CN1346308A - Moldable composite article and method of manufacture - Google Patents
Moldable composite article and method of manufacture Download PDFInfo
- Publication number
- CN1346308A CN1346308A CN00805961A CN00805961A CN1346308A CN 1346308 A CN1346308 A CN 1346308A CN 00805961 A CN00805961 A CN 00805961A CN 00805961 A CN00805961 A CN 00805961A CN 1346308 A CN1346308 A CN 1346308A
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- cloth
- layer
- goods
- shaped
- variable compressive
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- 239000002131 composite material Substances 0.000 title claims description 43
- 238000000034 method Methods 0.000 title description 10
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000004744 fabric Substances 0.000 claims abstract description 100
- 239000000126 substance Substances 0.000 claims abstract description 3
- 238000003825 pressing Methods 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 15
- 229920000728 polyester Polymers 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 7
- 238000001467 acupuncture Methods 0.000 claims description 5
- 238000010998 test method Methods 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims 2
- 238000007493 shaping process Methods 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract description 5
- 238000007906 compression Methods 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 64
- 239000012790 adhesive layer Substances 0.000 description 12
- 239000003351 stiffener Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 239000002346 layers by function Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 241000272470 Circus Species 0.000 description 1
- 241000876833 Emberizinae Species 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000881 depressing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
- B60R13/0212—Roof or head liners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/738—Thermoformability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/003—Interior finishings
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Nonwoven Fabrics (AREA)
Abstract
An article (1) which includes a layer of formable fabric (5) of the type which when subjected to molding under heat and/or pressure possesses a high degree of stiffness. A layer of variable compression fabric (2) capable of assuming variable thickness when subjected to molding under heat and/or pressure is bonded to the surface of the formable fabric (5), where the layers are made of the same thermoformable polymeric chemical substance.
Description
The cross reference of related application
The application is the part continuation application of the Application No. 08/839,016 submitted on April 23rd, 1997, and its whole contents is hereby incorporated by.
Background of invention
The present invention relates to a kind of composite article on the whole, and more specifically to a kind of moldable non-woven fibre composite article.
Preparation have contain sufficient intensity and rigidity with goods process as the polymeric material of body of a motor car liner in, be well known that, produce the sheet material of thermoformable material with different performance, they are processed into stratiform, and then the heating and add depress them compressed together in mould.At least use one deck to give the discrete material that strength and stiffness and another layer generation are enough to be used in mold pressing.United States Patent (USP) 5,298,319 disclose from skin and have made the body of a motor car liner for nonwoven and the intermediate layer be made up of the polypropylene staple fibre basically for extruding polyacrylic filamentary composites.This kind prior art fibrous composite is to make up with extruding simultaneously of intermediate layer polypropylene layer.The polypropylene surface that two outer field inner surfaces of nonwoven are extruded by being thermally bonded to of producing in expressing technique and the adjacently situated surfaces of fusion in this technology become molten state subsequently.Use contains three layers of same polymer (being polypropylene), helps finally recycling of resulting product.
In the method for this prior art, there are several intrinsic shortcomings.Be extruded because give the intermediate layer of the necessary discrete material of mold pressing, the goods of mold pressing must be to have homogeneous thickness thus.Another weakness is that fibrous composite must make up with extruding simultaneously of intermediate layer.
Summary of the invention
Therefore, an object of the present invention is to provide a kind of improved moldable fibrous composite, it can be used for preparing the pressing of different-thickness and density.
Another object of the present invention provides a kind of improved moldable composite of being made up of the layer of amalgamation successively.
Another purpose of the present invention provides a kind of improved moldable fibrous composite of being made by the compatible material that can easily recycle.
A further object of the present invention provides a kind of non-woven fibre composite that mold pressing has the goods of high thickness weight ratio that can be used in.
Also purpose of the present invention provides a kind of improved fibrous composite, and when mold pressing under heating and pressurization, it becomes the shape of mould easily and can not rupture or tear.
Of the present inventionly advance a purpose and provide and a kind ofly can be used in articles thermoformed therefrom and do not need the improved moldable fibrous composite of injecting resin.
