CN1362504A - Completely water-soluble hand-washing film - Google Patents
Completely water-soluble hand-washing film Download PDFInfo
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- CN1362504A CN1362504A CN 02100367 CN02100367A CN1362504A CN 1362504 A CN1362504 A CN 1362504A CN 02100367 CN02100367 CN 02100367 CN 02100367 A CN02100367 A CN 02100367A CN 1362504 A CN1362504 A CN 1362504A
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Abstract
The water-soluble hand-cleaning film is made up by adopting the following ingredients: polyvinyl alcohol, polyethylene glycol oxide and chitin as carrier, sodium lauryl sulfate, coconut oil acylaminodimethylpropyl betaine and sodium fatty alcohol-polyoxyethyleneether sulfate as detersive surfactant, dodecyldimethyl tertiary amine oxide and nonoxynol as germicide and SOD, sisu, sitai, fruit acid, moisture-holding factor and squalana with the functions of protecting skin and norishing skin. it is a soft, semi-transparent, water-soluble foam-rich film chip, and is easy to carry about and can prevent cross-infection and possesses extensive application.
Description
Technical field
The present invention relates to a kind of completely water-soluble hand-washing film, but particularly relate to a kind of water-soluble hand-washing film with cleaning, sterilization, skin care effect.
Background technology
Before the present invention proposed, perfumed soap had been used for many years as traditional cleaning supplies of washing one's hands, although it is a lot of to possess the perfumed soap kind of various functions, does not all have important breakthrough from content and form.After the tradition perfumed soap existed and is soaked in water for a long time, surfaces of tacky, piece be big, travel carry preserve inconvenience, sterilization effect is poor, the public arena is public many people of perfumed soap use can produce shortcomings such as cross infection.And have water-fast residue to exist after the paper soap use as matrix with paper or non-woven fabrics.In the technology in the past, adopt the single-material film forming more, but have many defectives, as the polyvinyl alcohol diaphragm, during hot and humid spending, diaphragm is clamminess, during low temperature, and the diaphragm embrittlement; Mierocrystalline cellulose diaphragm surface easily forms bubble, and solubility property is bad fast; Starch diaphragm tensile strength is weak etc.
Technology contents
The object of the invention is to provide a kind of completely water-soluble hand-washing film with cleaning, sterilization, skin care.
The present invention is combined with each other with one or more water-soluble high-molecular materials, support the carrier of skin composition as the tensio-active agent that plays cleaning action, sterilant, skin care, make the hand-washing film of the film like of complete water-soluble, disposable use has overcome the shortcoming that traditional perfumed soap exists.
The present invention is achieved through the following technical solutions:
Get: dodecyl dimethyl tertiary amine oxide 10-40 weight part
Nonoxinol 10-40 weight part
Cocamidopropyl betaine 80-200 weight part
Sodium lauryl sulphate 20-60 weight part
Polyoxyethylenated alcohol sodium sulfate 60-130 weight part
Chitin 5-15 weight part
Fibroin 1-10 weight part
Soap perfume 10-40 weight part
Polyvinyl alcohol 100-400 weight part
Polyoxyethylene 100-400 weight part
The sterilization component main separation dodecyl dimethyl tertiary amine oxide that the present invention selects for use, it is a kind of positive nonionogenic tenside, owing on molecular structure, have cation group and non-ionic group simultaneously, thereby it has the double effects of sterilization and decontamination.Its cation group has stronger killing and restraining effect to intestinal bacteria, staphylococcus aureus, Candida albicans, gonococcus, chlamydozoan etc. under the condition of the inclined to one side alkali of neutrality.The wetting ability of its non-ionic group can clean up dirt it again well.The present invention selects the balustrade of nonoxynolum as bactericidal active ingredient for use.Nonoxynolum has stated clearly in pharmacopeia as the birth control medicine, it can strengthen the bactericidal and bacteriostatic effect of cats product, it also has the effect of microbiostatic activity simultaneously, the total concn that the experiment proved that it and dodecyl dimethyl tertiary amine oxide had the expeling killing effect at 2 percent o'clock to parasitic ovum.The present invention selects for use cocamidopropyl betaine as main cleaning decontamination composition, is aided with sodium lauryl sulphate, polyoxyethylenated alcohol sodium sulfate etc. simultaneously and can removes difficult spot of cleaning, as the cigarette stain etc.Dodecyl dimethyl tertiary amine oxide and nonoxynolum have good wetting property and foaminess, also have stronger cleaning soil removability.One of membrane-forming agent that the present invention selects for use is degradable water-soluble high-molecular material chitin.It is because chitosan has favorable biological degradability as the main body of membrane-forming agent that the present invention selects chitosan for use, can protect environment preferably, and technology is not in the past being inquired into aspect the degradation property of film forming material.In 1% lactic acid aqueous solution of 2% chitosan, add SOD, fibroin, the silk peptide, hyaluronic acid, tartaric acid, squalane, protein-active materials such as Moisture factor, through stirring fast, chitosan and above-mentioned substance form oil-in-water structure, regulator solution is neutral alkali partially, chitosan is coating these protein-active materials and is flocculating, form microcapsule, make above-mentioned skin care support the skin composition at the making processes of hand-washing film and product between effective service life, remain higher activity, fully improve its availability, bring into play the effect that skin is supported in its skin care fully, simultaneously, because the raising of the availability of active substance descends the cost of product significantly.
