CN106496794A - There is the preparation method of the anion plastic inside gadget of purifying in-vehicle air function - Google Patents
There is the preparation method of the anion plastic inside gadget of purifying in-vehicle air function Download PDFInfo
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- CN106496794A CN106496794A CN201611003104.3A CN201611003104A CN106496794A CN 106496794 A CN106496794 A CN 106496794A CN 201611003104 A CN201611003104 A CN 201611003104A CN 106496794 A CN106496794 A CN 106496794A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses the preparation method of the anion plastic inside gadget with purifying in-vehicle air function, comprise and getting the raw materials ready, take acrylic resin, improvement in performance agent drops in mixer, add thermal agitation and form mixed material, mixed material is heated up and stirred, deliver in a cold mixed processor and slowly stir and lower the temperature, take except acrylic resin, other raw material outside improvement in performance agent is also put in high temperature mixer, heat temperature raising stirs, the material obtaining being put into injection machine and mold injection molding makes finished product. it is high that the present invention makes automotive upholstery product surface brightness, be not clamminess, good looking appearance, durable indeformable, good product quality, applied widely, there is good development prospect.
Description
Technical field
The present invention relates to automotive interior material technical field, relate in particular to the preparation method of the anion plastic inside gadget with purifying in-vehicle air function.
Background technology
Due to improving constantly of World Economics fast development and living standards of the people, automobile industry development, especially car produce and make rapid progress, vehicle is constantly updated. and automotive trim (Automotive Interior) mainly refers to automotive interior repacking institute the automobile product of using, relate to the every aspect of automotive interior, such as automobile steering wheel cover, automobile cushion, automatic foot-mat, in portion's goods of furniture for display rather than for use, containing box, instrument desk etc. is all automotive trim product. common automotive upholstery is plastic products, to with vehicle the interior material matching requires also more and more higher. such as Auto Instrument desk, complex structure, the normal splicing structure that adopts, instrument platform curved surface is many, area is large, require higher to the processing technology of instrument desk, especially production cost is higher, one-component material material can not meet the demands. in recent years, people adopt textile material to become interior material with other base material through Compound Machining conventionally, ? in compound processing course, need be by two or more base materials (as textile material+textile material or textile material+plastics+rubber) warp adhesive is composited. but solvent for use type adhesive contains a large amount of volatile harmful organic solvents, formaldehyde, using in journey, in process, overflow and pollute environment inside car, if solvent is de-unclean, remain in composite and also can pollute in car and use environment. in addition, dust granules in car in gap, second-hand-cigarette, pm2.5 tail gas, vehicle exhausts etc. are ubiquity also, danger and driver's health.
Summary of the invention
The object of the invention is to, for the deficiencies in the prior art, the preparation method of the anion plastic inside gadget with purifying in-vehicle air function is provided, can be made into the plastics inside gadgets such as automobile steering wheel cover, automobile cushion, automatic foot-mat, inner goods of furniture for display rather than for use, containing box, instrument desk, upholstery sheet material.
The technical solution used in the present invention is as follows.
The preparation method with the anion plastic inside gadget of purifying in-vehicle air function, it comprises the steps:
Step 1: get the raw materials ready, take by weight
200～350 parts of acrylic resins;
2～5 parts of photo-catalytic nano powders;
80～150 parts of improvement in performance agent;
6～12 parts, PE wax;
6～12 parts, activator;
2～5 parts of the two oleamides of ethylene;
12～25 parts of inorganic combustion inhibitors;
6～15 parts of external lubricants;
5～10 parts of in-lubricants;
10～25 parts of stabilizing agents;
2～5 parts, adsorbent;
Dyestuff is appropriate.
Tissuemat E (PE wax), claims again macromolecule wax to be called for short Tissuemat E. because of its good cold resistance, heat resistance, resistance toization the property learned and wearability and being widely used. in normal production, this part wax can directly be added to polyene as a kind of additive in hydrocarbon processing, it can increase gloss and the processing characteristics of product. as lubricant, and its stable chemical nature, electrical property is good. Tissuemat E and polyethylene, polypropylene, poly-cerinic acid ethene, EP rubbers, the good .Polyethylene can of butyl rubber intermiscibility be improved, gathered propylene, the mobility of ABS and polymethyl methacrylate, the release property of Merlon. for PVC and other exterior lubricant compare, Tissuemat E has stronger internal lubrication effect. and Tissuemat E (approximately 100～140 DEG C) in high temperature is dissolved in solvent in, and separate out in the time being cooled to normal temperature, be present in coating with microcrystalline form, because its thixotropy is conducive to the storage of coating, and After coating application application, film top layer can be moved in solvent volatilization process, finally form one with coating other components the top layer of individual " wax ". the raw materials of described improvement in performance agent comprises sericite in powder, calcium carbonate, tourmaline powder, medical stone powder, albumen stone flour, coupling agent, sulphur ester antioxidant, phosphite, lauryl sodium sulfate, dispersant, wetting agent, anion powder, its preparation method is that the raw material of improvement in performance agent is put into after reactor adds thermal agitation and made, heating and temperature control is 95～115 DEG C, mixer rotating speed is 300～1000RPM, and process time is 15～25min. sericite (Sericite) is mica one, it belongs to the silicate mineral .Sericite has very extensive purposes with layer structure, for rubber, plastics, painting material, paint, pottery, insulation, cosmetics, pigment, papermaking, the industries such as metallurgy.
The two oleamides of ethylene are synthetic wax .Make lubricant, brightener, and slipping agent, antitack agent and releasing agent in the plastic, Glassine paper antistatic additive. this product be applicable to ABS, polystyrene, polyvinyl chloride, nylon, cellulose acetate, polyvinyl acetate and The in-lubricant of phenolic resins and external lubricant; Be specially adapted to polyethylene and polypropylene film. can be used as pigment grind agent and Pigment dispersing agent, polyamide paraffin coupling agent. can improve polyacrylic compatibility and the hot ageing stability of filling talcum. can change Become the compatibility of paraffin and resin.This product can be used for the thermoplastic resin in injection molding as releasing agent.The double oleamides of ethylene The certain heat-resisting, weatherability of automotive interior material and antistatic behaviour can also be given.
