CN100537867C - The blended yarn of a kind of uvioresistant, antibiotic double wet-guide quick-drying and method for making and application - Google Patents
The blended yarn of a kind of uvioresistant, antibiotic double wet-guide quick-drying and method for making and application Download PDFInfo
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- 229960003500 triclosan Drugs 0.000 claims description 3
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- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
技术领域 technical field
本发明涉及一种具有抗紫外线、抗菌兼导湿快干的多功能纱线及其制备方法和应用。The invention relates to a multifunctional yarn with anti-ultraviolet, antibacterial, moisture-conducting and quick-drying properties, a preparation method and application thereof.
背景技术 Background technique
由于夏季是太阳辐射强、温度高、出汗多的季节,而服装作为人体与外界的屏障,应该能有效保护人体。随着消费观念和健康观念的转变,人们对夏季服装有了更多更新的要求,为此,具有保健、舒适功能的服装开始倍受青睐。Since summer is a season of strong solar radiation, high temperature, and a lot of sweating, clothing, as a barrier between the human body and the outside world, should be able to effectively protect the human body. With the change of consumption concepts and health concepts, people have more and more updated requirements for summer clothing. For this reason, clothing with health care and comfort functions has begun to be favored.
服装由纱线构成,而纱线是由纤维组成。在各种服用纤维中,化学纤维以其优良的适纺性、资源可开发性以及消费者的可接受性,获得了广泛的应用。然而由于大部分化纤分子结构致密以及缺乏吸湿性基团,在穿着舒适性、美观性等方面都比天然纤维差,由此限制了其在更大范围内的应用。因此,对于化纤,主要是涤纶的舒适性研究就成为人们关注的焦点。Clothing is made of yarn, and yarn is made of fibers. Among all kinds of clothing fibers, chemical fibers have been widely used because of their excellent spinnability, resource availability and consumer acceptance. However, due to the dense molecular structure and lack of hygroscopic groups of most chemical fibers, they are inferior to natural fibers in terms of wearing comfort and aesthetics, which limits their wider application. Therefore, for chemical fibers, mainly polyester comfort research has become the focus of attention.
目前提高化纤纱和织物舒适性和功能性的方法包括:Current methods to improve the comfort and functionality of synthetic yarns and fabrics include:
1)用改性涤纶短纤(长丝)或者异形截面涤纶短纤(长丝)纺纱织造可得到导湿快干织物,提高织物的湿舒适性;1) Moisture-conducting and quick-drying fabrics can be obtained by spinning and weaving modified polyester staple fibers (filaments) or polyester staple fibers (filaments) with special-shaped cross-sections, which can improve the wet comfort of the fabrics;
2)用异形截面短纤和抗菌短纤或异形截面长丝和抗菌长丝纺纱织造得到抗菌导湿快干织物,提高织物的湿舒适性和卫生性;2) Antibacterial, moisture-conducting and quick-drying fabrics are obtained by spinning and weaving special-shaped cross-section staple fibers and antibacterial short fibers or special-shaped cross-section filaments and antibacterial filaments, so as to improve the wet comfort and hygiene of the fabrics;
3)用添加紫外线屏蔽剂的异形截面长丝纺纱织造得到抗紫外线导湿快干织物,提高织物的湿舒适性和防护性;3) The anti-ultraviolet and moisture-conducting quick-drying fabric is obtained by spinning and weaving the filament yarn with special-shaped cross-section added with ultraviolet shielding agent, so as to improve the wet comfort and protection of the fabric;
4)采用吸湿排汗剂对织物进行后整理,但是存在时效性的问题。4) The fabric is finished with a moisture-absorbing and sweat-wicking agent, but there is a problem of timeliness.
US6399705,US6322886,US6303739和US6454982都介绍了聚乙二醇改性聚酯长丝的制备方法及在纱线和织物上的应用,这种改性聚酯纤维织物具有吸湿性、芯吸性、快干性、阻燃性、抗静电性和柔软手感,比传统聚酯织物的性能要优越的多。US6399705, US6322886, US6303739 and US6454982 have all introduced the preparation method of polyethylene glycol modified polyester filament and the application on yarn and fabric, this modified polyester fiber fabric has hygroscopicity, wicking property, fast Dryness, flame retardancy, antistatic and soft touch are much superior to those of traditional polyester fabrics.
