CN1386806A - Stone powder-acrylic acid material for surface decoration and its preparing process - Google Patents

Stone powder-acrylic acid material for surface decoration and its preparing process Download PDF

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Publication number
CN1386806A
CN1386806A CN 02111586 CN02111586A CN1386806A CN 1386806 A CN1386806 A CN 1386806A CN 02111586 CN02111586 CN 02111586 CN 02111586 A CN02111586 A CN 02111586A CN 1386806 A CN1386806 A CN 1386806A
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CN
China
Prior art keywords
stone flour
surface decoration
polydimethylsiloxane
stone
acrylic emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 02111586
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Chinese (zh)
Inventor
曹民干
吴火碰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongji University
Original Assignee
Tongji University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University filed Critical Tongji University
Priority to CN 02111586 priority Critical patent/CN1386806A/en
Publication of CN1386806A publication Critical patent/CN1386806A/en
Pending legal-status Critical Current

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)
  • Finishing Walls (AREA)

Abstract

A decorative material for the surface of wall, tile, column, etc is prepared from stone powder as aggregate, acrylic emulsion, sodium hexametaphosphate, sodium benzoate, propanediol, polydimethyl siloxane, methylcellulose, and colouring agent through proportional mixing.

Description

A kind of stone powder-acrylic acid material for surface decoration and preparation method thereof
Technical field
The invention belongs to building material technical field, be specifically related to a kind of aqueous environment protection surface decoration material that utilizes the waste resource making and preparation method thereof.
Background technology
On the one hand, in field of stone processing, sawdust stone flour that produces in a large amount of machining slits and aggregate chips have brought great pollution for the processing of stone area.Stone flour makes atmospheric pollution, river course obstruction, the crops underproduction, has seriously influenced ecotope and people's health.
On the other hand, in the architectural finish field, be that quality and quantity all has the requirement of constantly bringing forth new ideas to the aqueous, environmental protective surface decoration material.
With exterior wall class surface decoration material is example, generally adopts ornamental brick or exterior coating.Though ornamental brick is beautiful, easily come off, construction and repairing are inconvenient, the danger that having drops works the mischief.Also increased the buildings deadweight on the other hand.Advocate the environmental type external-wall coating at present for promoting the quality of exterior wall surface decoration materials.We wish that exterior wall jewelry has higher water resistance, antistrip performance, weathering resistance, and health is not lost surface decoration function preferably again.
This processing of stone area is on a grand scale, and estimating has 1,500,000 tons of stone flours in year, is that fabulous processing utilizes resource again.
Summary of the invention
The objective of the invention is to propose a kind of is raw material with the waste stone powder, all reasonable architectural finish material of water resistance, antistrip performance, weather resistance and preparation method thereof.
The architectural finish material that the present invention proposes is that main raw material and following chemical materials assembly form with the stone flour:
ACRYLIC EMULSION 30~40%
Sodium hexametaphosphate 99 0.3~0.4%
Sodium Benzoate 0.2~0.3%
Propylene glycol 1~2%
Polydimethylsiloxane 0.02~0.03%
Methylcellulose gum 0.2~0.3%
It is the weight percent of radix that above-mentioned per-cent is with the stone flour.
In the above-mentioned finishing material, also can be added with tinting material, its consumption is 0.1~0.2% of a stone flour weight.Tinting material can color as required be selected.
The present invention also proposes above-mentioned architectural finish preparation methods, concrete steps are as follows: take by weighing stone flour and various chemical materials by above-mentioned composition proportioning weight, earlier ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, polydimethylsiloxane, methylcellulose gum are mixed, then it is joined in the stone flour, be uniformly dispersed, add polydimethylsiloxane at last, stirring gets final product.
Among the present invention, stone flour can be spontaneous saw kerf powder and a grinding ground-slag in washing in the processing of stone process, cutting, saw kerf and the ground finish.This stone flour is taken away by water after precipitate, and obtains after taking out drying.The stone flour particle diameter is generally below 60 orders.
The stone powder-acrylic acid material for surface decoration that the present invention proposes has good physicochemical performance.Press GB through appropriate authority and detect, material property is as follows:
Time of drying: 1h~2h
Water tolerance (48 hours): the surface no bubble, slight crack, peel off
The saturated aqua calcis of alkali resistance (48 hours): the no bubble in surface, slight crack and peeling phenomenon
Washing fastness (50 times): do not have and destroy
Adhesion strength (Mpa): 0.51~0.56
Winter hardiness (40 ℃, 24 hours): no change
Thermotolerance (80 ℃, 24 hours): no change
Above-mentioned surface decoration material has improved economic worth greatly owing to use stone flour as aggregate, and product itself also has fabulous physicochemical property.During construction, can spray, also can brush with spray gun.Also have by decorating requirement, surface decoration is carried out in various moulding, once shaped need not other any adhesive.Can satisfy the different shape requirement, and cost is extremely low.
Material of the present invention can be used for making decorates the high-grade metope of having relatively high expectations, room stone watt surface etc., also can be used for the surface decoration of column, upright stone tablet, post, makes it to look to have simple and unsophisticated style.Also can make various decorative patterns and natural pattern on demand.
This product is owing to be water-based environment-friendly, and nontoxic, harmless, odorlessness in making, construction prolonged application do not produce new pollution yet.
Embodiment embodiment 1: the component proportioning is as follows:
Stone flour: 1000g
ACRYLIC EMULSION: 360g
Sodium hexametaphosphate 99: 3g
Sodium Benzoate: 2g
Propylene glycol: 20g
Methylcellulose gum: 2g
Tinting material: 2g
Dimethyl siloxane: 0.2g is in the above-mentioned raw materials ratio, and according to the stone flour surface decoration material that foregoing processing step makes, its performance index are:
Time of drying: 1.5h
Adhesion strength: 0.52Mpa
All other indexs are ditto described.Embodiment 2: the component proportioning is as follows:
Stone flour: 1000g
ACRYLIC EMULSION: 390g
Sodium hexametaphosphate 99: 3.5g
Sodium Benzoate: 2.2g
Propylene glycol: 25g
Methylcellulose gum: 2.2g
Tinting material: 1.5g
Dimethyl siloxane: 0.25g is in the above-mentioned raw materials ratio, and according to the stone flour surface decoration material that foregoing processing step makes, its performance index are:
Time of drying: 1.4h
Adhesion strength: 0.54Mpa
All other indexs are constant ditto described.Embodiment 3: the component proportioning is as follows:
Stone flour: 1000g
ACRYLIC EMULSION: 380g
Sodium hexametaphosphate 99: 3.5g
Sodium Benzoate: 2.5g
Propylene glycol: 30g
Methylcellulose gum: 2g
Tinting material: 3g
Dimethyl siloxane: 0.3g is in the above-mentioned raw materials ratio, and according to the stone flour surface decoration material that foregoing processing step makes, its performance index are:
Time of drying: 1.6h
Adhesion strength: 0.55Mpa
All other indexs are constant ditto described.