Sericite (Sericite) is a kind of natural particulate muscovite, is the silicate of layer structure, can be split into pole
Thin sheet, piece are thick up to below 1um (can be whittled into 0.001um in theory), and radius-thickness ratio is big;Wear resistence and wearability are good;
High temperature insulation;It is insoluble in acid-base solution;Stable chemical nature.In addition the chemical composition of sericite, structure and kaolin are close,
There are some characteristics of clay mineral again, i.e., dispersion suspension is good in aqueous medium and organic solvent, and the white grain of color is thin, has viscous
Property etc..Therefore, sericite has the various features of mica mineral and clay minerals concurrently.Tourmaline powder is tourmaline raw ore
After going the removal of impurity, through the powder that mechanical crushing is obtained.Through the tourmaline powder of processing purification have higher bear from
Sub- yield and far infrared transmissivity.Tourmaline is also Tourmaline.Tourmaline (tourmaline) chemical general formula is
NaR3Al6Si6O18BO33 (OH, F) 4, crystal belong to the general name of family's circulus silicate mineral of trigonal system.R generations in formula
Table metal cation, when R is Fe2+, constitutes black crystals tourmaline.Column of the tourmaline crystal in nearly triangle, two ends are brilliant
Shape is different, and cylinder has longitudinal grin, is often in the form of a column, needle-like, radial and block aggregate.Glassy lustre, fracture resinous luster are semi-transparent
Bright to transparent.Without cleavage.Mohs hardness 7～7.5, proportion 2.98～3.20.There are piezoelectricity and pyroelectricity.Medical stone powder extensively should
Make of health care, food, beverage and purification of water quality, sewage disposal, anti-corrosion, deodorization, fresh-keeping, decontamination, porcelain and plant
Plant the field such as industry and aquaculture.Thioesters antioxidant thinester antioxidant are to prevent the oxidation of macromolecular compound bad
Change and add the sulphur of people to acetify compound.Its antioxidation mechanism is:Sulphur class compound during hydroperoxide decomposition ox into time
The acidic materials such as sulfonic acid have catalytic action to the decomposition of hydroperoxides, so as to show good antioxygen property.This kind of antioxygen
Agent is mainly thio-2 acid vinegar.Phosphite is a kind of reducing agent.Lauryl sodium sulfate, white or faint yellow powdery are molten
Yu Shui, insensitive to alkali and hard water.There is decontamination, emulsification and excellent foaming power.It is a kind of nontoxic anion surface active
Agent.Its biological degradability>90%.Purposes：It is used as emulsifying agent, extinguishing chemical, foaming agent and textile auxiliary.Also serve as toothpaste and paste,
Powdery, the foaming agent of shampoo.The double oleamides of support are synthetic wax.Make lubricant, brightener, slipping agent, anti-in the plastic
Stick and releasing agent, glassine paper antistatic additive.This product be applied to ABS, polystyrene, polyvinyl chloride, nylon, cellulose acetate,
Polyvinyl acetate and the in-lubricant and external lubricant of phenolic resin；It is particularly well-suited to polyethylene and polypropylene film.Available
Make pigment grind agent and pigment dispersing agent, polyamide paraffin coupling agent.The polyacrylic compatibility and heat of filling talcum can be improved
Ageing stability.The compatibility of paraffin and resin can be changed.This product can be used for the thermoplastic resin in injection molding as releasing agent
Fat.Anion is shown in medical circle " air vitamin " its main effect of being known as：
1st, nervous system
Anion has sedation, and it can improve corticocerebral function, inspire enthusiasm, and dispelling fatigue is improved the health care of sleep, and strengthens
Appetite, excited parasympathetic improve the effect such as operating efficiency.
2nd, respiratory system
Improve PFT, accelerate respiratory tract fiber hair histokinesis, increase coefficienting respiration（Absorbing amount of oxygen increases by 20%, row
CO2 amounts increase by 14.5%）, strengthen the motion of tunica mucosa tracheae epithelial cilia, glandular secretion increases, while nasal epithelial can also be promoted
The regeneration of cell, recovers the secreting function of mucous membrane.
3rd, metabolism
Anion all has a certain impact to the carbohydrate of body, protein, fat metabolism and water and electrolyte metabolism, inhales
Enter anion, it is possible to decrease blood sugar and cholesterol, blood potassium equal size, increase the discharge rate of nitrogen, creatinine etc. in urine volume and urine；While energy
Enzyme system is affected, multiple enzymes in vivo are activated, promotes body metabolism；The tissue oxidizing such as brain, liver, kidney process can also strengthened,
Accelerate basic metabolism, the growth and development of body is played a driving role.
4th, the circulatory system
Negative aeroion has the therapeutic action for reducing blood pressure, and it can improve heart function and cardiac muscular dystrophy situation, increases blood
The content of middle hemoglobin, reduces blood sugar, raises pH value, shortens blood clotting time, stimulates human body hematopoiesis function.Domestic someone uses
Neuroleptic Leukocytopenia caused by the peripheral leukopenia of negative aeroion treatment pure and radiotherapy, obtains certain treatment
Effect.
5th, treatment and health
Treatment breathing problem, bronchitis, bronchial astehma, pulmonary emphysema etc. have certain curative effect.
6th, immune system
Improve body function, strengthen human body resistance against diseases.
7th, purification of air
Flue dust can be effectively eliminated, air peculiar smell is eliminated, eliminating toxic gas that finishing is produced etc. improves the pollution of environment.
The Main Function of performance improvement agent is to confer to inside gadget negative ion generating function well, and sericite in powder is through improving
Afterwards, in the presence of light, anion can be produced.Roasting need not be carried out to each raw material such as tourmaline in preparation process, therefore work
Skill is simple, is easily controlled.The ductility of raising inside gadget, hardness, tensile strength, elongation at break, elastic modelling quantity, thermal deformation temperature
The abilities such as degree, deflection, antistatic behaviour.
The coupling agent is silane coupler, titanate coupling agent, the mixing of one or more in aluminate coupling agent
Thing.Silane coupler is a class in the molecule while the organo-silicon compound containing two kinds of different chemical property groups, which is classical
Product can use formula YSiX3Represent.In formula, Y is non-hydrolytic group, including alkenyl（Predominantly vinyl）, and end band
There are Cl, NH2, SH, epoxy, N3、（Methyl）The alkyl of the functional groups such as acryloxy, NCO, i.e. carbon functional group；X is can
Hydrolysising group, including Cl, OMe, OEt, OC2H4OCH3, OSiMe3, and OAc etc..Due to this special construction, in its molecule
In simultaneously have can and inanimate matter material（Such as glass, silica sand, metal etc.）Chemically combined reactive group and with organic material
（Synthetic resin etc.）Chemically combined reactive group, can be used for being surface-treated.Titanate coupling agent is the later stage seventies by U.S.