US5888914介绍了使用拒水纤维和亲水纤维混纺得到了亲水性比使用拒水性纤维纯纺纱高的舒适性纱线及织物。US5888914 introduced the use of water-repellent fiber and hydrophilic fiber blending to obtain comfortable yarns and fabrics with higher hydrophilicity than pure spinning of water-repellent fiber.
US6439270介绍了一种轻质、快干并且单向吸收和消散汗液的经纱机织物,通过使用导湿性能好的丙纶(PP)和氯纶(PVC)作为经纱或纬纱,纬纱直条分布,经纱起伏穿梭于纬纱,因此经纱与皮肤点状接触以吸收汗液,然后转移至纬纱,汗液在织物上单向流动而扩散快干,使人体感觉干爽舒适。US6439270 introduces a warp woven fabric that is lightweight, quick-drying, and unidirectionally absorbs and dissipates sweat. By using polypropylene (PP) and polyvinyl chloride (PVC) with good moisture permeability as warp or weft, the weft is distributed in straight strips, and the warp The undulations shuttle through the weft yarns, so the warp yarns make point contact with the skin to absorb sweat, and then transfer to the weft yarns. The sweat flows in one direction on the fabric and spreads and dries quickly, making the human body feel dry and comfortable.
CN1560341A介绍了一种通过使用不同种类、不同细度、不同长度的纤维混纺得到一种新型导湿透气纱线,以此纱线编织的织物具有导湿快干的功能。CN1560341A introduces a new type of moisture-conducting and air-permeable yarn obtained by blending fibers of different types, different finenesses, and different lengths. The fabric woven with this yarn has the function of moisture-conducting and quick-drying.
CN1563533A介绍了一种使用不同种类、不同细度、不同混比的纤维混纺得到的一种一种新型导湿纱线,以此纱线编织的织物具有导湿快干接触舒适的功能。CN1563533A introduces a new type of moisture-conducting yarn obtained by blending fibers of different types, different finenesses, and different mixing ratios. The fabric woven with this yarn has the function of moisture-conducting, quick-drying, and comfortable contact.
上述专利中多以介绍涤纶纤维织物的舒适性功能获得,而以多功能纱线的介绍鲜见报道。Most of the above-mentioned patents are obtained by introducing the comfort function of polyester fiber fabrics, while the introduction of multifunctional yarns is rarely reported.
发明内容 Contents of the invention
本发明的目的之一是提供一种抗紫外线、抗菌兼导湿快干的混纺纱线;One of the purposes of the present invention is to provide a blended yarn that is anti-ultraviolet, antibacterial, and moisture-conducting and quick-drying;
本发明目的之二是提供所述混纺纱线的制备方法;Two of the object of the present invention is to provide the preparation method of described blended yarn;
本发明目的之三是公开所述混纺纱线的应用。The third object of the present invention is to disclose the application of said blended yarn.
本发明的抗紫外线、抗菌兼导湿快干的混纺纱线的组分和重量百分比为:The components and weight percentages of the anti-ultraviolet, antibacterial and wet-drying blended yarn of the present invention are:
导湿纤维25-60%,抗菌纤维20-60%,抗紫外线纤维10-30%。Moisture-conducting fiber 25-60%, antibacterial fiber 20-60%, anti-ultraviolet fiber 10-30%.
