CN109517402B - Prestressed fiber wood-plastic floor - Google Patents
Prestressed fiber wood-plastic floor Download PDFInfo
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- CN109517402B CN109517402B CN201811196940.7A CN201811196940A CN109517402B CN 109517402 B CN109517402 B CN 109517402B CN 201811196940 A CN201811196940 A CN 201811196940A CN 109517402 B CN109517402 B CN 109517402B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
- B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B21/042—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
- B32B2419/04—Tiles for floors or walls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2234—Oxides; Hydroxides of metals of lead
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a prestressed fiber wood-plastic floor, which comprises a core layer and an outer layer which are combined together through co-extrusion molding; the core layer comprises the following raw materials in parts by weight: 35-45 parts of wood fiber, 4-6 parts of polyamide fiber, 2-4 parts of polyacrylonitrile fiber, 10-20 parts of polyethylene, 6-10 parts of polyethylene-acrylate, 6-12 parts of polyimide resin, 2-5 parts of calcium carbonate, 1-3 parts of silicon dioxide, 2-4 parts of nano magnesium oxide, 1-1.5 parts of lead oxide, 0.5-1 part of graphite, 0.1-0.3 part of methyl phenyl silicone oil, 0.5-1.5 part of stearic acid and 0.4-1 part of silane coupling agent; the outer layer comprises the following raw materials in parts by weight: 40-50 parts of wood fiber, 3-6 parts of polyaramide fiber, 1-3 parts of ceramic fiber, 10-30 parts of polyethylene, 13-23 parts of polypropylene, 4-8 parts of bentonite, 3-6 parts of montmorillonite, 3-5 parts of mica, 1-2 parts of magnesium oxide, 0.8-1.2 parts of polytetrafluoroethylene, 0.5-1.5 parts of lead oxide, 0.5-1 part of molybdenum disulfide and 0.5-1.5 parts of aluminate coupling agent. The floor board of the invention can form a prestressed structure.
Description
Technical Field
The invention relates to the field of wood-plastic materials, in particular to a prestressed fiber wood-plastic floor.
Background
Wood-plastic, i.e. wood-plastic composite material, is a new type of composite material which has been vigorously raised in recent years at home and abroad, and refers to a new wood material which is produced by mixing plastic with plant fibers such as wood flour, rice hulls, straws and the like, and then carrying out processing technologies such as extrusion, mould pressing, injection molding and the like, so as to produce a plate or a section, which is mainly used in industries such as building materials, furniture, logistics packaging and the like.
In some cases, the material needs to be reinforced, wherein the prestressed structure is widely applied to buildings and various materials, but in the field of wood-plastic materials, no means for implementing the prestressed structure is researched so far.
Disclosure of Invention
The invention aims to solve the technical problem of providing a prestressed fiber wood-plastic floor with a prestressed structure and a preparation method thereof.
In order to solve the technical problems, the invention adopts the following technical scheme: a prestressed fiber wood-plastic floor comprises a core layer and an outer layer which are combined together through co-extrusion molding;
the core layer comprises the following raw materials in parts by weight: 35-45 parts of wood fiber, 4-6 parts of polyamide fiber, 2-4 parts of polyacrylonitrile fiber, 10-20 parts of polyethylene, 6-10 parts of polyethylene-acrylate, 6-12 parts of polyimide resin, 2-5 parts of calcium carbonate, 1-3 parts of silicon dioxide, 2-4 parts of nano magnesium oxide, 1-1.5 parts of lead oxide, 0.5-1 part of graphite, 0.1-0.3 part of methyl phenyl silicone oil, 0.5-1.5 part of stearic acid and 0.4-1 part of silane coupling agent;
the outer layer comprises the following raw materials in parts by weight: 40-50 parts of wood fiber, 3-6 parts of polyaramide fiber, 1-3 parts of ceramic fiber, 10-30 parts of polyethylene, 13-23 parts of polypropylene, 4-8 parts of bentonite, 3-6 parts of montmorillonite, 3-5 parts of mica, 1-2 parts of magnesium oxide, 0.8-1.2 parts of polytetrafluoroethylene, 0.5-1.5 parts of lead oxide, 0.5-1 part of molybdenum disulfide and 0.5-1.5 parts of aluminate coupling agent.
Further, the wood fiber is one or a mixture of more than two of corn straw, wheat straw, rice straw and wood which are mixed according to any proportion.
