CN1342448A - Mascara containing vinyl lactam - Google Patents
Mascara containing vinyl lactam Download PDFInfo
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- CN1342448A CN1342448A CN 01132835 CN01132835A CN1342448A CN 1342448 A CN1342448 A CN 1342448A CN 01132835 CN01132835 CN 01132835 CN 01132835 A CN01132835 A CN 01132835A CN 1342448 A CN1342448 A CN 1342448A
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- carboxylic acid
- unsaturated carboxylic
- film forming
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A transparent or translucent mascara composition for curving eyelashes, comprises a vinyl lactam film forming polymer, an ethylenically unsaturated carboxylic acid and optionally a hydrophobic monomer. The invention also relate to methods of coating the mascaras which can curve eyelashes nicely and forming a transparent coating.
Description
Technical field
The mascara that the present invention relates to contain the vinyl lactam polymer is used to make the purposes of crimping eyelash.The invention still further relates to the transparent or semitransparent eyelashes compositions that contains this polymer.This purposes of the present invention and said composition are specially adapted to people's eyelashes or false eyelashes.Term " mascara " is meant the product (also claim outside oiling) of eyelashes with make-up composition, cosmetic substrate, coating on the layer of making up, or the eyelashes beauty treatment care product.
Background technology
Generally contain film forming polymer in the mascara, thereby when the coating eyelashes, on eyelashes, apply a skim.This class mascara is is specifically recorded and narrated in document WO 91/1273, EP-A-530084 and WO 95/15741.The user seeks to make the remarkable mascara that curls of eyelashes.But be not that all film forming polymers all can reach gratifying crimping eyelash effect.In addition, some film forming polymer for example hydroxyethyl-cellulose or hydroxypropyl chitosan be filmed can forming white on eyelashes after the mummification, causes indecency dressing effect.Therefore this base polymer should not be used for limpid mascara.
Therefore, need have good curl characteristics and can on eyelashes, form the mascara of transparent dressing effect especially.
Summary of the invention
Therefore, the objective of the invention is to propose a kind of eyelashes compositions that contains film forming polymer, it can make eyelashes have good curl characteristics, can form transparent coating especially when it is coated on the eyelashes.
The applicant finds to adopt the vinyl lactam polymer can obtain such mascara.Adopt this base polymer can obtain to make the mascara of crimping eyelash.In addition, this film forming polymer forms transparent coating, make the eyelashes typing and do not change its appearance color: therefore can use and adopt this base polymer in the coating composition, thereby can obtain being different from the transparent or semitransparent compositions of conventional coloured mascara own at curling eyelashes.In addition, the transparent or semitransparent compositions of this class both can be coated on the coloured mascara that has been deposited on the eyelashes, so that eyelashes curl more and do not change the color of application of mascaras, also can before the coloured mascara of coating, directly be coated on the eyelashes, to reach required crimping eyelash effect.
More particularly, a theme of the present invention is to adopt a kind of eyelashes with compositions be used for the curling purposes of eyelashes, and these eyelashes contain the film forming polymer of a kind of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer in the acceptable medium on improving looks with compositions.
Another theme of the present invention is a kind of transparent or semitransparent eyelashes with compositions be used for the curling purposes of eyelashes, and these eyelashes contain the film forming polymer of a kind of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer in the acceptable medium on improving looks with compositions.
Another theme of the present invention is that the film forming polymer with a kind of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer is used for a kind ofly containing eyelashes that beauty treatment goes up acceptable medium with the purposes of compositions with the eyelashes that curl.
Another theme of the present invention is a kind of transparent or semitransparent eyelashes compositions, it contains a kind of film forming polymer in acceptable medium in beauty treatment, it is characterized in that this film forming polymer is the polymer of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer.
Another theme of the present invention is a kind of eyelash, and it comprises the container that contains above-mentioned eyelashes usefulness compositions, and adds the system of coating said composition on eyelashes.
Another theme of the present invention is the method for coating eyelashes, and it comprises above-mentioned eyelashes are coated on the eyelashes with compositions.The method of coating eyelashes specifically is a kind of non-therapeutic beauty and make-up or care method that is used for eyelashes.
Term " acceptable medium in the beauty treatment " is meant the medium compatible with horn.
The film forming polymer that is present in the used mascara of the present invention is the polymer that is obtained through polyreaction by vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer.
