CN1343469A - Environmental protection-type rubber shoes modified by nano composition and its making method - Google Patents
Environmental protection-type rubber shoes modified by nano composition and its making method Download PDFInfo
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- CN1343469A CN1343469A CN 01126073 CN01126073A CN1343469A CN 1343469 A CN1343469 A CN 1343469A CN 01126073 CN01126073 CN 01126073 CN 01126073 A CN01126073 A CN 01126073A CN 1343469 A CN1343469 A CN 1343469A
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- nano
- sio
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An environmental protection type of modified rubber shoes applying with nanometre particles composite adds certain ratio of nanometer particles into sole, middle sole and shoe lining aims at raising the rubbing wearabitities bending ability and elastic resiliece as well as changing sole colour and increasing anti-aging property by utilizing the exotic characteristcs of nanometre material. To add functional nanometre in middle sole and shoe lining it can play role of antibiosis, diodorization, adsorbing and resolving particular smell.
Description
The present invention relates to a kind of footwear, the invention of particularly a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof.
Rubber overshoes in the background technology all are to adopt traditional starting material to be made, and as sole, middle sole formula, generally adopt rubber, promotor, stearic acid, filler etc. through refining glue sulfidization molding; Xie Li material selection cotton, chemical fibre are made upper of a shoe by cutting out the back with vamp; Sole and the middle end, upper of a shoe set firmly and are made into integration rubber overshoes, the rubber overshoes that adopt this prescription, technology, raw material to make, the indexs such as antibacterial of the deodorizing effect, Xie Li at the abrasive wear resistance at its big end, the middle end are lower, in use do not reach the ideal result of use.
Along with growth in the living standard, people are more and more higher to the requirement of footwear environmental protection, health care consciousness, and the therefore existing existing deficiency of rubber overshoes is fairly obvious, and its major defect is summarized as follows:
One, because pavement of road hardness improves, and people's body weight strengthens, and the rubber overshoes sole wear resisting property that makes original Recipe manufacture is relatively poor, elastic effect is not obvious.
Two, because the specificity of starting material and moulding process makes that the rubber overshoes chemistry peculiar smell in the background technology is denseer, produce foul odour when mixing with pin excretory material, polluted air is unfavorable for environmental protection and health of human body.
Three, since existing rubber overshoes employed in the material pad do not have antibacterial, therefore bacterium in the footwear is not had restraining effect.
Four, generally to adopt carbon black be main raw material to the enhancing composition at the big end of existing rubber overshoes, and therefore, utilizing this product manufactured generally all is black, and the color of rubber overshoes product is very dull.
In view of the deficiency that rubber overshoes in the background technology exist, the inventor is through years of researches and exploration, and the expertise of utilizing rich experiences and being familiar with works out the present invention finally.
Main purpose of the present invention is to propose a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, is used for increasing sole fastness to rubbing and elastic technical scheme, in order to solve the relatively poor defective of rubber overshoes sole wear resisting property in the background technology.
Another object of the present invention is to propose a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, the rubber overshoes sterilising effect is poor in order to solve, the serious deficiency of peculiar smell in the footwear, to eliminate the phenomenon more than humidity, stench, the bacterium in the rubber overshoes.
Another purpose of the present invention is to propose a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, in order to the dullness of solution sole color and the technical scheme of black pollution of the middle end.
