CN1366099A - Process for preparing functional superfine composite polyamide-polypropylene fibre - Google Patents
Process for preparing functional superfine composite polyamide-polypropylene fibre Download PDFInfo
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- CN1366099A CN1366099A CN 01106855 CN01106855A CN1366099A CN 1366099 A CN1366099 A CN 1366099A CN 01106855 CN01106855 CN 01106855 CN 01106855 A CN01106855 A CN 01106855A CN 1366099 A CN1366099 A CN 1366099A
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Abstract
A composite spinning method for preparing superfine (dpf less than 1 dtex) functional composite fiber features that the mixture of polyamide chips and organic bacteriostat M particles is used as core and the mixture of polypropylene chips and inorganic bacteriostat HN particles or far infrared particles is used as coating, and includes such steps as spinning with dual-screw and shaped hole spinneret assembly, winding, stretching, thermal shape fixation, finishing and stripping to obtain the functional composite superfine fibre. Its advantages are simple technology, good hand, and good antibacterial, deodouring. Warming and health-care functions.
Description
The present invention relates to a kind of method that adopts composite spinning technology manufacturing function type superfine composite polyamide-polypropylene fibre and fabric.
In the prior art, antibiotic or the far IR fibre of relevant one-component, the report that splits release composite ultrafine fiber are a lot of, but thin dawn, super fine denier functional fibre majority are to adopt conventional one-component high speed spinning method, but adopt conventional high speed spinning method to produce thin dawn, super fine denier functional fibre because the adding of functional mass makes that the spining technology difficulty is big, consume high, the technology controlling and process complexity is difficult to form large-scale industrial production.Abroad also have to utilize and split release composite spinning method and produce antibacterial polyester-polyamide compound fibre, its deodorizing antibiotic agent is with polyamide blended, splits the method for release function composite fibre and does not appear in the newspapers as yet but cortex and sandwich layer add the production of function composition simultaneously.
Purpose of the present invention, be to solve and use conventional high speed spinning method to spin thin dawn, the high problem of super fine denier functional form polypropylene filament yarn technical difficulty, and a kind of functional superfine composite polyamide-polypropylene fibre spinning technology is provided, the technology of employing is simple, reliable, but large-scale industrial production.
In order to achieve the above object; the present invention has adopted following technical scheme: adopt polyamide section and organic bacteriostatic agent-M master batch blend composition make core; the blend composition of polypropylene chip and inorganic antiseptic HN master batch or far-infrared matrix is made skin; the weight ratio of core-skin is 50～80: 50～20; with twin-screw and the spinning of profiled holes composite spinneret pack, after coiling, drawing-off, HEAT SETTING arrangement, peel off the functional form composite ultrafine fiber.
The present invention's technical scheme preferably can be: the polyamide core fibre is that the addition of organic bacteriostatic agent is 0.02～0.1wt%, again through melt spinning by polyamide section and the master batch blend that contains organic bacteriostatic agent of alkylamide and imidazolines mixture; The polypropylene sheath fiber is by polypropylene chip and contains Ag ion nanometer grade inorganic antibacterial agent blend that the addition of inorganic antiseptic is 0.2～0.5wt%, again through melt spinning.
The present invention's technical scheme preferably also can be: adopt * type or rice font hole composite spinneret pack to make the composite fibre of respective cross-section in the spinning, peel off then the function composite ultrafine fiber.The interfacial structure of described composite spinneret pack distribution plate is stable, and the profiled composite fibre that makes is easy to peel off, and the function composite ultrafine fiber performance that obtains after peeling off is good and applicability is strong.
The present invention's technical scheme preferably can also be: the polyamide core fibre is that the addition of organic bacteriostatic agent is 0.02～0.1wt%, again through melt spinning by polyamide section and the master batch blend that contains organic bacteriostatic agent of alkylamide and imidazolines mixture; The polypropylene sheath fiber is that the addition of far infrared agent is 3.0～6.0wt%, again through melt spinning by polypropylene chip and the master batch blend that contains the nanoscale far infrared agent of Al, Si, Zr, Ti ion.
The total fiber number of the functional superfine composite polyamide-polypropylene fibre that makes with said method is: 55.6dtex～166.7dtex, the fiber number of peeling off the back polyamide fiber is that the fiber number of every rhizoid is: 0.46～3.47dtex, the fiber number of polypropylene fibre is that the fiber number of every rhizoid is: 0.19～0.93dtex.
