CN1384179A - Industrial detergent composition and its production process - Google Patents
Industrial detergent composition and its production process Download PDFInfo
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- CN1384179A CN1384179A CN01123973A CN01123973A CN1384179A CN 1384179 A CN1384179 A CN 1384179A CN 01123973 A CN01123973 A CN 01123973A CN 01123973 A CN01123973 A CN 01123973A CN 1384179 A CN1384179 A CN 1384179A
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- Prior art keywords
- ether
- composition
- alcohol
- oil
- detergent composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 28
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 18
- 239000010696 ester oil Substances 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims description 40
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- -1 alkyl phenol ether Chemical compound 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 7
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 239000004064 cosurfactant Substances 0.000 claims description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 4
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical group CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 claims description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 150000007520 diprotic acids Chemical class 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 claims description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 claims description 2
- PDBMKOUAWURVBE-UHFFFAOYSA-N 2-methyl-2-(2-methylpentan-2-yloxy)pentane Chemical compound CCCC(C)(C)OC(C)(C)CCC PDBMKOUAWURVBE-UHFFFAOYSA-N 0.000 claims description 2
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 claims description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 2
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 2
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004440 Isodecyl alcohol Substances 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 2
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims description 2
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 1
- 239000000600 sorbitol Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 93
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003760 tallow Substances 0.000 abstract description 5
- 239000002480 mineral oil Substances 0.000 abstract description 4
- 235000010446 mineral oil Nutrition 0.000 abstract description 4
- 239000004982 mineral liquid crystal Substances 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract 3
- 239000010730 cutting oil Substances 0.000 abstract 1
- 239000010705 motor oil Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 14
- 239000004530 micro-emulsion Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 239000013543 active substance Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 229940087305 limonene Drugs 0.000 description 7
- 235000001510 limonene Nutrition 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 235000015278 beef Nutrition 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 125000001309 chloro group Chemical class Cl* 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010685 fatty oil Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C11D2111/20—
Abstract
Provided is an industrial detergent composition and its production process, used for cleaning the contamination of motor oil, cutting oil, tallow, mineral oil or liquid crystal contamination of precision parts and electronic parts, which dose not deplete ozone, reduces the danger of fire due to high flash point, has contamination being effectively separated from water in the washing tank, has high detergent recovery, and is non-expensively. The industrial detergent composition contains (a) 50-70vol% of C12-C24 hydrocarbon, (b) 1-20vol% of C12-C22 ester oil, (c) 0.01-30vol% of a nonionic surfactant with a HLB of 4-20, wherein the volume ratio of the hydrocarbon/the ester oil is 99/1-70/30.
Description
Technical field
The present invention relates to contain oil, tensio-active agent, the industrial detergent of water and pure composition and manufacture method thereof, in more detail, relate to the mixing oil that contains more than at least 2 kinds, nonionic surfactant, water, alcohol and other additives, to machine oil attached to the surface of electronic component and precision parts, machining oil, Tallow, beef, multiple pollutent such as mineral oil or liquid crystal pollution, has high washability, the flash-point height, fire hazard is little, can separate effectively with pollutant component in the rinse bath washed water, the regeneration efficiency height of washings, can use detergent composition that does not particularly damage the ozone layer and manufacture method thereof economically.
Background technology
In the last few years, people are carrying out being used to substitute at multiple industrial circle energetically, promptly in accurate washing fields such as automobile, electric, electronics, precision optical machinery, optics industry fields as material with good washing force, and damaging the ozone layer of being widely used 1,1, the research of 1-TCE and CFC-113.
If these alternative washing composition technology are roughly distinguished, then can be categorized as chlorine class, hydro carbons, water class, accurate water class etc.
Wherein, the first kind chlorine class washing composition of washing composition it is found that it occupies the major part in whole markets now as an alternative.Yet chlorine class washing composition has intensive human toxicity and carinogenicity etc., has serious problem aspect security, can envision, not only be subjected to the restriction of environmental standard, and, expand to restriction, so its market scale will reduce gradually to the operating environment standard relevant with human body.
As the hydro carbons washing composition of the alternative washing composition of second class, the market share of occupying now is inferior to above-mentioned chlorine class, yet people scold its ignition quality and dry problem.In addition, in such hydro carbons washing composition, aromatic hydrocarbon solvent type washing composition such as benzene and xylol, big to the toxicity of human body, still having problem aspect the security of human body and the environmental pollution, be subjected to strict restriction at the washing scene.