State agrees a kind of coupling agent of Leech's petrochemistry company exploitation.For thermal plastic polymer and the filler for drying, there is good idol
Connection effect；This kind of coupling agent can use formula：ROO (4～n) Ti (OX～R ' Y) n (n=2,3) is represented；Wherein RO～it is hydrolyzable
Lower alkyloxy, can react with mineral surfaces hydroxyl, so as to reach the purpose of chemical coupling；OX～can be carboxyl,
Alkoxyl, sulfonic group, phosphorus base etc., these groups are critically important, determine that the specific function that titanate esters have, such as sulfonic group give and having
The certain thixotropy of machine thing；Pyrophosphoryl epoxide has fire-retardant, antirust, and the performance for strengthening bonding.Aluminate coupling agent,
Aluminate coupling agent, are transformed for inorganic pigment surface-active.(distearyl acyl-oxygen is different SG～Al821
Propyl group Aluminate), DL～411, DL～411AF, DL～411D, DL～411DF, anti-settling Aluminate ASA.ASA contains can
With the group of active hydrogen reaction, thus bonding action can occur with the inorganic filler of hydroxyl, carboxyl or surface adsorption water, improve
Inorganic filler and the compatibility and adhesion of organic polymer, so as to produce result of prevention, can also improve adhesive strength.
The dispersant be calgon, sodium polyphosphate, PTPP, tetrapotassium pyrophosphate, zinc stearate, poly- third
The mixture of one or more in olefin(e) acid salt.Glassy phosphate of the calgon for NA2O/P2O5 molecular proportions nearly 1.
Past is referred to as " Glan Durham " salt.Found by Glan Durham in 1832.He by salt obtained by sodium dihydrogen phosphate thermal dehydration,
Its fusing point（625℃）Lower heating, and fused mass is cooled down rapidly, and being obtained has hygroscopic Glan Durham salt.Sodium polyphosphate
Dissolubility is splendid, can dissolve, can improve the pliability of product in hypothermic saline.PTPP is industrial to be mainly used in
Soil improvement, oils are emulsified, buffer of liquid detergent etc.；It is a kind of efficient phospho potash complex fertilizer, adds appropriate micro-
Secondary element can be made into multi-element high-effect composite fertilizer material.It is used as texturizers, chelating agent and water retention agent in food industry.Burnt
Potassium phosphate is also called tetrapotassium pyrophosphate, white powder or blocks of solid.Relative density 2.534.1109 °C of fusing point.Water is dissolved in, molten
Solution degree 187g/100g water（25°C）.The aqueous solution is in alkalescence, 1% aqueous solution pH=10.5.Ethanol is not dissolved in.Property is similar to which
His polyphosphate.Potassium pyrophosphate is with ageing resistance.Zinc stearate is mainly used as styrene resin, phenolic resin, amido tree
The lubricant and releasing agent of fat.Polyacrylate is a kind of new functional macromolecule material and important chemical products, with fixation
The effect of metal ion, can prevent negative consequence of the metal ion to product, be that a kind of surface with multiple properties is lived
Property agent.
The wetting agent is lauryl sodium sulfate that pH value is 5.5～7.5, pull open powder, diisobutyl sodium naphthalene sulfonate, list
The mixture of one or more in tristerin.Using this formula, but mixture has decontamination, emulsifying capacity.
The adsorbent is carbon black, bamboo charcoal powder, activated carbon, diatomite, one or several in natural silicate minerals.Add
Plus after adsorbent, containing a large amount of micropores, with huge specific surface area, can effectively adsorb organic and some inorganic pollutions.
Described photo-catalytic nano powder is nanometer titanium phosphate, can form uniformly transparent nano coating, play purification
The effect of in-car air.Photocatalyst is a kind of photosemiconductor material with photo-catalysis function with Nano titanium dioxide as representative
The general name of material, it coats substrate surface, in the presence of light, produces strong catalytic degradation function：Effectively can degrade sky
Toxic and harmful in gas；Various bacteria can be effectively killed, and the toxin that can be discharged bacterium or fungi decomposes and innoxious
Process；The functions such as deodorant, anti-soil are also equipped with simultaneously.
Inorganic combustion inhibitor is one or several of antimony oxide, magnesium hydroxide, aluminium hydroxide.Increased fire-retardant rental
Antimony oxide, magnesium hydroxide, aluminium hydroxide, can be effectively fire-retardant, and does not produce new pollution, while can be as filling out
Thing is filled, the intensity of inside gadget is enhanced.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 100～105 DEG C, stir 20～30 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 120～125 DEG C, stops stir process；The mixed material is transferred
Cooling is slowly stirred in a cold mixed processor, drops to 30 DEG C～40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 150～230 DEG C, stops heating, stirring 5
～10 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.
As optimal technical scheme, stabilizer include by weight percentage 10～50% organic tin stabilizer, 20～40%
Calcium-zinc composite stabilizing agent, the mixture of 30～40% lead salt stabilizer.Organic tin stabilizer is the one kind in heat stabilizer.
It is mainly characterized by efficiently, with high transparent, excellent heat resistance, and resistance to sulfide staining.Industrial conventional have laurate esters,
Maleic acid esters and thio-alcohol.Early stage tinctorial property when there is prominent suppressions PVC product to process, remarkable UV resistant with
Long-time stability, with good mobility, during processing, color and luster retentivity is good, product excellent transparency. it is particularly its light thermally-stabilised
Property is reached the international leading level, and can effectively keep the recycled of secondary operation.Calcium-zinc composite stabilizing agent heat endurance
Excellent, initial stage form and aspect are little, and amalgamation is good, without precipitation phenomenon, with efficient weatherability.Lead salt stabilizer has monomer and compound two
Big class, substantially makees main stabilizer using lead salt stabilizer in China, with remarkable heat endurance, with complexing power, excellent
Good electrical insulating property, lower-price characteristic.
As optimal technical scheme, the in-lubricant include by weight percentage 40～60% OPE, 10
～30% calcium stearate, 30～50% stearic acid, external lubricant is paraffin.OPE is excellent new polarity
Wax, as OPE strand is with a certain amount of carbonyl and hydroxyl, so with filler, pigment, polar resin phase
Dissolubility just significantly improves.Wetability, dispersiveness in polar system is better than Tissuemat E, while also having concurrently coupled.