For realizing aforementioned and other purpose and the shortcoming that overcomes above-mentioned prior art, from specifically and in a broad aspect the invention provides a kind of moldable non-woven fibre composite and preparation method thereof.Non-woven fibre composite according to the present invention has at least two functional layers, and this is two-layer all to be to be made by the non-woven polymer chemical substance or the material of identical thermoformable.The suitable polymers material comprises polypropylene, polyvinyl chloride, polyvinyl acetate, polyamide, polyvinyl alcohol, polyethylene, polyurethane and polyester.In a preferred embodiment, this two-layer be to make by polyester.These composites can be used for usually but are not limited to prepare automotive headliners, lining of car body, main cabin goods, luggage, furniture, motion goods and filtration article.
Selected polymer chemistry material is to make two kinds of different cloth with difference and/or other physical property.At least a cloth is shapable cloth, and it is in heating and/or add the die forming of depressing by final, has the intensity and the hardness of higher degree.Another kind of cloth is a kind of transformable compression cloth (also being referred to as the cloth of variable thickness), and when mold pressing under heating and/or pressurization, it can have variable thickness and density.Require end article to have in the purposes of uniform thickness and density at some, also can use this variable compression cloth.The variable compression cloth of this kind is U.S. Patent number 5,532,050 theme, and it is hereby incorporated by.In another embodiment, another layer that constitutes surperficial layer of cloth can be applied to be used to improve by the outward appearance of the goods of described composite the outer surface of one deck.Functional layer becomes with surperficial layer of cloth capable assembling can be as the composite of the shapable finished product of preparation.Terminology used here " composite " comprises the pantostrat of any accumulation, no matter bonding whether the raising by chemistry and/or physics mode between these layers.The composite adjacent layer bonding can by bonding such as the spraying powder, use liquid dispersion/solution, pressing, flame laminating, between functional layer, use the technology intermediate adhesion cloth and the mechanical acupuncture to be enhanced, all these all are that the one skilled in the art knows.
In this notion, what also comprise is another embodiment, the blend that wherein has the selected fiber of predetermined melt temperature scope be included in the hardness that influences the bonding and final pressing between each layer of composite one deck or two-layer in.This mechanism of bonding generation is to be referred to as " thermoplastic bonded " and is to be described in United States Patent (USP) 5,456,976 more fully that 3, the 36-50 are capable on the hurdle, and its reference content is hereby incorporated by.Sheet material with composite is placed in the mould then, and heating and/or press molding to be obtaining the shape of die cavity, and forms the resultant articles shape thus.
Brief description of drawings
In order to understand essence of the present invention and purpose more fully, should be with reference to the detailed description of implementing preference pattern of the present invention, the while is with reference to accompanying drawing, wherein:
Fig. 1 is the perspective view of the moldable fibrous composite of one embodiment of the invention, has shown its stratiform configuration.
Fig. 2 be preparation another embodiment of the invention the schematically illustrating of system of pressing.
Detailed description of the present invention
Now describe the present invention in detail with reference to specific embodiment and accompanying drawing.
According to the present invention, goods are to be made by each coiled material or the sheet material of variable compressive and the layer of cloth mold pressing that can be shaped respectively.As shown in Figure 2, the cloth that can be shaped (25 and 26) is to be folded down from deflector roll (being respectively 29 and 32), and variable compression cloth (28) is to be folded down from deflector roll (31), and optionally, surperficial layer of cloth is from deflector roll (30).These layer of cloths are from their deflector rolls separately are fed through the have top die device of (33) and bottom (34), as shown in Figure 2.
Car roof is by each layer of the variable compressive cloth and the cloth (they contain binder fiber) that can be shaped is suppressed film (shape of its die cavity is exactly the shape of inside roof lining) by one, because the coiled material of composite does not batch.In order to implement mold pressing, composite is to stand the high temperature of scheduled time length and cool off in mould then.Adhesive fiber in each layer is softening and/or fusion and mixing mutually under heat and/or pressure, and by the demoulding, binder fiber will cool off and harden and each layer is bonded together.
According to another embodiment, can be shaped and variable compressive layer of cloth and optionally surperficial layer of cloth before making goods, be to form a composite.
With reference to Fig. 1, it has shown each layer, and it comprises composite article of the present invention.For easy explanation, the thickness of each layer does not draw according to scale.