Vinyl lactam can be vinyl pyrrolidone or caprolactam.The preferred vinyl pyrrolidone that adopts.
The ethylenic unsaturated carboxylic acid can be selected from: (methyl) acrylic acid, itaconic acid, maleic acid and .beta.-methylacrylic acid.The preferred acrylic acid that adopts.
Term " hydrophobic monomer " is meant that its homopolymer is water insoluble and contains the monomer of 1-4 carbon atom lower alcohol or water and lower alcohol mixture.
Hydrophobic monomer can be Arrcostab ((methyl) acrylic acid C particularly of alpha-olefin, alkyl vinyl ether, ethylenic unsaturated carboxylic acid
6-C
30Arrcostab), N-alkyl (methyl) acrylamide, N, N-dialkyl group (methyl) acrylamide, C
6-C
30The vinyl esters of carboxylic acid is (by vinyl alcohol and C
6-C
30Carboxylic esterification makes), N-cyclopolymers of alkyldiallylamine and salt thereof, wherein alkyl contains at least 6 (particularly 6-30) carbon atoms.
That is worth mentioning in the example of hydrophobic monomer has:
-alpha-olefin: hexadecene, vaccenic acid, to propylstyrene;
-alkyl vinyl ether: octadecyl vinyl ether, cetyl vinylether;
The Arrcostab of-ethylenic unsaturated carboxylic acid: (methyl) 2-EHA, (methyl) 1-Octyl acrylate, (methyl) acrylic acid Lauryl Ester, (methyl) stearyl acrylate base ester;
-N-alkyl (methyl) acrylamide: N-dodecyl methyl acrylamide, N-octadecyl methyl acrylamide;
-N, N-dialkyl group (methyl) acrylamide: N, N-dihexyl Methacrylamide;
-C
6-C
30The vinyl esters of carboxylic acid: octadecanoid acid vinyl esters, hexadecanoic acid vinyl esters, vinyl-acetic ester.
Used hydrophobic monomer is the C of ethylenic unsaturated carboxylic acid preferably
6-C
30Arrcostab, particularly (methyl) acrylic acid C
6-C
30Arrcostab is more preferably methacrylic acid C
8-C
16Arrcostab as methacrylic acid Lauryl Ester or methacrylic acid stearyl, preferably adopts the methacrylic acid Lauryl Ester.
Can comprise the following component of percentage by weight in the film forming polymer in total polymer weight:
-20-99% vinyl lactam,
-1-55% ethylenic unsaturated carboxylic acid,
-0-25% (particularly 1-25%) hydrophobic monomer.
Be preferably and can comprise the following component of percentage by weight in the membrane polymer in total polymer weight:
-40-85% (more preferably 40-70%) vinyl lactam,
-1-55% (more preferably 15-40%) ethylenic unsaturated carboxylic acid,
-1-25% (more preferably 5-20%) hydrophobic monomer.
Film forming polymer is suitable for basic terpolymer by vinyl lactam, ethylenic unsaturated carboxylic acid and hydrophobic monomer and constitutes.This base polymer is specifically sold with title " Acrylidonee " by ISP company.
Film forming polymer is known in the prior art, and specifically is found in patent US-A-5015708.
Particularly preferred a kind of polymer is vinyl pyrrolidone/acrylic acid/methacrylic acid Lauryl Ester terpolymer; This polymer is sold (weight ratio is respectively 68/23/9) by ISP company with title " AcrylidoneLM ".
In the present composition, the content that contains the film forming polymer of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer can account for the 0.1-15% (weight) of composition total weight, be preferably 0.5-10% (weight), more preferably 1-5% (weight).
Be used for compositions of the present invention except that containing film forming polymer, also can contain at least a wax.
In this application, term " wax " is meant under room temperature (25 ℃) and is solid lipophilic cpd that it can change through reversible liquid/solid, and fusing point is up to 120 ℃ more than or equal to 30 ℃.By wax being changed into liquid state (fusion), can make it miscible, and form the mixture of microcosmic homogenizing, but when mixture temperature ash during again to room temperature, recrystallization can appear in the wax in the mixture oil with oil.
Wax is optional from animal wax, vegetable wax, mineral wax, synthetic wax, and the different fractions of native paraffin.The content of wax can account for the 0.5-40% (weight) (particularly 2-40% (weight)) of composition total weight, is preferably 5-30% (weight), more preferably 10-25% (weight).