Recently, when considering the operational security of human safety and igniting security etc., accurate water class or water class washing composition technology are subjected to people and gaze at.Such washing composition, as being aqueous washing composition basically, to compare with the solvent based washing composition, its human safety and operational security are good, add kinds of surface promoting agent and buider (builder), have the advantages that to improve washing force and scourability.Yet, in the occasion of this water class and accurate water class washing composition,, require exploitation appropriate solvent and surfactant system in order to bring into play and the equal performance of existing above-mentioned other types organic solvent, at USP 6,136,775, USP 5,271,773, USP 6, in 071,867, a kind of employing limonene (mixed style of D-limonene, L-limonene and their isomers) or terebinthine high-performance washing composition are provided.The washing force of these washing composition is good, at operation field, existing as an alternative CFCs washing composition and frequently being used, yet, limonene and turps, as crude substance, the amplitude of fluctuation of price is big, compares with other organic solvents, and it is high that price is wanted relatively, so the problem of its existence is that human consumer and supplier's cost burden wants big relatively.In addition, limonene and turps because the intensive stink is arranged self, in the occasion of working continuously, also have the problem that the operator is felt sick.In addition, because have low relatively flash-point, so during operation, because of moisture reduces, the danger of fire increases, and strict task management must be arranged.In addition, because hydrobiont is had toxicity, so during the wastewater treatment after washing, also existing such as hope has special facility and note etc. especially, manages problems such as miscellaneous afterwards.
In order to remedy above-mentioned the deficiencies in the prior art, the former USP that provides 5,350,457, USP5,567,348 and USP 5,725,679 in, propose to use the method for the hydrocarbon of no stink as organic solvent.Existing scheme like this is by using the hydrocarbon of no stink, make job status good, can carrying out separating of oiliness pollutant component and washing water after the washing in rinse bath, the consumption of washing water is reduced, so expense and burden with wastewater treatment reduce advantages such as good economy performance.Yet, the flash-point of employed hydrocarbon is relatively low, therefore the occasion that moisture content reduces during operation, the danger of fire strengthens, when washing high viscosity oil contact scar thing, can form the thin layer liquid crystal structure of tensio-active agent and oil, exist problem in hair line and curved part detersive efficiency difference.
Summary of the invention
The present invention is in order to solve the invention that above-mentioned existing problem has been done, and it is good that first purpose of the present invention provides a kind of washing force, existing 1,1 as the depletion of the ozone layer material, and the surrogate of 1-TCE and CFC-113 is to the nondestructive washing composition of ozone.
Second purpose of the present invention provides a kind of oiliness to high viscosity and pollutes performance good washing efficient, aspect precision parts washing and electronic component washing, and the high-performance washing composition of excellent in efficiency.
The 3rd purpose of the present invention provides a kind of washing composition that can reduce fire hazard.
The 4th purpose of the present invention provides and a kind ofly shows good washing power in wash temperature scope in a big way, and stable washing composition on the thermodynamics.
The 5th purpose of the present invention provides a kind of Biodegradable brilliance, and environmental safety is good, in rinse bath can be isolating in addition oil component that comprises pollutent and water, can significantly reduce the waste water generating capacity, with the affine washing composition of environment.
The 6th purpose of the present invention provides a kind of low to human toxicity, thereby the agent of operating environment good washing.
The 7th purpose of the present invention provides a kind of manufacture method according to first purpose of the invention described above～6th a purpose washing composition.
In order to reach first purpose of the invention described above～6th purpose, an embodiment according to the present invention wishes provides a kind of high-performance industrial detergent, wherein contain (a) carbon former several 12～24 hydrocarbon 50～70% (volume); (b) ester oil 1～20% (volume) of 12～22 of carbonatomss; (c) nonionic surfactant 0.01～30% (volume) of HLB4～20, volume ratio is (a)/(b)=99/1～70/30.
In order to reach first purpose of the invention described above～6th purpose, another embodiment of wishing according to the present invention, provide a kind of in the composition of above-mentioned first embodiment, also contain (d) alcohol 0.01～30% (volume), high-performance industrial detergent (d)/(c)=0.1～1.5.
In order to reach first purpose of the invention described above～6th purpose, according to desirable another embodiment of the present invention, provide a kind of above-mentioned first or the composition of second embodiment in, contain the high-performance industrial detergent of (e) water 0～30% (volume) again.