The preparation method of the prestressed fiber wood-plastic floor comprises the following steps:
(1) preparation of core layer raw material particles
Crushing wood fibers into powder, mixing the powder with the rest raw materials, stirring for 30-40 min at 85-95 ℃ to obtain a core layer primary mixed material, putting the core layer primary mixed material into an extrusion granulator, and extruding and granulating at 140-160 ℃ to obtain core layer raw material particles;
(2) preparation of outer layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring for 25-35 min at 100-115 ℃ to obtain an outer layer primary mixed material, putting the outer layer primary mixed material into an extrusion granulator, and extruding and granulating at 160-200 ℃ to obtain outer layer raw material particles;
(3) co-extrusion molding
Placing the outer layer raw material particles in a single-screw extruder, wherein the temperature of a machine barrel is 165-215 ℃, and placing the core layer raw material particles in a double-screw extruder, wherein the temperature of the machine barrel is 160-190 ℃; and then, synchronously enabling the molten and plasticized products of the single-screw extruder and the double-screw extruder to pass through a die, and extruding and shaping the products by the die to obtain the prestressed fiber wood-plastic floor.
The invention has the beneficial effects that:
the invention provides a prestressed fiber wood-plastic floor, which is characterized in that the shrinkage rate of a core layer is larger than that of an outer layer, the outer layer is wrapped outside the core layer, so that a prestressed structure similar to prestressed reinforcement is formed in the floor, the product has more reliable stability in use, in addition, the core layer and the outer layer have good strength, wear resistance and heat resistance, and the core layer and the outer layer have good binding force.
Detailed Description
The invention is further described below with reference to the following examples:
the various starting materials used in the following examples are all commercially available products known in the art unless otherwise specified.
Example 1
Preparation of prestressed fiber wood-plastic floor
The prestressed fiber wood-plastic floor comprises a core layer and an outer layer which are combined together through co-extrusion molding;
the core layer comprises the following raw materials in parts by weight: wood fiber 40, polyamide fiber 5, polyacrylonitrile fiber 3, polyethylene 15, polyethylene-acrylate 8, polyimide resin 9, calcium carbonate 3.5, silicon dioxide 2, nano-magnesium oxide 3, lead oxide 1.3, graphite 0.8, methyl phenyl silicone oil 0.2, stearic acid 1 and silane coupling agent 0.7;
the outer layer comprises the following raw materials in parts by weight: wood fiber 45, polyaramide fiber 4.5, ceramic fiber 2, polyethylene 20, polypropylene 18, bentonite 6, montmorillonite 4.5, mica 4, magnesium oxide 1.5, polytetrafluoroethylene 1, lead oxide 1, molybdenum disulfide 0.8 and aluminate coupling agent 1.
The preparation method comprises the following steps:
(1) preparation of core layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring at 90 ℃ for 35min to obtain a core layer primary mixed material, putting the core layer primary mixed material into an extrusion granulator, and carrying out extrusion granulation at 150 ℃ to obtain core layer raw material particles;
(2) preparation of outer layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring for 30min at 108 ℃ to obtain an outer layer primary mixed material, putting the outer layer primary mixed material into an extrusion granulator, and extruding and granulating at 180 ℃ to obtain outer layer raw material particles;
(3) co-extrusion molding
Placing the outer layer raw material particles in a single-screw extruder, wherein the temperature of a machine barrel is 190 ℃, the rotating speed of a screw is 8r/min, and placing the core layer raw material particles in a double-screw extruder, wherein the temperature of the machine barrel is 175 ℃, and the rotating speed of the screw is 5 r/min; and then, synchronously enabling the molten and plasticized products of the single-screw extruder and the double-screw extruder to pass through a die, and extruding and shaping the products by the die to obtain the prestressed fiber wood-plastic floor.
Example 2
Preparation of prestressed fiber wood-plastic floor
The prestressed fiber wood-plastic floor comprises a core layer and an outer layer which are combined together through co-extrusion molding;
the core layer comprises the following raw materials in parts by weight: wood fiber 35, polyamide fiber 4, polyacrylonitrile fiber 2, polyethylene 10, polyethylene-acrylate 6, polyimide resin 6, calcium carbonate 2, silicon dioxide 1, nano-magnesium oxide 2, lead oxide 1, graphite 0.5, methyl phenyl silicone oil 0.1, stearic acid 0.5 and silane coupling agent 0.4;
the outer layer comprises the following raw materials in parts by weight: wood fiber 40, polyaramide fiber 3, ceramic fiber 1, polyethylene 10, polypropylene 13, bentonite 4, montmorillonite 3, mica 3, magnesium oxide 1, polytetrafluoroethylene 0.8, lead oxide 0.5, molybdenum disulfide 0.5 and aluminate coupling agent 0.5.