In view of above-mentioned purpose, technical scheme among the present invention can realize like this, a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, comprise sole, the middle end, upper of a shoe, it is characterized in that: at the big end of rubber overshoes, the manufacturing in the process of middle end, Xie Li, add nanoparticle according to a certain percentage, wherein:
1, raw material is selected for use:
A, be used for the big end strengthen, toughness reinforcing nano material selects nano silicon oxide Sio for use
2-xOr a phase Al
2O
3:
B, be used for aging-resistant nano material of the big end and select rutile phase oxidation titanium TiO for use
2
It is silicon-base oxide SiO that c, the nano material that is used to sterilize adopt silver
2-XAg
+Or zinc is silica-based oxidation SiO
2-XZn
++
D, the nano material that is used for adsorption function adopt how mesoporous silicon based oxide S iO
2-X
E, the nano material that is used to decompose katalysis are selected anatase octahedrite phase TiO for use
2Or γ phase alumina γ-Al
2O
3
F, the nano material that is used to eliminate the unusual smell adopt the how mesoporous silicon based oxide compound of nano level to carry fragrant particle;
Wherein nanometer is carried the preparation method of fragrant particle:
Adopting particle diameter is that many micropores of 60nm-100nm silicon-base oxide is a solid support material; The odor type material adopts essence such as forest incense or rose scent, ratio in 0.05%--0.2% splashes in the alcohol solvent, then nano material and the ethanolic soln that contains spices are carried out excessive immersion 2--4 hour by weight 1: 5 ratio, stir with mulser then, behind the natural at normal temperatures volatile dry, carry out air seasoning in 60 ℃ baking oven, making liquid residue is about 0.5%, it is carried out taking out after ball milling 2-4 minute with ball mill get final product;
2, configuration proportion:
(1) configuration proportion of rubber overshoes sole (weight ratio):
With the gum that is used to manufacture sole is standard
Gum/SiO
2-X/ TiO
2=100/0.5-2/0.2-0.5
(2) the ratio weight ratio at the end in the making:
To be used for manufacturing end gum is standard
Gum/SiO
2-XZn
++/ SiO
2-X/ γ-Al
2O
3/ SiO
2-XMuscat Hamburg=100/1-2/1-1.5/0.5-1/2-3
(3) Xie Li, shoe-pad adopt the silver of 0.5-1% be silicon-base oxide as anti-biotic material, the bright emulsion of the benzene of 5--10%, the water of 80--94% mixes, and with mulser emulsification 15 minutes, it is sprayed on Xie Li or gets final product above the pad material.
3, making method:
(1) aforesaid a kind of environmental protection rubber overshoes that adopt the nano composition modification and preparation method thereof, it is characterized in that: in sole making processes, ratio according to above-mentioned sole making, nano material is added in other powder filler, carry out ball milling with ball mill, make in the abundant finely dispersed adding rubber of nano material, refine glue, make the speed difference maximum of rubber mixing machine two rotor wheels, refine and carried out sulfidization molding in 5-10 minute.
(2) aforesaid a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, it is characterized in that: in mixing process of the middle end, according to the ratio of making of the end in above-mentioned nano material is mixed with other powder filler, carry out carrying out in ball milling 5-10 minute sulfidization molding with ball mill.To set firmly one through the sole of modification, the middle end, upper of a shoe.
Advantage and positively effect that the present invention is had compared with the prior art are: the sole that adopts the technique scheme manufacturing, because the effect of the surface-area effects of nanoparticle, volume effect, quantum effect, quantum tunneling effect, make elasticity, toughness, the fastness to rubbing at the big end be significantly improved, anti-aging index, anti-ultraviolet very competent; Because the effect of nanoparticle enhanced, make the intensity and the each side index of making colored rubber overshoes that tangible increase all be arranged with the present invention, particularly sterilization, deodorizing effect are very remarkable, and sterilization rate reaches more than 99%, and the deodorizing rate reaches more than 98%.It is poor to have solved the wear resisting property that rubber overshoes exist in the background technology, the chemical peculiar smell in the footwear and because of the ventilative bad pin that causes smelly with defectives such as footwear are smelly.
Below with embodiment progressive of the present invention is further elaborated.
A kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof comprises sole, the middle end, upper of a shoe, it is characterized in that: in the making processes of sole, middle end, Xie Li, add specific nano composition in proportion; Wherein:
The sole making method is proportionally to mix nano composition in the sole original formulation:
1, material choice:
A, be used to increase wear-resisting and elastic material selection 50 nano silicon-based oxide Sio
2-X
B, be used for the titanium oxide Tio that the aging-resistant nano material is selected the rutile phase for use
2
2, configuration proportion (weight ratio): with the gum is standard
Rubber/SiO
2-X/ Tio
2=100/1.5/0.2
3, making method:
With nano material Sio
2-X, Tio
2After dosing material mixing with the powder of making sole, carried out ball milling 30-50 minute with ball mill, nano material is fully disperseed, the powder body material that ball milling is good adds in the glue uniformly during refining glue, and the refining glue time was taken out sulfidization molding after 20 minutes.
