CN1371952A - Sugar series compound fertilizer adhesion agent - Google Patents

Sugar series compound fertilizer adhesion agent Download PDF

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Publication number
CN1371952A
CN1371952A CN 02115612 CN02115612A CN1371952A CN 1371952 A CN1371952 A CN 1371952A CN 02115612 CN02115612 CN 02115612 CN 02115612 A CN02115612 A CN 02115612A CN 1371952 A CN1371952 A CN 1371952A
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CN
China
Prior art keywords
fertilizer
kilograms
binding agent
sugar
sucrose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 02115612
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Chinese (zh)
Inventor
刘南必
关善振
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Luzhai Chemical Fertilizer General Factory Guangxi Zhuang Nationality Autonomou
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Luzhai Chemical Fertilizer General Factory Guangxi Zhuang Nationality Autonomou
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luzhai Chemical Fertilizer General Factory Guangxi Zhuang Nationality Autonomou filed Critical Luzhai Chemical Fertilizer General Factory Guangxi Zhuang Nationality Autonomou
Priority to CN 02115612 priority Critical patent/CN1371952A/en
Publication of CN1371952A publication Critical patent/CN1371952A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to a cohesive material suitable for various inorganic composite fertilizer and organic composite fertilizer. It is formed from cane sugar or polysaccharide-like material, carboxymethyl cellulose and calcium oxide. Its cohesive action is good, and adding quantity only is 1-5%, its cost is low, it can stabilize fertilizer effect, can make it not not volatilize, and can be quickly decomposed if it is mixed with water, so that it is favourable for growth of crops.