The present invention is owing to adopted microcapsulary, and spices is coated by microcapsule, and spices is not volatilized in heat-processed in hand-washing film making processes, thereby can make product keep fragrance preferably, and the function that makes product remove peculiar smell is improved.
Water-soluble high-molecular material polyvinyl alcohol and the mixed film of polyoxyethylene with chitosan and low polymerization degree, can make film forming properties such as the tensile strength and the suppleness raising of product, add glycerine as solubility promoter and softening agent, can make hand-washing film have snappiness preferably, outward appearance is beautiful, practical.
Owing to adopted the scientific combination of above material, made hand-washing film is soft translucent laminar at normal temperatures, and the diaphragm physical behavior is good, and outward appearance is beautiful, has better water solubility.Be under 1: 1 the condition, can dissolve preferably in the quality of diaphragm and water.Hand-washing film can discharge its contained attached material when dissolving fully, because membrane-forming agent and tensio-active agent can compare film forming with 1: 1 quality, although diaphragm can do less being easy to carry, its decontamination is compared with traditional perfumed soap with sterilization effect, can meet or exceed traditional perfumed soap.If the skin composition not being supported in the skin care that adds is protected; this class material more easily runs off in the course of processing, owing to adopted microcapsulary, has fully kept skin care to support the activity of skin composition; improved the effective availability of this class material, skin care is supported the skin effect and is strengthened greatly.Filmogen is degradable water-soluble high-molecular material, can be biodegradable into glucosamine as chitin, polyvinyl alcohol can be aided with microbiological treatment and be degraded into carbonic acid gas and water under the daylight ultraviolet irradiation, the water-soluble hand-washing film can be considered Green Product fully.Use sterilant of the present invention can avoid the resistance that produces because of antibiotic use.
The sterilization effect of main component dodecyl dimethyl tertiary amine oxide of the present invention is confirmed by experiment.
Experimental example 1:
The dodecyl dimethyl tertiary amine oxide to intestinal bacteria,
Streptococcus aureus, Candida albicans quantitative disinfecting test report one, equipment
1, test strain: in the 7th generation of intestinal bacteria (8099), in the 7th generation of streptococcus aureus (ATCC6538), in the 6th generation of Candida albicans (ATCC10231), sterilization inspection center of preventive medicine academy of sciences provides.
2, sterilizing agent composition: dodecyl dimethyl tertiary amine oxide (hereinafter to be referred as TMT) (content is 1%).
3, balustrade composition: nonoxynolum (hereinafter to be referred as Np-9).
4, neutralizing agent composition: the PBS solution of 0.2% Yelkin TTS, 2.0% soil temperature-80,0.1% Sulfothiorine.
5, support methods is used in this experiment.Two, method
1, test basis: the Ministry of Health's " disinfection technology standard " (third edition) first fascicle 2＞6 in 1999.
2, sterilizing agent preparation:
A, get 30%TMT stoste, add polyvinyl alcohol-04, chitin lactic acid solution, skin care and support skin composition and spices, tensio-active agent cocamidopropyl methyl betaine, sodium lauryl sulphate, aliphatic alcohol polyethenoxy sodium sulfate etc., glycerol and make the content of above composition and be respectively 1%, 15%, 2.5%, 1.25%, 20%, 3% solution.PH6.5
B, change the content of the TMT in the above-mentioned solution into 0.5%, other adds Np-9 content is 0.5%, PH6.5.
C, above two kinds of solution for later use.
3, bactericidal assay: test temperature 20 degree, sterilizing agent test use respectively that the content of TMT is 1% and 0.5%, the content of TMT and Np-9 content respectively are 0.5% soup, and test repeats 3 times.
4, bacteria suspension, carrier-pellet preparation, viable bacteria are cultivated counting respectively with reference to the Ministry of Health's " disinfection technology standard " (third edition) first fascicle 22 in 1999.