Claims (3)

1, a kind of architectural finish material is characterized in that with the stone flour being that main raw material and following chemical materials assembly form:
ACRYLIC EMULSION 30~40%
Sodium hexametaphosphate 99 0.3~0.4%
Sodium Benzoate 0.2~0.3%
Propylene glycol 1~2%
Polydimethylsiloxane 0.02~0.03%
It is the weight percent of radix that methylcellulose gum 0.2~0.3% above-mentioned per-cent is with the stone flour.
2, architectural finish material according to claim 1 is characterized in that also being added with tinting material, and its consumption is 0.1~0.2% of a stone flour weight.
3, architectural finish preparation methods as claimed in claim 1, it is characterized in that concrete steps are as follows: take by weighing stone flour and various chemical materials by above-mentioned composition proportioning weight, earlier ACRYLIC EMULSION, Sodium hexametaphosphate 99, Sodium Benzoate, propylene glycol, polydimethylsiloxane, methylcellulose gum are mixed, then it is joined in the stone flour, be uniformly dispersed, add polydimethylsiloxane at last, stirring gets final product.
CN 02111586 2002-04-30 2002-04-30 Stone powder-acrylic acid material for surface decoration and its preparing process Pending CN1386806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 02111586 CN1386806A (en) 2002-04-30 2002-04-30 Stone powder-acrylic acid material for surface decoration and its preparing process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02111586 CN1386806A (en) 2002-04-30 2002-04-30 Stone powder-acrylic acid material for surface decoration and its preparing process

Publications (1)

Publication Number Publication Date
CN1386806A true CN1386806A (en) 2002-12-25

Family

ID=4741654

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 02111586 Pending CN1386806A (en) 2002-04-30 2002-04-30 Stone powder-acrylic acid material for surface decoration and its preparing process

Country Status (1)

Country Link
CN (1) CN1386806A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294100C (en) * 2003-06-19 2007-01-10 同济大学 Steel slag water slag composite acrylic acid faced decorative material and its preparation process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294100C (en) * 2003-06-19 2007-01-10 同济大学 Steel slag water slag composite acrylic acid faced decorative material and its preparation process

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