That is worth mentioning in the animal wax has Cera Flava, lanocerin and white beeswax.
That is worth mentioning in the vegetable wax has: rice bran wax, Brazil wax, candelilla wax, ouricury wax, cork fibrous wax, cerosin, Japan wax, sumac wax and cotton wax.
That is worth mentioning in the mineral wax has: paraffin, microwax, montan wax and ceresine.
Particularly suitable is polyolefin-wax in the synthetic wax, Tissuemat E particularly, and through the wax that Fischer-Tropsch synthesis is made, its wax shape copolymer and ester, and silicone waxes.
Also can adopt hydrogenated animal oil or vegetable oil.That is worth mentioning in these oil has: by straight chain or non-straight chain C
8-C
32The hydrogenated oil and fat that the fatty material that aliphatic chain constitutes makes through catalytic hydrogenation, hydrogenation Oleum helianthi, castor oil hydrogenated, hydrogenated coconut oil, hydrogenated jojoba oil, hydrogenated lanolin and hydrogenated palm oil.
The wax that is applicable to the present composition preferably is solid under 50 ℃ the condition and is inflexible being lower than.
Wax is suitable for being selected from that fusing point is 70-110 ℃, particularly needling method hardness is the wax of 1-7.5.This class wax can keep the good of eyelashes to curl.The needling method hardness of wax adopts French Standard NF T 60-123 or Unite States Standard ASTM D 1321 to measure, and measuring temperature is 25 ℃.According to these standards, needling method hardness is measuring of the degree of depth, and the standard pricker that its sign is installed in the heavy 2.5g on the moving component that weighs 97.5g places on the tested wax, and the degree of depth of thrusting wax through 5 seconds is in 0.1 millimeter.
Also can contain at least a other film forming polymer except that above-mentioned vinyl lactam film forming polymer in the said composition, its content can account for the 0-15% (weight) (particularly 0.1-15% (weight)) of composition total weight, more preferably 0.1-10% (weight).
That is worth mentioning in its film forming polymer altogether for example has:
-cellulosic polymer is as hydroxyethyl-cellulose, hydroxypropyl cellulose, Cellulose ethyl hydroxypropyl ether or ethylhydroxyethylcellulose;
-acrylate polymer or copolymer are as polyacrylate or polymethacrylates;
-polyvinyl, for example vinyl-acetic ester polymer; Polyvinyl alcohol;
-polyurethane, polyester, polyamide and epoxy ester resin;
The polymer of the natural origin of-optional modification is as Radix Acaciae senegalis, guar gum, xanthan derivatives and karaya;
-and their mixture.
The compositions that is applicable to purposes of the present invention can be the aqueous gel form, water bag wax, wax Bao Shui, oil-in-water and water-in-oil type dispersion.Water content can account for the 1-95% (weight) of composition total weight, more preferably 10-80% (weight).
According to a specific embodiments of the present invention, said composition is transparent or semitransparent.This transparent or semitransparent compositions is the content of wax not specifically, still can make eyelashes have good curl characteristics simultaneously.
This transparent or semitransparent compositions is coated on the eyelashes, treats can form the transparent coating that is coated on the eyelashes after the mummification.Therefore obtained transparent and had the mascara of curling action.This mascara can make crimping eyelash and don't can change its appearance color: it is applicable to the curling effect of the eyelashes that improvement has been made up by the mascara that does not have or do not have substantially curl characteristics fully, and can not change the color that has been coated in the cosmetics on the eyelashes.Also this class mascara directly can be coated on the eyelashes, and then on formed transparent coating, apply coloured mascara.Therefore this coating composition is applicable to the colourless typing of eyelashes fully.
According to the present invention, term " transparent composition " is meant that compositions can make the light transmission and refraction or reflection migrating can not take place.Can adopt scopometer to measure the transparency of compositions.For example can adopt the portable turbidimeter 2100P type that derives from Hach company, be used to measure the transparency scope of compositions.Think that compositions is transparent when the measured value of turbidity during for 0-250NTU, think that when turbidity value is 250-1000 NTU compositions is translucent.
Term " the not compositions of the content of wax " is meant that the content of wax in the compositions is lower than 0.4% (weight) of composition total weight, preferably is lower than 0.2% (weight), perhaps the more preferably content of wax not fully.
Can contain the additive of mentioning among other the application in the transparent composition, condition is the transparent characteristic that keeps compositions.
