CN1347646A - No-tillage rice field herbicide and preparation method thereof - Google Patents
No-tillage rice field herbicide and preparation method thereof Download PDFInfo
- Publication number
- CN1347646A CN1347646A CN 00119017 CN00119017A CN1347646A CN 1347646 A CN1347646 A CN 1347646A CN 00119017 CN00119017 CN 00119017 CN 00119017 A CN00119017 A CN 00119017A CN 1347646 A CN1347646 A CN 1347646A
- Authority
- CN
- China
- Prior art keywords
- bensulfuron
- methyl
- white carbon
- isopropyl amine
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000007164 Oryza sativa Nutrition 0.000 title claims abstract description 34
- 235000009566 rice Nutrition 0.000 title claims abstract description 34
- 238000003971 tillage Methods 0.000 title claims abstract description 31
- 239000004009 herbicide Substances 0.000 title claims abstract description 30
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 26
- 240000007594 Oryza sativa Species 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims abstract description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000005472 Bensulfuron methyl Substances 0.000 claims abstract description 42
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000006229 carbon black Substances 0.000 claims abstract description 39
- 241000209094 Oryza Species 0.000 claims abstract description 33
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 239000003463 adsorbent Substances 0.000 claims abstract description 3
- 235000019241 carbon black Nutrition 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 24
- 238000010521 absorption reaction Methods 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 238000009313 farming Methods 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 10
- -1 Doule Chemical compound 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 2
- YLPGTOIOYRQOHV-UHFFFAOYSA-N Pretilachlor Chemical compound CCCOCCN(C(=O)CCl)C1=C(CC)C=CC=C1CC YLPGTOIOYRQOHV-UHFFFAOYSA-N 0.000 abstract 1
- 238000010899 nucleation Methods 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 229960001413 acetanilide Drugs 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 238000009333 weeding Methods 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 1
- 239000005562 Glyphosate Substances 0.000 description 1
- QPJVMBTYPHYUOC-UHFFFAOYSA-N Methyl benzoate Natural products COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 1
- 125000006598 aminocarbonylamino group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A no-tillage rice field herbicide and a manufacturing method thereof relate to a herbicide suitable for being applied before seeding of a no-tillage rice field and a production method thereof. It contains bensulfuron-methyl, butachlor or its analogue pretilachlor, Doule, glyphosate isopropylamine salt and adsorbent white carbon black, in which the weight ratio of bensulfuron-methyl effective component to butachlor and glyphosate isopropylamine salt effective active component is 1: 2-100: 10-250, and the weight ratio of bensulfuron-methyl to white carbon black is 1: 1-300. The invention has the advantages that the weeds in the rice field before and after the no-tillage rice field is sown can be solved by applying the pesticide once, and the no-tillage rice cultivation technology can be simplified.
Description
The present invention relates to a kind of weed killer herbicide and production method thereof, particularly a kind of weed killer herbicide and production method that is suitable for no-tillage paddy field.
Existing steriland herbicide glyphosate, glyphosate isopropyl amine salt and gram do not have track and all only can kill the weeds that germinated before no-tillage ground paddy rice is broadcast, and be then invalid to the weeds that sprout behind the rice growing; Existing other herbicides for use in paddy can only kill and wound the weeds seedling of firm sprouting, then can not prevent and kill off the weeds that have been grown in the field before sowing.
The objective of the invention is: a kind of herbicide for zero-tillage rice field and manufacture method thereof are provided, this weed killer herbicide can not only be killed the residual weeds of the preceding stubble of zero-tillage rice field, can prevent and kill off simultaneously single broadleaf weed of field germinating behind seed rice premature rice again, solving zero-tillage rice field needs first stubble-cleaning to sow the difficult problem of weeding again, simplifies no-tillage rice culture technology.
Technical scheme of the present invention is: a kind of herbicide for zero-tillage rice field includes Bensulfuron-methyl, butachlor or the isoreagent third careless amine, Dou Er, the white carbon black of glyphosate isopropyl amine salt and adsorbent, wherein Bensulfuron-methyl effective active components and butachlor or the isoreagent third careless amine, Dou Er, the weight ratio of glyphosate isopropyl amine salt effective active components is 1: 2-100: 10-250, Bensulfuron-methyl is 1 with the weight ratio of white carbon black: 1-300.
