CN1337162A - Antiseptic dedorant of nanometer particle composite material for shoes - Google Patents
Antiseptic dedorant of nanometer particle composite material for shoes Download PDFInfo
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- CN1337162A CN1337162A CN 01122745 CN01122745A CN1337162A CN 1337162 A CN1337162 A CN 1337162A CN 01122745 CN01122745 CN 01122745 CN 01122745 A CN01122745 A CN 01122745A CN 1337162 A CN1337162 A CN 1337162A
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- nano
- nanometer
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- silicon
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention relates to a nano particle composite material which can be used as antimicrobial deodorization agent for shoes. It is characterized by that it adopts nano antimicrobial material, nano adsorption material, nano decomposition material and nano fragrant particle material to effectively kill bacteria in the shoe, inhibit propagation of bacteria, at the same time quickly adsorb and decompose several odour molecules in the shoe to attain the goal of antimicrobial deodorization. Said invention is non-toxic and has no toxic side effect, and can be extensively used for curing beriberi, tinea pedis and othe skin disease of foot.
Description
The present invention relates to a kind of footwear antibacterial deodorant, particularly a kind of invention of adopting the footwear of electrodeless nano composition preparation with antibacterial deodorant.
At present, people are smelly to pin, footwear are smelly and various methods has been taked in the inhibition of bacterium, pulvis, liquor and the medical shoe pad that manufactures are arranged and suppress the smelly functional shoe of pin from the form of product, above-mentioned these products are seen technically, its composition is made of organic drug or electrodeless pharmaceutical compositions, though these medicines have certain effect to pin is smelly, great majority all have negative interaction to human body.
Footwear antibacterial deodorant in the background technology has adopted chlorhexidine acetate, sodium salicylate composition in the patented technology of patent No. 98121830X; Though contain sulfuric acid, first chlorobenzene, hexamethylenetetramine, benzoic acid, lauryl sodium sulfate etc. in most of like products, these medicines have certain effect, be easy to volatilization, generally can only make liquid antibiotic, deodoring materials.In use do not reach ideal effect.Exist defective and deficiency in the background technology are summarized as follows:
One, antibiotic, the deodorant of liquid one is pin to be immersed in the soup or with shoe-pad soak in use, uses very inconvenient.
Though two, some medical shoe pad drug effect is longer, in use, the thick hard cocoon of one deck is shut and formed to the sweat gland on the pin, very unfavorable to health.
For above shortcomings in the background technology, the inventor is according to abundant professional knowledge and working experience, and continuous research works out the technical program finally and is used for to solve the deficiency that background technology exists.
Technical scheme of the present invention is to realize like this, a kind of antiseptic dedorant of nanometer particle composite material for shoes, it is characterized in that: adopted nano composite antibiotic material in this technical scheme, nano-catalytic anti-biotic material, nano adsorption material, the fragrant particle composite material of nanometer decomposing material and nanometer, nano composite antibiotic material wherein, nano-catalytic anti-biotic material, nano adsorption material, the fragrant particle composite material of nanometer decomposing material and nanometer is the powder of particle diameter below 100nm.
Technical scheme of the present invention can be achieved by following steps.A kind of antiseptic dedorant of nanometer particle composite material for shoes is characterized in that:
Raw material is selected for use:
It is carrier (Sio that a, nano composite antibiotic material can adopt silicon-base oxide
2-x) the anti-biotic material that contains silver ion or zinc ion, ratio is 8%--12%;
B, nano-catalytic anti-biotic material can adopt nano-titanium oxide (TiO
2), ratio is 3%--7%.
D, nanometer decomposing material (1) can be selected aluminium oxide (Al for use
2O
3), ratio is 10%--20%.
E, nanometer decomposing material (2) can be selected zinc oxide (ZnO) for use, and ratio is 8%--12%.
F, the fragrant particle of nanometer adopt and contain forest incense or rosaceous nano material, and ratio is 10%--20%.
