CN1363701A - Refining agent of Mg alloy and its preparing process - Google Patents
Refining agent of Mg alloy and its preparing process Download PDFInfo
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- CN1363701A CN1363701A CN 01142611 CN01142611A CN1363701A CN 1363701 A CN1363701 A CN 1363701A CN 01142611 CN01142611 CN 01142611 CN 01142611 A CN01142611 A CN 01142611A CN 1363701 A CN1363701 A CN 1363701A
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- alloy
- chloride
- refining agent
- magnesium
- carbonate
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Abstract
A refining agent of Mg-alloy contains magnesium chloride (40-60%), potassium chloride (10-25%), sodium chloride (10-25%), calcium chloride (1-10%), calcium fluoride (5-15%), barium chloride (1-10%), nano carbonate adsorbent (1-10%) and rare-earth compound as hidrogen-fixing agent (1-10%). Its advantages include high activity, high effect on fixating hydrogen, removing impurities, and improving mechanical and anticorrosion performance, and high chemical stability.
Description
Technical field:
What the present invention relates to is a kind of novel magnesium alloy refining agent and production method, relates in particular to a kind of novel magnesium alloy refining agent and production method that adopts nano-carbonate sorbent material and rare earth compound solid hydrogen agent, belongs to metallic substance and metallurgical class field.
Background technology:
The magnesium chemical property is active, often contains impurity elements such as a large amount of oxide compounds and Fe, Ni, Cu in the magnesium alloy, and these impurity significantly reduce the mechanical property and the corrosion stability of magnesium alloy.Therefore, will use refining agent that it is carried out refining treatment in the magnesium alloy smelting process, the purpose of refining treatment is to remove impurity element and the non-metallic inclusion such as the oxide skin etc. of sneaking in the alloy.Require flux can adsorb impurity well, and can separate fully, be mingled with to avoid producing flux with magnesium alloy fused mass, otherwise can remarkable mechanical property and the corrosive nature that reduces magnesium alloy.The present RJ2 flux that generally uses, this flux is strong inadequately to the molten intravital inclusion adsorptivity of magnesium, and flux is hydrogen effect admittedly, is unfavorable for reducing the porosity of magnesium alloy, and flux is easy to sneak into alloy liquid and becomes flux and be mingled with, and has a strong impact on the performance of alloy.As document (National Defense Industry Press publishes May nineteen eighty-three for Lu Shusun etc., " non-ferrous casting alloy and melting ", P195-199) described in.
Summary of the invention:
The objective of the invention is to overcome the weak point of existing refining agent of Mg alloy, a kind of very strong activity that in use has is proposed, and novel magnesium alloy refining agent and production method thereof that can solid hydrogen, in use, the small rare gas element bubble that hypersober in the refining agent produces, improved the clearance of small non-metallic inclusion in the magnesium melt greatly, the solid hydrogen agent in the refining agent can melt intravital hydrogen solid solution in magnesium alloy with magnesium effectively simultaneously, reduces the porosity of magnesium alloy.
For achieving this end, the chemical constitution of refining agent of Mg alloy provided by the invention has been done adjustment on the basis of existing refining agent, and has added sorbent material and solid hydrogen agent.The mass percent of concrete composition is: 40-60% magnesium chloride Mg Cl
2, 10-25% potassium chloride (KCl), 10-25% sodium chloride nacl, 1-10% calcium chloride CaCl
2, 5-15% Calcium Fluoride (Fluorspan) CaF
2, 1-10% bariumchloride BaCl
2, 1-10% nano-carbonate sorbent material, 1-10% rare earth compound solid hydrogen agent.Sorbent material can be the nano-calcium carbonate magnesium of 40-300 nanometer, nano strontium carbonate, nano-calcium carbonate etc.The rare earth compound solid hydrogen agent can be RECl
3, REF
3, RE
2(CO
3)
3Deng.
The production method of this novel refining agent is: after crucible is warmed up to certain temperature, add magnesium chloride, Repone K, sodium-chlor, calcium chloride and bariumchloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750-790 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with 20-40 number sieve.Add nano-carbonate and rare earth compound afterwards and mix with ball mill.The flux for preparing should be packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible is warmed up to about 740 ℃, the refining agent of 2-3% constantly is spread on liquid level, stir up and down with the refining spoon simultaneously, make the magnesium liquid recycle stream moving, to prolong the flow process of solvent droplets, increase flux and contact with oxide inclusion and adsorb chance, keep usually that liquid level is till the bright mirror surface about 10 minutes.