Butachlor is Chinese common name, and chemical name is: N-(fourth oxygen methyl)-a-chloro-2 ', and 6 ' one diethyl acetanil, molecular formula is C
17H
26CINO
2Structural formula is:
Bensulfuron-methyl is Chinese common name, and chemical name is: 2-{[(4,6-dimethoxypyridin-2-yl) amino carbonyl amino] the sulfonyl methyl } methyl benzoate, molecular formula is: C
16H
18N
4O
7The S structural formula is:
The third careless amine is Chinese common name, and chemical name is: N-(the 2-third oxygen ethyl)-a-chloro-2 ', and 6 ' one diethyl acetanil, molecular formula is C
17H
26CINO
2Structural formula is:
All you are the trade name of isopropyl methoxalamine, and isopropyl methoxalamine is Chinese common name, and chemical name is: N-(1-methyl, 2-methoxy ethyl)-2-ethyl, and 6-methyl-nitrogen-chloro acetanilide, structural formula is:
Glyphosate isopropyl amine salt is Chinese common name, and chemical name is: N-phosphine carboxymerhyl-glycine isopropyl amine salt, molecular formula is: C
6H
17N
2O
5P
When calculating proportioning, press the content of Bensulfuron-methyl in the Bensulfuron-methyl pulvis, the content of butachlor in the butachlor ec, the content meter of glyphosate isopropyl amine salt claims in the glyphosate isopropyl amine salt pulvis.The metering of butachlor isoreagent is also like this.
Butachlor can adopt commercially available homemade 60% butachlor ec, contains butachlor effective ingredient 60 grams in promptly per 100 gram butachlor ecs.
Bensulfuron-methyl can adopt commercially available homemade 10% Bensulfuron-methyl pulvis, contains Bensulfuron-methyl effective ingredient 10 grams in promptly per 100 gram Bensulfuron-methyl pulvis.
41,%00 grass that glyphosate isopropyl amine salt can adopt commercially available homemade commodity 41% glyphosate isopropyl amine salt pulvis or chemical plant, Suzhou to produce, 41% farming clear or that U.S. Monsanto Company produces reaches or with the former powder processing of glyphosate isopropyl amine salt, as 1 kilogram of glyphosate isopropyl amine salt pulvis or hundred grass are clear or farming contains glyphosate isopropyl amine salt effective ingredient 410 grams in reaching.
A kind of herbicide for zero-tillage rice field also includes filler precipitated calcium carbonate or diatomite or kaolin or activated carbon or potter's clay, and the weight ratio of glyphosate isopropyl amine salt and above-mentioned filler is 1: 0.2-5.
A kind of manufacture method of herbicide for zero-tillage rice field, earlier load weighted butachlor ec makes it be adsorbed in load weighted by weight ratio fineness with spray-on process to pass through in the white carbon black of 250 purposes 95% or more by weight ratio, stir white carbon black while spraying, and then, get finished product with it and by the good glyphosate isopropyl amine salt pulvis uniform mixing of proportioning weight weighing.
Major advantage of the present invention is: is applicable to zero-tillage rice field sowing previous crops one-time weeding, can effectively goes out to remove and broadcast preceding weeds in field, can prevent and kill off the weeds of broadcasting the back germinating again, and broad weed-killing spectrum, preventive effect is good, can simplify the zero-tillage rice field culture technique.
Embodiment 1:
A kind of herbicide for zero-tillage rice field includes Bensulfuron-methyl, butachlor, glyphosate isopropyl amine salt and white carbon black, wherein the weight ratio of Bensulfuron-methyl and butachlor and glyphosate isopropyl amine salt effective ingredient is 1: 5-9520-200, Bensulfuron-methyl is 1 with the weight ratio of white carbon black: 1.5-200.
Embodiment 2:
With the difference of embodiment 1 be: the weight ratio of Bensulfuron-methyl and butachlor and glyphosate isopropyl amine salt effective ingredient is 1: 3: 150, and Bensulfuron-methyl is 1: 100 with the weight ratio of white carbon black.
Embodiment 3:
With the difference of embodiment 1 or 2 be: the weight ratio of Bensulfuron-methyl and butachlor and glyphosate isopropyl amine salt effective ingredient is 1: 90: 200, and Bensulfuron-methyl is 1: 30 with the weight ratio of white carbon black.
Embodiment 4:
A kind of manufacture method of herbicide for zero-tillage rice field is: the 60% butachlor ec 30ml that will contain 18.0 gram butachlors earlier, adopting spray-on process to make it be adsorbed in fineness restrains in the white carbon black by 250 purposes 100 more than 95%, stir white carbon black while spraying, the consumption of white carbon black is as the criterion can satisfy the used butachlor ec of absorption, can be greater or less than 100 grams, to exceed can satisfy the absorption butachlor ec when being less than 100 grams, make missible oil absorption evenly, mix with 10% Bensulfuron-methyl pulvis, 10 grams that contain Bensulfuron-methyl 1 gram and 41% glyphosate isopropyl amine salt pulvis, 40 grams that contain 16.4 gram glyphosate isopropyl amine salts again, finished product.
