CN1142301C - Flux for removing iron from Mg alloy and its preparing process - Google Patents
Flux for removing iron from Mg alloy and its preparing process Download PDFInfo
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- CN1142301C CN1142301C CNB021362009A CN02136200A CN1142301C CN 1142301 C CN1142301 C CN 1142301C CN B021362009 A CNB021362009 A CN B021362009A CN 02136200 A CN02136200 A CN 02136200A CN 1142301 C CN1142301 C CN 1142301C
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Abstract
The present invention relates to a magnesium alloy iron removing fusing agent and a production method thereof. Chemical components of the magnesium alloy iron removing fusing agent are also added with 20 to 45% of titanium compounds or a manganese compound iron removing agent except for 20 to 35% of magnesium chloride, 5 to 20% of potassium chloride, 5 to 20% of sodium chloride, 1 to 5% of calcium chloride and 2 to 10% of calcium fluoride. The magnesium alloy iron removing fusing agent produced by the present invention can effectively reduce the iron content in magnesium alloy and improves the mechanical performance and the corrosion resisting performance of the magnesium alloy; the activity of the fusing agent is relatively strong, the magnesium alloy iron removing fusing agent has extremely strong absorption to inclusions in a magnesium melting body, can effectively eliminate the inclusions in the magnesium melting body and has good deslagging performance, the price is low, and the refining effect of the magnesium melting body can be increased.
Description
Technical field:
What the present invention relates to is a kind of flux for removing iron from Mg alloy, relates in particular to a kind of flux for removing iron from Mg alloy and production method thereof that adopts titanium compound and manganic compound, belongs to metallic substance and metallurgical class technical field.
Background technology:
It is little that magnesium alloy has density, and specific tenacity and specific rigidity height, damping capacity is good and advantage such as electromagnetic shielding, becomes the important light material of automobile and electron trade in recent years.Along with MAGNESIUM METAL is used more and morely in industry, the purity of magnesium is also had higher requirement, requirement can be removed metal and the nonmetallic impuritys such as iron, nickel, copper, aluminium and silicon in the magnesium effectively usually.On the other hand, because the material use efficiency of magnesium alloy die casting is not high, generally can only reach about 30-50%, so can produce a large amount of waste materials in the die casting production process, the magnesium alloy parts of scrapping is along with the use of magnesium alloy is increasing.Because the content of the ferro element in the magnesium alloy waste material is often higher, having a strong impact on the mechanical property and the corrosion resistance of magnesium alloy, the deironing of current magnesium alloy waste material is the urgent problems that solve of a needs.The deironing of magnesium waste material economizes on resources for reasonable recovery waste material, reduces magnesium die casting cost and environmental pollution, and prolongation magnesium alloy life cycle is significant.Document (Xu Riyao, metallurgy of megnesium, metallurgical industry press, 1981) has been introduced the flux of being made up of lower chloride and Repone K, sodium-chlor, calcium chloride and the magnesium chloride of titanium and has been had the effect of deironing, but does not introduce concrete prescription.In addition, the lower chloride of titanium is (as TiCl
4) price height not only, and owing to be in a liquid state under the normal temperature, add in the magnesium melt extremely inconveniently as flux, therefore be necessary to develop other flux for removing iron from Mg alloy.
Summary of the invention:
The objective of the invention is to overcome the deficiency of existing flux for removing iron from Mg alloy, propose a kind of new flux for removing iron from Mg alloy and production method thereof, the flux for removing iron that makes can remove the gred in the use of magnesium alloy waste material removal process and can deironing, and cheap.
For achieving this end, flux for removing iron from Mg alloy provided by the invention, its composition range is: 20-35% magnesium chloride (MgCl
2), 5-20% Repone K (KCl), 5-20% sodium-chlor (NaCl), 1-5% calcium chloride (CaCl
2), 2-10% Calcium Fluoride (Fluorspan) (CaF
2), the iron removing reagent of 20-45%.The iron removing reagent that adopts is Manganous chloride tetrahydrate and/or titanium dioxide etc.