Be applicable in the compositions of purposes of the present invention and also can contain at least a ethereal oil.Term " ethereal oil " is meant the oil that at room temperature can evaporate from coated support face, promptly at room temperature have can survey vapour pressure oil.
Specifically can adopt one or more at room temperature volatilizable oil, and if its boiling point greater than 30 ℃, its vapour pressure that has under the normal pressure and temperature condition is greater than 0 millimetres of mercury (0Pa), particularly 10
-3-300 millimetress of mercury (0.13Pa-40000Pa).This class ethereal oil is suitable for obtaining to have " makeup-removing prevention " characteristic and well filming of retain strength fully.This class ethereal oil also can make compositions be easy to apply on eyelashes.These oil can be to contain hydrocarbon ils, polysiloxane oil, fluorinated oil or their mixture.
Term " contains hydrocarbon ils " and is meant and mainly contains H and C and the optional oil that contains O, N, S or P atom.It specifically is the hydrocarbon ils that contains, particularly C that contains 8-16 carbon atom that the preferred volatile that is applicable to the present composition contains hydrocarbon ils
8-C
16Isoparaffin (or claiming isomery paraffin), and C
8-C
16Branched ester, Fancol ID (being also referred to as 2,2,4,4, the 6-five methylheptane) for example, isodecane, 2-Methylpentadecane, or isohesyl pivalate, and their mixture.Other volatility contain hydrocarbon ils for example petroleum distillate also be suitable for, particularly by Shell company with title Shell Solt product sold.
Other ethereal oils that are suitable for have Y 7175, for example ring-type and Y 7175 oil, particularly viscosity≤8 centistokes (8 * 10
-6m
2/ s) this composition, as octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, ten pregnancy basic rings, six siloxanes, the volatile straight chain polysiloxanes, as octamethyltrisiloxane, seven methyl hexyl trisiloxanes, seven Methyl Octyl trisiloxanes and decamethyl tetrasiloxanes, or the volatility fluorinated oil, as nine fluoro methyl butyl ethers or perfluorinate methyl cyclopentane.
Be applicable to that the content of ethereal oil in the compositions of the present invention can account for the 0-80% of composition total weight (particularly 1% to 80% weight), is preferably 0-65% (weight) (particularly 1-65% weight).
The compositions that is applicable to purposes of the present invention can contain emulsifying surfactant, and its content accounts for the 2-30% (weight) of composition total weight, more preferably 5-15% (weight).These surfactants can be selected from anion surfactant and non-ionic surface active agent.But list of references " encyclopedia of chemical technology, Kirk-Othmer " (the 22nd volume, the 333-432 page or leaf, the 3rd edition, 1979, Wiley) determine the anion surfactant and the non-ionic surface active agent of 347-377 page or leaf of the definition, particularly this list of references of the characteristic of surfactant and function (emulsification function).
The preferred surfactant that adopts can be selected from:
-non-ionic surface active agent: the fatty acid ester of fatty acid, aliphatic alcohol, polyethoxylated or bound to polyglycerol aliphatic alcohol such as polyethoxylated stearyl alcohol or cetyl stearyl alcohol, sucrose, alkyl glucose ester, particularly polyoxyethylene C
1-C
6The fatty ester of alkyl glucose, polysiloxane surfactant such as dimethicone copolyol, and their mixture.
-anion surfactant: through the neutral C of amine, ammonia or alkali metal salt
16-C
30Fatty acid, and their mixture.
The compositions that is applicable to purposes of the present invention can contain at least a coloring agent such as powder compounds, and its content for example can account for the 0.01-25% (weight) of composition total weight.The powder compounds can be selected from pigment and/or pearly-lustre delustering pigment and/or the filler that is usually used in mascara.
Pigment can be white or colored, and can be inorganic and/or organic.That is worth mentioning in the inorganic pigment has titanium dioxide, and it is randomly through surface treatment, zirconium oxide or cerium oxide, and ferrum oxide or chromium oxide, manganese violet, ultramarine, chromic oxide gel and barba hispanica.That is worth mentioning in the organic pigment has white carbon black, a D﹠amp; C class pigment and based on the color lake of carmine, barium, strontium, calcium or aluminum.
Pearlescent pigment is optional from white pearlescent pigment, as the Muscovitum that coats through titanium or bismuth oxychloride, the odenite of coloured pearlescent pigment as coating, the particularly odenite that coats through barba hispanica or chromium oxide through ferrum oxide, the odenite that coats through above-mentioned organic pigment, and based on the pearlescent pigment of bismuth oxychloride.