The content of Bensulfuron-methyl effective ingredient differs and is decided to be 10% in the Bensulfuron-methyl pulvis, also can adopt the Bensulfuron-methyl pulvis of other content, but should calculate by the amount of Bensulfuron-methyl effective ingredient during proportioning, the content of effective ingredient differs and is decided to be 41% in the glyphosate isopropyl amine salt pulvis, also can adopt the glyphosate isopropyl amine salt pulvis of other content, or with the processing of the former powder of glyphosate isopropyl amine salt, but should calculate by the amount of glyphosate isopropyl amine salt effective ingredient during proportioning; Butachlor in the butachlor ec differs and is decided to be 60%, also can adopt the butachlor ec of other content, but should calculate by the amount of butachlor effective ingredient during proportioning.
Embodiment 5:
As different from Example 4: a kind of manufacture method of herbicide for zero-tillage rice field is the 60% butachlor ec 150ml that will contain 90 gram butachlors earlier, reach aqua or hundred careless water cleaning agent 250ml with 41% farming that contains 102.5 gram glyphosate isopropyl amine salts, adopting spray-on process to make it be adsorbed in fineness respectively restrains in the white carbon black by 250 purposes, 350 gram white carbons and 600 more than 95%, stir white carbon black while spraying, the consumption principle of white carbon black and embodiment 4 are mutually, after making it absorption evenly, again two kinds of absorption powder and 10% Bensulfuron-methyl pulvis, 40 grams that contain 4 gram Bensulfuron-methyls are mixed, get finished product.
Embodiment 6:
Different with embodiment 4 or 5 is: a kind of manufacture method of herbicide for zero-tillage rice field is earlier the former medicine processing of glyphosate isopropyl amine salt to be become the 80% glyphosate isopropyl amine salt pulvis that contains glyphosate isopropyl amine salt 80 grams in per 100 grams, the 60% butachlor ec 80ml that will contain 48 gram butachlors simultaneously, adopting spray-on process to make it be adsorbed in fineness restrains in the white carbon black by 250 purposes 200 more than 95%, stir white carbon black while spraying, the consumption principle of white carbon black is identical with embodiment 4, after making it absorption evenly, with itself and 10% Bensulfuron-methyl pulvis, 50 grams that contain Bensulfuron-methyl 5 grams, 80% glyphosate isopropyl amine salt pulvis, 130 grams that contain glyphosate isopropyl amine salt 104 grams mix, and get finished product.
Embodiment 7:
Different with embodiment 4,5 or 6 is: in embodiment 4 or 5 or 6 gained finished products, add glyphosate isopropyl amine salt weight 0.2-5 respectively doubly, fineness is that 95% powder is crossed 250 purpose precipitated calcium carbonates or diatomite, kaolin, activated carbon, potter's clay powder as filler, stir, finished product.
Embodiment 8:
As different from Example 4, a kind of manufacture method of herbicide for zero-tillage rice field is the 50% the third careless amine missible oil 120ml that will contain 60 grams, the third careless amine earlier, reach aqua or hundred careless water cleaning agent 200ml with 41% farming that contains 82 gram glyphosate isopropyl amine salts, adopting spray-on process to make it be adsorbed in fineness respectively restrains in the white carbon black by 250 purposes, the 300 white carbon blacks of gram and 500 more than 95%, stir white carbon black while spraying, the consumption principle of white carbon black is identical with embodiment 4, after making it absorption evenly, again two kinds of absorption powder and 10% Bensulfuron-methyl pulvis, 30 grams that contain 3 gram Bensulfuron-methyls are mixed, get finished product.
The 50% the third careless amine missible oil also available 50% are auspicious to fly special missible oil, and wherein every 100ml includes isopropyl methoxalamine effective ingredient 50 grams.Certainly the third careless amine content in the oil slick can not be 50% also, is as the criterion with the third careless amine during metering.
Embodiment 9: as different from Example 4, a kind of manufacture method of herbicide for zero-tillage rice field is: 72% your missible oil 50ml all that will contain 36 gram isopropyl methoxalamines earlier, reach aqua or hundred careless water cleaning agent 300ml with 41% farming that contains 123 gram glyphosate isopropyl amine salts, adopting spray-on process to make it be adsorbed in fineness respectively restrains in the white carbon black by 250 purposes, the 150 white carbon blacks of gram and 700 more than 95%, stir white carbon black while spraying, the consumption principle of white carbon black is identical with embodiment 4, after making it absorption evenly, again two kinds of absorption powder and 10% Bensulfuron-methyl pulvis, 50 grams that contain 5 gram Bensulfuron-methyls are mixed, get finished product.