Calcium stearate is white powder, water insoluble, cold ethanol and ether, is dissolved in the organic solvents such as hot benzene, benzene and turpentine oil, slightly soluble
Ethanol and ether in heat.It is heated to slowly decomposing when 400 DEG C, flammable, meet strong acid and be decomposed into stearic acid and corresponding calcium salt, have
Hygroscopicity.The stabilizer of material high is given, the effect of lubricant is had concurrently, is made material be easy to the demoulding.Stearic acid is a kind of plastics
Cold resistant plasticizer.
Used as optimal technical scheme, the activator is dimethylaniline, the one kind in cobalt naphthenate.
Used as optimal technical scheme, described performance improvement agent includes by weight percentage：Calcium carbonate 40～80%, thin,tough silk cloud
Female powder 10～30%, tourmaline powder 3～5%, medical stone powder 0.5～2%, albumen stone flour 0.5～2%, coupling agent 12～35%, thioesters
Kind antioxidant 1～3%, phosphite 2～3%, lauryl sodium sulfate 0.5～1%, dispersant 3～8%, wetting agent 0.5～1%,
Negative ion powder 3～5%.
Used as optimal technical scheme, described performance improvement agent includes by weight percentage：Calcium carbonate 50～65%, thin,tough silk cloud
Female powder 15～20%, tourmaline powder 3～5%, medical stone powder 0.5～1%, albumen stone flour 0.5～1%, coupling agent 12～20%, thioesters
Kind antioxidant 1～3%, phosphite 2～3%, lauryl sodium sulfate 0.5～1%, dispersant 5～7%, wetting agent 0.5～1%；
In processability modifier, first calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, albumen stone flour are added to mill and are set
Ultra-fine grinding is carried out in standby, until particle diameter distribution is obtained in 50～80nm mixtures, then by the mixture and performance
The other compositions of modifier are added heat in reactor and are stirred, heating and temperature control at 100～115 DEG C, mixer rotating speed for 600～
900RPM, process time are 20～23min.
As optimal technical scheme, the dispersant include by weight percentage 30～50% calgon, 10～
20% sodium polyphosphate, 5～20% PTPP, 5～10% tetrapotassium pyrophosphate, 5～10% zinc stearate, 5～10%
Polyacrylate；The wetting agent include by weight percentage 40～50% lauryl sodium sulfate, 10～30% pull open powders,
5～20% diisobutyl sodium naphthalene sulfonates, 20～50% glycerin monostearates.
As optimal technical scheme, the adsorbent include by weight percentage 30～50% carbon blacks, 30～50% activated carbons,
30～50% natural silicate minerals.
As optimal technical scheme, inorganic combustion inhibitor include by weight percentage 30～50% antimony oxide, 20～
40% magnesium hydroxide, 30～50% aluminium hydroxide;The anion-generating capacity of the negative ion powder be 600～2000/ml, grain
Footpath is more than 100～1500 mesh, and product purity is more than 90%.
Used as optimal technical scheme, injection machine technological parameter is：175～200 DEG C of extruder temperature, injection pressure 50～
60bar, 85～90/s of injection speed.
The invention has the beneficial effects as follows：According to foregoing invention design, make, test, it was demonstrated that the production technology letter of the present invention
Single, easy to operate, interfacial combined function is compared the performance of wooden recombinant product and will be got well, and disclosure satisfy that the processing stream of different finished products
Dynamic, ductility, pliability, resistance to ag(e)ing, inotropic requirement, nontoxic, tasteless, heavy metal free；Negative ion powder consumption is little, makes
Valency is low.Volatilization negative ion amount is big, can purify in-car air, safety and environmental protection.Ore also without high-temperature process, such that it is able to avoid
The problem that ore occurs denaturation in particular during a heating process, ionizing power weakens, sustainable volatilization anion fine-purification.Modeling used
Doses is few, and the stability for making product is strong, and hardness is high, intensity is big, and impact resistance is nonflammable, and smooth surface is difficult the dust that bonds.Can
Automotive upholstery, process is simple, low cost are generated with disposable injection.Make automotive upholstery product surface brightness high, no
Tacky, good looking appearance is durable indeformable, and good product quality is applied widely, with good development prospect.
Specific embodiment
The specific embodiment of the present invention is illustrated with reference to example.
Embodiment 1.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, it is characterised in that bag
Include following steps.
Step 1：Get the raw materials ready, weigh following material by weight.
200 parts of acrylic resin；
2 parts of photo-catalytic nano powder；
80 parts of performance improvement agent；
6 parts of PE waxes；
6 parts of activator；
Double 2 parts of the oleamides of ethylene；
12 parts of inorganic combustion inhibitor；
6 parts of external lubricant；
5 parts of in-lubricant；
10 parts of stabilizer；
2 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 20%, tourmaline powder 3%, medical stone powder
0.5%th, albumen stone flour 0.5%, coupling agent 12%, sulphur ester antioxidant 1%, phosphite 2%, lauryl sodium sulfate 0.5%, dispersion
Agent 3%, wetting agent 0.5%, negative ion powder 3%, remaining is calcium carbonate.Its preparation method is to be put into anti-the raw material of performance improvement agent
Answer in kettle and be obtained after heating stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone
Powder, albumen stone flour are added in grinding equipment and carry out ultra-fine grinding, until obtaining particle diameter distribution in 50nm mixtures, then will
The mixture is added to heat in reactor with the other compositions of performance improvement agent and is stirred.Heating and temperature control at 95 DEG C, mixer
Rotating speed is 300RPM, and process time is 15min.
The coupling agent is silane coupler.
The wetting agent include by weight percentage 40% lauryl sodium sulfate, 10% pull open powder, 20% diisobutyl naphthalene
Sodium sulfonate, 30% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 40% OPE, 20% calcium stearate, 40% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 30% organic tin stabilizer, 40% calcium-zinc composite stabilizing agent, 30% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 30% carbon black, 50% activated carbon, 20% natural silicate minerals.