In order to reach the 7th purpose of the present invention, according to the desirable embodiment of the present invention, a kind of manufacture method of high-performance industrial detergent is provided, its by: as the diprotic acid ester oil of 12～22 of the saturated or unsaturated hydrocarbons of 12～24 of the carbonatomss of oil component and carbonatomss with 99/1～70/30 ratio in addition blended the step of oiliness system is provided; And the step of adding nonionic surfactant.
In order to reach the 7th purpose of the present invention, according to the desirable another embodiment of the present invention, a kind of manufacture method of high-performance industrial detergent is provided, this method also comprises: the alcohol as cosurfactant, with the ratio of alcohol/nonionic surfactant=0.1～1.5 blended step in addition; And/or, be benchmark with all compositions, add the stage of 0～30% (volume) water.
Description of drawings
The state graph of the formed oil/nonionic surfactant of w/o type microemulsion/aqueous systems that Fig. 1 wishes for the present invention;
Fig. 2 is the interpolation along with alcohol, the formation temperature area schematic of the w/o type microemulsion of Fig. 1.
Embodiment
Below the present invention is illustrated in greater detail.
At first, the oil component that constitutes washing composition of the present invention is illustrated, as hydrocarbon ils colourless, no stink, wish selection boiling point height, flash-point low relatively, environmental safety and the good oil of human safety.
When using the alkane of straight chain, be accompanied by the increase of carbonatoms, boiling point rises, fire hazard reduces, yet, have mobile the reduction, form firm liquid crystal with tensio-active agent, make the sorrow of washing time increase, so, among the present invention, more wish to use normal olefine compared with the alkane of straight chain, yet the present invention does not get rid of the use straight-chain paraffin.
When using alkene, because there is unsaturated group,, reach at 18 o'clock at carbonatoms so, flowability is arranged also at normal temperatures even carbonatoms increases, still have low-down viscosity and relative low fire hazard.The alkene that uses in the washing composition of the present invention, its carbonatoms are in 12～24 scope, and preferred carbonatoms is in 12～20 scope, and preferably carbonatoms is in 14～18 scope, and still, the present invention does not limit this.
As other oil components that can be used in washing composition of the present invention, can enumerate the oil of diester shape.Compare with alkene and paraffinic hydrocarbons, it is high that natural degradation is wanted relatively, the flash-point height, and fire hazard is low, and the interface location of whole oil components of blended and water in alkene and paraffinic hydrocarbons forms a little stable emulsion.Wish the ester oil of the diprotic acid that uses as the present invention, can enumerate dioctyl maleate, Octyl adipate, dioctyl succinate etc.When mixing, show high workability and the effect that the wetting ability pollutants removal rate is increased with hydrocarbon.
Above-mentioned mixing oil as employed oil component in the washing composition of the present invention is a kind of no stink, the flash-point height, fire hazard is relatively little, the normal temperature current downflow is big, can remove the oil of pollutant component rapidly, the blending ratio of above-mentioned hydrocarbon and diester is considered from expense and relative safety aspect, wishes in 99: 1～70: 30 scope.With whole compositions is benchmark, and above-mentioned mixing oil is the scope of 50% (volume)～90% (volume), is preferably the scope of 60% (volume)～85% (volume), is preferably the scope of 65% (volume)～80% (volume).
Secondly, the tensio-active agent that constitutes washing composition of the present invention is illustrated, its natural degradation is good, does not wish the occasion that has ionic substance residual owing to have at electronic component etc., therefore wishes to use nonionic surfactant.
Wish the nonionic surfactant of use in the washing composition of the present invention, its average HLB wishes in 4～20 scope.Tensio-active agent is for emulsification that improves oil component and detergency, owing to the detergency of water and the phase security of goods well are used.As the example of above-mentioned nonionic surfactant, can enumerate polyoxyalkylene alkyl, polyoxyalkylene alkyl phenol ether, polyoxyalkylene aryl phenolic ether, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan-fatty acid ester, polyoxyalkylene alkylamine, sorbitan-fatty acid ester, alkyl alcoholamine, aryl hydramine or their any mixture.When considering natural degradation and performance, wish to use polyoxyalkylene alkyl.These nonionic surfactants are benchmark with all compositions, are the scope of 0.01% (volume)～30% (volume), are preferably the scope of 5% (volume)～25% (volume), are preferably the scope of 10% (volume)～20% (volume).
Only ratio of components is as shown in Figure 1 in the blended system of the present invention in addition at above-mentioned three components and water.