所说的导湿纤维,多指对合成纤维的物理改性,使疏水性纤维变成亲水性纤维。纺丝的时候使用异形喷丝孔,生产成中空或异形截面纤维,在纤维表面形成很多沟槽,或者形成中空,在中空壁上面有很多孔洞。这样就可以通过毛细管效应来吸湿导湿。合成纤维吸收的基本都是游离水,这种水散失很快。只要能把它迅速扩散开,就可以蒸发掉,从而具备导湿快干的功能。本发明采用的是“十”字型截面导湿纤维,其表面的纵向四道凹槽有利于水分的传导,如仪征化纤有限公司生产的产品coolbest,美国杜邦公司的coolmax,或台湾中兴公司的coolplus。The so-called moisture-wicking fibers mostly refer to the physical modification of synthetic fibers to make hydrophobic fibers into hydrophilic fibers. When spinning, special-shaped spinneret holes are used to produce hollow or special-shaped cross-section fibers, forming many grooves on the surface of the fibers, or forming hollows with many holes on the hollow walls. In this way, moisture can be absorbed and conducted through the capillary effect. Synthetic fibers basically absorb free water, which is lost quickly. As long as it can be diffused quickly, it can be evaporated, so that it has the function of moisture-wicking and quick-drying. The present invention adopts the "ten" cross-section moisture-conducting fiber, and the longitudinal four grooves on its surface are conducive to the conduction of moisture, such as the coolbest product produced by Yizheng Chemical Fiber Co., Ltd. , DuPont's coolmax , or coolplus from Taiwan ZTE Corporation .
所说的抗菌纤维是指在纺丝原液中加入名为Triclosan或纳米银离子的抗菌剂。抗菌剂能有效抑制许多细菌的繁殖,如:金黄葡萄球菌、鼠伤寒沙门氏菌、大肠杆菌和克雷伯氏肺炎菌等。这种抗菌剂以颗粒状分布在纤维内,不是分子状地散落在纤维整个结构中,因而抗菌剂颗粒能像仓库一样缓缓将抗菌剂溶出到纤维表面,发挥抗菌效果。所说的抗菌纤维可以采用市售产品,如中国纺织科学研究院开发的纳米银系纤维,台湾豪杰股份集团公司生产的texcare纳米银抗菌纤维,或英国考陶尔兹公司的Amicor纤维。Said antibacterial fiber refers to the addition of an antibacterial agent called Triclosan or nano silver ions in the spinning stock solution. Antibacterial agents can effectively inhibit the reproduction of many bacteria, such as: Staphylococcus aureus, Salmonella typhimurium, Escherichia coli and Klebsiella pneumoniae. The antibacterial agent is distributed in the fiber in the form of particles, not scattered in the entire structure of the fiber in a molecular form, so the antibacterial agent particles can slowly dissolve the antibacterial agent to the surface of the fiber like a warehouse, and exert an antibacterial effect. Said antibacterial fiber can adopt commercially available product, as the nano-silver series fiber that China Academy of Textile Sciences develops, the texcare nano-silver antibacterial fiber that Taiwan Haojie Co., Ltd. produces, or the Amicor of British Courtaulds company fiber.
所说的抗紫外线纤维,具有抗紫外线破坏能力的纤维或含有抗紫外线添加剂的纤维。如腈纶为优良的抗紫外线纤维;而锦纶抗紫外线的能力较差,因此需要在制造锦纶的聚合物中加入少量的添加剂(如锰盐和次磷酸、硼酸锰、硅酸铝及锰盐-铈盐混合物等),即能制得抗紫外线锦纶。抗紫外线涤纶是采用在聚酯中掺入陶瓷紫外线遮挡剂的方法制成。本发明使用的是将纳米级钛系或锌系粉体作为紫外线屏蔽因子加入聚酯原液中纺丝制得,这种纤维织造的织物耐光热老化性能大幅提高,且具有防晒降温的功能,从而减低患上皮肤癌的机会。可以采用市售产品,如上海交通大学开发的抗紫外线纤维,台湾新光合成纤维有限公司生产cooltouch等。Said anti-ultraviolet fiber refers to the fiber with anti-ultraviolet damage ability or the fiber containing anti-ultraviolet additive. For example, acrylic fiber is an excellent anti-ultraviolet fiber; while nylon has poor anti-ultraviolet ability, it is necessary to add a small amount of additives (such as manganese salt and hypophosphorous acid, manganese borate, aluminum silicate and manganese salt-cerium) to the polymer for making nylon. salt mixture, etc.), that can make anti-ultraviolet nylon. UV-resistant polyester is made by incorporating ceramic UV blocking agents into polyester. The present invention uses nano-scale titanium-based or zinc-based powders as ultraviolet shielding factors and adds them into polyester stock solution for spinning. The light-heat aging resistance of the fabric woven by this fiber is greatly improved, and it has the function of sun protection and cooling, thus Reduce the chance of getting skin cancer. Commercially available products can be used, such as the anti-ultraviolet fiber developed by Shanghai Jiaotong University, and cooltouch produced by Taiwan Xinguang Synthetic Fiber Co., Ltd. wait.