The functional superfine composite polyamide-polypropylene fibre that makes with said method, when weaving dyeing and finishing, adopt the finishing technique of weaving of polypropylene fibre, the dyeing of polyamide makes polypropylene peel off into the function superfine fibre from polyamide, make fabric have submissive comfortable feel, stronger single face is led sweat and anti-bacterial anti-foul function or insulation, health care, the bacteriostatic deodorizing function, antibacterial composite fibers is to Escherichia coli, the fungistatic effect of staphylococcus aureus is good, record the average bacteriostasis rate that contact 24h after all greater than 95% with reference to GB15979-1995 (appendix B-product antibacterial with bactericidal property and stability test method) and disinfection technology standard (third edition) with the vibration flask method by Hunan Hygienic ﹠ Epidemic Prevention Station, adopting IRE-1 type infrared radiometer to record the far infrared composite fibre under 50 ℃ by Shanghai Inst. of Technical Physics, Chinese Academy of Sciences is 84% at the far infrared transmissivity of 8～25 μ m.
Compared with prior art, the present invention has following tangible advantage:
1, the technology of this manufacturing technology employing simply, reliably, easily realizes the big production of industrialization.Adopt composite spinning technology production function composite ultrafine fiber, the problem that solved and used the conventional high speed spinning method spinning thin dawn of functional form, the superfine Denier fibre technical difficulty is big, consumption is high, is difficult to form industrialized production;
2, the functional fibre of this manufacturing technology production adopts two kinds of different functional agglomerates to be scattered in respectively in the polymer of skin, core, it is respond well, can overcoming organic bacteriostatic agent-M, to add in the polypropylene washability to poor, inorganic antiseptic, far infrared agent influence shortcomings such as fibre property, spinnability difference, have also solved the shortcoming of far IR fibre antibacterial effect difference simultaneously;
3, color depth can reach moderate depth on the function composite ultrafine fiber of this method spinning, and fiber and fabric are both soft comfortable, has good single face again and leads sweat and anti-bacterial anti-foul function or insulation, health care, bacteriostatic deodorizing function.
Implementation example:
Embodiment 1: add dry good inorganic antiseptic HN master batch and the polyacrylic blend composition of YS-820 in No. 1 screw rod of KV461 composite spinning machine, the effective content of antiseptic HN is 0.5wt%, and particle diameter 90% is less than 0.3 μ m; Add dry good nylon 6 slice and the blend composition of organic bacteriostatic agent M in No. 2 screw rods, the effective content of bacteriostatic agent M is 0.05wt%.Melt extrude respectively, polyacrylic spinning temperature is controlled at 258 ℃, the spinning temperature of polyamide is controlled at 268 ℃, through the measuring pump accurate measurement, control compound than PP: PA6 is 70: 30, extrude through * type composite spinneret pack jointly, cool off the coiling and molding that oils, winding speed is 860m/min, and stretching 3.0 times and obtaining fiber number is 83.3dtex, powerful 3.05cN/dtex, the composite fibre of ductility 25.0% is with this nonwoven fiber complex, dyeing, the HEAT SETTING arrangement is peeled off composite fibre, can obtain the antibiotic superfine fibre fabric, this fabric can be painted with ACID DYES or the higher DISPERSE DYES of polarity, and last color depth is medium.Wherein the dpf value of polypropylene fibre is 0.40dtex.
Embodiment 2: as embodiment 1, change measuring pump metering ratio, (PP: PA6), other process conditions are constant, obtain antibiotic superfine fibre and fabric that dpf is 0.46dtex to control compound ratio and be 80: 20.
Embodiment 3: as embodiment 1, change measuring pump metering ratio, (PP: PA6), other condition is constant, obtains antibiotic superfine fibre and fabric that dpf is 0.29dtex to control compound ratio and be 50: 50.
Embodiment 4: as embodiment 1, the effective content that changes antiseptic HN is 0.3wt%, and the effective content of bacteriostatic agent M is 0.8wt%, and polyacrylic spinning temperature is controlled at 262 ℃, obtains antibiotic superfine fibre and fabric that dpf is 0.40dtex.
Embodiment 5: as embodiment 1, the effective content that changes antiseptic HN is 0.2wt%, and the effective content of bacteriostatic agent M is 0.1wt%, and polyacrylic spinning temperature is controlled at 264 ℃, other process conditions are constant, obtain antibiotic superfine fibre and fabric that dpf is 0.40dtex.
Embodiment 6: as embodiment 1, change * type composite spinneret pack and be rice font composite spinneret pack, other condition is constant, obtains antibiotic superfine fibre and fabric that dpf is 0.30dtex.
Embodiment 7: as embodiment 1, in No. 1 screw rod of KV461 composite spinning machine, add dry good nanoscale far-infrared matrix and the polyacrylic blend composition of YS-820, the effective content of far infrared agent is 5wt%, and particle diameter 90% is less than 0.3 μ m, and polyacrylic spinning temperature is controlled at 254 ℃; Other process conditions are constant, obtain far infrared antibacterial superfine fibre and the fabric of dpf value for 0.40dtex.