Usually,, can make 3 types emulsification, promptly 1 with the mixed system of oil component/tensio-active agent/water) O/W type microemulsion; 2) doubly-linked ideotype microemulsion; 3) w/o type microemulsion.In the occasion of doubly-linked ideotype milk sap, good to the washing force of nonpolar and polar contaminants, yet, because the phase stability problem when preserving in the long period, can produce segregation, therefore have the shortcoming that is difficult to become goods.In the occasion of O/W type milk sap, outstanding to the washing force of polar contaminants, yet, have the shortcoming a little less than the washing force of nonpolar pollutent.Therefore, for multiple nonpolar pollutents such as fatty and oil, machine oil, machining oil, Tallow, beef, mineral oil, liquid crystal pollutions, as detergent system, wish to adopt the w/o type emulsion system, will be according to pollutent being had good washing power, because of thermodynamic stability can be preserved for a long time, particularly, the saving that can obtain water in washing process decides composition.In order to form good, the thermodynamically stable microemulsion of detergency, must predict balancing each other of oil/nonionic surfactant/aqueous systems of depending on formation temperature.Therefore, observation is because of the phase change that volume change caused of water, oil and nonionic surfactant, in view of the above, after confirming to form the microemulsion zone of phase shown in Figure 1, observation is because of the phase change of the composition solution around this zone that temperature variation caused, and the state graph of oil/nonionic surfactant/aqueous systems of the w/o type microemulsion of formation phase as shown in Figure 1 is shown.
By the nonionic surfactant that hydrophilic parts and hydrophobic parts constitute, hydrophobicity is increased.Therefore, big with the affinity of water under cold condition, and under hot conditions, with the affinity increasing of oil.If raising wash temperature, the hydrophobicity of nonionic surfactant is increased, so, in order to improve the washing force of tensio-active agent, the ratio of components of considering the B zone of Fig. 1 is favourable, under cryogenic wash conditions, in contrast, the design that the ratio of components of consideration a-quadrant carries out composition is favourable.In addition, in the HLB of used nonionic surfactant (hydrophilic-lipophilic balance), in the occasion of tensio-active agent, even the ratio of components in B zone also can form the microemulsion of stable phase with high HLB.From The above results as can be known, when making the w/o type washing composition, the addition of water, with whole compositions is benchmark, in the scope of 0% (volume)～30% (volume),, be preferably in the scope of 5% (volume)～15% (volume) preferably in the scope of 2% (volume)～25% (volume).
Secondly, to what use in the washing composition of the present invention, be illustrated as the alcohols of other compositions.Alcohols is that the phase stability of the emulsion that generated for the 3 composition systems that increase oil, nonionic surfactant and water is added, in addition, by in a very wide temperature range, keeping the stable of emulsion, thereby can in multiple wash temperature scope, be well on washing, in addition, the raising for washing force also has important effect.Generally speaking, when adding cosurfactant such as alcohol in the 3 composition systems that oil/nonionic surfactant/water constitutes, phase change becomes the hydrophilic and hydrophobic character that depends on alcohol.If add the few alcohol of carbonatoms such as butanols or amylalcohol, the wetting ability of system is increased, the temperature that forms microemulsion is risen, if add the many alcohol of number of carbon atoms such as enanthol or octanol, then the hydrophobicity of system increases, and the temperature that forms microemulsion is reduced [with reference to J.C.Lim, C.A.Miller, and C.Yang, Colloids and Surfaces, 66,45～53 (1992), R.Stray and M.Jonstromer, J.Phys.Chem.96,4537～4542 (1992)].
Example as the above-mentioned alcohols that uses among the present invention, can enumerate: ethanol, propyl alcohol, butanols, hexanol, Virahol, enanthol, octanol, decyl alcohol, isohexyl alcohol, isooctyl alcohol, isodecyl alcohol, ethylene glycol, glycol ether, triglycol, ethylene glycol monomethyl ether, diethylene glycol methyl ether, the triglycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, the triglycol ether, ethylene glycol ether, the diglycol monotertiary propyl ether, triglycol list propyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, the triethylene monobutyl ether, ethylene glycol dibutyl ether, diethylene glycol dibutyl ether, the triglycol dibutyl ether, ethylene glycol ether, the diglycol monotertiary hexyl ether, the triglycol monohexyl ether, perhaps can use their any mixture, yet, the alcohol that carbonatoms is few, the fire hazard height, situation residual in the waste liquid of washing back is more, has the sorrow of the COD increase that makes in the discharge water.For this reason, use can improve the phase stability of washing composition, the flash-point height of alcohol itself, and the alcohol that fire hazard is few is particularly suitable.As the alcohol that meets this hope, can enumerate: glycol ether, triglycol, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene monobutyl ether, ethylene glycol ether, triglycol monohexyl ether or their any mixture.What more wish is: diethylene glycol monobutyl ether, triethylene monobutyl ether, or their mixture.The decision of these pure blending ratios is by other compositions being fixed, Yi Bian change the ratio of surfactant component and alcohol, being decided Yi Bian observe the zone that forms single-phase emulsion.
