CN1337062A - Equipment for UV wafer heating and photochemical processing - Google Patents
Equipment for UV wafer heating and photochemical processing Download PDFInfo
- Publication number
- CN1337062A CN1337062A CN98814315A CN98814315A CN1337062A CN 1337062 A CN1337062 A CN 1337062A CN 98814315 A CN98814315 A CN 98814315A CN 98814315 A CN98814315 A CN 98814315A CN 1337062 A CN1337062 A CN 1337062A
- Authority
- CN
- China
- Prior art keywords
- substrate
- radiation
- heating
- front side
- lampshade
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010438 heat treatment Methods 0.000 title claims abstract description 77
- 238000012545 processing Methods 0.000 title claims abstract description 30
- 239000000758 substrate Substances 0.000 claims abstract description 158
- 230000005855 radiation Effects 0.000 claims abstract description 68
- 150000001875 compounds Chemical class 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 48
- 238000006243 chemical reaction Methods 0.000 claims description 49
- 238000006552 photochemical reaction Methods 0.000 claims description 34
- 230000003287 optical effect Effects 0.000 claims description 18
- 239000004065 semiconductor Substances 0.000 claims description 12
- 229910052724 xenon Inorganic materials 0.000 claims description 12
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 12
- 238000012935 Averaging Methods 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 125000001475 halogen functional group Chemical group 0.000 claims description 4
- 239000000126 substance Substances 0.000 abstract 2
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 24
- 239000000463 material Substances 0.000 description 15
- 238000010521 absorption reaction Methods 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 238000004377 microelectronic Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000012495 reaction gas Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 238000006303 photolysis reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000002146 bilateral effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000008713 feedback mechanism Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02041—Cleaning
- H01L21/02043—Cleaning before device manufacture, i.e. Begin-Of-Line process
- H01L21/02046—Dry cleaning only
- H01L21/02049—Dry cleaning only with gaseous HF
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67115—Apparatus for thermal treatment mainly by radiation
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- High Energy & Nuclear Physics (AREA)
- Drying Of Semiconductors (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The apparatus of the present invention provides for the dual use of a UV source to heat a substrate and to facillitate photochemistry necessary for the treatment of the substrate. The present invention also provides a method for processing a substrate by heating the substrate to a temperature above ambient via UV radiation at a first powder level and conditioning the substrate by exposing the substrate to photochemically (UV) reactive chemical, or a reactive chemical that can react with a compound on the surface of the substrate to form a photochemically reactive compound, in the presence of UV radiation at a second power level.
Description
Background of invention
1. invention field
The present invention relates to a kind of device and a kind of method of utilizing described device that described substrate is handled of substrate (comprising Semiconductor substrate) being made UV heating and photochemical treatment with ultraviolet ray (UV) source.Discovery can be applied to especially integrated circuit make under about 400 ℃ or lower temperature etching, cleaning or from a large amount of films of the sur-face peeling of Semiconductor substrate and fouling products.
2. the description of prior art
In the Semiconductor substrate that comprises cleaning, etching or other processing was handled, it was well-known using ultraviolet ray (UV) active gases.People's such as Hiatt United States Patent (USP) 5,580,421 is described and a kind ofly can be activated the device that adjustments of gas is handled substrate with UV, is incorporated herein by reference.Disclose a kind of method of using fluorinated gas to remove unwanted material in No. the 08/621st, 538, the uncertain application that proposes on March 25th, 1996, be incorporated herein by reference from substrate.Disclose a kind of method of using the UV/ halogen to remove metal in No. the 08/818th, 890, the uncertain application that proposes on March 17th, 1997, be incorporated herein by reference.Because chemical reaction rate is general relevant with temperature, so the efficient of handling depends on the temperature when handling.May be required under the preferable state of a control preferred process temperature that substrate is preheating on the ambient temperature with the enhancement process performance.Can also use heating that the volatile materials that is adsorbed on the substrate surface is carried out pyrolysis except that absorption.