The activator is dimethylaniline.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 50% calgon, 20% sodium polyphosphate, 5% trimerization phosphorus
Sour potassium, 5% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 600/ml, and, more than 100 mesh, product purity is more than 90% for particle diameter.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 100 DEG C, stir 20 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 120 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 30 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 150 DEG C, stops heating, is stirred 5 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
175 DEG C, injection pressure 50bar, 85/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 50MPa, and notch impact strength reaches
32KJ/m2, tensile strength are less than 1.5 by 25MPa, bending modulus 2100MPa, antiseized grade, and after inundation, deflection is less than
0.092, rupture strength 10.2.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9400/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 98.32%, air sterilization effect killing rate is 98.12%.
Embodiment 2.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, in including following step
Suddenly.
Step 1：Get the raw materials ready, weigh following material by weight.
300 parts of acrylic resin；
3 parts of photo-catalytic nano powder；
100 parts of performance improvement agent；
8 parts of PE waxes；
8 parts of activator；
Double 3 parts of the oleamides of ethylene；
15 parts of inorganic combustion inhibitor；
12 parts of external lubricant；
8 parts of in-lubricant；
14 parts of stabilizer；
3 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 20%, tourmaline powder 5%, medical stone powder
1%th, albumen stone flour 1%, coupling agent 15%, sulphur ester antioxidant 2%, phosphite 2%, lauryl sodium sulfate 1%, dispersant 5%,
Wetting agent 1%, negative ion powder 5%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor to add
It is obtained after thermal agitation.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, albumen
Stone flour is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 60nm mixtures, then will be described mixed
Compound is added to heat in reactor with the other compositions of performance improvement agent and is stirred.At 100 DEG C, mixer rotating speed is heating and temperature control
500RPM, process time are 20min.
The coupling agent is titanate coupling agent.
The wetting agent include by weight percentage 50% lauryl sodium sulfate, 20% pull open powder, 10% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 20% organic tin stabilizer, 40% calcium-zinc composite stabilizing agent, 40% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 40% carbon black, 30% activated carbon, 30% natural silicate minerals.
The activator is the one kind in cobalt naphthenate.
Described photo-catalytic nano powder is nanometer titanium phosphate.Photocatalyst is a kind of with Nano titanium dioxide as representative
There is the general name of the photosemiconductor material of photo-catalysis function, it coats substrate surface, in the presence of light, produce strong
Catalytic degradation function：Effectively can degrade toxic and harmful in air；Can effectively kill various bacteria, and can by bacterium or
The toxin that fungi discharges decomposes and harmless treatment；The functions such as deodorant, anti-soil are also equipped with simultaneously.
The dispersant include by weight percentage 40% calgon, 20% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 10% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 1000/ml, and particle diameter is more than 1000 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 25 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 200 DEG C, stops heating, is stirred 8 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
180 DEG C, injection pressure 55bar, 88/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 53MPa, and notch impact strength reaches
35KJ/m2, tensile strength are less than 1.3 by 28MPa, bending modulus 2300MPa, antiseized grade, and after inundation, deflection is less than
0.085, rupture strength 9.1.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 12000/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 99.12%, air sterilization effect killing rate is 99.12%.
Embodiment 3.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, it is characterised in that bag
Include following steps.
Step 1：Get the raw materials ready, weigh following material by weight.
350 parts of acrylic resin；
5 parts of photo-catalytic nano powder；
150 parts of performance improvement agent；
12 parts of PE waxes；
12 parts of activator；
Double 5 parts of the oleamides of ethylene；
25 parts of inorganic combustion inhibitor；
15 parts of external lubricant；
10 parts of in-lubricant；
25 parts of stabilizer；
5 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 40%, tourmaline powder 5%, medical stone powder
2%th, albumen stone flour 2%, coupling agent 10%, sulphur ester antioxidant 3%, phosphite 3%, lauryl sodium sulfate 1%, dispersant 8%,
Wetting agent 1%, negative ion powder 15%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor
It is obtained after heating stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, egg
Albarium is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 80nm mixtures, then will be described
Mixture is added to heat in reactor with the other compositions of performance improvement agent and is stirred.Heating and temperature control at 115 DEG C, mixer rotating speed
For 1000RPM, process time is 25min.
The coupling agent is aluminate coupling agent.
The wetting agent include by weight percentage 45% lauryl sodium sulfate, 30% pull open powder, 5% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 50% organic tin stabilizer, 20% calcium-zinc composite stabilizing agent, 30% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 50% carbon black, 20% activated carbon, 30% natural silicate minerals.
Adsorbent contains a large amount of micropores, with huge specific surface area, can effectively adsorb organic and some inorganic pollutions.
The activator is dimethylaniline.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 50% calgon, 10% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 10% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 50% antimony oxide, 20% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 2000/ml, and particle diameter is more than 1500 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 30 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 230 DEG C, stops heating, is stirred 10 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
200 DEG C, injection pressure 60bar, 90/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 54MPa, and notch impact strength reaches
36KJ/m2, tensile strength are less than 1.4 by 26MPa, bending modulus 2200MPa, antiseized grade, and after inundation, deflection is less than
0.075, rupture strength 11.3.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 13000/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 99.32%, air sterilization effect killing rate is 99.12%.
Embodiment 4.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, in including following step
Suddenly.
Step 1：Get the raw materials ready, weigh following material by weight.
280 parts of acrylic resin；
3 parts of photo-catalytic nano powder；
125 parts of performance improvement agent；
8 parts of PE waxes；
8 parts of activator；
Double 3 parts of the oleamides of ethylene；
20 parts of inorganic combustion inhibitor；
12 parts of external lubricant；
8 parts of in-lubricant；
24 parts of stabilizer；
3 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 40%, tourmaline powder 5%, medical stone powder
1%th, albumen stone flour 1%, coupling agent 10%, sulphur ester antioxidant 2%, phosphite 2%, lauryl sodium sulfate 1%, dispersant 5%,
Wetting agent 1%, negative ion powder 5%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor to add
It is obtained after thermal agitation.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, albumen
Stone flour is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 60nm mixtures, then will be described mixed
Compound is added to heat in reactor with the other compositions of performance improvement agent and is stirred.At 100 DEG C, mixer rotating speed is heating and temperature control
500RPM, process time are 20min.
The coupling agent is titanate coupling agent.
The wetting agent include by weight percentage 50% lauryl sodium sulfate, 20% pull open powder, 10% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 20% organic tin stabilizer, 40% calcium-zinc composite stabilizing agent, 40% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 40% carbon black, 30% activated carbon, 30% natural silicate minerals.
