stirring is cooled to 20-50 DEG C, can obtain premix；
Step 5: the resulting premix of step 4 is placed in temperature is 130-190 DEG C, twin-screw revolving speed is 30-50r/min's It carries out melting in screw extruder and compound wood plastic composite melt can be obtained；
Step 6: wood plastic composite melt obtains Moisture-proof corrosion-proof by squeezing out, after injection, hot pressing or compression molding Wood plastic composite.
The present embodiment effectively increases the corrosion resistance of wood plastic composite, durability and anti-by changing component ratio Ageing properties significantly improve the mechanical property of wood plastic composite, so that the structural strength of wood plastic composite is higher.
Embodiment three:
Each raw material composition parts by weight are as follows: 45 parts of wood powder, 35 parts of vinyon, and degradable thermoplastic resin 30 Part, 5 parts of activated Calcium carbonate, 20 parts of ceramic powder, 15 parts of polypropene staple, 15 parts of polyester fiber, 25 parts of glass powdered steel, carbonization 10 parts of silicon, 15 parts of Nano-sized Alumina Powder, 7 parts of adhesive, 6 parts of adjuvant, 7 parts of foaming agent, 9 parts of coupling agent, Moisture-proof corrosion-proof Wood plastic composite is prepared according to the following steps:
Step 1: vinyon being put into kneader molten plastic mixture, is ground into partial size in 1mm or less after cooling Particle or powder it is stand-by；
Step 2: and then raw material is weighed according to each component parts by weight, and weighed wood powder raw material is placed in heat-treating machine Stir process, until the moisture content in wood powder raw material is 0.5%-3%, the temperature for controlling raw material is 100-180 DEG C；
Step 3: by the wood powder handled well in step 2 put into high-speed mixer in, be added coupling agent, 80 DEG C -110 DEG C with It is interior, it stirs evenly, coupling agent is made sufficiently to wrap up wood powder；
Step 4: and then by ceramic powder, polypropene staple, polyester fiber, glass powdered steel, silicon carbide, nano aluminium oxide The vinyon particle or powder handled well in powder and step 1 are placed in high-speed mixer, are then sequentially added degradable Thermoplastic resin, activated Calcium carbonate, adhesive, adjuvant and foaming agent, mix 5- under the conditions of 75-120 DEG C of temperature 10min, then stirring is cooled to 20-50 DEG C, can obtain premix；
Step 5: the resulting premix of step 4 is placed in temperature is 130-190 DEG C, twin-screw revolving speed is 30-50r/min's It carries out melting in screw extruder and compound wood plastic composite melt can be obtained；
Step 6: wood plastic composite melt obtains Moisture-proof corrosion-proof by squeezing out, after injection, hot pressing or compression molding Wood plastic composite.
The present embodiment significantly improves the Moisture-proof corrosion-proof performance of wood plastic composite by adjusting each component ratio, increases The structural strength of strong wood plastic composite and internal bonding strength.
In conclusion in the present embodiment, according to the Moisture-proof corrosion-proof wood plastic composite of the present embodiment and its preparation side Method, Moisture-proof corrosion-proof wood plastic composite provided in this embodiment and preparation method thereof are glass powdered steel high-strength light, corrosion-resistant Performance is good, designability is good, and ceramic powder is made of inert component, and chemical analysis is stable, intensity is high, enhances wood plastic composite Hardness, wash-resistant property and wearability, at the same be used in combination with glass powdered steel effectively improve wood plastic composite durability, Weatherability, corrosion resistance and chemical resistance；Polypropene staple has cracking resistance anti-permeability performance, and polyester fiber moisture content is low, gathers The moisture content that can effectively reduce wood plastic composite is used in combination in propylene staple fiber, polyester fiber and glass powdered steel, improves The anti-permeability performance of wood plastic composite effectively improves moisture protection, while polyester fiber has good wrinkle resistance and conformality, Wood plastic composite can be protected indeformable；Silicon carbide and nano oxidized reactive aluminum generate graininess, increase wood plastic composite Paste the frictional force on ground.
The above, further embodiment only of the present invention, but scope of protection of the present invention is not limited thereto, and it is any Within the scope of the present disclosure, according to the technique and scheme of the present invention and its design adds those familiar with the art With equivalent substitution or change, protection scope of the present invention is belonged to.

Claims (10)