In Fig. 1, the composite article (1) that comprises variable compressive cloth is to be clipped in the be shaped layer of cloth (5) of have upper surface (6) and lower surface (7), and have between the be shaped layer of cloth (8) of upper surface (9) and lower surface (10), last adhesive layer (14) and following adhesive layer (11) are to be embedded in variable compressive layer of cloth (2) respectively and can be shaped between layer of cloth (5) and (8), so that the upper surface of variable compressive layer (2) is near the lower surface of adhesive layer (14), and the upper surface (15) of adhesive layer (14) is close to the lower surface (7) of layer of cloth (5) that can be shaped, and the lower surface (4) of the upper surface (12) of adhesive layer (11) next-door neighbour's variable compressive layer (2), and can the be shaped upper surface (9) of layer of cloth (8) of the lower surface (13) of adhesive layer (11) next-door neighbour has improved bonding between layer of cloth (5) and the variable compressive layer (2) of can being shaped thus.
Aforesaid embodiment can be applied to the upper surface (6) of layer of cloth (5) that can be shaped and modification with the lower surface (19) of surperficial layer of cloth (17) by utilizing adhesive layer (20), so that the upper surface (21) of the lower surface (19) of surperficial layer of cloth (17) next-door neighbour's adhesive layer (20), and the lower surface (22) of adhesive layer (20) is close to the upper surface (6) of layer of cloth (5) that can be shaped, and has improved the outward appearance of the outer surface of composite and pressing thereof thus.Automobile liner or lining of car body can be shaped by this composite is passed die arrangement then, and make this composite stand high temperature and/or high pressure, and its time is to be enough to make this composite to form the shape of described die cavity.
In order to be used for the present invention, found that the basic weight of the cloth that can be shaped or harden should be the 4-18 ounce per square yard.Preferred range is the 6-12 ounce per square yard.The best of breed of the economy of the controlled hardness performance of feel, mold pressing finished product and preparation finished product when these scopes obtain preparing.
In another embodiment of the invention, the sheet material of polyester variable compressive cloth is between two sheet materials that are mixed in to the be shaped polyester of needle punched felt shape, makes with composite product thus.Described needle punched felt is the Knowlton Nonwovens Inc's manufacturing by the New York Utica.Cohesive between the adjacent sheet is to improve by mechanical acupuncture.Then composite is rolled into the storage coiled material.Can be with one deck bunting, such as the loop bonding polyester or the Foss needle-punching polyester of HOF AHMV8 printing, be applied to one deck and can be shaped on the outer surface of mylar.
A kind of goods, for example body of a motor car liner or inside roof lining are in heating and/or add to depress in mould and form.Then pressing is cooled to environment temperature.Above-mentioned US5,298,319 teachings be used to prepare the basic mould pressing method and the equipment of the goods of the alleged type of the present invention, and draw at this and to be reference.
It should be understood that improving fusible distinct methods can use having between the different layer of cloths of same compound material.For example, surperficial layer of cloth and high bonding can the enforcement between the layer of cloth of can being shaped by the embedding between the adhesive layer, high bonding can enforcement by needle point method between layer of cloth and the variable thickness layer of cloth can be shaped simultaneously.
In addition, the composite that is suitable for mold pressing can be made from can be shaped cloth and one deck variable compressive cloth of one deck.The surface layer of cloth can be applied on the outer surface of can be shaped one of layer of cloth or variable compressive layer of cloth.Between the function layer of cloth bonding can by the mechanical device such as acupuncture and/or by bonding such as the spraying powder, use the liquid dispersion and/or the embedding of solution, flame laminating and/or adhesive layer and their adhesive bonding methods such as combination to be enhanced.
The following example has shown various structure embodiment of the present invention and how to have controlled the physical property of structure of the present invention by changing some technological parameter.In the following example, the first and second stiffening agent layers are to make by needle-punching method: at first with the blending on standard weaving mixing apparatus of selected fiber, subsequently described fiber is carded to nonwoven, its then with its overlapping lapping to make the multilayer felt of highly-flexible, subsequently this felt layers is carried out acupuncture with the puncture of about 1000 pins.