Filler can be selected from those skilled in the art and know and be usually used in those compositions in the cosmetic composition.The filler that is suitable for specifically can be:
-Pulvis Talci, its for usually being lower than the hydrated magnesium silicate that 40 micron particle forms are used,
-Muscovitum, it is the different aluminosilicates of forming, stratiform form for 2-200 micron size, be preferably 5-70 micron size, and be the 0.1-5 micron thickness, preferred 0.2-3 micron thickness, these Muscovitums can be natural origins, as be white mica, emerylite, roscoelite, lipidolite or biotite, or be synthetic the source.
-starch, particularly rice starch,
-Kaolin, its aluminium hydrosilicate for existing with isotropic particle form, its particle diameter generally is lower than 30 microns,
-zinc oxide and titanium oxide, it is generally size and is no more than several microns particle form,
-calcium carbonate, magnesium carbonate or magnesium bicarbonate,
-microcrystalline Cellulose,
-silicon dioxide,
-synthetic polymer powder such as polyethylene, polyester (polyethylene glycol isophthalate or polyethylene terephthalate), polyamide are as with trade name " nylon " or " polytetrafluoroethylene " product sold, and the polysiloxanes powder.
Be applicable in the compositions of purposes of the present invention and also can contain the composition that is usually used in cosmetics, as trace element, softening agent, chelating agen, spice, thickening agent, vitamin, protein, ceramide, plasticizer and binding agent, and basifier or acidulant, emollient and antiseptic.
The compositions that is applicable to purposes of the present invention does not preferably contain:
The mixture of-cationic polymer, hydrogenated vegetable oil and polyoxygenated alkylene polysiloxanes, it is described that it is found in patent application FR-A-2789894; Perhaps
-cationic polymer and (methyl) acrylic acid C
1-C
6The mixture of Arrcostab aqueous dispersion; Or
The mixture of-cationic polymer and aqueous polyurethane dispersion.
Need not go into the details, those skilled in the art tackle optional attached as chemical compound and/or the careful selection of its consumption of this or this class, so that its possible adding can or can not have a negative impact to the beneficial characteristics of the present composition substantially.
The compositions that is applicable to purposes of the present invention can be prepared according to this area method commonly used through consideration.
Compositions of the present invention specifically can be used in the eyelashes product, and this product comprises the system that contains the described eyelashes container of compositions, applies described compositions on eyelashes.This container is equipped with the opening that can hold the brushing system by known way.The brushing system can comprise brush holder, and the one end has brushing, the other end has the lid that can seal this container.This class packing specifically can be referring to the accompanying drawing 7 of patent application EP-A-611170, and it is introduced in the present invention as a reference.
Adopt following examples to further specify the present invention.
Embodiment 1:
Preparation has the limpid mascara of following composition:
-vinyl pyrrolidone/acrylic acid/methacrylic acid Lauryl Ester terpolymer is sold 2.6g by ISP with title Acrylidone LM
-be present in polyvinylpyrrolidone/vinyl-acetic ester copolymer in the ethanol with 50% weight, sell 3.5gAM by BASF AG with title Luviskol VA 73 E
-CVP Carbopol ETD2050 (available from the synthalen K of 3VSA company) 0.6g
-amino methyl propanol 0.65g
-triethanolamine 0.6g
-dimethicone copolyol (available from the Q2 5220 of Dow Coming) 1g
-antiseptic qs
-water qs 100g
This mascara is a transparent gel form, can make eyelashes be easy to typing.After the mummification, it can form transparent coating on eyelashes, and makes eyelashes well curl.
Embodiment 2:
Preparation has the mascara of following composition:
-Brazil wax 4.7g
-rice bran wax 2.2g
-paraffin 2.2g
-Cera Flava 8.2g
-Pulvis Talci 1g
-bentonite 5g
-vinyl-acetic ester/stearic acid allyl ester copolymer (65/35) 6.7g
-polyoxyethylene lauryl vinyl acetate (available from the Mexomer PP of Chimex) 0.7g
-Fancol ID 52.8g
-propylene carbonate 1.6g
-vinyl pyrrolidone/acrylic acid/methacrylic acid Lauryl Ester terpolymer is sold 0.58g by ISP with title Acrylidone LM
-amino methyl propanol 0.14g
-pigment 4.9g
-antiseptic qs
-water qs 100g
Make the waterproof mascara, it is easy to evenly coating on eyelashes, can make eyelashes well curl.