Wherein: the preparation of the fragrant particle of nanometer: adopting particle diameter is that many micropores of 60nm-100nm silicon-base oxide is a carrier material; The odor type material adopts forest incense or flavoring rose essence, ratio in 0.05%--0.2% splashes in the alcohol solvent, then nano material and the ethanolic solution that contains spices are carried out excessive immersion 2--4 hour by weight 1: 5 ratio, stir with mulser then, behind the natural at normal temperatures volatile dry, carry out aeration-drying in 60 ℃ baking oven, making liquid residue is about 0.5%, it is carried out taking out after ball milling 2-4 minute with ball mill get final product.
2, configuration proportion (weight ratio)
a∶b∶c∶d∶e∶f=10%∶5%∶45%∶14%∶10%∶16%
3, preparation method:
Above-mentioned nano material is mixed by configuration proportion, puts into agitator and fully stirred 3-5 minute.
Advantage that technical scheme of the present invention and background technology comparison are had and good effect are owing to adopt the prepared footwear antibacterial deodorant of technique scheme, do not contain volatile pharmaceutical compositions, be to utilize organic nano particle specific surface area effect, bulk effect, quantum tunneling effect etc., unusual extraordinary characteristic reaches the purpose that antibiotic in the footwear suppressed and smelly molecule is adsorbed, decomposes, therefore, have effect obvious, nontoxic, have no side effect, advantage pollution-free, easy to use has overcome the deficiency that exists in the background technology.
Below with embodiment technical scheme of the present invention and progressive are further elaborated.
Embodiment:
1, raw material is selected for use:
A, nano composite antibiotic material: nano silver-carrying silica (Sio
2-xAg
+)
B, nano-catalytic anti-biotic material: nano-titanium oxide (Tio
2)
C, nano adsorption material: many micropores silicon-base oxide (Sio
2-x)
D, nanometer decomposing material 1:r phase alumina (r-AL
2O
3)
E, nanometer decomposing material 2: zinc oxide (ZnO)
F, the fragrant particulate material of nanometer: silica-based year fragrant material (Sio
2-x-X)
2, the fragrant particulate material (Sio of nanometer
2-x-X) preparation: the silicon-base oxide that adopts particle diameter 60nm to have multi-cellular structure is a carrier material; Fragrant molecular material selects for use forest incense to splash in 0.1% ratio in 99% the ethanolic solution; Then many porous nanos silicon-base oxide was put into the ethanolic solution that contains fragrant molecular material in 1: 5 by weight proportion, carry out excessive immersion 2-4 hour, stir taking-up in 2 minutes with mulser then, at normal temperatures behind the volatile dry, in 60 ℃ baking oven, carry out aeration-drying, making the ethanol residual quantity is below 0.5%, it is carried out ball milling with ball mill, promptly obtain the fragrant particulate material of nanometer.
3, configuration proportion:
a∶b∶c∶d∶e∶f=10%∶5%∶45%∶14%∶10%∶16%
4, preparation method:
The above-mentioned nano material of getting ready mixed fully to stir with agitator according to configuration proportion got final product in 5 minutes.
Then whole proposal is implemented to finish.
Above technical scheme is preferred embodiment of the present invention, the present invention is not done any pro forma restriction, and every foundation technical spirit of the present invention is done the technology equivalent variations, and ratio modification etc. all belongs to the scope of the invention.