Embodiment
Wherein one deck variable compressive cloth is to be clipped in two-layer or two a kind of moldable composite structures that can be shaped between (stiffening agent) cloth are by making by following technology.
Three kinds of material layers are as follows:
The first stiffening agent layer 50%Fiber Inovation Technologies 3.5 dawn *
2 inches crystalline polyester bicomponent binder fibers
50%Kosa 15 dawn * 3 in2s 95 type polyester
Basic weight-6 ounce per square yard
Needle point method is weaved (stiffening agent cloth)
Fiber, the mixed yarn that the second stiffening agent layer is same as described above and weaving
Basic weight-9 ounce per square yard
Variable compressive layer 50%Fiber Innovation 3.5 dawn of Technologies
* 2 inches crystalline polyester bicomponent binder fibers
25%6.7 dtex polyester
25%17.0 dtex polyester
Basic weight-20 ounce per square yard
Thickness-20 millimeter
(variable compressive cloth) is weaved in longitudinal lap joint
Between each of these materials, there is not adhesive layer.Longitudinal lap joint product variable compressive cloth is to make on Strudo machine, and the manufacturer of this machine is:
I.N.T.，s.r.o
460?05?liberec，Karla?Capka?302/22
Czech Republic
In order to prepare described variable compressive layer, with described three polyester fibers (comprising an adhesive fiber) blending and be carded to nonwoven on the textile fabric blending equipment of standard.The cloth of combing is sent into longitudinal lap joint Strudo machine so that it is folding or pleating, thereby obtain the longitudinal folding product of given thickness.Should thick product by a baking oven with this product by heating at least about 150 ℃, its softening or bond vitrified agent fiber is so that they are thermally bonded on other fiber in the blend, makes a softness, thick three-dimensional objects thus.
In order to make above-mentioned pressing, described technology comprises, described cloth is laminated into a composite, this composite is preheated to about 400 °F reaches about 8 minutes, this composite is put into to mould, closing molding becomes 16 millimeters slit to reach about 4 minutes, and die sinking with take out pressing, for warm mould sample, this mould (warm instrument) is to be preheated to about 300 °F.
The composite three-layer sample is: the variable compressive layer be clipped in longitudinally and the first and second stiffening agent layers that horizontal direction is made between.Other sample with same composition is to use without heated mold (cold instrument) at room temperature longitudinally to be made with horizontal direction.Four kinds of samples making according to said method are to use ASTM design D790-92, method of testing I-A three point load systems (center is on a simple crossbeam that supports), test according to the standard method of test with flexural property plastics that strengthen and electrically insulating material that be used for not strengthening.
Test result is to be listed in the table below in 1.
Table 1 deflection test result
| Sample *Describe | Thickness (millimeter) | Compensation yield load (ox) | Yield load under 1 inch (newton) (%) | Slope (Newton/millimeter) | |
| Cold instrument SSL VCL FSL (vertically) | ??16.50 | ????20.9 | ????21.2 | ????101 | ????5.72 |
| Warm instrument SSL VCL FSL (vertically) | ??17.50 | ????21.5 | ????22.5 | ????105 | ????5.65 |
| Cold instrument SSL VCL FSL (laterally) | ??17.50 | ????24.5 | ????29 | ????118 | ????6.46 |
| Warm instrument SSL VCL FSL (laterally) | ??17.75 | ????22.4 | ????28.5 | ????127 | ????5.90 |
*The SSL=second stiffening agent layer
VCL=variable compressive layer
The FSL=first stiffening agent layer
To molded composite material of the present invention provide the opereating specification of suitable stiffness be to the compensation yield load be about 13-26 newton.1 inch yield load of the present invention is about 90-140%, and slope hardness is the scope in about 2.5-7.0 Newton/millimeter.