Embodiment 3:
(a) preparation has the Brazil wax differential prose style free from parallelism of following composition:
-Brazil wax 30g
-polyoxyethyleneization (30EO) glyceryl monostearate (available from the Tagat S of Goldschmidt) 7.5g
-antiseptic 0.3g
-water qs 100g
Wax, surfactant and antiseptic are heated to 95 ℃, simultaneously this chemical compound of moderate agitation homogenize.Continuing to add the water that has been heated to 95 ℃ under the stirring then.This mixture is cooled to room temperature, makes the wax differential prose style free from parallelism that mean diameter is about 285nm.
(b) preparation has the mascara of following composition:
-(a) in the preparation wax differential prose style free from parallelism 5g
-vinyl pyrrolidone/acrylic acid/methacrylic acid Lauryl Ester terpolymer is sold 2.6g by ISP with title Acrylidone LM
-be present in polyvinylpyrrolidone/vinyl-acetic ester copolymer in the ethanol with 50% weight, sell 3.5gAM by BASF AG with title Luviskol VA 73 E
-CVP Carbopol ETD2050 (available from the Synthalen K of 3VSA company) 0.6g
-amino methyl propanol 0.65g
-triethanolamine 0.6g
-dimethicone copolyol (available from the Q2 5220 of Dow Coning) 1g
-antiseptic qs
-water qs 100g
Make the mascara with curling action, it is easy to evenly coating on eyelashes.
Claims (33)
1. eyelashes are used to make the purposes of crimping eyelash with compositions, said composition contains the film forming polymer of a kind of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer in the acceptable medium in beauty treatment, said composition not cation-containing copolymer or
-hydrogenated vegetable oil and polyoxygenated alkylene polysiloxanes, or
-(methyl) acrylic acid C
1-C
6The aqueous dispersion of Arrcostab; Or
-polyurethane aqueous dispersion.
2. the purposes of claim 1 is characterized in that said composition is transparent or semitransparent.
3. transparent or semitransparent eyelashes are used to make the purposes of crimping eyelash, said composition to contain the film forming polymer of a kind of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer in the acceptable medium in beauty treatment with compositions.
The film forming polymer of vinyl lactam, ethylenic unsaturated carboxylic acid and optional hydrophobic monomer at a kind of eyelashes that contain acceptable medium in the beauty treatment with in the compositions, the purposes of the eyelashes that are used for curling.
5. each purposes is characterized in that said composition can form transparent or semitransparent filming on eyelashes during aforesaid right required.
6. each purposes is characterized in that the ethylenic unsaturated carboxylic acid in the described film forming polymer is selected from: (methyl) acrylic acid, itaconic acid, maleic acid and .beta.-methylacrylic acid during aforesaid right required.
7. each purposes is characterized in that the ethylenic unsaturated carboxylic acid in the described film forming polymer is (methyl) acrylic acid during aforesaid right required.
8. each purposes is characterized in that vinyl lactam is selected from: vinyl pyrrolidone and caprolactam during aforesaid right required.
9. each purposes is characterized in that described vinyl lactam is a vinyl pyrrolidone during aforesaid right required.
10. each purposes during aforesaid right requires is characterized in that containing in the film forming polymer vinyl lactam that accounts for total polymer weight 20-99% weight and the ethylenic unsaturated carboxylic acid of 1-55% weight.
11. each purposes during aforesaid right requires is characterized in that hydrophobic monomer is selected from: the Arrcostab of alpha-olefin, alkyl vinyl ether, ethylenic unsaturated carboxylic acid ((methyl) acrylic acid C particularly
6-C
30Arrcostab), N-alkyl (methyl) acrylamide, N, N-dialkyl group (methyl) acrylamide, C
6-C
30The vinyl esters of carboxylic acid, N-cyclopolymers of alkyldiallylamine and salt thereof, wherein alkyl contains at least 6 carbon atoms.
12. each purposes is characterized in that hydrophobic monomer is ethylenic unsaturated carboxylic acid C during aforesaid right required
6-C
30Arrcostab.
13. each purposes is characterized in that hydrophobic monomer is selected from methacrylic acid Lauryl Ester and methacrylic acid stearyl during aforesaid right required.