本发明中涉及的混纺比例,须按照上述比例投料,否则将会使终端产品难以兼具抗紫外线、抗菌和导湿功能,就不能同时满足抗紫外线织物、抗菌织物和导湿快干织物的标准。The blending ratio involved in the present invention must be fed according to the above ratio, otherwise it will be difficult for the end product to have anti-ultraviolet, antibacterial and moisture-conducting functions, and it will not be able to meet the standards of anti-ultraviolet fabrics, antibacterial fabrics and moisture-conducting quick-drying fabrics at the same time .
所说的标准如:Said standards such as:
抗紫外线标准:GB/T18830;UV resistance standard: GB/T18830;
抗菌性能标准:ASTME2149-2001(美),JISL1902:2002(日);Antibacterial performance standards: ASTME2149-2001 (US), JISL1902: 2002 (Japan);
吸水速度:FTTS-Γ A-04(台湾);Water absorption speed: FTTS-Γ A-04 (Taiwan);
优选的如下:The preferred ones are as follows:
导湿纤维35-45%,抗菌纤维25-40%,抗紫外线纤维15-30%。Moisture-conducting fiber 35-45%, antibacterial fiber 25-40%, anti-ultraviolet fiber 15-30%.
本发明的抗紫外线、抗菌兼导湿快干的混纺纱线的制备方法,包括如下步骤:The preparation method of the anti-ultraviolet, antibacterial and moisture-conducting quick-drying blended yarn of the present invention comprises the following steps:
将导湿纤维、抗菌纤维和抗紫外线纤维按照重量比例,在开棉机中开棉成卷,在梳棉机中成条,在条卷机中成卷,并条,粗纱,细纱和络筒;The moisture-conducting fiber, antibacterial fiber and anti-ultraviolet fiber are opened into rolls in the opener according to the weight ratio, formed into slivers in the carding machine, formed into rolls in the sliver winder, drawing, roving, spun yarn and winding ;
开清棉采用梳针打手,梳棉工序中,刺辊速度为700-850r/min,锡林速度280-320r/min。Carding needle beaters are used for opening and cleaning. In the carding process, the licker-in speed is 700-850r/min, and the cylinder speed is 280-320r/min.
本发明的优点:Advantages of the present invention:
(1)使纱线具有更全面的功能。使服装满足人体的热湿舒适性和健康需求。(1) Make the yarn have more comprehensive functions. Make the clothing meet the heat and humidity comfort and health needs of the human body.
(2)填补国内空白。目前使用多组分纱线的织物都不能同时达到抗紫外线织物、抗菌织物和导汗快干织物的标准。(2) To fill the gap in the country. None of the current fabrics using multi-component yarns can simultaneously meet the standards of UV-resistant fabrics, antibacterial fabrics, and sweat-wicking and quick-drying fabrics.
(3)可适应于现有纺纱企业的生产体系,不需作设备更新。(3) It can be adapted to the production system of existing spinning enterprises, and does not need to be updated for equipment.
本发明中混纺纱线可制成针织或机织面料,然后按照人们的需求可以制成内衣、袜子、手套、夏季衬衣,T恤等纺织品。The blended yarn in the present invention can be made into knitted or woven fabrics, and then can be made into underwear, socks, gloves, summer shirts, T-shirts and other textiles according to people's needs.