Product of the present invention in a preferred embodiment, demanding stiffness is being suitable for automotive headliners, term " high stiffness " is by introducing and deflection result discussed above and definition in table 1.The demanding stiffness of mold pressing inside roof lining is with in order to support its weight in its span (it can be up to 8 feet in miniature circus caravan), additional weight with indoor lamp and sunglasses, and when assess by the standard environment tolerance test institute that is used for inside roof lining when exposing up to 3 days, can bending in-40 ℃ to 185 wide temperature range and rupture.Product must or be bent to breakdown point not by deflection, will break at this breakdown point inside roof lining, make it can not bear add the weight of roof liner component.And the destruction fracture in the inside roof lining will show by the ornamental layer of cloth in this inside roof lining, makes outward appearance attractive in appearance inadequately, should not be installed in the automobile.When stress surpassed its limit, product of the present invention was with bending and destroy fracture then, because above-mentioned reason makes it be not suitable for use in automotive headliners." low modulus " product can not destroy fracture, and does not show to bear and add the required stiffness of element weight in use, particularly in above-mentioned environment tolerance test.Therefore, the low modulus product was not to be suitable for automotive headliners originally.
Though described each embodiment of the present invention at this, these are only used for explaining and purpose of the present invention being described, and should not be construed as and limit the scope of the invention.To those skilled in the art will be that fairly obvious of the present invention various improvement are to be within the scope of the present invention, and be to be included in the appending claims.
Though with reference to preference pattern as shown in the drawing, show particularly and describe the present invention, but it will be understood by those skilled in the art that under situation about not departing within defined spiritual essence of the present invention of claims and the scope, can at length implement various changes.
Claims (20)
1, a kind of goods that are suitable for being molded into automotive headliners, it comprises: the be shaped nonwoven layer of the following type of one deck, promptly when its in heating and/or add to depress and have high stiffness when standing mold pressing, the about 13-26 newton of compensation yield load, one inch following yield load is about 90-140%, and slope range is about 2.5-7.0 ox/millimeter, these all are to measure by ASTM D-790-92 method of testing I, the described layer of cloth that is shaped has a upper surface and a lower surface, with the following type variable compressive of one deck nonwoven layer, promptly when it stands heating and/or pressurizes mold pressing down, can have variable thickness, described variable compressive cloth has a upper surface and a lower surface, and the lower floor of the described cloth that is shaped is bonded to the upper strata of described variable compressive cloth, and wherein said each layer is that polymer chemistry material by identical thermoformable makes.
2, goods as claimed in claim 1, wherein said cloth and the described variable compressive cloth of being shaped is formed by polyester basically.
3, goods as claimed in claim 2 are to improve mechanically in described bonding between layer of cloth and the described variable compressive layer of cloth of being shaped wherein.
4, goods as claimed in claim 3, the mechanical system that wherein improves between each layer is acupuncture.
5, goods as claimed in claim 2 are to improve by adhesive means in described bonding between layer of cloth and the described variable compressive layer of cloth of being shaped wherein.
6, goods as claimed in claim 2, the surperficial layer of cloth that wherein has a upper surface and a lower surface are to be applied on the variable compressive layer of cloth so that the lower surface of described surperficial cloth is the upper surface of next-door neighbour's variable compressive cloth.
7, goods as claimed in claim 2, the surperficial layer of cloth that wherein has a upper surface and a lower surface are to be applied on the variable compressive layer of cloth so that the lower surface of described surperficial cloth is the lower surface of next-door neighbour's variable compressive cloth.
8, a kind of goods that are suitable for being molded into automotive headliners, it comprises: the variable compressive nonwoven layer of the following type of one deck, promptly when in heating and/or add to depress and have variable thickness when standing mold pressing, be shaped nonwoven layer with two-layer following type, promptly when its in heating and/or add to depress and have high stiffness when standing mold pressing, the about 13-26 newton of compensation yield load, one inch following yield load is about 90-140%, and slope range is about 2.5-7.0 ox/millimeter, these all are to measure by ASTM D-790-92 method of testing I, the described layer of cloth that is shaped has a upper surface and a lower surface, described variable compressive layer of cloth is to be clipped in can the be shaped upper surface of cloth and another layer of one deck can be shaped between the lower surface of layer of cloth, and described each layer is to be made by identical thermoformed polymeric chemical substance.
9, goods as claimed in claim 8, wherein said cloth and the described variable compressive cloth of being shaped is formed by polyester basically.
10, goods as claimed in claim 9 are to improve mechanically in described bonding between layer of cloth and the described variable compressive layer of cloth of being shaped wherein.