The activator is the one kind in cobalt naphthenate.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 40% calgon, 20% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 10% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 1000/ml, and particle diameter is more than 1000 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 25 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 200 DEG C, stops heating, is stirred 8 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
180 DEG C, injection pressure 55bar, 88/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 51MPa, and notch impact strength reaches
33KJ/m2, tensile strength are less than 1.5 by 27MPa, bending modulus 2000MPa, antiseized grade, and after inundation, deflection is less than
0.098, rupture strength 10.5.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9600/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 99.02%, air sterilization effect killing rate is 99.02%.
Embodiment 5.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, in including following step
Suddenly.
Step 1：Get the raw materials ready, weigh following material by weight.
320 parts of acrylic resin；
3 parts of photo-catalytic nano powder；
150 parts of performance improvement agent；
8 parts of PE waxes；
8 parts of activator；
Double 3 parts of the oleamides of ethylene；
20 parts of inorganic combustion inhibitor；
12 parts of external lubricant；
8 parts of in-lubricant；
15 parts of stabilizer；
3 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 30%, tourmaline powder 5%, medical stone powder
1%th, albumen stone flour 1%, coupling agent 8%, sulphur ester antioxidant 2%, phosphite 2%, lauryl sodium sulfate 1%, dispersant 5%, wet
Profit agent 1%, negative ion powder 5%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor to heat
It is obtained after stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, opal
Powder is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 60nm mixtures, then by the mixing
Thing is added to heat in reactor with the other compositions of performance improvement agent and is stirred.At 100 DEG C, mixer rotating speed is heating and temperature control
500RPM, process time are 20min.
The coupling agent is titanate coupling agent.
The wetting agent include by weight percentage 50% lauryl sodium sulfate, 20% pull open powder, 10% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 30% organic tin stabilizer, 30% calcium-zinc composite stabilizing agent, 40% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 40% carbon black, 30% activated carbon, 30% natural silicate minerals.
The activator is the one kind in cobalt naphthenate.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 40% calgon, 10% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 15% tetrapotassium pyrophosphate, 15% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 1000/ml, and particle diameter is more than 1000 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 25 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 200 DEG C, stops heating, is stirred 8 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
180 DEG C, injection pressure 55bar, 88/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 50MPa, and notch impact strength reaches
32KJ/m2, tensile strength are less than 1.4 by 25MPa, bending modulus 1950MPa, antiseized grade, and after inundation, deflection is less than
0.085, rupture strength 10.5.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9600/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 99.12%, air sterilization effect killing rate is 99.02%.
Embodiment 6.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, in including following step
Suddenly.
Step 1：Get the raw materials ready, weigh following material by weight.
350 parts of acrylic resin；
3 parts of photo-catalytic nano powder；
100 parts of performance improvement agent；
8 parts of PE waxes；
8 parts of activator；
Double 3 parts of the oleamides of ethylene；
20 parts of inorganic combustion inhibitor；
12 parts of external lubricant；
8 parts of in-lubricant；
10 parts of stabilizer；
3 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 20%, tourmaline powder 5%, medical stone powder
1%th, albumen stone flour 1%, coupling agent 6%, sulphur ester antioxidant 2%, phosphite 2%, lauryl sodium sulfate 1%, dispersant 6%, wet
Profit agent 1%, negative ion powder 5%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor to heat
It is obtained after stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, opal
Powder is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 60nm mixtures, then by the mixing
Thing is added to heat in reactor with the other compositions of performance improvement agent and is stirred.At 100 DEG C, mixer rotating speed is heating and temperature control
500RPM, process time are 20min.
The coupling agent is titanate coupling agent.
The wetting agent include by weight percentage 50% lauryl sodium sulfate, 20% pull open powder, 10% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 30% organic tin stabilizer, 30% calcium-zinc composite stabilizing agent, 40% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 40% carbon black, 30% activated carbon, 30% natural silicate minerals.
The activator is the one kind in cobalt naphthenate.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 40% calgon, 10% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 15% tetrapotassium pyrophosphate, 15% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 1000/ml, and particle diameter is more than 1000 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 25 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 200 DEG C, stops heating, is stirred 8 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
180 DEG C, injection pressure 55bar, 88/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 50MPa, and notch impact strength reaches
32KJ/m2, by 25MPa, more than bending modulus 1800MPa, antiseized grade is less than 1.5 to tensile strength, and after inundation, deflection is less than
0.085, rupture strength 9.2.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9200/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 98.42%, air sterilization effect killing rate is 98.92%.
Embodiment 7.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, it is characterised in that bag
Include following steps.
Step 1：Get the raw materials ready, weigh following material by weight.
280 parts of acrylic resin；
2 parts of photo-catalytic nano powder；
125 parts of performance improvement agent；
6 parts of PE waxes；
6 parts of activator；
Double 2 parts of the oleamides of ethylene；
20 parts of inorganic combustion inhibitor；
6 parts of external lubricant；
5 parts of in-lubricant；
10 parts of stabilizer；
2 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 30%, tourmaline powder 3%, medical stone powder
0.5%th, albumen stone flour 0.5%, coupling agent 30%, sulphur ester antioxidant 1%, phosphite 2%, lauryl sodium sulfate 0.5%, dispersion
Agent 3%, wetting agent 0.5%, negative ion powder 3%, remaining is calcium carbonate.Its preparation method is to be put into anti-the raw material of performance improvement agent
Answer in kettle and be obtained after heating stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone
Powder, albumen stone flour are added in grinding equipment and carry out ultra-fine grinding, until obtaining particle diameter distribution in 50nm mixtures, then will
The mixture is added to heat in reactor with the other compositions of performance improvement agent and is stirred.Heating and temperature control at 95 DEG C, mixer
Rotating speed is 300RPM, and process time is 15min.
The coupling agent is silane coupler.
The wetting agent include by weight percentage 40% lauryl sodium sulfate, 10% pull open powder, 20% diisobutyl naphthalene
Sodium sulfonate, 30% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 40% OPE, 20% calcium stearate, 40% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 30% organic tin stabilizer, 40% calcium-zinc composite stabilizing agent, 30% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 30% carbon black, 50% activated carbon, 20% natural silicate minerals.