Description

Sugar series compound fertilizer adhesion agent
Technical field
The present invention relates to a kind of fertilizer binding agent, particularly be fit to various inorganic composite fertilizers, the binding agent of mixed organic manure.
Background technology
Directly spread fertilizer over the fields in ground mostly at the chemical fertilizer of using in the farmland or composite fertilizer, mixed organic manure etc. at present, because the fertile volatile inefficacy of some mineral manure such as ammonia, the fertilizer that the has agglomerating difficult dispersion of luming easily again, unevenness of application also is difficult for dissolving by plant absorbing.So many fertiliser production factory all is made into particulate state with fertilizer, what have also wraps a skim on the surface, fertilizer is spread fertilizer over the fields easily, and not volatile, crop absorption is also more favourable, as disclosed Chinese patent 85101008, be a kind of parcel fertilizer, this is to be core with nitrogenous fertilizer, and phosphate fertilizer is shell, with nitrogen phosphorus mud is binding agent, has potash fertilizer, little fertilizer, plant-growth regulator, agricultural chemicals to constitute interlayer between core and shell; The mixing fertilizer of Chinese patent 87107446 is made up of nitrogen, phosphorus, potassium, agricultural chemicals, conditioning agent and binding agent, and binding agent adopts modified polyvinyl formal liquid; The adhering method of the granulated calcium magnesium phosphate fertilizer of Chinese patent 88109005 is to be binding agent with the alkaline metal salt of humic-acid kind or humic acids, coal alkali lye; Chinese patent 89105907 be with wilkinite, white clay, white clay, ground dolomite, terra calcis, potter's clay, loess, clay, snake put stone flour, talcum powder is an ammonium chloride fertilizer binding agent: 90105673 and No. 90105674 Chinese patent has been narrated with attapulgite raw ore as fertilizer sources binding agent.
But still there is weak point separately in above-mentioned disclosed fertilizer binding agent, and the cost that has is higher, and raw material sources are wideless, and the binding agent that has and the associativity of fertilizer are bad, and chemical reaction easily takes place.
Technology contents
The inventor is through overtesting and research, observing and summing up the technology of existing composite fertilizer, fertilizer, inorganic fertilizer coating and binding agent, reach from the performance of analyzing fertilizer and binding agent the crop absorption situation is started with, found a kind of binding agent that can be widely used in various fertilizer, make its adhesive property good, can stablize fertilizer efficiency and make it not volatile, meet water and can degrade rapidly again, promote plant growth.
It is as follows that fertilizer binding agent of the present invention accounts for the composition and the weight percentage of fertilizer total mass:
Sucrose or polysaccharose substance (pressing solid amount) 1.5-2.5%
Carboxymethyl cellulose 0.1-0.2%
Calcium oxide 0.3-3%
The fertilizer surplus
Above-described sucrose material is selected from sucrose, waste molasses of sugar plant, molasses alcohol waste liquid, polysaccharose substance is selected from potato class or cereal starch, preferred Tapioca Starch, sweet potato powder, potato powder, rice meal, it mainly plays cohesive action, these glucides bounding force when heating to more than 50 ℃ can strengthen greatly, it is dispersed in fertilizer can be bondd agglomeratingly in the fertilizer, be difficult for loose.
Described calcium oxide mainly is a unslaked lime, and well-known, unslaked lime is exactly a kind of adhesive for building since ancient times, after ancients stir itself and mortar, rice meal, can be used as and build a wall, beat floor etc., ancients also impose on the farmland with it as calcareous fertilisers, make the well developed root system of crop, fruit plentiful.So the present invention as binding agent, not only can make the cohesive force of fertilizer improve it, also can suitably increase quantitative calcareous fertilisers for the crops.
Carboxymethyl cellulose, its effect are to fill the fertilizer space, reduce its shatter value, increase cohesiveness, and it still is a kind of tensio-active agent preferably, and the activity of sugar is improved; In addition, also play swelling action, make particle fertilizer when arid, keep granular, and can make the fertilizer prevented from caking than good dissolving after meeting water.
The binding agent production method of compound fertilizer of the present invention: mainly determine according to the situation (solution or solid) of sucrose or polysaccharose substance; when selecting solid sucrose for use; during as brown sugar raw material sugar; directly carboxymethyl cellulose, calcium oxide are added in the fertilizer in proportion and stir; deliver to the tablets press granulation then, the fertiliser granulates oven dry is got final product with hotblast stove.
When adopting sugar refinery molasses or alcohol slops, need add the neutralization of appropriate bases or lime earlier, be concentrated into solid matter water content<50% then, be added in the fertilizer with carboxymethyl cellulose, calcium oxide, mix granulation again, oven dry.