11, goods as claimed in claim 9 are to improve by adhesive means in described bonding between layer of cloth and the described variable compressive layer of cloth of being shaped wherein.
12, goods as claimed in claim 9, the surperficial layer of cloth that wherein has a upper surface and a lower surface are to be applied on the variable compressive layer of cloth so that the upper surface of the described cloth that is shaped is the lower surface of next-door neighbour's variable compressive cloth.
13, goods as claimed in claim 8, the surperficial layer of cloth that wherein has a upper surface and a lower surface are to be applied on the variable compressive layer of cloth so that the upper surface of described variable compressive layer is the lower surface of the surperficial layer of cloth of next-door neighbour.
14, a kind of goods that are suitable for being molded into automotive headliners, it comprises the variable compressive nonwoven layer of two-layer following type, promptly when in heating and/or add to depress and have variable thickness when standing mold pressing, be shaped nonwoven layer with the following type of one deck, promptly when in heating and/or add to depress and have high stiffness when standing mold pressing, the about 13-26 newton of compensation yield load, one inch following yield load is about 90-140%, and slope range is about 2.5-7.0 ox/millimeter, these all are to measure by ASTM D-790-92 method of testing I, described variable compressive cloth has a upper surface and a lower surface, the described layer of cloth that is shaped is to be clipped between the lower surface of the upper surface of one deck variable compressive cloth and another layer variable compressive layer of cloth, and each layer is that polymer chemistry material by identical thermoformable makes.
15, a kind of goods that are suitable for the variable thickness that is shaped as the non-woven fibre composite of automotive headliners, described fibrous composite is a sandwich construction, this sandwich construction comprises the be shaped nonwoven layer of the following type of one deck, promptly when in heating and/or add to depress and have high stiffness when standing mold pressing, the compensation yield load is about 13-26 newton, one inch following yield load is about 90-140%, and slope range is about 2.5-7.0 ox/millimeter, these all are to measure by ASTM D-790-92 method of testing I, variable compressive nonwoven layer with the following type of one deck, promptly down can have variable thickness during mold pressing, and described each layer is that polymer chemistry material by identical thermoformable makes when standing heating and/or pressurization.
16, the goods of variable thickness as claimed in claim 15, wherein the variable thickness layer of cloth is to be clipped in two-layer the shaping between the cloth.
17, the goods of variable thickness as claimed in claim 15, the layer of cloth that wherein can be shaped is to be clipped between the two-layer variable compressive cloth.
18, goods as claimed in claim 15, wherein said cloth and the described variable compressive cloth of being shaped is formed by polyester.
19, goods as claimed in claim 15, it is the shape for the body of a motor car liner.
20, goods as claimed in claim 15, it is the shape for automotive headliners.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/286,916 | 1999-04-06 | ||
| US09/286,916 US6008149A (en) | 1997-04-23 | 1999-04-06 | Moldable composite article and method of manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1346308A true CN1346308A (en) | 2002-04-24 |
| CN1159150C CN1159150C (en) | 2004-07-28 |
Family
ID=23100709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008059616A Expired - Fee Related CN1159150C (en) | 1999-04-06 | 2000-02-29 | Moldable composite article and method of manufacture |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1171291A4 (en) |
| JP (1) | JP2002540981A (en) |
| KR (1) | KR20010108459A (en) |
| CN (1) | CN1159150C (en) |
| BR (1) | BR0009554A (en) |
| CA (1) | CA2368738A1 (en) |
| MX (1) | MXPA01010157A (en) |
| TW (1) | TW500665B (en) |