Novel magnesium alloy refining agent activity provided by the invention is stronger, and the molten intravital inclusion of magnesium is had extremely strong adsorptivity, and the small indifferent gas physical efficiency of nano-carbonate sorbent material generation is in use effectively removed the small inclusion in the magnesium melt.And hydrogen improves the mechanical property and the corrosion resistance of magnesium alloy greatly to the disadvantageous effect of magnesium foundry goods porosity in the magnesium melt because the rare earth compound solid hydrogen agent can effectively reduce.Refining agent of the present invention and alloy liquid have bigger difference in specific gravity, and viscosity is suitable, and chemical stability is good, not with alloy, furnace lining and furnace gas generation chemical reaction, and are difficult for sneaking into alloy liquid, do not produce flux and are mingled with, and have improved the refining effect of magnesium melt.Obnoxious flavour is less simultaneously, meets industrial hygiene standard and exhaust gas emission requirement.
Embodiment:
Below by specific embodiment technical scheme of the present invention is further described.
Embodiment 1:
Refining agent of Mg alloy composition (mass percent): 50% magnesium chloride (MgCl
2), 15% Repone K (KCl), 15% sodium-chlor (NaCl), 5% calcium chloride (CaCl
2), 6% Calcium Fluoride (Fluorspan) (CaF
2), 4% bariumchloride (BaCl
2), 3% magnesiumcarbonate, 2% rare earth chloride.
After crucible is warmed up to certain temperature, add magnesium chloride, Repone K, sodium-chlor, calcium chloride and bariumchloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to about 760 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 30 sieves.Add magnesiumcarbonate and rare earth chloride afterwards and mix with ball mill.The flux for preparing should be packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible is warmed up to about 740 ℃, refining agent with 3% constantly is spread on liquid level, stir up and down with the refining spoon simultaneously, make the magnesium liquid recycle stream moving, to prolong the flow process of solvent droplets, increase flux and contact with oxide inclusion and adsorb chance, keep usually that liquid level is till the bright mirror surface about 10 minutes.The above inclusion of 30 μ m is removed substantially in the magnesium melt, is used for the ZMgAl8Zn magnesium alloy, and the tensile strength of metal mold sample is more than the 180MPa, and unit elongation is 3.0%.
Embodiment 2:
Refining agent of Mg alloy composition (mass percent): 45% magnesium chloride (MgCl
2), 15% Repone K (KCl), 10% sodium-chlor (NaCl), 10% calcium chloride (CaCl
2), 6% Calcium Fluoride (Fluorspan) (CaF
2), 4% bariumchloride (BaCl
2), 8% lime carbonate, 2% rare earth fluoride.
The production method of this novel refining agent is: after crucible is warmed up to certain temperature, add magnesium chloride, Repone K, sodium-chlor, calcium chloride and bariumchloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to about 760 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 30 sieves.Add lime carbonate and rare earth fluoride afterwards and mix with ball mill.The flux for preparing should be packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible be warmed up to～740 ℃ the time, refining agent with 3% constantly is spread on liquid level, stir up and down with the refining spoon simultaneously, make the magnesium liquid recycle stream moving, to prolong the flow process of solvent droplets, increase flux and contact with oxide inclusion and adsorb chance, keep usually that liquid level is till the bright mirror surface about 10 minutes.The above inclusion of 20 μ m is removed substantially in the magnesium melt, is used for the ZMgAl8Zn magnesium alloy, and the tensile strength of metal mold sample is more than the 183MPa, and unit elongation is 3.4%.
Embodiment 3:
Refining agent of Mg alloy composition (mass percent): 40% magnesium chloride (MgCl
2), 10% Repone K (KCl), 15% sodium-chlor (NaCl), 10% calcium chloride (CaCl
2), 6% Calcium Fluoride (Fluorspan) (CaF
2), 9% bariumchloride (BaCl
2), 5% Strontium carbonate powder, 5% carbonated rare earth.
The production method of this novel refining agent is: after crucible is warmed up to certain temperature, add magnesium chloride, Repone K, sodium-chlor, calcium chloride and bariumchloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to about 760 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 30 sieves.Add Strontium carbonate powder and carbonated rare earth afterwards and mix with ball mill.The flux for preparing should be packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible be warmed up to～740 ℃ the time, refining agent with 3% constantly is spread on liquid level, stir up and down with the refining spoon simultaneously, make the magnesium liquid recycle stream moving, to prolong the flow process of solvent droplets, increase flux and contact with oxide inclusion and adsorb chance, keep usually that liquid level is till the bright mirror surface about 10 minutes.The above inclusion of 15 μ m is removed substantially in the magnesium melt, is used for the ZMgAl8Zn magnesium alloy, and the tensile strength of metal mold sample is more than the 186MPa, and unit elongation is 4%.