Fig. 2 is when diethylene glycol monobutyl ether glycols auxiliarys such as (BDG) is added in oil/nonionic surfactant/aqueous systems as cosurfactant, and the formation temperature zone of single-phase w/o type emulsion becomes wide synoptic diagram.
The conclusion that obtains from The above results is, the ratio of alcohol/nonionic surfactant is in 0.50～1.50 occasion, can confirm to form thermodynamically stable emulsion in the wide temperature province of about 0 ℃～80 ℃ or 90 ℃.These alcohol are benchmark with whole compositions, in the scope of 0.01% (volume)～30% (volume), preferably in the scope of 3% (volume)～25% (volume), are preferably in the scope of 5% (volume)～17% (volume).
In washing composition of the present invention is formed substantially, in the scope of the physical properties of raising that does not influence washing composition stability and not obvious change washing composition, can also contain a spot of other additives.As representational additive, can cooperate the rust-preventive agent and the antioxidant that are used to improve the washing composition rust-proof effect in right amount, be used for the metal washing sequestrant, be used to remove the defoamer of bubble etc.These all are within the scope of the invention.With whole compositions is benchmark, and use level preferably in the scope of 0.1% (weight)～1% (weight), is preferably in the scope of 0.1% (weight)～0.5% (weight) in the scope of 0.01% (weight) 5% (weight).Yet, can change use level according to kind, purpose and the mode of washing of washings.
Below with reference to embodiment and comparative example and test example, illustrate in greater detail the present invention, yet these are interpreted as is illustration of the present invention, and the present invention is not limited to these examples.
Embodiment 1～12 and comparative example 1～4
The preparation of test piece:
Abietic acid 4g is dissolved in the IPA (Virahol) of 10ml, is coated in 7.5 * 2.4 * 0.2cm thinly
3In the stainless steel test piece (SUS plate) of size.Placed about 2～4 hours in room temperature, then, in 70 ℃～90 ℃ baking oven, placed about 12 hours.
The evaluation of washing force:
Wash temperature, 40 ℃ of the wash temperatures that employing is generally used, in the microemulsion washing composition 50ml that makes according to above-mentioned composition, the pollution test piece that dipping is made as stated above, each is using normal-temperature distilled water (specific conductivity: respectively each was polluted the test piece dipping 2 minutes again in the washings about 18 μ s/cm) respectively through after 2 minutes the timed interval.Then, warm braw is after dry about 2 minutes, and it is heavy to measure the pollutent of removing from test piece, estimates washing force.
Washing force evaluation method and metewand:
(in the formula: the pollutent weight of A for adhering to before testing, B is the pollutent weight of washing force test postadhesion to clearance (%)=(A-B)/A * 100.)
The oily water separation evaluation
Carry out the oily water separation evaluation with rinse bath, 10g washing composition and 0.3g solubility promoter, machining oil and Tallow, beef are mixed, after making contaminating fluid, with distilled water with 3%, 5%, 10% ratio dilute make washing water after, placed 25 minutes respectively at 25 ℃, 40 ℃, 60 ℃, after making water layer and layer of contaminants being separated, measure the COD of water layer, estimate oily water separation.
The evaluation method of oily water separation and metewand:
(in the formula: A is the COD before the oily water separation, and B is the COD of the water layer after the oily water separation in oily water separation (%)=(A-B)/A * 100.)