1. a kind of Moisture-proof corrosion-proof wood plastic composite, which is characterized in that each raw material composition parts by weight are as follows:
30-50 parts of wood powder；
20-40 parts of vinyon；
15-35 parts of degradable thermoplastic resin；
2-5 parts of activated Calcium carbonate；
10-20 parts of ceramic powder；
5-15 parts of polypropene staple；
5-15 parts of polyester fiber；
15-25 parts of glass powdered steel；
5-10 parts of silicon carbide；
10-15 parts of Nano-sized Alumina Powder；
3-8 parts of adhesive；
2-7 parts of adjuvant；
2-10 parts of foaming agent；
4-10 parts of coupling agent.
2. a kind of Moisture-proof corrosion-proof wood plastic composite as described in claim 1, which is characterized in that adhesive is synthetic resin Adhesive.
3. a kind of Moisture-proof corrosion-proof wood plastic composite as described in claim 1, which is characterized in that adjuvant be antioxidant, The mixture of plasticizer, colorant and paraffin.
4. a kind of Moisture-proof corrosion-proof wood plastic composite as described in claim 1, which is characterized in that foaming agent is polyurethane hair Infusion.
5. a kind of Moisture-proof corrosion-proof wood plastic composite as described in claim 1, which is characterized in that coupling agent is silane coupled Agent or titanate coupling agent.
6. a kind of preparation method of the Moisture-proof corrosion-proof wood plastic composite as described in claim 1-5 any one, feature It is, includes the following steps:
Step 1: vinyon being put into kneader molten plastic mixture, is ground into partial size at 1mm below after cooling Grain or powder are stand-by；
Step 2: and then raw material is weighed according to each component parts by weight, and weighed wood powder raw material is placed in heat-treating machine and is stirred Processing, until the moisture content in wood powder raw material is 0.5%-3%, the temperature for controlling raw material is 100-180 DEG C；
Step 3: the wood powder handled well in step 2 is put into high-speed mixer, coupling agent is added, within 80 DEG C -110 DEG C, It stirs evenly, coupling agent is made sufficiently to wrap up wood powder；
Step 4: and then by ceramic powder, polypropene staple, polyester fiber, glass powdered steel, silicon carbide, Nano-sized Alumina Powder It is placed in high-speed mixer with the vinyon particle or powder handled well in step 1, is then sequentially added degradable heat Plastic resin, activated Calcium carbonate, adhesive, adjuvant and foaming agent mix 5-10min under the conditions of 75-120 DEG C of temperature, Then stirring is cooled to 20-50 DEG C, can obtain premix；
Step 5: the resulting premix of step 4 is placed in the screw rod that temperature is 130-190 DEG C, twin-screw revolving speed is 30-50r/min It carries out melting in extruder and compound wood plastic composite melt can be obtained；
Step 6: wood plastic composite melt obtains Moisture-proof corrosion-proof wood moulding by squeezing out, after injection, hot pressing or compression molding Composite material.
7. a kind of preparation method of Moisture-proof corrosion-proof wood plastic composite as claimed in claim 6, which is characterized in that step 6 In, wood plastic composite melt extrusion is formed using conical double screw extruder one-step method, barrel temperature is 140 DEG C~190 DEG C, 165 DEG C~195 DEG C of die temperature, die end water flowing is cooling.
8. a kind of preparation method of Moisture-proof corrosion-proof wood plastic composite as claimed in claim 6, which is characterized in that step 6 In, double one steps of rank unit that compound, single-screw machine or conical double screw extruder squeeze out are melted using parallel double-screw extruder Method extrusion molding, die temperature are 160~195 DEG C, and die end water flowing is cooling.
9. a kind of preparation method of Moisture-proof corrosion-proof wood plastic composite as claimed in claim 6, which is characterized in that by this The Moisture-proof corrosion-proof wood plastic composite of preparation method preparation includes composite layer (1), is separately positioned on the composite layer (1) two sides Upper erosion resistant coating (2) and lower erosion resistant coating (4), be arranged in top layer waterproof layer (3) and be arranged in undermost frosted layer (5), the composite layer (1), the upper erosion resistant coating (2), the waterproof layer (3), the lower erosion resistant coating (4) and the frosted layer (5) it is connected by adhesive bonding between.
10. a kind of preparation method of Moisture-proof corrosion-proof wood plastic composite as claimed in claim 9, which is characterized in that described Composite layer (1) includes wood powder, vinyon, activated Calcium carbonate, degradable thermoplastic resin, foaming agent and coupling agent, institute Stating erosion resistant coating (2) and the lower erosion resistant coating (4) includes ceramic powder, glass powdered steel, adjuvant and adhesive, the waterproof Layer (3) includes wood powder, vinyon, polypropene staple, polyester fiber, glass powdered steel, adjuvant and coupling agent, described Frosted layer (5) includes wood powder, vinyon, silicon carbide, Nano-sized Alumina Powder and adjuvant.
CN201910531568.9A 2019-06-19 2019-06-19 A kind of Moisture-proof corrosion-proof wood plastic composite and preparation method thereof Withdrawn CN110408223A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115141337A (en) * 2021-03-29 2022-10-04 万华化学集团股份有限公司 Micro-foaming polyurethane damping material and preparation method thereof
CN116176086A (en) * 2023-04-24 2023-05-30 济南市阿波罗木塑复合材料有限公司 Wood-plastic micro-foaming composite material for cold chain container board and preparation method thereof
CN116254007A (en) * 2023-01-09 2023-06-13 山东维克曼新材料有限公司 Novel environment-friendly anti-pollution wood-plastic composite material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115141337A (en) * 2021-03-29 2022-10-04 万华化学集团股份有限公司 Micro-foaming polyurethane damping material and preparation method thereof
CN115141337B (en) * 2021-03-29 2023-08-11 万华化学集团股份有限公司 Micro-foaming polyurethane damping material and preparation method thereof
CN116254007A (en) * 2023-01-09 2023-06-13 山东维克曼新材料有限公司 Novel environment-friendly anti-pollution wood-plastic composite material and preparation method thereof
CN116176086A (en) * 2023-04-24 2023-05-30 济南市阿波罗木塑复合材料有限公司 Wood-plastic micro-foaming composite material for cold chain container board and preparation method thereof
CN116176086B (en) * 2023-04-24 2023-08-08 济南市阿波罗木塑复合材料有限公司 Wood-plastic micro-foaming composite material for cold chain container board and preparation method thereof

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Application publication date: 20191105