The preparation method comprises the following steps:
(1) preparation of core layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring at 85 ℃ for 40min to obtain a core layer primary mixed material, putting the core layer primary mixed material into an extrusion granulator, and carrying out extrusion granulation at 160 ℃ to obtain core layer raw material particles;
(2) preparation of outer layer raw material particles
Pulverizing wood fiber into powder, mixing with the rest raw materials, stirring at 115 deg.C for 25min to obtain outer layer primary mixed material, feeding the outer layer primary mixed material into an extrusion granulator, and extruding and granulating at 160 deg.C to obtain outer layer raw material particles;
(3) co-extrusion molding
Placing the outer layer raw material particles in a single-screw extruder, wherein the temperature of a machine barrel is 165 ℃, the rotating speed of a screw is 5r/min, and placing the core layer raw material particles in a double-screw extruder, wherein the temperature of the machine barrel is 160 ℃, and the rotating speed of the screw is 4 r/min; and then, synchronously enabling the molten and plasticized products of the single-screw extruder and the double-screw extruder to pass through a die, and extruding and shaping the products by the die to obtain the prestressed fiber wood-plastic floor.
Example 3
Preparation of prestressed fiber wood-plastic floor
The prestressed fiber wood-plastic floor comprises a core layer and an outer layer which are combined together through co-extrusion molding;
the core layer comprises the following raw materials in parts by weight: wood fiber 45, polyamide fiber 6, polyacrylonitrile fiber 4, polyethylene 20, polyethylene-acrylate 10, polyimide resin 12, calcium carbonate 5, silicon dioxide 3, nano-magnesium oxide 4, lead oxide 1.5, graphite 1, methyl phenyl silicone oil 0.3, stearic acid 1.5 and silane coupling agent 1;
the outer layer comprises the following raw materials in parts by weight: 50 parts of wood fiber, 6 parts of polyaramide fiber, 3 parts of ceramic fiber, 30 parts of polyethylene, 23 parts of polypropylene, 8 parts of bentonite, 6 parts of montmorillonite, 5 parts of mica, 2 parts of magnesium oxide, 1.2 parts of polytetrafluoroethylene, 1.5 parts of lead oxide, 1 part of molybdenum disulfide and 1.5 parts of aluminate coupling agent.
The preparation method comprises the following steps:
(1) preparation of core layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring for 30min at 95 ℃ to obtain a core layer primary mixed material, putting the core layer primary mixed material into an extrusion granulator, and carrying out extrusion granulation at 140 ℃ to obtain core layer raw material particles;
(2) preparation of outer layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring for 35min at 100 ℃ to obtain an outer layer primary mixed material, putting the outer layer primary mixed material into an extrusion granulator, and carrying out extrusion granulation at 200 ℃ to obtain outer layer raw material particles;
(3) co-extrusion molding
Placing the outer layer raw material particles in a single-screw extruder, wherein the barrel temperature is 215 ℃, the screw rotating speed is 10r/min, and placing the core layer raw material particles in a double-screw extruder, wherein the barrel temperature is 190 ℃, and the screw rotating speed is 6 r/min; and then, synchronously enabling the molten and plasticized products of the single-screw extruder and the double-screw extruder to pass through a die, and extruding and shaping the products by the die to obtain the prestressed fiber wood-plastic floor.
Example 4
Performance test of prestressed fiber wood-plastic floor
The core layer and the outer layer of the prestressed fiber wood-plastic floor manufactured in the embodiment are subjected to shrinkage rate, strength and other performance tests, and the results are shown in the following table 1, wherein the tensile strength is detected according to GB/T1040-92; the tensile modulus is measured according to GB/T1040-92; the heat distortion temperature is detected according to GB1634-79, and the wear rate is detected according to GB 3960-88.
TABLE 1
In addition, the prestressed fiber wood-plastic flooring prepared in the above examples is tested for surface bonding strength according to GB/T15102-2006, and the results of examples 1 to 3 are 11.9MPa, 12.3MPa and 11.8MPa in sequence, which shows that the prestressed fiber wood-plastic flooring has very good bonding force between the core layer and the outer layer.
It should be understood that the examples and embodiments described herein are for illustrative purposes only and are not intended to limit the scope of the present disclosure, and that various modifications or changes in light thereof will be suggested to persons skilled in the art and are to be included within the spirit and purview of this disclosure.