Table 1
| Washing force | ◎: contamination-free is residual in the test piece: very good |
| Zero: roughly contamination-free is residual in the test piece: good | |
| △: have some pollutents residual in the test piece: not so good | |
| *: residual contaminants in the test piece: bad | |
| Detergency (scrubbing property) | ◎: very good |
| Zero: good | |
| △: not so good | |
| *: bad | |
| Oily water separation | ◎: the COD clearance is greater than 95% |
| Zero: COD clearance 94～85% | |
| △: COD clearance 84～65% | |
| *: the COD clearance is less than 65% |
Table 2
| Composition (volume %) | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | |
| Polyoxyethylene (2) bay ether | ??14.0 | ??14.0 | |||||||
| Polyoxyethylene (3) bay ether | ??14.0 | ||||||||
| Polyoxyethylene (5) bay ether | ??14.0 | ??14.0 | |||||||
| Polyoxyethylene (7) bay ether | ??9.5 | ??9.3 | ??9.5 | ??9.3 | |||||
| Aliphatic hydrocarbon | ??64.8 | ??55.6 | ??64.8 | ??55.6 | ??59.8 | ??59.8 | ??59.8 | ??59.8 | |
| The toxilic acid dibutyl ester | ??16.2 | ??23.8 | ??15.0 | ??15.0 | ??15.0 | ||||
| The hexanodioic acid dibutyl ester | ??16.2 | ??23.8 | ??15.0 | ||||||
| The D-limonene | |||||||||
| Water | ??4.8 | ??4.7 | ??4.8 | ??4.7 | ??4.7 | ??4.7 | ??4.7 | ??4.7 | |
| Diethylene glycol monobutyl ether | ??4.8 | ??6.5 | ??6.5 | ||||||
| The triglycol monobutyl ether | ??4.8 | ??6.5 | ??6.5 | ??6.5 | ??6.5 | ||||
| Propyl alcohol | |||||||||
| Butanols | |||||||||
| Add up to | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | |
| Alcohol/nonionic surfactant | ??0.5 | ??0.7 | ??0.5 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | |
| Fatty oil/hydrocarbon | ??0.8 | ??0.7 | ??0.8 | ??0.7 | ??0.8 | ??0.8 | ??0.8 | ??0.8 | |
| Phase stability | Normal temperature | Stable | Stable | Stable | Stable | Stable | Stable | Stable | Stable |
| ????40℃ | Stable | Stable | Stable | Stable | Stable | Stable | Stable | Stable | |
| Estimate | Washing force | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ |
| Washing (scrubbing) property | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | |
| Separating of oil property | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | |
| Operation | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | ??◎ | |
| Ignition quality | Low | Low | Low | Low | Low | Low | Low | Low | |
Table 3
| Composition (volume %) | Embodiment 9 | | Embodiment 11 | Embodiment 12 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| Polyoxyethylene (2) bay ether | ??16.7 | ||||||||
| Polyoxyethylene (3) bay ether | ??17.5 | ??17.5 | |||||||
| Polyoxyethylene (5) bay ether | ??16.3 | ??16.0 | ??16.7 | ?16.7 | |||||
| Polyoxyethylene (7) bay ether | ??15.4 | ||||||||
| Aliphatic hydrocarbon | ??52.6 | ??50.0 | ??48.8 | ??48.0 | ??62.5 | ||||
| The toxilic acid dibutyl ester | ??13.2 | ??12.5 | |||||||
| The hexanodioic acid dibutyl ester | ??12.2 | ??12.0 | |||||||
| The D-limonene | ??65.8 | ?62.5 | ??57.7 | ||||||
| Water | ??4.4 | ??4.2 | ??6.5 | ??8.0 | ??4.2 | ??4.4 | ?4.2 | ??3.8 | |
| Diethylene glycol monobutyl ether | ??12.3 | ??16.7 | ??16.7 | ||||||
| The triglycol monobutyl ether | ??16.3 | ??16.0 | ??16.7 | ||||||
| Propyl alcohol | ?16.7 | ||||||||
| Butanols | ??23.1 | ||||||||
| Add up to | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ?100 | ??100 | |
| Alcohol/nonionic surfactant | ??0.7 | ??1.0 | ??1.0 | ??1.0 | ??1.0 | ??0.7 | ?1.0 | ??1.5 | |
| Fatty oil/hydrocarbon | ??0.8 | ??0.8 | ??0.8 | ??0.8 | ???- | ???- | ??- | ???- | |
| Phase stability | Normal temperature | Stable | Stable | Stable | Stable | Stable | Stable | Stable | Stable |
| ????40℃ | Stable | Stable | Stable | Unstable | Stable | Unstable | Stable | Stable | |
| Estimate | Washing force | ??◎ | ??◎ | ??◎ | ??◎ | ??○ | ??◎ | ??◎ | ??◎ |
| Washing (scrubbing) property | ??◎ | ??◎ | ??○ | ??◎ | ??○ | ??◎ | ??◎ | ??◎ | |
| Separating of oil property | ??◎ | ??◎ | ??○ | ??◎ | ??◎ | ??△ | ??△ | ??× | |
| Operation | ??◎ | ??◎ | ??◎ | ??◎ | ??○ | ??× | ??× | ??× | |
| Ignition quality | Low | Low | Low | Low | Low | Low | In | In | |
The occasion of the comparative example 2～4 of above-mentioned table 3 has been expressed the ratio of the alcohol/nonionic surfactant that is similar to embodiment etc., and still, 2～4 of comparative examples use limonene, and detergency is good, yet because the intensive stink of limonene, operation is relatively poor.In comparative example 1, owing to replaced limonene with hydrocarbon, then there is not the stink of limonene, make the operation raising, yet, having only the occasion that constitutes oil component with the hydrocarbon of alkenes, washing is during as the sylvic acid of oil component, at the washing initial stage, between tensio-active agent and pollutent, form liquid crystal, then, clean, show the phenomenon that overall detersive efficiency reduces through making it behind the certain hour.Composition in the embodiments of the invention 1～12 etc., the occasion of the hydrocarbon of employing alkenes and the mixing oil of diester, in the early stage, they all do not form firm liquid crystal between pollutent and tensio-active agent, when washing, show very fast detersive efficiency.In addition, in rinse bath, separating of washing water and pollutant component is good, and the consumption of washing water reduces, and demonstrates the effect that the overall operation expense reduces.