Claims (4)
1, a kind of refining agent of Mg alloy is characterized in that the mass percent of its composition is: 40-60% magnesium chloride Mg Cl
2, 10-25% potassium chloride (KCl), 10-25% sodium chloride nacl, 1-10% calcium chloride CaCl
2, 5-15% Calcium Fluoride (Fluorspan) CaF
2, 1-10% bariumchloride BaCl
2, 1-10% nano-carbonate sorbent material, 1-10% rare earth compound solid hydrogen agent.
2,, it is characterized in that said carbonate sorbent material is that granular size is nano-calcium carbonate magnesium, nano strontium carbonate, nano-calcium carbonate of 40-300 nanometer etc. as the said refining agent of Mg alloy of claim 1.
3,, it is characterized in that said rare earth compound solid hydrogen agent is RECl as the said refining agent of Mg alloy of claim 1
3, REF
3, RE
2(CO
3)
3Deng.
4, a kind of production method of refining agent of Mg alloy, it is characterized in that after the crucible intensification, add magnesium chloride, Repone K, sodium-chlor, calcium chloride and bariumchloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750-790 ℃, stir, pour into piece, the ball mill milling powdering of packing into after the fragmentation, the back of sieving adds nano-carbonate and rare earth compound and mixes with ball mill, and the flux for preparing is packed into standby in the encloses container.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01142611XA CN1164777C (en) | 2001-12-11 | 2001-12-11 | Refining agent of Mg alloy and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01142611XA CN1164777C (en) | 2001-12-11 | 2001-12-11 | Refining agent of Mg alloy and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1363701A true CN1363701A (en) | 2002-08-14 |
| CN1164777C CN1164777C (en) | 2004-09-01 |
Family
ID=4676844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB01142611XA Expired - Fee Related CN1164777C (en) | 2001-12-11 | 2001-12-11 | Refining agent of Mg alloy and its preparing process |
Country Status (1)
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|---|---|
| CN (1) | CN1164777C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100344779C (en) * | 2005-11-10 | 2007-10-24 | 上海交通大学 | Composite clarifying flux of La-containing aluminium alloy and its production process |
| CN100344778C (en) * | 2005-11-10 | 2007-10-24 | 上海交通大学 | Composite purification flux containing cerium-magnesium alloy, and production method |
| CN100398680C (en) * | 2006-08-14 | 2008-07-02 | 中国铝业股份有限公司 | Flux for heat resistant magnesium alloy |
| CN102296188A (en) * | 2011-08-30 | 2011-12-28 | 吴江市精工铝字制造厂 | Iron removing agent and iron removal preparation method of regenerated aluminum alloy |
| CN102851524A (en) * | 2012-08-22 | 2013-01-02 | 淄博宏泰防腐有限公司 | Novel flux for ZK60 magnesium alloy, and preparation method and usage method thereof |
| CN103215460A (en) * | 2013-05-13 | 2013-07-24 | 西南大学 | Slag conglomeration agent for treating magnesium and magnesium alloy |
| CN103468976A (en) * | 2013-10-12 | 2013-12-25 | 青海三工镁业有限公司 | No-pollution green environment-friendly fluxing agent for magnesium and magnesium alloy and preparation method thereof |
| CN103805791A (en) * | 2014-03-03 | 2014-05-21 | 攀钢集团攀枝花钢铁研究院有限公司 | Rough magnesium aluminum-removal refining method and rough magnesium aluminum-removal refining flux |
| CN103834816A (en) * | 2014-03-20 | 2014-06-04 | 湖南斯瑞摩科技有限公司 | Magnesium alloy desilication fusing agent and preparation method thereof |
| CN103911522A (en) * | 2012-12-31 | 2014-07-09 | 北京有色金属研究总院 | Recovery treatment method for used magnesium smelting fluxing agent or magnesium alloy smelting fluxing agent |
| CN103937930A (en) * | 2014-04-10 | 2014-07-23 | 铜陵南江鑫钢实业有限公司 | Refining agent used for alloy steel smelting and preparation method thereof |
| CN105385873A (en) * | 2015-11-19 | 2016-03-09 | 南京云海轻金属精密制造有限公司 | Refining agent capable of being used for purifying magnesium alloy liquid in pressure casting process and production process of refining agent |
| CN109112323A (en) * | 2018-09-30 | 2019-01-01 | 成都先进金属材料产业技术研究院有限公司 | Refined magnesium electrolyte and method of refining |