4, technical process:
Filler
Nano material---→ rubber---→ refining glue-→ sulfidization molding
Ball milling
Aforesaid a kind of environmental protection-type rubber shoes that adopts the nano composition modification, wherein the making method at the end is: in original formulation of the middle end, add the nanoparticle matrix material in proportion, wherein:
1, material choice:
(1) being used to the nano material of sterilizing, to adopt zinc be silicon-base oxide SiO
2-XZn
++
(2) be used for the silicon-base oxide Sio of the how mesoporous specific surface of material selection more than 600 of adsorption function
2-X
(3) nano material that is used to decompose katalysis is selected the aluminium oxide Al of γ phase for use
2O
3
(4) nano material that is used to eliminate the unusual smell is selected for use and is loaded with rosaceous silicon-dioxide Sio
2-perfume (or spice):
2, configuration proportion (weight ratio) is standard with the gum:
Rubber/Sio
2-XZn
++/ SiO
2-X/ Al
2O
3/ Sio
2Fragrant particle=100/2/1.5/1/2.5
3, making method:
With nano material Sio
2-XZn
++, SiO
2-X, Al
2O
3, Sio
2Fragrant particle, with make in after the powder at the end doses material mixing, carried out ball milling 15 minutes with ball mill, nano material is fully disperseed, the powder body material that ball milling is good adds in the glue uniformly during refining glue, the refining glue time is 15 minutes, takes out sulfidization molding.
4, manufacture craft:
Filler,
Nano material-→ rubber-→ refining glue-→ sulfidization molding
Ball milling
Aforementioned a kind of environmental protection-type rubber shoes of nano composition modification that adopts is characterized in that being provided with the nano-carrier anti-biotic material on: Zai Xie Li, the shoe-pad, and its making method is:
1, material choice and ratio (weight ratio):
(1) anti-biotic material selection nanometer zinc is silicon-base oxide 1%;
(2) medium adopts the bright emulsion 5% of benzene;
(3) solution is selected water 94% for use;
2, compound method:
Nanometer is carried the zinc anti-biotic material adds in the bright emulsion of benzene, carry out emulsification 5-10 minute with mulser after, add and carry out emulsification 2-3 minute in the entry.
3, end making method in antibiotic:
The antimicrobial fluid for preparing is sprayed on it on material of Xie Li, shoe-pad with spraying method gets final product.
At last sole, the middle end, upper of a shoe are set firmly one then whole proposal implement to finish.
Above scheme is preferred embodiment among the present invention, the present invention is not done any pro forma restriction, and the modification equivalent variations that all foundations technical spirit of the present invention is done all belongs to the scope of the invention.