When adopting polysaccharose substance, during as potato class or cereal starch, need starch is added 1-2 clear water doubly by weight, heating on one side, stir on one side, make it become starchiness, be added to and add carboxymethyl cellulose-calcium oxide in the fertilizer and mix, granulation, oven dry obtain the particle fertilizer product.
This binding agent is fit to various inorganic composite fertilizers, and mixed organic manure is made the product of particle fertilizer, as is applicable to neutrality, alkalescence, slightly acidic Bulk Blending Fertilizer, and especially to the noncohesive chemical fertilizer of vitriolate of tartar, Repone K, fused(calcium magnesium)phosphate etc. itself, effect is better.
The present invention compares with existing fertilizer binding agent, and its outstanding substantive distinguishing features and obvious improvement is; 1, consumption is few, and various inorganic composite fertilizers or mixed organic manure, its binding agent incorporation only are that cost is also lower between the 1-5%; 2, viscosity is good, makes the polymerization of various fertilizer good, is difficult for scattering under the drying conditions; Chemical action does not take place with material (fertilizer) in 3, inertia, does not influence the character of fertilizer; 4, after particle fertilizer was manured into soil, binding agent can be degraded fully, and noresidue is harmless to plant, can also be beneficial to plant, as impose on the orchard, and can make fruit increase sugar part, sugariness improves, and executes in soybean or the peanut ground, and volume increase is more than 5%; 5, the binding agent source is wide, can carry out waste reclaimation, as molasses, alcohol slops, is the tankage behind production white sugar or the alcohol, as makes full use of, and can save cost greatly, reduces the blowdown flow rate of grain distillery.
Embodiment
Embodiment 1
Get 2 kilograms of sucrose, 0.1 kilogram of carboxymethyl cellulose, 2 kilograms of unslaked limes, be added to 50 kilograms of ammonium chlorides, 35 kilograms in fused(calcium magnesium)phosphate mixes in the chemical fertilizer that Repone K is 10 kilograms, adopt the static stoving process of disk granulation, extruder grain obtains the inorganic compounding fertilizer product.
Embodiment 2
Get 20 kilograms (solid content 30%) of waste liquid honey; 0.15 kilogram of carboxymethyl cellulose; 2.5 kilograms of unslaked limes; be added in the container of agitator 60 kilograms in interior adding bicarbonate of ammonia, 20 kilograms of potassium primary phosphates; 10 kilograms of humic acid fertilizers; mix, with the granulating disc granulation and quote the hot-air seasoning of hotblast stove, obtain compound fertilizer product.
Embodiment 3
Get concentration and be 100 kilograms of the alcohol slopss of 10BX, it is concentrated into 70BX, then with 0.2 kilogram of carboxymethyl cellulose, 3 kilograms of unslaked limes; 50 kilograms in ammonium sulfate, 30 kilograms in calcium phosphate, 15 kilograms in Repone K; be put into stirrer together and stir,, obtain inorganic composite fertilizer with disk pelletizing mechanism grain.
Embodiment 4
Get 3 kilograms of tapioca (flour)s, be added in 80 ℃ of hot water and stir into starchiness, again with 0.12 kilogram of carboxymethyl cellulose, 2 kilograms of unslaked limes, be put into 45 kilograms in ammonium nitrate, 30 kilograms in fused(calcium magnesium)phosphate, granulate and obtain inorganic composite fertilizer in the back that stirs in the stirrer that vitriolate of tartar is 15 kilograms.
Embodiment 5
Get 1 kilogram of brown sugar, 1 kilogram of rice meal is stirred to starchiness with hot water, add 0.15 kilogram of carboxymethyl cellulose, 3 kilograms of unslaked limes are put in the agitator, add 20 kilograms in urea again, 15 kilograms of vitriolate of tartar, 20 kilograms of ammonium hydrogen phosphates, 30 kilograms of fertilizers mix, granulation obtains mixed organic manure.
Embodiment 6
Get 10 kilograms of waste molasses, 0.1 kilogram of carboxymethyl cellulose, 1 kilogram in calcium oxide has been added to 60 kilograms of drying in the sun chicken manures, and 20 kilograms of plant ash in the stirrer that ammonium nitrate is 20 kilograms, are put into granulation in the disk pelletizing machine after stirring, and oven dry obtains compound fertilizer.
Fertilizer adhesive of the present invention and some materials are made the comparable situation table 1 of tackiness agent
Title Sulfuric acid Clay Gelatine Water glass The present invention
Bake out temperature (℃) ??25-50 ???250-300 ???250-300 ??250-300 ????250-300
Drying time (minute) ????- ????20-22 ????20-25 ????20-30 ????15-20
Drying mode Normal temperature is static to be placed The revolution hot air seasoning Static hot air seasoning The revolution oven dry Static hot air seasoning
Granule strength (N) ????≥11 ????≥14 ????≤5 ????≥14 ????≥15
Rate of cleavage in the particle water 〉=92 hours 〉=92 hours ≤ 1 minute 〉=108 hours ≤ 3 minutes
Particle telogenesis situation Coarse Coarse Rough porous Smooth Dead smooth
Particle was placed situation 48 days Keep Keep Rotten Keep Keep