Therefore, as mentioned above, contain oil, nonionic surfactant, the washing composition of the present invention of the thermodynamically stable w/o type microemulsion type of water and pure composition, to machine oil attached to surfaces such as electronic component and/or precision parts, machining oil, Tallow, beef, multiple pollutent such as mineral oil or liquid crystal pollution, in wash temperature scope widely, washing force and washing (scrubbing) property is good, the natural degradation brilliance, the environmental safety height, to the human body low toxicity, operating environment is also good, particularly can in rinse bath, separate oil component and the water that contains pollutent, therefore has the effect that can greatly reduce waste water, it is available ultrasonic washing, the dipping washing, the washing composition that multiple washing methodss such as vibration washing and jet cleaning wash is the high-performance washing composition that can replace the CFSs of depletion of the ozone layer material.
Claims (10)
1, a kind of industrial detergent composition is characterized in that, contains: (a) hydrocarbon 50～70% (volume) of 21～24 of carbonatomss; (b) ester oil 1～20% (volume) of 12～22 of carbonatomss; (c) nonionic surfactant 0.01～30% (volume) of HLB 4～20, its volume ratio (a)/(b)=99/1～70/30.
2, industrial detergent composition as claimed in claim 1 is characterized in that, also contains (d) alcohol 0.01～30% (volume), (d)/(c)=0.1～1.5.
3, industrial detergent composition as claimed in claim 1 is characterized in that, also contains (e) water 0～30% (volume).
As any described industrial detergent composition in the claim 1～3, it is characterized in that 4, the hydrocarbon of composition (a) is the straight or branched hydrocarbon of 12～20 of carbonatomss, the oil of composition (b) is the ester oil of 14～18 of carbonatomss.
5, industrial detergent composition as claimed in claim 4, it is characterized in that, the hydrocarbon of composition (a) is the straight or branched alkene of 14～18 of atomicities, and the oil of composition (b) is at least a compound that is selected from the group that is made up of dioctyl maleate, Octyl adipate and dioctyl succinate.
6, as any described industrial detergent composition in the claim 1～3, it is characterized in that the nonionic surfactant of composition (c) is at least a compound that is selected from the group that is made up of polyoxyalkylene alkyl, polyoxyalkylene alkyl phenol ether, polyoxyalkylene aryl phenolic ether, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan-fatty acid ester, polyoxyalkylene alkylamine, sorbitol anhydride fatty acid fat, alkyl alcoholamine and aryl hydramine.
7, as any described industrial detergent composition in the claim 1～3, it is characterized in that the alcohol of composition (d) is to be selected from by ethanol, propyl alcohol, butanols, hexanol, Virahol, enanthol, octanol, decyl alcohol, isohexyl alcohol, isooctyl alcohol, isodecyl alcohol, ethylene glycol, glycol ether, triglycol, ethylene glycol monomethyl ether, diethylene glycol methyl ether, the triglycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, the triglycol ether, ethylene glycol ether, the diglycol monotertiary propyl ether, triglycol list propyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, the triethylene monobutyl ether, ethylene glycol dibutyl ether, diethylene glycol dibutyl ether, the triglycol dibutyl ether, ethylene glycol ether, at least a compound in the group that diglycol monotertiary hexyl ether and triglycol monohexyl ether are formed.