The production method of this flux for removing iron from Mg alloy is: after crucible is warmed up to certain temperature, add magnesium chloride, Repone K, sodium-chlor and calcium chloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750-790 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with 20-40 number sieve.Add iron removing reagent afterwards and mix with ball mill.The flux for preparing is packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible was warmed up to 730~740 ℃, the flux for removing iron with 3% constantly was spread on liquid level, stir up and down simultaneously, make the magnesium liquid recycle stream moving,, keep usually that liquid level is till the bright mirror surface about 10 minutes to prolong the flow process of solvent droplets.
Flux for removing iron from Mg alloy provided by the invention has significant advantage, titanium in the flux in use of the present invention or manganese element can interact the bigger intermetallic compound of a kind of density of formation and precipitate with the ferro element in the magnesium melt, the iron amount in the magnesium alloy be can reduce effectively, thereby the mechanical property and the corrosion resistance nature of magnesium alloy improved.The activity of flux is stronger, and the molten intravital inclusion of magnesium is had extremely strong adsorptivity, can remove the molten intravital inclusion of magnesium effectively, has good residue eliminating performance, and cheap.With alloy liquid bigger difference in specific gravity is arranged, viscosity is suitable, chemical stability is good, and be difficult for sneaking into alloy liquid,, do not produce flux and be mingled with, improved the refining effect of magnesium melt with alloy, furnace lining and furnace gas generation chemical reaction, obnoxious flavour is less simultaneously, meets industrial hygiene standard and exhaust gas emission requirement.
Embodiment:
Below by specific embodiment technical scheme of the present invention is further described.
Embodiment 1:
Flux for removing iron from Mg alloy composition (mass percent): 35% magnesium chloride, 18% Repone K, 15% sodium-chlor, 2% calcium chloride, 5% Calcium Fluoride (Fluorspan), 25% Manganous chloride tetrahydrate.
The production method of flux for removing iron is: after crucible is warmed up to about 300 ℃, add magnesium chloride, Repone K, sodium-chlor and calcium chloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 20 sieves.Add Manganous chloride tetrahydrate afterwards and mix with ball mill.The flux for preparing is packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible was warmed up to 740 ℃, the flux for removing iron with 3% constantly was spread on liquid level, stir up and down simultaneously, make the magnesium liquid recycle stream moving,, keep usually that liquid level is till the bright mirror surface about 10 minutes to prolong the flow process of solvent droplets.Be used for the ZMgAl8Zn magnesium alloy, its iron amount drops to 0.0071% from 0.0473%.
Embodiment 2:
Flux for removing iron from Mg alloy composition (mass percent): 20% magnesium chloride, 20% Repone K, 13% sodium-chlor, 4% calcium chloride, 3% Calcium Fluoride (Fluorspan), 20% titanium dioxide, 20% Manganous chloride tetrahydrate.
The production method of this flux for removing iron is: after crucible is warmed up to 250 ℃, add magnesium chloride, Repone K, sodium-chlor and calcium chloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 760 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 40 sieves.Add titanium dioxide and Manganous chloride tetrahydrate afterwards and mix with ball mill.The flux for preparing is packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible was warmed up to 730 ℃, the refining agent with 3% constantly was spread on liquid level, stir up and down with the refining spoon simultaneously, make the magnesium liquid recycle stream moving,, keep usually that liquid level is till the bright mirror surface about 10 minutes to prolong the flow process of solvent droplets.Be used for the ZMgAl8Zn magnesium alloy, its iron amount drops to 0.0057% from 0.0465%.
Embodiment 3:
Flux for removing iron from Mg alloy composition (mass percent): 30% magnesium chloride, 15% Repone K, 20% sodium-chlor, 5% calcium chloride, 10% Calcium Fluoride (Fluorspan), 20% titanium dioxide.