Claims (2)
1. environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof comprises sole, the middle end, upper of a shoe, it is characterized in that: at the big end of rubber overshoes, the manufacturing in the process of the middle end, footwear Li, add nanoparticle according to a certain percentage, wherein:
(1), raw material is selected for use:
A, be used for the big end strengthen, toughness reinforcing nano material selects nano silicon oxide Sio for use
2-xOr a phase Al
2O
3
B, be used for aging-resistant nano material of the big end and select rutile phase oxidation titanium TiO for use
2
It is silicon-base oxide SiO that c, the nano material that is used to sterilize adopt silver
2-XAg
+Or zinc is silica-based oxidation SiO
2-XZn
++
D, the nano material that is used for adsorption function adopt how mesoporous silicon based oxide S iO
2-X
E, the nano material that is used to decompose katalysis are selected anatase octahedrite phase TiO for use
2Or γ phase alumina γ-Al
2O
3
F, the nano material that is used to eliminate the unusual smell adopt the how mesoporous silicon based oxide compound of nano level to carry fragrant particle;
Wherein nanometer is carried the preparation method of fragrant particle:
Adopting particle diameter is that many micropores of 60nm-100nm silicon-base oxide is a solid support material; The odor type material adopts essence such as forest incense or rose scent, ratio in 0.05%--0.2% splashes in the alcohol solvent, then nano material and the ethanolic soln that contains spices are carried out excessive immersion 2--4 hour by weight 1: 5 ratio, stir with mulser then, behind the natural at normal temperatures volatile dry, carry out air seasoning in 60 ℃ baking oven, making liquid residue is about 0.5%, it is carried out taking out after ball milling 2-4 minute with ball mill get final product;
(2), configuration proportion:
A. the configuration proportion of rubber overshoes sole (weight ratio):
With the gum that is used to manufacture sole is standard
Gum/SiO
2-X/ TiO
2=100/0.5-2/0.2-0.5
B. the ratio weight ratio at the end in making:
To be used for manufacturing end gum is standard
Gum/SiO
2-XZn
++/ SiO
2-X/ γ-Al
2O
3/ SiO
2-XMuscat Hamburg=100/1-2/1-1.5/0.5-1/2-3
C. Xie Li, shoe-pad adopt the silver of 0.5--1% be silicon-base oxide as anti-biotic material, the bright emulsion of the benzene of 5--10%, the water of 80--94% mixes, and with mulser emulsification 15 minutes, it is sprayed on Xie Li or gets final product above the pad material.
(3), making method:
Aforesaid a kind of environmental protection rubber overshoes that adopt the nano composition modification and preparation method thereof, it is characterized in that: in sole making processes, ratio according to above-mentioned sole making, nano material is added in other powder filler, carry out ball milling with ball mill, make in the abundant finely dispersed adding rubber of nano material, refine glue, make the speed difference maximum of rubber mixing machine two rotor wheels, refine and carried out sulfidization molding in 5-10 minute.
Aforesaid a kind of environmental protection-type rubber shoes that adopts the nano composition modification and preparation method thereof, it is characterized in that: in mixing process of the middle end, according to the ratio of making of the end in above-mentioned nano material is mixed with other powder filler, carry out carrying out in ball milling 5-10 minute sulfidization molding with ball mill.To set firmly one through the sole of modification, the middle end, upper of a shoe.
2. according to described a kind of environmental protection-type rubber shoes that adopts the nano composition modification of claim 1 and preparation method thereof, comprise sole, the middle end, upper of a shoe, it is characterized in that: in the making processes of sole, middle end, Xie Li, add specific nano composition in proportion; Wherein:
The sole making method is proportionally to mix nano composition in the sole original formulation:
(1), material choice:
A, be used to increase wear-resisting and elastic material selection 50 nano silicon-based oxide Sio
2-X
B, be used for the titanium oxide Tio that the aging-resistant nano material is selected the rutile phase for use
2
(2), configuration proportion (weight ratio): with the gum is standard
Rubber/SiO
2-X/ Tio
2=100/1.5/0.2
(3), making method:
With nano material Sio
2-X, Tio
2After dosing material mixing with the powder of making sole, carried out ball milling 30 minutes with ball mill, nano material is fully disperseed, the powder body material that ball milling is good adds in the glue uniformly during refining glue, and the refining glue time was taken out sulfidization molding after 20 minutes.