Claims (2)
1. The prestressed fiber wood-plastic floor is characterized in that: the prestressed fiber wood-plastic floor comprises a core layer and an outer layer which are combined together through co-extrusion molding, wherein the shrinkage rate of the core layer is larger than that of the outer layer, and the tensile strength of the core layer is larger than that of the outer layer;
the core layer comprises the following raw materials in parts by weight: 35-45 parts of wood fiber, 4-6 parts of polyamide fiber, 2-4 parts of polyacrylonitrile fiber, 10-20 parts of polyethylene, 6-10 parts of polyethylene-acrylate, 6-12 parts of polyimide resin, 2-5 parts of calcium carbonate, 1-3 parts of silicon dioxide, 2-4 parts of nano magnesium oxide, 1-1.5 parts of lead oxide, 0.5-1 part of graphite, 0.1-0.3 part of methyl phenyl silicone oil, 0.5-1.5 part of stearic acid and 0.4-1 part of silane coupling agent;
the outer layer comprises the following raw materials in parts by weight: 40-50 parts of wood fiber, 3-6 parts of polyaramide fiber, 1-3 parts of ceramic fiber, 10-30 parts of polyethylene, 13-23 parts of polypropylene, 4-8 parts of bentonite, 3-6 parts of montmorillonite, 3-5 parts of mica, 1-2 parts of magnesium oxide, 0.8-1.2 parts of polytetrafluoroethylene, 0.5-1.5 parts of lead oxide, 0.5-1 part of molybdenum disulfide and 0.5-1.5 parts of aluminate coupling agent;
the preparation method of the prestressed fiber wood-plastic floor comprises the following steps:
(1) preparation of core layer raw material particles
Crushing wood fibers into powder, mixing the powder with the rest raw materials, stirring for 30-40 min at 85-95 ℃ to obtain a core layer primary mixed material, putting the core layer primary mixed material into an extrusion granulator, and extruding and granulating at 140-160 ℃ to obtain core layer raw material particles;
(2) preparation of outer layer raw material particles
Crushing wood fibers into powder, mixing with the rest raw materials, stirring for 25-35 min at 100-115 ℃ to obtain an outer layer primary mixed material, putting the outer layer primary mixed material into an extrusion granulator, and extruding and granulating at 160-200 ℃ to obtain outer layer raw material particles;
(3) co-extrusion molding
Placing the outer layer raw material particles in a single-screw extruder, wherein the temperature of a machine barrel is 165-215 ℃, and placing the core layer raw material particles in a double-screw extruder, wherein the temperature of the machine barrel is 160-190 ℃; and then, synchronously enabling the molten and plasticized products of the single-screw extruder and the double-screw extruder to pass through a die, and extruding and shaping the products by the die to obtain the prestressed fiber wood-plastic floor.
2. The prestressed fiber wood-plastic floor according to claim 1, wherein: the wood fiber is one or a mixture of more than two of corn straw, wheat straw, rice straw and wood which are mixed according to any proportion.
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CN110512830A (en) * | 2019-08-28 | 2019-11-29 | 安徽中科达美新材料科技有限公司 | Wood-plastic floor capable of releasing negative ions |
CN115029014B (en) * | 2022-06-29 | 2024-02-02 | 安徽国风木塑科技有限公司 | Wood-plastic profile with surface coated with flexible material and preparation method thereof |
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CN102850816A (en) * | 2011-06-27 | 2013-01-02 | 上海杰事杰新材料(集团)股份有限公司 | Thermoplastic resin composite material and preparation method and application thereof |
CN103522511A (en) * | 2013-09-03 | 2014-01-22 | 许黎明 | Manufacturing method of wood-plastic composite sectional material with prestressed tendons |
CN204920115U (en) * | 2015-08-03 | 2015-12-30 | 大亚(江苏)地板有限公司 | Real wood composite floor warms up crack control |
CN105385181A (en) * | 2015-12-15 | 2016-03-09 | 天紫环保装备制造(天津)有限公司 | Double-layer co-extruded wood-plastic composite plate and preparation method thereof |
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GB201416456D0 (en) * | 2014-09-17 | 2014-10-29 | Imerys Minerals Ltd | Polymeric compositions |
CN105566755B (en) * | 2015-12-31 | 2017-11-17 | 南京林业大学 | A kind of watch core layer synchronization co-extrusion flame-retardant wood-plastic composite material and its manufacture method |
CN106827707B (en) * | 2016-12-30 | 2019-11-22 | 宁波禾隆新材料股份有限公司 | A kind of imitation wood wood-plastic co-extrusion section bar preparation method |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102850816A (en) * | 2011-06-27 | 2013-01-02 | 上海杰事杰新材料(集团)股份有限公司 | Thermoplastic resin composite material and preparation method and application thereof |
CN103522511A (en) * | 2013-09-03 | 2014-01-22 | 许黎明 | Manufacturing method of wood-plastic composite sectional material with prestressed tendons |
CN204920115U (en) * | 2015-08-03 | 2015-12-30 | 大亚(江苏)地板有限公司 | Real wood composite floor warms up crack control |
CN105385181A (en) * | 2015-12-15 | 2016-03-09 | 天紫环保装备制造(天津)有限公司 | Double-layer co-extruded wood-plastic composite plate and preparation method thereof |
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