14. each purposes during aforesaid right requires is characterized in that described film forming polymer comprises:
-account for the ethylenic unsaturated carboxylic acid of total polymer weight 20-90% weight,
-1-55% weight vinyl lactam,
-1-25% weight hydrophobic monomer.
15. each purposes during aforesaid right requires is characterized in that described film forming polymer comprises:
-account for the ethylenic unsaturated carboxylic acid of total polymer weight 40-70% weight,
-15-40% weight vinyl lactam,
-5-20% weight hydrophobic monomer.
16. each purposes is characterized in that the content of described film forming polymer accounts for the 0.1-15% weight of composition total weight, is preferably 0.5-10% weight during aforesaid right required.
17. each purposes during aforesaid right requires is characterized in that in the said composition the not content of wax.
18. transparent or semitransparent eyelashes compositions, it contains a kind of film forming polymer in acceptable medium in beauty treatment, it is characterized in that this film forming polymer is the polymer of ethylenic unsaturated carboxylic acid and vinyl lactam.
19. the compositions of claim 18 is characterized in that the ethylenic unsaturated carboxylic acid is selected from: (methyl) acrylic acid, itaconic acid, maleic acid and .beta.-methylacrylic acid.
20. each compositions in claim 18 and 19 is characterized in that the ethylenic unsaturated carboxylic acid in the described film forming polymer is (methyl) acrylic acid.
21. each compositions among the claim 18-20 is characterized in that vinyl lactam is selected from: vinyl pyrrolidone and caprolactam.
22. each compositions among the claim 18-21 is characterized in that described vinyl lactam is a vinyl pyrrolidone.
23. each compositions among the claim 18-22 is characterized in that containing in the film forming polymer vinyl lactam that accounts for total polymer weight 20-99% weight and the ethylenic unsaturated carboxylic acid of 1-55% weight.
24. each compositions among the claim 18-23 is characterized in that film forming polymer is the polymer of vinyl lactam, ethylenic unsaturated carboxylic acid and hydrophobic monomer.
25. the compositions of claim 24 is characterized in that hydrophobic monomer is selected from: the Arrcostab of alpha-olefin, alkyl vinyl ether, ethylenic unsaturated carboxylic acid ((methyl) acrylic acid C particularly
6-C
30Arrcostab), N-alkyl (methyl) acrylamide, N, N-dialkyl group (methyl) acrylamide, C
6-C
30The vinyl esters of carboxylic acid, N-cyclopolymers of alkyldiallylamine and salt thereof, wherein alkyl contains at least 6 carbon atoms.
26. each compositions in claim 24 and 25 is characterized in that hydrophobic monomer is the C of ethylenic unsaturated carboxylic acid
6-C
30Arrcostab.
27. each compositions among the claim 24-26 is characterized in that hydrophobic monomer is selected from methacrylic acid Lauryl Ester and methacrylic acid stearyl.
28. each compositions among the claim 18-27 is characterized in that described film forming polymer comprises:
-account for the ethylenic unsaturated carboxylic acid of total polymer weight 20-90% weight,
-1-55% weight vinyl lactam,
-1-25% weight hydrophobic monomer.
29. each compositions among the claim 18-28 is characterized in that described film forming polymer comprises:
-account for the ethylenic unsaturated carboxylic acid of total polymer weight 40-70% weight,
-15-40% weight vinyl lactam,
-5-20% weight hydrophobic monomer.
30. each compositions among the claim 18-29 is characterized in that the content of described film forming polymer accounts for the 0.1-15% weight of composition total weight, is preferably 0.5-10% weight.
31. each compositions among the claim 18-30 is characterized in that in the said composition the not content of wax.
32. eyelash, it comprises and contains ciliation with the container of compositions, and described compositions is coated in system on the eyelashes, it is characterized in that said composition is each described compositions among the claim 18-31.