Claims (8)
1, a kind of herbicide for zero-tillage rice field, it is characterized in that: include Bensulfuron-methyl, butachlor, the white carbon black of glyphosate isopropyl amine salt and adsorbent, wherein the weight ratio of Bensulfuron-methyl effective active components and butachlor or the isoreagent third careless amine, Dou Er, glyphosate isopropyl amine salt effective active components is 1: 2-100: 10-250, Bensulfuron-methyl is 1 with the weight ratio of white carbon black: 1-300.
2, according to the described a kind of herbicide for zero-tillage rice field of claim 1, it is characterized in that: the weight ratio of Bensulfuron-methyl and butachlor and glyphosate isopropyl amine salt effective ingredient is 1: 5-95: 20-200, Bensulfuron-methyl is 1 with the weight ratio of white carbon black: 1.5-200.
3, according to claim 1 or 2 described a kind of herbicide for zero-tillage rice field, it is characterized in that: also include filler precipitated calcium carbonate or diatomite or kaolin or activated carbon or potter's clay, the weight ratio of glyphosate isopropyl amine salt and filler is 1: 0.2-5.
4, a kind of manufacture method of herbicide for zero-tillage rice field, it is characterized in that: earlier will load weighted by weight ratio butachlor ec adopt spray-on process to make it be adsorbed in load weighted by weight ratio fineness and pass through in the white carbon black of 250 purposes 95% or more, stir white carbon black while spraying, and then, get finished product with it and by good Bensulfuron-methyl pulvis and the uniform mixing of glyphosate isopropyl amine salt pulvis of proportioning weight weighing.
5, according to the manufacture method of the described a kind of herbicide for zero-tillage rice field of claim 4, it is characterized in that: the 60% butachlor ec 30ml that will contain 18.0 gram butachlors earlier, adopting spray-on process to make it be adsorbed in fineness restrains in the white carbon black by 250 purposes 100 more than 95%, stir white carbon black while spraying, after making absorption evenly, mix with 10% Bensulfuron-methyl pulvis, 10 grams that contain Bensulfuron-methyl 1 gram and 41% glyphosate isopropyl amine salt pulvis, 40 grams that contain 16.4 gram glyphosate isopropyl amine salts again, finished product.
6, according to the manufacture method of the described a kind of herbicide for zero-tillage rice field of claim 4, it is characterized in that: the 60% butachlor ec 150ml that will contain 90 gram butachlors earlier, reach aqua 250ml with 41% farming that contains 102.5 gram glyphosate isopropyl amine salts, adopting spray-on process to make it be adsorbed in fineness respectively restrains in the white carbon black by 250 purposes, the 350 white carbon blacks of gram and 600 more than 95%, stir white carbon black while spraying, after making it absorption evenly, again two kinds of absorption powder and 10% Bensulfuron-methyl pulvis, 40 grams that contain 4 gram Bensulfuron-methyls are mixed, get finished product.
7, manufacture method according to the described a kind of herbicide for zero-tillage rice field of claim 4, it is characterized in that: earlier the former medicine processing of glyphosate isopropyl amine salt is become the 80% glyphosate isopropyl amine salt pulvis that contains glyphosate isopropyl amine salt 80 grams in per 100 grams, the 60% butachlor ec 80ml that will contain 48 gram butachlors simultaneously, adopting spray-on process to make it be adsorbed in fineness restrains in the white carbon black by 250 purposes 200 more than 95%, stir white carbon black while spraying, after making it absorption evenly, with itself and 10% Bensulfuron-methyl pulvis, 50 grams that contain Bensulfuron-methyl 5 grams, 80% glyphosate isopropyl amine salt pulvis, 130 grams that contain glyphosate isopropyl amine salt 104 grams mix, and get finished product.
8, according to the manufacture method of claim 4 or 5,6,7 described a kind of herbicide for zero-tillage rice field, it is characterized in that: in finished product, add glyphosate isopropyl amine salt weight 0.2-5 fineness doubly again and be 95% powder and cross 250 purpose precipitated calcium carbonates or diatomite or kaolin or activated carbon or potter's clay and make filler, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00119017 CN1347646A (en) | 2000-10-10 | 2000-10-10 | No-tillage rice field herbicide and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00119017 CN1347646A (en) | 2000-10-10 | 2000-10-10 | No-tillage rice field herbicide and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1347646A true CN1347646A (en) | 2002-05-08 |
Family
ID=4587413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00119017 Pending CN1347646A (en) | 2000-10-10 | 2000-10-10 | No-tillage rice field herbicide and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1347646A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100356847C (en) * | 2006-03-10 | 2007-12-26 | 廖克祥 | Weeding pesticide-added fertilizer for paddy and method for preparing the same |
-
2000
- 2000-10-10 CN CN 00119017 patent/CN1347646A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100356847C (en) * | 2006-03-10 | 2007-12-26 | 廖克祥 | Weeding pesticide-added fertilizer for paddy and method for preparing the same |
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