Claims (4)
1, a kind of antiseptic dedorant of nanometer particle composite material for shoes is characterized in that: adopted the fragrant particle composite material of nano composite antibiotic material, nano-catalytic anti-biotic material, nano adsorption material, nanometer decomposing material and nanometer in this technical scheme;
Wherein: raw material is selected for use
It is carrier (Sio that a, nano composite antibiotic material can adopt silicon-base oxide
2-x) the anti-biotic material that contains silver ion or zinc ion, ratio is 8%--12%;
B, nano-catalytic anti-biotic material can adopt nano-titanium oxide (TiO
2), ratio is 3%--7%;
C, nano adsorption material adopt many micropores silicon-base oxide (Sio
2-x), ratio is 30%-50%;
D, nanometer decomposing material (1) can be selected alundum (Al (Al for use
2O
3), ratio is 10%--20%;
E, nanometer decomposing material (2) can be selected zinc oxide (ZnO) for use, and ratio is 8%--12%;
F, the fragrant particle of nanometer adopt and contain forest incense or rosaceous nano material, and ratio is 10%--20%;
2, according to the described a kind of antiseptic dedorant of nanometer particle composite material for shoes of claim 1, it is characterized in that: the fragrant particle of nanometer is that to adopt nano silicon-based oxide be carrier material, with fragrant MOLECULE DESIGN in the micropore of nano silicon-based oxide;
3, fall smelly dose according to the described a kind of nanometer particle composite material for shoes of claim 1 with antibiotic, it is characterized in that:
(1) raw material is selected for use:
A, nano composite antibiotic material: nano silver-carrying silica (Sio
2-xAg
+)
B, nano-catalytic anti-biotic material: nano-titanium oxide (Tio
2)
C, nano adsorption material: many micropores silicon-base oxide (Sio
2-x)
D, nanometer decomposing material 1:r phase alumina (r-AL
2O
3)
E, nanometer decomposing material 2: zinc oxide (ZnO)
F, the fragrant particulate material of nanometer: silica-based year fragrant material (Sio
2-x-X)
(2) nano composite antibacterial deodorant: configuration proportion (weight ratio)
a∶b∶c∶d∶e∶f=10%∶5%∶45%∶14%∶10%∶16%
(3) preparation method:
The above-mentioned nano material of getting ready mixed fully to stir with agitator according to configuration proportion got final product in 5 minutes;
4, according to right 1 or 2 described a kind of antiseptic dedorant of nanometer particle composite material for shoes, it is characterized in that: the fragrant particle preparation method of nanometer is
The silicon-base oxide that adopts particle diameter 60nm to have multi-cellular structure is a carrier material; Fragrant molecular material selects for use forest incense to splash in 0.1% ratio in 99% the ethanolic solution, then many porous nanos silicon-base oxide was put into the ethanolic solution that contains fragrant molecular material by weight sharp 1: 5, carry out excessive immersion 2-4 hour, stir taking-up in 2 minutes with mulser then, behind the natural at normal temperatures volatile dry, in 60 ℃ baking oven, carry out aeration-drying, making the ethanol residual quantity is below 0.5%, and it is carried out ball milling with ball mill, promptly obtains the fragrant particulate material of nanometer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01122745 CN1337162A (en) | 2001-07-15 | 2001-07-15 | Antiseptic dedorant of nanometer particle composite material for shoes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01122745 CN1337162A (en) | 2001-07-15 | 2001-07-15 | Antiseptic dedorant of nanometer particle composite material for shoes |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1337162A true CN1337162A (en) | 2002-02-27 |
Family
ID=4664874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 01122745 Pending CN1337162A (en) | 2001-07-15 | 2001-07-15 | Antiseptic dedorant of nanometer particle composite material for shoes |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103637501A (en) * | 2013-11-25 | 2014-03-19 | 青岛亨达股份有限公司 | Ultralight shoe sole with slip preventing, damping and deodorization functions |
CN103653536A (en) * | 2013-11-25 | 2014-03-26 | 青岛亨达股份有限公司 | Filial piety shoes |
CN104817791A (en) * | 2015-05-11 | 2015-08-05 | 湖州福泽鞋业有限公司 | Environment-friendly stable-light-emission polyvinyl chloride shoe sole material and preparation method thereof |
-
2001
- 2001-07-15 CN CN 01122745 patent/CN1337162A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103637501A (en) * | 2013-11-25 | 2014-03-19 | 青岛亨达股份有限公司 | Ultralight shoe sole with slip preventing, damping and deodorization functions |
CN103653536A (en) * | 2013-11-25 | 2014-03-26 | 青岛亨达股份有限公司 | Filial piety shoes |
CN104817791A (en) * | 2015-05-11 | 2015-08-05 | 湖州福泽鞋业有限公司 | Environment-friendly stable-light-emission polyvinyl chloride shoe sole material and preparation method thereof |
CN104817791B (en) * | 2015-05-11 | 2018-05-01 | 陈妍雨 | A kind of polyvinyl chloride material for sole of shoe of environmental protection stable luminescence and preparation method thereof |
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