33. the method for coating eyelashes is included in and applies each described compositions among the claim 18-31 on the eyelashes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR00/10267 | 2000-08-03 | ||
| FR0010267A FR2812543B1 (en) | 2000-08-03 | 2000-08-03 | MASCARA COMPRISING A VINYL LACTAME POLYMER |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1342448A true CN1342448A (en) | 2002-04-03 |
Family
ID=8853275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01132835 Pending CN1342448A (en) | 2000-08-03 | 2001-08-02 | Mascara containing vinyl lactam |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2002121119A (en) |
| CN (1) | CN1342448A (en) |
| AR (1) | AR030096A1 (en) |
| BR (1) | BR0104227A (en) |
| FR (1) | FR2812543B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102274134A (en) * | 2010-06-12 | 2011-12-14 | 浙江美雪化妆品有限公司 | Eyelash mascara and preparation method thereof |
| CN105726355A (en) * | 2016-03-24 | 2016-07-06 | 四川力久知识产权服务有限公司 | Long-eyelashes mascara and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4053019B2 (en) | 2003-04-21 | 2008-02-27 | 花王株式会社 | Mascara applicator |
| US9364418B2 (en) * | 2010-01-14 | 2016-06-14 | Basf Se | Water-resistant cosmetic formulations comprising a hydrophobically modified vinylpyrrolidone copolymer |
| US10420714B2 (en) | 2016-09-30 | 2019-09-24 | L'oreal | Foaming cosmetic compositions and methods for producing the same |
| US10172782B2 (en) | 2016-09-30 | 2019-01-08 | L'oreal | Compositions and methods for treating hair |
| US20200022900A1 (en) * | 2017-03-23 | 2020-01-23 | Is Investments Llc | Skin care compositions comprising a terpolymer, process for preparing the same and method of use thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0635372B2 (en) * | 1984-10-05 | 1994-05-11 | ポーラ化成工業株式会社 | Cosmetics |
| DE3627970A1 (en) * | 1986-08-18 | 1988-02-25 | Basf Ag | TERPOLYMERS, THEIR USE IN HAIR TREATMENT PRODUCTS AND THE HAIR TREATMENT CONTAINERS THEREOF |
| DE4031912A1 (en) * | 1990-10-08 | 1992-04-09 | Basf Ag | TERPOLYMERS, THEIR USE IN HAIR FASTENERS WITH INCREASED FIXING EFFECT, AND THEIR HAIR FASTENERS CONTAINING THEM |
| US5389363A (en) * | 1993-04-23 | 1995-02-14 | Revlon Consumer Products Corporation | Cosmetic compositions for lengthening, coloring and curling eyelashes |
| FR2704771B1 (en) * | 1993-05-07 | 1995-07-13 | Oreal | Use of a terpolymer derived from vinyl lactam as a foaming agent in compositions forming an aerosol foam and composition for use. |
| FR2743297B1 (en) * | 1996-01-05 | 1998-03-13 | Oreal | COSMETIC COMPOSITION BASED ON MULTISEQUENCE IONIZABLE POLYCONDENSATES POLYSILOXANE / POLYURETHANE AND / OR POLYUREE IN SOLUTION AND USE |
| DE19746468A1 (en) * | 1997-10-21 | 1999-04-22 | Henkel Kgaa | Mascara for temporary coloring of human hair |
| FR2772602B1 (en) * | 1997-12-22 | 2000-01-28 | Oreal | NON-TRANSFER COSMETIC COMPOSITION COMPRISING A DISPERSION OF POLYMER PARTICLES IN A LIQUID FAT PHASE AND A LIPOSOLUBLE POLYMER |
-
2000
- 2000-08-03 FR FR0010267A patent/FR2812543B1/en not_active Expired - Fee Related
-
2001
- 2001-08-01 BR BR0104227-0A patent/BR0104227A/en not_active IP Right Cessation
- 2001-08-01 AR ARP010103665A patent/AR030096A1/en not_active Application Discontinuation
- 2001-08-02 CN CN 01132835 patent/CN1342448A/en active Pending
- 2001-08-03 JP JP2001236614A patent/JP2002121119A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102274134A (en) * | 2010-06-12 | 2011-12-14 | 浙江美雪化妆品有限公司 | Eyelash mascara and preparation method thereof |
| CN102274134B (en) * | 2010-06-12 | 2013-10-02 | 浙江美雪化妆品有限公司 | Eyelash mascara and preparation method thereof |
| CN105726355A (en) * | 2016-03-24 | 2016-07-06 | 四川力久知识产权服务有限公司 | Long-eyelashes mascara and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AR030096A1 (en) | 2003-08-13 |
| FR2812543B1 (en) | 2002-09-13 |
| BR0104227A (en) | 2002-05-28 |
| JP2002121119A (en) | 2002-04-23 |
| FR2812543A1 (en) | 2002-02-08 |
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