| CN113174506A (en) * | 2021-04-08 | 2021-07-27 | 上海交通大学 | Refining flux suitable for magnesium-lithium alloy and preparation method thereof |
| CN114381628A (en) * | 2021-12-15 | 2022-04-22 | 中国科学院金属研究所 | Refining agent and preparation method and application thereof |
| CN115386747A (en) * | 2022-08-02 | 2022-11-25 | 山西银光华盛镁业股份有限公司 | Method for preparing ZM5 and ZM6 magnesium alloy |
-
2001
- 2001-12-11 CN CNB01142611XA patent/CN1164777C/en not_active Expired - Fee Related
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100344778C (en) * | 2005-11-10 | 2007-10-24 | 上海交通大学 | Composite purification flux containing cerium-magnesium alloy, and production method |
| CN100344779C (en) * | 2005-11-10 | 2007-10-24 | 上海交通大学 | Composite clarifying flux of La-containing aluminium alloy and its production process |
| CN100398680C (en) * | 2006-08-14 | 2008-07-02 | 中国铝业股份有限公司 | Flux for heat resistant magnesium alloy |
| CN102296188A (en) * | 2011-08-30 | 2011-12-28 | 吴江市精工铝字制造厂 | Iron removing agent and iron removal preparation method of regenerated aluminum alloy |
| CN102851524A (en) * | 2012-08-22 | 2013-01-02 | 淄博宏泰防腐有限公司 | Novel flux for ZK60 magnesium alloy, and preparation method and usage method thereof |
| CN103911522A (en) * | 2012-12-31 | 2014-07-09 | 北京有色金属研究总院 | Recovery treatment method for used magnesium smelting fluxing agent or magnesium alloy smelting fluxing agent |
| CN103911522B (en) * | 2012-12-31 | 2016-03-30 | 北京有色金属研究总院 | Magnesium smelting fusing agent after using or magnesium alloy smelting flux recovery and treatment method |
| CN103215460A (en) * | 2013-05-13 | 2013-07-24 | 西南大学 | Slag conglomeration agent for treating magnesium and magnesium alloy |
| CN103215460B (en) * | 2013-05-13 | 2014-07-30 | 西南大学 | Slag conglomeration agent for treating magnesium and magnesium alloy |
| CN103468976A (en) * | 2013-10-12 | 2013-12-25 | 青海三工镁业有限公司 | No-pollution green environment-friendly fluxing agent for magnesium and magnesium alloy and preparation method thereof |
| CN103805791A (en) * | 2014-03-03 | 2014-05-21 | 攀钢集团攀枝花钢铁研究院有限公司 | Rough magnesium aluminum-removal refining method and rough magnesium aluminum-removal refining flux |
| CN103805791B (en) * | 2014-03-03 | 2016-01-06 | 攀钢集团攀枝花钢铁研究院有限公司 | Crude magnesium is except aluminium method of refining and crude magnesium are except aluminium refining flux |
| CN103834816B (en) * | 2014-03-20 | 2015-10-07 | 湖南斯瑞摩科技有限公司 | A kind of magnesium alloy desilicon flux and preparation method thereof |
| CN103834816A (en) * | 2014-03-20 | 2014-06-04 | 湖南斯瑞摩科技有限公司 | Magnesium alloy desilication fusing agent and preparation method thereof |
| CN103937930B (en) * | 2014-04-10 | 2016-04-13 | 铜陵南江鑫钢实业有限公司 | A kind of refining agent for steel alloy melting and preparation method thereof |
| CN103937930A (en) * | 2014-04-10 | 2014-07-23 | 铜陵南江鑫钢实业有限公司 | Refining agent used for alloy steel smelting and preparation method thereof |
| CN105385873A (en) * | 2015-11-19 | 2016-03-09 | 南京云海轻金属精密制造有限公司 | Refining agent capable of being used for purifying magnesium alloy liquid in pressure casting process and production process of refining agent |
| CN109112323A (en) * | 2018-09-30 | 2019-01-01 | 成都先进金属材料产业技术研究院有限公司 | Refined magnesium electrolyte and method of refining |
| CN113174506A (en) * | 2021-04-08 | 2021-07-27 | 上海交通大学 | Refining flux suitable for magnesium-lithium alloy and preparation method thereof |
| CN113174506B (en) * | 2021-04-08 | 2022-07-15 | 上海交通大学 | Refining flux suitable for magnesium-lithium alloy and preparation method thereof |
| CN114381628A (en) * | 2021-12-15 | 2022-04-22 | 中国科学院金属研究所 | Refining agent and preparation method and application thereof |
| CN115386747A (en) * | 2022-08-02 | 2022-11-25 | 山西银光华盛镁业股份有限公司 | Method for preparing ZM5 and ZM6 magnesium alloy |
Also Published As
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|---|---|
| CN1164777C (en) | 2004-09-01 |
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