The activator is dimethylaniline.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 50% calgon, 20% sodium polyphosphate, 5% trimerization phosphorus
Sour potassium, 5% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 40% antimony oxide, 30% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 600/ml, and, more than 100 mesh, product purity is more than 90% for particle diameter.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 100 DEG C, stir 20 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 120 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 30 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 150 DEG C, stops heating, is stirred 5 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
175 DEG C, injection pressure 50bar, 85/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 52MPa, and notch impact strength reaches
35KJ/m2, tensile strength are less than 1.5 by 28MPa, bending modulus 2000MPa, antiseized grade, and after inundation, deflection is less than
0.092, rupture strength 10.2.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9700/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to remove
Rate is 99.42%, and air sterilization effect killing rate is 99.92%.
Embodiment 8.There is the preparation method of the anion plastic inside gadget for purifying in-car air function, it is characterised in that bag
Include following steps.
Step 1：Get the raw materials ready, weigh following material by weight.
250 parts of acrylic resin；
5 parts of photo-catalytic nano powder；
100 parts of performance improvement agent；
12 parts of PE waxes；
12 parts of activator；
Double 5 parts of the oleamides of ethylene；
15 parts of inorganic combustion inhibitor；
15 parts of external lubricant；
10 parts of in-lubricant；
20 parts of stabilizer；
5 parts of adsorbent；
Appropriate dyestuff.
Described performance improvement agent includes including by weight percentage：Sericite in powder 30%, tourmaline powder 5%, medical stone powder
2%th, albumen stone flour 2%, coupling agent 20%, sulphur ester antioxidant 3%, phosphite 3%, lauryl sodium sulfate 1%, dispersant 8%,
Wetting agent 1%, negative ion powder 10%, remaining is calcium carbonate.Its preparation method is that the raw material of performance improvement agent is put in reactor
It is obtained after heating stirring.In processability modifier, first by calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, egg
Albarium is added in grinding equipment and carries out ultra-fine grinding, until particle diameter distribution is obtained in 80nm mixtures, then will be described
Mixture is added to heat in reactor with the other compositions of performance improvement agent and is stirred.Heating and temperature control at 115 DEG C, mixer rotating speed
For 1000RPM, process time is 25min.
The coupling agent is aluminate coupling agent.
The wetting agent include by weight percentage 45% lauryl sodium sulfate, 30% pull open powder, 5% diisobutyl naphthalene
Sodium sulfonate, 20% glycerin monostearate.The wetting agent pH value is 5.5～7.5.
The in-lubricant include by weight percentage 60% OPE, 10% calcium stearate, 30% tristearin
Acid, external lubricant are paraffin.
Stabilizer include by weight percentage 50% organic tin stabilizer, 20% calcium-zinc composite stabilizing agent, 30% lead salt
The mixture of stabilizer.
The adsorbent include by weight percentage 50% carbon black, 20% activated carbon, 30% natural silicate minerals.
The activator is dimethylaniline.
Described photo-catalytic nano powder is nanometer titanium phosphate.
The dispersant include by weight percentage 50% calgon, 10% sodium polyphosphate, 10% trimerization phosphorus
Sour potassium, 10% tetrapotassium pyrophosphate, 10% zinc stearate, 10% polyacrylate.
Inorganic combustion inhibitor include by weight percentage 50% antimony oxide, 20% magnesium hydroxide, 30% hydroxide
Aluminium.
The anion-generating capacity of the negative ion powder is 2000/ml, and particle diameter is more than 1500 mesh, and product purity is more than
90%.
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat temperature raising
To 105 DEG C, stir 30 minutes, start mixer and be stirred, form mixed material.
Step 3：Mixed material temperature is risen to 125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in cold mixed processor, drops to 40 DEG C.
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into
In high temperature mixer, and the mixed material that step 3 is obtained is added, and heats to 230 DEG C, stops heating, is stirred 10 minutes.
Step 5：The material for obtaining is put into injection machine and mold injection molding.Injection machine technological parameter is：Extruder temperature
200 DEG C, injection pressure 60bar, 90/s of injection speed.
After tested, automotive interior material obtained in the present invention, tensile strength reach 50MPa, and notch impact strength reaches
33KJ/m2, by 26MPa, more than bending modulus 1900MPa, antiseized grade is less than 1.4 to tensile strength, and after inundation, deflection is less than
0.087, rupture strength 9.6.Fire protecting performance is A levels, and VCM do not detect, and soluble metal lead, volatile matter meet country
Standard.Anion burst size is 9600/cm3.Making automatic foot-mat, automotive upholstery uses in-car, PM2.5 effectively to go
Except rate is 98.22%, air sterilization effect killing rate is 98.23%.
Above content is detailed description made for the present invention in conjunction with specific embodiments, it is impossible to assert that the present invention is concrete
Implement to be only limitted to these explanations.For those skilled in the art, without departing from present inventive concept
Under the premise of, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.
Claims (10)
1. there is the preparation method of the anion plastic inside gadget for purifying in-car air function, it is characterised in that including following step
Suddenly：
Step 1：Get the raw materials ready, weigh by weight
200～350 parts of acrylic resin；
2～5 parts of photo-catalytic nano powder；
80～150 parts of performance improvement agent；
6～12 parts of PE waxes；
6～12 parts of activator；
Double 2～5 parts of the oleamides of ethylene；
12～25 parts of inorganic combustion inhibitor；
6～15 parts of external lubricant；
5～10 parts of in-lubricant；
10～25 parts of stabilizer；
2～5 parts of adsorbent；
Appropriate dyestuff；
The preparing raw material of described performance improvement agent include sericite in powder, calcium carbonate, tourmaline powder, medical stone powder, albumen stone flour,
Coupling agent, sulphur ester antioxidant, phosphite, lauryl sodium sulfate, dispersant, wetting agent, negative ion powder；Its preparation method
Be that the raw material of performance improvement agent is put in reactor after heating stirring to be obtained, heating and temperature control at 95～115 DEG C, mixer
Rotating speed is 300～1000RPM, and process time is 15～25min；
The coupling agent is silane coupler, titanate coupling agent, the mixture of one or more in aluminate coupling agent；
The wetting agent is lauryl sodium sulfate that pH value is 5.5～7.5, pull open powder, diisobutyl sodium naphthalene sulfonate, single stearic
The mixture of one or more in acid glyceride；
The adsorbent is carbon black, bamboo charcoal powder, activated carbon, diatomite, one or several in natural silicate minerals；
Described photo-catalytic nano powder is nanometer titanium phosphate；
The dispersant is calgon, sodium polyphosphate, PTPP, tetrapotassium pyrophosphate, zinc stearate, polyacrylic acid
The mixture of one or more in salt；
Inorganic combustion inhibitor is one or several of antimony oxide, magnesium hydroxide, aluminium hydroxide；
Step 2：Weigh in acrylic resin, performance improvement agent input mixer according to the weight proportion, heat to 100
～105 DEG C, stir 20～30 minutes, start mixer and be stirred, form mixed material；
Step 3：Mixed material temperature is risen to 120～125 DEG C, stops stir process；The mixed material is transferred to one
Cooling is slowly stirred in individual cold mixed processor, drops to 30 DEG C～40 DEG C；
Step 4：Other raw materials in addition to acrylic resin, performance improvement agent are weighed according to weight proportion and is put into high temperature
In mixer, and the mixed material that step 3 is obtained is added, and heats to 150～230 DEG C, stops heating, stirring 5～10
Minute；
Step 5：The material for obtaining is put into injection machine and mold injection molding.
2. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：Stabilizer include by weight percentage 10～50% organic tin stabilizer, 20～40% calcium-zinc composite stabilizing agent, 30
The mixture of～40% lead salt stabilizer.
3. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：The in-lubricant include by weight percentage 40～60% OPE, 10～30% calcium stearate, 30
～50% stearic acid, external lubricant are paraffin.
4. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：The activator is dimethylaniline, the one kind in cobalt naphthenate.
5. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：
Described performance improvement agent includes by weight percentage：Calcium carbonate 40～80%, sericite in powder 20～40%, tourmaline powder 3
～5%, medical stone powder 0.5～2%, albumen stone flour 0.5～2%, coupling agent 12～35%, sulphur ester antioxidant 1～3%, phosphite
2～3%, lauryl sodium sulfate 0.5～1%, dispersant 3～8%, wetting agent 0.5～1%, negative ion powder 3～15%.
6. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 5, which is special
Levy and be：
Described performance improvement agent includes by weight percentage：Calcium carbonate 50～65%, sericite in powder 15～20%, tourmaline powder 3
～5%, medical stone powder 0.5～1%, albumen stone flour 0.5～1%, coupling agent 12～20%, sulphur ester antioxidant 1～3%, phosphite
2～3%, lauryl sodium sulfate 0.5～1%, dispersant 5～7%, wetting agent 0.5～1%, negative ion powder 3～15%；
In processability modifier, calcium carbonate, sericite in powder, tourmaline powder, medical stone powder, albumen stone flour are added grind first
Ultra-fine grinding is carried out in mill equipment, until obtain particle diameter distribution in 50～80nm mixtures, then by the mixture with
The other compositions of performance improvement agent are added to heat in reactor and are stirred, and at 100～115 DEG C, mixer rotating speed is heating and temperature control
600～900RPM, process time are 20～23min.
7. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：
The dispersant includes by weight percentage：30～50% calgon, 10～20% sodium polyphosphate, 5～20%
PTPP, 5～10% tetrapotassium pyrophosphate, 5～10% zinc stearate, 5～10% polyacrylate；The moistening
Agent include by weight percentage 40～50% lauryl sodium sulfate, 10～30% pull open powders, 5～20% diisobutyl naphthalene sulfonic acids
Sodium, 20～50% glycerin monostearates.
8. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：
The adsorbent includes by weight percentage：30～50% carbon black, 30～50% activated carbon, 30～50% natural silicon
Hydrochlorate mineral.
9. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：
Inorganic combustion inhibitor includes by weight percentage：30～50% antimony oxide, 20～40% magnesium hydroxide, 30～50%
Aluminium hydroxide；The anion-generating capacity of the negative ion powder is 600～2000/ml, and particle diameter is more than 100～1500 mesh, product
Product purity is more than 90%.
10. there is the preparation method of the anion plastic inside gadget for purifying in-car air function as claimed in claim 1, which is special
Levy and be：Injection machine technological parameter is：175～200 DEG C of extruder temperature, 50～60bar of injection pressure, injection speed 85～90
㎜/s.
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Cited By (4)
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| CN107321308A (en) * | 2017-07-19 | 2017-11-07 | 张翔 | It is a kind of for material of indoor air purification and preparation method thereof |
| CN108164832A (en) * | 2017-12-25 | 2018-06-15 | 广州科苑新型材料有限公司 | PP composite materials with negative ion-releasing function and preparation method and application |
| CN109734985A (en) * | 2018-12-27 | 2019-05-10 | 常州市福欧车辆配件有限公司 | Macromolecule composite foot pad preparation method |
| CN110204827A (en) * | 2019-06-11 | 2019-09-06 | 东莞市欧诗特塑胶五金科技有限公司 | A kind of goods of furniture for display rather than for use utensil and its production technology |
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| CN101033317A (en) * | 2006-05-24 | 2007-09-12 | 卓玉国 | Preparation of multifunctional wood-plastic composite material |
| CN103924756A (en) * | 2014-03-22 | 2014-07-16 | 烟台斯坦普精工建设有限公司 | Ceiling with indoor air purification function and manufacturing method thereof |
| CN104497417A (en) * | 2014-12-17 | 2015-04-08 | 山东鑫海新材料股份有限公司 | Flame-retardant and environment-friendly material for electric automotive trims and preparation method of material |
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| CN101033317A (en) * | 2006-05-24 | 2007-09-12 | 卓玉国 | Preparation of multifunctional wood-plastic composite material |
| CN103924756A (en) * | 2014-03-22 | 2014-07-16 | 烟台斯坦普精工建设有限公司 | Ceiling with indoor air purification function and manufacturing method thereof |
| CN104497417A (en) * | 2014-12-17 | 2015-04-08 | 山东鑫海新材料股份有限公司 | Flame-retardant and environment-friendly material for electric automotive trims and preparation method of material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107321308A (en) * | 2017-07-19 | 2017-11-07 | 张翔 | It is a kind of for material of indoor air purification and preparation method thereof |
| CN108164832A (en) * | 2017-12-25 | 2018-06-15 | 广州科苑新型材料有限公司 | PP composite materials with negative ion-releasing function and preparation method and application |
| CN109734985A (en) * | 2018-12-27 | 2019-05-10 | 常州市福欧车辆配件有限公司 | Macromolecule composite foot pad preparation method |
| CN110204827A (en) * | 2019-06-11 | 2019-09-06 | 东莞市欧诗特塑胶五金科技有限公司 | A kind of goods of furniture for display rather than for use utensil and its production technology |
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