本发明将在下文中通过实施例进行具体说明,在实施例采用下列的测试方法及标准:The present invention will be described in detail below by embodiment, adopts following test method and standard in embodiment:
防紫外线性能:参考GB/T 18830-2002,使用UV-VIS8500紫外分光光度计,UPF>30,T(UVA)<5%,为抗紫外线产品。Anti-ultraviolet performance: Refer to GB/T 18830-2002, use UV-VIS8500 ultraviolet spectrophotometer, UPF>30, T(UVA)<5%, it is an anti-ultraviolet product.
抗菌性能:ASTM E2149-2001,JIS L 1902:2002。Antibacterial properties: ASTM E2149-2001, JIS L 1902:2002.
具体实施方式 Detailed ways
实施例1Example 1
导湿纤维,选用“+”型截面纤维,采用中兴公司生产的coolplus;Moisture-conducting fiber, choose "+" cross-section fiber, adopt coolplus produced by Zhongxing Company;
抗菌纤维是指在纺丝原液中加入名为纳米银离子抗菌剂的纤维。采用台湾豪纤公司texcare纳米银纤维;Antibacterial fiber refers to adding nano-silver ion antibacterial agent to the spinning dope. Using texcare nano-silver fiber from Taiwan Haofiber Company;
所说的抗紫外线纤维采用台湾新光合成纤维公司生产的cooltouch;Said anti-ultraviolet fiber adopts cooltouch produced by Taiwan Xinguang Synthetic Fiber Company;
导湿纤维:抗紫外线纤维:抗菌纤维混纺比(重量比)为35:40:25,得到30s机织纱。The blending ratio (weight ratio) of moisture-conducting fiber: anti-ultraviolet fiber: antibacterial fiber is 35:40:25, and 30s woven yarn is obtained.
用这种纱线织造平纹织物,147g/m2,制备方法如下:A plain weave fabric, 147 g/m 2 , was woven from this yarn, prepared as follows:
将导湿纤维、抗菌纤维和抗紫外线纤维按照重量比例,在开棉机中开棉成卷,在梳棉机中成条,在条卷机中成卷,并条,粗纱,细纱和络筒;The moisture-conducting fiber, antibacterial fiber and anti-ultraviolet fiber are opened into rolls in the opener according to the weight ratio, formed into slivers in the carding machine, formed into rolls in the sliver winder, drawing, roving, spun yarn and winding ;
开清棉采用梳针打手,梳棉工序中,刺辊速度为850r/min,锡林速度320r/min。经测试其功能性指标如下:Carding needle beaters are used for opening and cleaning. In the carding process, the licker-in speed is 850r/min, and the cylinder speed is 320r/min. After testing, its functional indicators are as follows:
抗紫外线性(织物):UPF≥50+,T(UVA)<3%,是抗紫外线织物;UV resistance (fabric): UPF ≥ 50+, T (UVA) < 3%, is an anti-ultraviolet fabric;
抗菌性能(纱线):对金黄色葡萄球菌抑菌率>99.9%,是抗菌纺织品;Antibacterial performance (yarn): the antibacterial rate of Staphylococcus aureus >99.9%, is an antibacterial textile;
水分扩散时间(织物):7″72,导湿性能非常好。Moisture diffusion time (fabric): 7″72, very good moisture conductivity.