Claims (3)
1, a kind of manufacture method of functional superfine composite polyamide-polypropylene fibre; it is characterized in that adopting the polyamide section and the blend composition of organic bacteriostatic agent-M master batch to make core; the blend composition of polypropylene chip and inorganic antiseptic HN master batch or far-infrared matrix is made skin; the weight ratio of core-skin is 80: 50 ∽ 20 of 50 ∽; with twin-screw and the spinning of profiled holes composite spinneret pack, again through coiling, drawing-off, HEAT SETTING arrangement.
2, method according to claim 1 is characterized in that the profiled holes composite spinneret pack is * shape or rice font structure.
3, method according to claim 1 and 2 is characterized in that polyamide fiber contains the alkylamide of 0.02 ∽ 0.1wt% and organic bacteriostatic agent of imidazolines mixture; Polypropylene fibre contains the nanometer grade inorganic antibacterial agent that contains the Ag ion of 0.2～0.5wt% or contains the nanoscale far infrared agent that contains Al, Si, Zr, Ti ion of 3.0～6.0wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011068558A CN1164809C (en) | 2001-01-19 | 2001-01-19 | Process for preparing functional superfine composite polyamide-polypropylene fibre |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011068558A CN1164809C (en) | 2001-01-19 | 2001-01-19 | Process for preparing functional superfine composite polyamide-polypropylene fibre |
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| Publication Number | Publication Date |
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| CN1366099A true CN1366099A (en) | 2002-08-28 |
| CN1164809C CN1164809C (en) | 2004-09-01 |
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| CNB011068558A Expired - Fee Related CN1164809C (en) | 2001-01-19 | 2001-01-19 | Process for preparing functional superfine composite polyamide-polypropylene fibre |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320894A (en) * | 2013-05-24 | 2013-09-25 | 宁波三邦日用品有限公司 | Colored antibiotic polypropylene fiber and nylon composite superfine fiber and production method thereof |
| CN103320893A (en) * | 2013-05-24 | 2013-09-25 | 宁波三邦日用品有限公司 | Colored polypropylene fiber and nylon composite superfine fiber and production method thereof |
| CN104073899A (en) * | 2014-06-25 | 2014-10-01 | 杭州师范大学 | Application of ionic liquid in polylactic acid composite fibers |
| CN104073900A (en) * | 2014-06-25 | 2014-10-01 | 杭州师范大学 | Application of ionic liquid to polyurethane complex fiber |
| CN104805518A (en) * | 2015-05-12 | 2015-07-29 | 南通市京山锦纶有限公司 | Antimicrobial acrylic/polyamide composite fiber |
| CN109183190A (en) * | 2018-08-24 | 2019-01-11 | 东华大学 | A kind of functional new textile material and its preparation method and application |
-
2001
- 2001-01-19 CN CNB011068558A patent/CN1164809C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320894A (en) * | 2013-05-24 | 2013-09-25 | 宁波三邦日用品有限公司 | Colored antibiotic polypropylene fiber and nylon composite superfine fiber and production method thereof |
| CN103320893A (en) * | 2013-05-24 | 2013-09-25 | 宁波三邦日用品有限公司 | Colored polypropylene fiber and nylon composite superfine fiber and production method thereof |
| CN103320894B (en) * | 2013-05-24 | 2015-07-15 | 宁波三邦日用品有限公司 | Colored antibiotic polypropylene fiber and nylon composite superfine fiber and production method thereof |
| CN103320893B (en) * | 2013-05-24 | 2015-11-25 | 宁波三邦日用品有限公司 | The production method of coloured third brocade composite superfine fibre |
| CN104073899A (en) * | 2014-06-25 | 2014-10-01 | 杭州师范大学 | Application of ionic liquid in polylactic acid composite fibers |
| CN104073900A (en) * | 2014-06-25 | 2014-10-01 | 杭州师范大学 | Application of ionic liquid to polyurethane complex fiber |
| CN104805518A (en) * | 2015-05-12 | 2015-07-29 | 南通市京山锦纶有限公司 | Antimicrobial acrylic/polyamide composite fiber |
| CN109183190A (en) * | 2018-08-24 | 2019-01-11 | 东华大学 | A kind of functional new textile material and its preparation method and application |
| CN109183190B (en) * | 2018-08-24 | 2021-04-02 | 东华大学 | Functional textile material and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN1164809C (en) | 2004-09-01 |
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Owner name: BALING PETROCHEMICAL CO., LTD., SINOPEC Free format text: FORMER OWNER: YUEYANG PETROCHEMICAL PLANT, BALING PETROCHEMICAL CORP. Effective date: 20030103 |
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Effective date of registration: 20030103 Applicant after: Baling Petrochemical Co., Ltd., SINOPEC Address before: 414014 Yunxi District, Hunan, Yueyang Applicant before: Yueyang Chemical General Plant, Baling Petrochemical |
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