Three, result
Test repeats 3 times under temperature 20 degree conditions, and experimental result shows that experiment is 1% solution effects 1 minute with the content of sterilizing agent TMT, and the killing rate of intestinal bacteria, streptococcus aureus, Candida albicans is all reached 99.90%; Experiment is 0.5% solution effects 1 minute with the content of sterilizing agent TMT, to the killing rate of intestinal bacteria, streptococcus aureus, Candida albicans all reach 98.50% experiment with the content of sterilizing agent TMT be 0.5%, Np-9 content is 0.5% solution effects 1 minute, and the killing rate of intestinal bacteria, streptococcus aureus, Candida albicans is all reached 99.90%.
Four, conclusion
Test-results shows, the dodecyl dimethyl tertiary amine oxide is 1% o'clock in strength of solution, intestinal bacteria, streptococcus aureus, Candida albicans there is good killing effect: the concentration of dodecyl dimethyl tertiary amine oxide is reduced at 0.5% o'clock, because the nonoxynolum of adding 0.5%, the sterilization effect of dodecyl dimethyl tertiary amine oxide and its concentration are that 1% o'clock sterilization effect is identical, and this result shows that nonoxynolum has played the support effect to the sterilization effect of dodecyl dimethyl tertiary amine oxide.
Embodiment:
Chitin 10 gram is dissolved in makes viscous solution A in 100 milliliter of 1% lactic acid aqueous solution and get the above-mentioned solution of 10 grams and be diluted to 75 milliliters with 1% lactic acid solution, add skin care and support skin composition 5 grams, add 20 gram soap perfumes simultaneously, stirred 30 minutes fast, use 1% sodium hydrate regulator solution to neutral alkali partially simultaneously, make chitosan and skin care support skin composition and spices formation microcapsule solution B; 600 ml waters are heated to 70 degree, get each 300 gram of polyvinyl alcohol and polyoxyethylene and add, fully stirring and dissolving is made translucent solution C, filters; With various tensio-active agent quality in sodium lauryl sulphate: polyoxyethylenated alcohol sodium sulfate: the ratio of cocamidopropyl betaine=1: 2: 3, the total amount of three kinds of compositions is that 350 grams add in 500 ml waters, heating is until dissolving.Add each 25 gram of dodecyl dimethyl tertiary amine oxide and nonoxynolum, fully stir, make solution D; Above-mentioned four kinds of solution are mixed, stir, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the sheet glass, and heating, drying can obtain thickness and be 0.05 millimeter flexible film.Film is taken off from sheet glass, cut, pack and make finished product.
Claims (6)
1, a kind of hand-washing film with cleaning, sterilization, skin care effect is characterized in that this hand-washing film made by following raw material:
Dodecyl dimethyl tertiary amine oxide 10-40 weight part
Nonoxinol 10-40 weight part
Cocamidopropyl betaine 80-200 weight part
Sodium lauryl sulphate 20-60 weight part
Polyoxyethylenated alcohol sodium sulfate 60-130 weight part
Chitin 5-15 weight part
Fibroin 1-10 weight part
Soap perfume 10-40 weight part
Polyvinyl alcohol 100-400 weight part
Polyoxyethylene 100-400 weight part
2, hand-washing film as claimed in claim 1 is characterized in that this hand-washing film made by following raw material:
Dodecyl dimethyl tertiary amine oxide 25 weight parts
Nonoxynolum 25 weight parts
Cocamidopropyl betaine 176 weight parts
Sodium lauryl sulphate 58 weight parts
Polyoxyethylenated alcohol sodium sulfate 116 weight parts
Chitin 10 weight parts
Fibroin 5 weight parts
Soap perfume 20 weight parts
Polyvinyl alcohol 300 weight parts
Polyoxyethylene 300 weight parts
3, hand-washing film as claimed in claim 1 or 2 is characterized in that the fibroin that uses in this hand-washing film can use SOD, silk peptide, tartaric acid, Moisture factor or squalane to substitute.