实施例2Example 2
导湿纤维,选用“十”型截面纤维,采用杜邦公司公司生产的coolmax产品;抗菌纤维是指在纺丝原液中加入名为Triclosan的抗菌剂的纤维。采用英国考陶尔兹公司的Amicor纤维;Moisture-conducting fibers are selected from "ten" cross-section fibers, and coolmax products produced by DuPont Company are used; antibacterial fibers refer to fibers that add an antibacterial agent named Triclosan to the spinning stock solution. Using Amicor from Courtaulds, UK fiber;
所说的抗紫外线纤维采用的上海交通大学开发的抗紫外线纤维;The anti-ultraviolet fiber developed by Shanghai Jiao Tong University that said anti-ultraviolet fiber adopts;
导湿纤维:抗紫外线纤维:抗菌纤维混纺比(重量比)为45:25:15,得到30s机织纱。用这种纱线织造平纹织物,155g/m2;制备方法如下:The blending ratio (weight ratio) of moisture-conducting fiber: anti-ultraviolet fiber: antibacterial fiber is 45:25:15, and 30s woven yarn is obtained. Plain weave fabric was woven from this yarn, 155 g/m 2 ; the preparation method was as follows:
将导湿纤维、抗菌纤维和抗紫外线纤维按照重量比例,在开棉机中开棉成卷,在梳棉机中成条,在条卷机中成卷,并条,粗纱,细纱和络筒;The moisture-conducting fiber, antibacterial fiber and anti-ultraviolet fiber are opened into rolls in the opener according to the weight ratio, formed into slivers in the carding machine, formed into rolls in the sliver winder, drawing, roving, spun yarn and winding ;
开清棉采用梳针打手,梳棉工序中,刺辊速度为700r/min,锡林速度280r/min。Carding needle beaters are used for opening and cleaning. In the carding process, the licker-in speed is 700r/min, and the cylinder speed is 280r/min.
经测试其功能性指标如下:After testing, its functional indicators are as follows:
抗紫外线性(织物):UPF≥50+,T(UVA)<3%,是抗紫外线织物;UV resistance (fabric): UPF ≥ 50+, T (UVA) < 3%, is an anti-ultraviolet fabric;
抗菌性能(纱线):对金黄色葡萄球菌抑菌率>99.9%,是抗菌纺织品;Antibacterial performance (yarn): the antibacterial rate of Staphylococcus aureus >99.9%, is an antibacterial textile;
水分扩散时间(织物):3″58,导湿性能非常好。Moisture diffusion time (fabric): 3″58, very good moisture conductivity.
实施例3Example 3
导湿纤维,选用“+”型截面纤维,采用仪征化纤公司生产的coolbest;Moisture-conducting fiber, choose "+" cross-section fiber, adopt coolbest produced by Yizheng Chemical Fiber Company;
抗菌纤维是指在纺丝原液中加入名为纳米银离子抗菌剂的纤维。采用中国纺织科学研究院开发的纳米银抗菌纤维;Antibacterial fiber refers to adding nano-silver ion antibacterial agent to the spinning dope. Nano-silver antibacterial fiber developed by China Textile Science Research Institute;
所说的抗紫外线纤维采用上海交通大学开发的抗紫外线纤维;The said anti-ultraviolet fiber adopts the anti-ultraviolet fiber developed by Shanghai Jiaotong University;
导湿纤维:抗紫外线纤维:抗菌纤维混纺比(重量比)为40:30:30,得到30s机织纱。用这种纱线织造平纹织物,134g/m2,制备方法同实施例1。Moisture-conducting fiber: anti-ultraviolet fiber: antibacterial fiber blending ratio (weight ratio) is 40:30:30, and 30s woven yarn is obtained. Use this yarn to weave plain fabric, 134g/m 2 , and the preparation method is the same as in Example 1.
经测试其功能性指标如下:After testing, its functional indicators are as follows:
抗紫外线性(织物):UPF≥50+,T(UVA)<3%,是抗紫外线织物;UV resistance (fabric): UPF ≥ 50+, T (UVA) < 3%, is an anti-ultraviolet fabric;
抗菌性能(纱线):对金黄色葡萄球菌抑菌率>99.0%,是抗菌纺织品;Antibacterial performance (yarn): the antibacterial rate of Staphylococcus aureus > 99.0%, is an antibacterial textile;
水分扩散时间(织物):7″80,导湿性能非常好。Moisture diffusion time (fabric): 7″80, very good moisture conductivity.
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| CN102586911A (en) * | 2011-01-14 | 2012-07-18 | 新光合成纤维股份有限公司 | Fiber with humidity regulating function, its production method and use |
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| CN102586911A (en) * | 2011-01-14 | 2012-07-18 | 新光合成纤维股份有限公司 | Fiber with humidity regulating function, its production method and use |
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