8, a kind of manufacture method of industrial detergent composition comprises the following steps:
(a) provide stage of oiliness system, the diprotic acid ester oil as 12～22 of the saturated or unsaturated hydrocarbons of 12～24 of the carbonatomss of oil component and carbonatomss is mixed with 99/1～70/30 ratio; And
(b) stage of the nonionic surfactant of interpolation HLB 4～20.
9, the manufacture method of industrial detergent composition as claimed in claim 8 is characterized in that, described step (b) is that remix is as the alcohol of cosurfactant with alcohol/nonionic surfactant=0.1～1.5 ratio.
10, the manufacture method of industrial detergent composition as claimed in claim 8 or 9 is characterized in that, comprises that also (c) is benchmark with whole compositions, adds the step of the water of 0～30% (volume).
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| KR10-2001-0024510A KR100462314B1 (en) | 2001-05-07 | 2001-05-07 | Deterent compositions for industrial use and preparing method thereof |
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| CN1198914C CN1198914C (en) | 2005-04-27 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1297641C (en) * | 2003-11-28 | 2007-01-31 | 国际商业机器公司 | Detergent composition and detergent for liquid crystal cell |
| CN102994290A (en) * | 2012-12-06 | 2013-03-27 | 南通市华东润滑设备有限公司 | Washing agent for refrigerator |
| CN107130255A (en) * | 2017-06-08 | 2017-09-05 | 苏州龙腾万里化工科技有限公司 | A kind of circulation type cleaning agent for metal parts |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100427759B1 (en) * | 2001-11-13 | 2004-04-28 | 주식회사 아담스테크놀로지 | Microemulsion typed detergent aqueous composition for liquid crystal display panel |
| CN101565831B (en) * | 2009-04-30 | 2012-01-18 | 深圳市科玺化工有限公司 | Cyclic renewable water-based cleaning agent and cyclic renewing technology |
| KR101366211B1 (en) * | 2011-10-13 | 2014-02-25 | 에이치플러스에코 주식회사 | Environmental friendly cleaning agents using vegetable oil |
| KR102183624B1 (en) | 2020-04-28 | 2020-11-27 | 주식회사 세이프코어 | Insulating detergent composition for cleaning current flowing equipment and industrial equipment, cleaning method and equipment using same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5920754B2 (en) * | 1980-09-08 | 1984-05-15 | 日産自動車株式会社 | industrial metal cleaning agent |
| GB8914602D0 (en) * | 1989-06-26 | 1989-08-16 | Unilever Plc | Liquid detergent composition |
| JP2910498B2 (en) * | 1993-04-26 | 1999-06-23 | 新神戸電機株式会社 | Cleaning agent for chemical industry |
| JPH07145560A (en) * | 1993-11-24 | 1995-06-06 | Nippon Saafuakutanto Kogyo Kk | Finishing agent composition for fiber |
| KR960015153B1 (en) * | 1994-06-27 | 1996-11-01 | 애경산업 주식회사 | Detergent composition and its method |
| US5922665A (en) * | 1997-05-28 | 1999-07-13 | Minnesota Mining And Manufacturing Company | Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal |
| KR19990024460A (en) * | 1997-09-02 | 1999-04-06 | 엄기철 | Hydrocarbon-based detergent composition and preparation method thereof |
| KR100448993B1 (en) * | 1997-09-09 | 2004-11-26 | 씨제이 주식회사 | Particulate high-density non-ionic detergent composition having excellent flowability, solubility and cleaning power, and preparation thereof |
-
2001
- 2001-05-07 KR KR10-2001-0024510A patent/KR100462314B1/en active IP Right Grant
- 2001-08-09 CN CNB011239735A patent/CN1198914C/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1297641C (en) * | 2003-11-28 | 2007-01-31 | 国际商业机器公司 | Detergent composition and detergent for liquid crystal cell |
| CN102994290A (en) * | 2012-12-06 | 2013-03-27 | 南通市华东润滑设备有限公司 | Washing agent for refrigerator |
| CN107130255A (en) * | 2017-06-08 | 2017-09-05 | 苏州龙腾万里化工科技有限公司 | A kind of circulation type cleaning agent for metal parts |
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| KR100462314B1 (en) | 2004-12-23 |
| CN1198914C (en) | 2005-04-27 |
| KR20020085156A (en) | 2002-11-16 |
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