Claims (2)

1, a kind of sugar is the fertilizer binding agent, it is characterized in that: it is as follows that it accounts for the composition and the weight percentage of fertilizer total mass:
Sucrose or polysaccharose substance (pressing solid amount) 1.5-2.5%
Carboxymethyl cellulose 0.1-0.2%
Calcium oxide 0.3-3%
The fertilizer surplus
Described sucrose material is selected from sucrose, waste molasses of sugar plant, molasses alcohol waste liquid, and polysaccharose substance is selected from potato class or cereal starch.
2, a kind of sugar is the preparation method of fertilizer binding agent, it is characterized in that: sucrose or polysaccharose substance, carboxymethyl cellulose, calcium oxide are added in the fertilizer in proportion and stir, deliver to the tablets press granulation then, with hotblast stove fertiliser granulates is dried.
CN 02115612 2002-03-18 2002-03-18 Sugar series compound fertilizer adhesion agent Pending CN1371952A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 02115612 CN1371952A (en) 2002-03-18 2002-03-18 Sugar series compound fertilizer adhesion agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02115612 CN1371952A (en) 2002-03-18 2002-03-18 Sugar series compound fertilizer adhesion agent

Publications (1)

Publication Number Publication Date
CN1371952A true CN1371952A (en) 2002-10-02

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101774834B (en) * 2009-02-27 2011-12-28 张志元 Plant nutritional agent
CN102311284A (en) * 2010-07-01 2012-01-11 山东省花生研究所 Foliar fertilizer for peanut and method for applying foliar fertilizer
CN101801891B (en) * 2007-06-20 2014-01-08 欧亚生物科技有限公司 Microbial formulation and method of using the same promote plant growth
CN103796974A (en) * 2011-04-06 2014-05-14 Oms投资公司 Multi-purpose lignin-carbohydrate binding system
CN104030767A (en) * 2014-07-01 2014-09-10 广西力源宝科技有限公司 Method for producing fertilizer through dilute molasses alcohol wastewater
CN104230397A (en) * 2014-09-13 2014-12-24 南宁惠旺尔农化有限公司 Organic multiple calcium complex fertilizer additive as well as preparation method and application thereof
CN105980336A (en) * 2013-10-10 2016-09-28 纳幕尔杜邦公司 Soil conditioner compositions containing lignocellulosic biomass fermentation process syrup
CN107318579A (en) * 2017-06-20 2017-11-07 松桃苗族自治县继梅养殖专业合作社 A kind of method for culturing seedlings of grape
CN108384506A (en) * 2018-03-02 2018-08-10 南宁珀源能源材料有限公司 Add the preparation method of the One-component adhesive of the stabilization of silica flour
WO2022222355A1 (en) * 2021-04-23 2022-10-27 湖北富邦科技股份有限公司 Calcium magnesium phosphate fertilizer granulating agent and application thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101801891B (en) * 2007-06-20 2014-01-08 欧亚生物科技有限公司 Microbial formulation and method of using the same promote plant growth
CN101774834B (en) * 2009-02-27 2011-12-28 张志元 Plant nutritional agent
CN102311284A (en) * 2010-07-01 2012-01-11 山东省花生研究所 Foliar fertilizer for peanut and method for applying foliar fertilizer
CN103796974B (en) * 2011-04-06 2016-09-21 Oms投资公司 Multipurpose wooden quality-carbohydrate bonding system
CN103796974A (en) * 2011-04-06 2014-05-14 Oms投资公司 Multi-purpose lignin-carbohydrate binding system
CN105980336A (en) * 2013-10-10 2016-09-28 纳幕尔杜邦公司 Soil conditioner compositions containing lignocellulosic biomass fermentation process syrup
CN104030767B (en) * 2014-07-01 2016-01-20 广西力源宝科技有限公司 Diluted molasses alcohol slops is utilized to produce the method for fertilizer
CN104030767A (en) * 2014-07-01 2014-09-10 广西力源宝科技有限公司 Method for producing fertilizer through dilute molasses alcohol wastewater
CN104230397B (en) * 2014-09-13 2016-08-24 南宁惠旺尔农化有限公司 Organic multiple calcium complex fertilizer additive and its preparation method and application
CN104230397A (en) * 2014-09-13 2014-12-24 南宁惠旺尔农化有限公司 Organic multiple calcium complex fertilizer additive as well as preparation method and application thereof
CN107318579A (en) * 2017-06-20 2017-11-07 松桃苗族自治县继梅养殖专业合作社 A kind of method for culturing seedlings of grape
CN108384506A (en) * 2018-03-02 2018-08-10 南宁珀源能源材料有限公司 Add the preparation method of the One-component adhesive of the stabilization of silica flour
WO2022222355A1 (en) * 2021-04-23 2022-10-27 湖北富邦科技股份有限公司 Calcium magnesium phosphate fertilizer granulating agent and application thereof

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