4, the preparation method of hand-washing film as claimed in claim 1 or 2, it is characterized in that this method is: chitin 10 gram is dissolved in makes viscous solution A in 100 milliliter of 1% lactic acid aqueous solution and get the above-mentioned solution of 10 grams and be diluted to 75 milliliters with 1% lactic acid solution, add skin care and support skin composition 5 grams, add 20 gram soap perfumes simultaneously, stirred 30 minutes fast, use 1% sodium hydrate regulator solution to neutral alkali partially simultaneously, make chitosan and skin care support skin composition and spices formation microcapsule solution B; 600 ml waters are heated to 70 degree, get each 300 gram of polyvinyl alcohol and polyoxyethylene and add, fully stirring and dissolving is made translucent solution C, filters; With various tensio-active agent quality in sodium lauryl sulphate: polyoxyethylenated alcohol sodium sulfate: the ratio of cocamidopropyl betaine=1: 2: 3, the total amount of three kinds of compositions is that 350 grams add in 500 ml waters, heating is until dissolving; Add each 25 gram of dodecyl dimethyl tertiary amine oxide and nonoxynolum, fully stir, make solution D; Above-mentioned four kinds of solution are mixed, stir, stand-by; The thickness of above-mentioned solution with 0.10 millimeter is uniformly coated on the sheet glass, and heating, drying can obtain thickness and be 0.05 millimeter flexible film; Film is taken off from sheet glass, cut, pack and make finished product.
5, the dodecyl dimethyl tertiary amine oxide has application in the sterilizing agent of germicidal action in preparation.
6, the dodecyl dimethyl tertiary amine oxide has application in the medicine of germicidal action in preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02100367XA CN1142264C (en) | 2002-01-15 | 2002-01-15 | Completely water-soluble hand-washing film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02100367XA CN1142264C (en) | 2002-01-15 | 2002-01-15 | Completely water-soluble hand-washing film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1362504A true CN1362504A (en) | 2002-08-07 |
| CN1142264C CN1142264C (en) | 2004-03-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB02100367XA Expired - Fee Related CN1142264C (en) | 2002-01-15 | 2002-01-15 | Completely water-soluble hand-washing film |
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| CN (1) | CN1142264C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20313248U1 (en) * | 2003-08-27 | 2005-01-05 | Melitta Haushaltsprodukte Gmbh & Co Kommanditgesellschaft | Cleaning agent for spectacle lenses comprises water-soluble film containing embedded tensides which are released as film dissolves |
| CN100457883C (en) * | 2004-03-16 | 2009-02-04 | 武汉市科龙科技开发有限公司 | Formula of fancy soap in plant paper type and producing techmique |
| EP1556006A4 (en) * | 2002-10-09 | 2009-08-19 | Dial Corp | Water soluble sheet composition |
| CN101085850B (en) * | 2006-06-05 | 2011-03-16 | 许秀峰 | Degradable water soluble packaging film |
| CN108721124A (en) * | 2017-04-14 | 2018-11-02 | 滕州市悟通香料有限责任公司 | A kind of portable handguard piece |
| CN109715772A (en) * | 2016-09-06 | 2019-05-03 | 塞鲁贝股份公司 | The detergent composition of sheet-form |
| CN113004991A (en) * | 2011-05-13 | 2021-06-22 | Lg生活健康株式会社 | Washing sheet |
| CN113462483A (en) * | 2021-07-06 | 2021-10-01 | 株洲蓝海包装有限公司 | Disinfection and sterilization hand washing film and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100357417C (en) * | 2005-05-10 | 2007-12-26 | 刘桂堂 | Concentrated solution for washing and preparation method thereof |
-
2002
- 2002-01-15 CN CNB02100367XA patent/CN1142264C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1556006A4 (en) * | 2002-10-09 | 2009-08-19 | Dial Corp | Water soluble sheet composition |
| DE20313248U1 (en) * | 2003-08-27 | 2005-01-05 | Melitta Haushaltsprodukte Gmbh & Co Kommanditgesellschaft | Cleaning agent for spectacle lenses comprises water-soluble film containing embedded tensides which are released as film dissolves |
| CN100457883C (en) * | 2004-03-16 | 2009-02-04 | 武汉市科龙科技开发有限公司 | Formula of fancy soap in plant paper type and producing techmique |
| CN101085850B (en) * | 2006-06-05 | 2011-03-16 | 许秀峰 | Degradable water soluble packaging film |
| CN113004991A (en) * | 2011-05-13 | 2021-06-22 | Lg生活健康株式会社 | Washing sheet |
| CN109715772A (en) * | 2016-09-06 | 2019-05-03 | 塞鲁贝股份公司 | The detergent composition of sheet-form |
| CN108721124A (en) * | 2017-04-14 | 2018-11-02 | 滕州市悟通香料有限责任公司 | A kind of portable handguard piece |
| CN113462483A (en) * | 2021-07-06 | 2021-10-01 | 株洲蓝海包装有限公司 | Disinfection and sterilization hand washing film and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1142264C (en) | 2004-03-17 |
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Granted publication date: 20040317 Termination date: 20100222 |