The production method of this flux for removing iron is: after crucible is warmed up to 350 ℃, add magnesium chloride, Repone K, sodium-chlor and calcium chloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750 ℃, stir, pour into piece.The ball mill milling powdering of packing into after the fragmentation sieves with No. 20 sieves.Add titanium dioxide afterwards and mix with ball mill.The flux for preparing is packed into standby in the encloses container.
During use, when magnesium alloy melting in electrical crucible was warmed up to 740 ℃, the refining agent with 3% constantly was spread on liquid level, stir up and down simultaneously, make the magnesium liquid recycle stream moving,, keep usually that liquid level is till the bright mirror surface about 10 minutes to prolong the flow process of solvent droplets.Be used for the ZMgAl8Zn magnesium alloy, its iron amount drops to 0.0062% from 0.0479%.
Claims (2)
1, a kind of flux for removing iron from Mg alloy is characterized in that composition quality percentage ratio is: iron removing reagent Manganous chloride tetrahydrate and/or the titanium dioxide of 20-35% magnesium chloride, 5-20% Repone K, 5-20% sodium-chlor, 1-5% calcium chloride, 2-10% Calcium Fluoride (Fluorspan), 20-45%.
2, as the production method of the said flux for removing iron from Mg alloy of claim 1, it is characterized in that after the crucible intensification, add magnesium chloride, Repone K, sodium-chlor and calcium chloride, be warmed up to partial melting after, add Calcium Fluoride (Fluorspan), be warmed up to 750-790 ℃, stir, pour into piece, the ball mill milling powdering of packing into after the fragmentation, the back of sieving adds iron removing reagent and mixes with ball mill, and the flux for preparing is packed into standby in the encloses container.
Priority Applications (1)
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CNB021362009A CN1142301C (en) | 2002-07-25 | 2002-07-25 | Flux for removing iron from Mg alloy and its preparing process |
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CNB021362009A CN1142301C (en) | 2002-07-25 | 2002-07-25 | Flux for removing iron from Mg alloy and its preparing process |
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CN1390965A CN1390965A (en) | 2003-01-15 |
CN1142301C true CN1142301C (en) | 2004-03-17 |
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Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100398680C (en) * | 2006-08-14 | 2008-07-02 | 中国铝业股份有限公司 | Flux for heat resistant magnesium alloy |
CN101191163B (en) * | 2006-11-23 | 2010-09-22 | 北京有色金属研究总院 | Refining agent for magnesium alloy and preparation method thereof |
CN101463430B (en) * | 2007-12-20 | 2011-08-24 | 鸿富锦精密工业(深圳)有限公司 | Magnesium alloy smelting method |
CN102051492B (en) * | 2010-11-30 | 2012-01-25 | 中原工学院 | Method for removing iron impurity from magnesium alloy by using Al-B intermediate alloy |
CN102517458B (en) * | 2011-12-30 | 2013-05-01 | 中原工学院 | Method for removing Fe impurity in magnesium or magnesium alloys by adopting Mg-Zr intermediate alloy |
CN103468976B (en) * | 2013-10-12 | 2014-10-08 | 青海三工镁业有限公司 | No-pollution green environment-friendly fluxing agent for magnesium and magnesium alloy and preparation method thereof |
CN103805791B (en) * | 2014-03-03 | 2016-01-06 | 攀钢集团攀枝花钢铁研究院有限公司 | Crude magnesium is except aluminium method of refining and crude magnesium are except aluminium refining flux |
CN110157910A (en) * | 2018-03-20 | 2019-08-23 | 肇庆新联昌金属实业有限公司 | A kind of waste and old alum recovery reprocessing processing method |
CN111118361A (en) * | 2020-01-15 | 2020-05-08 | 山西神舟航天科技有限公司 | Purification method of Mg-Al-Zn magnesium alloy melt |
CN118127392A (en) * | 2024-05-07 | 2024-06-04 | 山西神舟航天科技有限公司 | Scandium-containing high-performance cast magnesium alloy and preparation method thereof |
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2002
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