| WO (1) | WO2000059716A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014000120A1 (en) * | 2012-06-26 | 2014-01-03 | 三香科技股份有限公司 | Method for manufacturing non-woven composite layer product with different hardnesses |
| CN103889707A (en) * | 2011-10-31 | 2014-06-25 | 南部工业联合股份公司 | Article made of a multilayer composite material and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITSV20020063A1 (en) * | 2002-12-30 | 2004-06-30 | Compass Sa | SHAPED PANEL IN THERMOPLASTIC MATERIAL, INTERMEDIATE SHEET FOR THE MANUFACTURE OF THE SAID PANEL AND PROCEDURE FOR THE MANUFACTURE OF THE SAID PANEL AND OF THE INTERMEDIATE SHEET |
| DE102019100919A1 (en) * | 2019-01-15 | 2020-07-16 | Adler Pelzer Holding Gmbh | Motor vehicle floor covering, luggage compartment covering or loading floor covering with textured needle-punched carpet surface (II) |
| DE202021103471U1 (en) | 2021-06-29 | 2021-07-07 | Tenowo GmbH | Composite material based on non-woven fabrics |
| EP4241979A1 (en) * | 2022-03-10 | 2023-09-13 | Carl Freudenberg KG | Sustainable nonwoven laminate for structural part applications |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60196332A (en) * | 1984-03-17 | 1985-10-04 | Ikeda Bussan Co Ltd | Manufacture of interior ornamental material for vehicle |
| US5532050A (en) * | 1986-06-30 | 1996-07-02 | Wm. T. Burnett & Co., Inc. | Densified thermo-bonded synthetic fiber batting |
| CA1327343C (en) * | 1987-08-28 | 1994-03-01 | Gates Formed-Fibre Products, Inc. | Semirigid luggage shell and method for its production |
| JP3351475B2 (en) * | 1992-10-03 | 2002-11-25 | ユニチカ株式会社 | Laminated plate and method of manufacturing the same |
| JPH06199182A (en) * | 1993-01-06 | 1994-07-19 | Dainippon Ink & Chem Inc | Manufacture of automobile trunk side-trim |
| US5591289A (en) * | 1995-06-29 | 1997-01-07 | Davidson Textron Inc. | Method of making a fibrous headliner by compression molding |
| WO1998030375A1 (en) * | 1997-01-08 | 1998-07-16 | Owens Corning | Molding media and process of making same |
| US6096669A (en) * | 1997-10-28 | 2000-08-01 | Gkn Westland Aerospace Inc. | Unidirectional fiber-random mat preform |
-
2000
- 2000-02-29 CA CA002368738A patent/CA2368738A1/en not_active Abandoned
- 2000-02-29 JP JP2000609253A patent/JP2002540981A/en active Pending
- 2000-02-29 KR KR1020017012737A patent/KR20010108459A/en not_active Application Discontinuation
- 2000-02-29 MX MXPA01010157A patent/MXPA01010157A/en unknown
- 2000-02-29 EP EP00913664A patent/EP1171291A4/en not_active Withdrawn
- 2000-02-29 CN CNB008059616A patent/CN1159150C/en not_active Expired - Fee Related
- 2000-02-29 WO PCT/US2000/005151 patent/WO2000059716A1/en not_active Application Discontinuation
- 2000-02-29 BR BR0009554-0A patent/BR0009554A/en not_active Application Discontinuation
- 2000-05-15 TW TW089106316A patent/TW500665B/en active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103889707A (en) * | 2011-10-31 | 2014-06-25 | 南部工业联合股份公司 | Article made of a multilayer composite material and preparation method thereof |
| CN103889707B (en) * | 2011-10-31 | 2016-08-17 | 南部工业联合股份公司 | Goods being made up of multilayer materials and preparation method thereof |
| WO2014000120A1 (en) * | 2012-06-26 | 2014-01-03 | 三香科技股份有限公司 | Method for manufacturing non-woven composite layer product with different hardnesses |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002540981A (en) | 2002-12-03 |
| BR0009554A (en) | 2002-01-29 |
| KR20010108459A (en) | 2001-12-07 |
| WO2000059716A1 (en) | 2000-10-12 |
| EP1171291A1 (en) | 2002-01-16 |
| MXPA01010157A (en) | 2003-07-14 |
| CN1159150C (en) | 2004-07-28 |
| CA2368738A1 (en) | 2000-10-12 |
| EP1171291A4 (en) | 2002-09-11 |
| TW500665B (en) | 2002-09-01 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: FRANKLIN QIEAN Free format text: FORMER OWNER: KNOWLTON NONWOVENS INC. Effective date: 20050304 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20050304 Address after: American New York Patentee after: Franklin Chean Address before: American New York Patentee before: Knowlton Nonwovens Inc. |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040728 Termination date: 20100229 |