(4), technical process:
Filler
Nano material---→ rubber---→ refining glue-→ sulfidization molding
Ball milling
Aforesaid a kind of environmental protection-type rubber shoes that adopts the nano composition modification, wherein the making method at the end is: in original formulation of the middle end, add the nanoparticle matrix material in proportion, wherein:
(1), material choice:
A. it is silicon-base oxide SiO that the nano material that is used to sterilize adopts zinc
2-XZn
++
B. the silicon-base oxide Sio of the how mesoporous specific surface of material selection more than 600 that is used for adsorption function
2-X
C. the nano material that is used to decompose katalysis is selected the aluminium oxide Al of γ phase for use
2O
3
D. the nano material that is used to eliminate the unusual smell is selected for use and is loaded with rosaceous silicon-dioxide Sio
2-perfume (or spice);
(2), configuration proportion (weight ratio) is standard with the gum:
Rubber/Sio
2-XZn
++/ SiO
2-X/ Al
2O
3/ Sio
2Fragrant particle=100/2/1.5/1/2.5
(3), making method:
With nano material Sio
2-XZn
++, SiO
2-X, Al
2O
3, Sio
2Fragrant particle, with make in after the powder at the end doses material mixing, carried out ball milling 15 minutes with ball mill, nano material is fully disperseed, the powder body material that ball milling is good adds in the glue uniformly during refining glue, the refining glue time is 15 minutes, takes out sulfidization molding.
(4), manufacture craft:
Filler
Nano material---→ rubber---→ refining glue---→ sulfidization molding
Ball milling
Aforementioned a kind of environmental protection-type rubber shoes of nano composition modification that adopts is characterized in that being provided with the nano-carrier anti-biotic material on: Zai Xie Li, the shoe-pad, and its making method is:
(1), material choice and ratio (weight ratio):
A. anti-biotic material selection nanometer zinc is silicon-base oxide 1%;
B. medium adopts the bright emulsion 5% of benzene;
C. solution is selected water 94% for use;
(2), compound method:
Nanometer is carried the zinc anti-biotic material adds in the bright emulsion of benzene, carry out emulsification 5-10 minute with mulser after, add and carry out emulsification 2-3 minute in the entry.
(3), end making method in antibiotic:
The antimicrobial fluid for preparing is sprayed on it on material of Xie Li, shoe-pad with spraying method gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01126073 CN1343469A (en) | 2001-08-18 | 2001-08-18 | Environmental protection-type rubber shoes modified by nano composition and its making method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01126073 CN1343469A (en) | 2001-08-18 | 2001-08-18 | Environmental protection-type rubber shoes modified by nano composition and its making method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1343469A true CN1343469A (en) | 2002-04-10 |
Family
ID=4666148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01126073 Pending CN1343469A (en) | 2001-08-18 | 2001-08-18 | Environmental protection-type rubber shoes modified by nano composition and its making method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1343469A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101725046B (en) * | 2009-12-04 | 2011-07-20 | 金猴集团有限公司 | Midsole material of leather shoes |
| CN102504355A (en) * | 2011-10-26 | 2012-06-20 | 金猴集团威海鞋业有限公司 | Elastic, antibacterial and deodorizing shoe material |
| CN104382290A (en) * | 2014-12-05 | 2015-03-04 | 北京华腾橡塑乳胶制品有限公司 | Rubber shoe lining impregnation device and method for automatically impregnating rubber shoe linings by rubber shoe lining impregnation device |
| CN112029214A (en) * | 2020-07-31 | 2020-12-04 | 温州金鸿远鞋业有限公司 | Sole material and preparation method thereof |
-
2001
- 2001-08-18 CN CN 01126073 patent/CN1343469A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101725046B (en) * | 2009-12-04 | 2011-07-20 | 金猴集团有限公司 | Midsole material of leather shoes |
| CN102504355A (en) * | 2011-10-26 | 2012-06-20 | 金猴集团威海鞋业有限公司 | Elastic, antibacterial and deodorizing shoe material |
| CN102504355B (en) * | 2011-10-26 | 2013-06-05 | 金猴集团威海鞋业有限公司 | Elastic, antibacterial and deodorizing shoe material |
| CN104382290A (en) * | 2014-12-05 | 2015-03-04 | 北京华腾橡塑乳胶制品有限公司 | Rubber shoe lining impregnation device and method for automatically impregnating rubber shoe linings by rubber shoe lining impregnation device |
| CN112029214A (en) * | 2020-07-31 | 2020-12-04 | 温州金鸿远鞋业有限公司 | Sole material and preparation method thereof |
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