Many methods to the substrate heating are arranged in chemically treated preparation or in the preparation of pyrolysis except that the absorption of volatile materials.Traditional heating means directly are placed on substrate on the heating element, do not allow the both sides near substrate.This may ask a question, and is special when hope is all handled the both sides of substrate.This does not allow to have many temperature program(me)s of rational throughput yet.
Another method of heated substrate is that the gas through heating is applied on the substrate.Yet it is inefficient that the gas of use through heating comes heated substrate.
Another method again of heated substrate is as in rapid thermal treatment infrared (IR) radiation being applied on the substrate.Yet, if not only required heating but also required the UV irradiation, can introduce considerable engineering roadblock, and be increased on the expense of any treatment facility of equipment like this.These difficult problems comprise the spuious oven temperature, degree of control, control underlayer temperature and in the logistics in conjunction with IR bulb, UV bulb and together with its control system separately in device.
The shortcoming of the above-mentioned heating means during Semiconductor substrate is handled has been given prominence to needs a kind of little method that spends, and this method can be heated to desired treatment temperature equably to substrate and UV is provided irradiation in single assembly.
Brief summary of the invention
The purpose of this invention is to provide and a kind ofly heat novel apparatus with optical processing to containing silicon substrate, the existence of this device by utilizing the UV source carried out optical processing also heating overcome the problem that is associated with above-mentioned heating means to substrate containing silicon substrate.The inventive system comprises the reaction chamber that holds and keep substrate, be configured to the UV radiation source of direct radiation on substrate and the control system of control UV radiation source.The UV source can provide the UV output of at least two kinds of different time average power level, and a kind of to heat level effective to the heating of bringing out substrate, and a kind of photochemistry level is effective to bringing out described optical processing.At random, the present invention further comprises compound is discharged into compound delivery system in the reaction chamber.The present invention can also comprise at least one UV transmissive window, can by this transmissive window the UV radiated emission in case.
In one embodiment of the invention, a UV light source is installed on the front side of reaction chamber, and the 2nd UV light source is installed on the rear side of described reaction chamber, can make substrate heating equably on both sides by the direct UV radiation of while in the both sides, front and back of substrate.In another embodiment, a side of substrate stands to heat the UV of level, and the opposite side of substrate stands the UV radiation of photochemistry level.In another embodiment, use single UV source for heating and photochemistry.
Another feature of the present invention provides a kind of method of handling substrate, and described method makes substrate be heated to temperature more than the ambient temperature in one or more heating stepses through the UV of average power level of the very first time (heating level) output; And when having the UV radiation under the second time average level (handle level, it is different with the first heating level), substrate is exposed to photochemistry (UV) compound of reaction and regulates substrate in one or more treatment steps.The photochemical reaction compound is broadly defined as and comprises those compounds that become sensitization owing to the effect such as the absorption on substrate surface.The photochemical reaction compound also is defined as comprising and is adsorbed on the substrate surface, owing to exist incident UV radiation meeting to cause the material of described foundation light releasing absorption.
Another feature of the present invention provides a kind of method of handling substrate, and described method makes substrate be heated to the temperature more than the ambient temperature in one or more heating stepses and regulating substrate by substrate being exposed to photochemistry (UV) compound of reaction in one or more treatment steps when not having photochemical reaction gas by UV output.
It is relevant to the invention further relates to a kind of method of carrying out the UV photochemical treatment on Semiconductor substrate, described method comprises at least one heating steps, in this step, the UV radiation is provided at least a portion substrate, from 0.1 0.3 watt/li of its total radiant power density that is accumulated to 1.0 micron wave lengths
2Or it is bigger; With at least one reactions steps, in this step, provide UV radiation with the power level that is different from the heating power level, UV radiation and at least one photochemical reaction compound interact, cause chemical reaction, realize the processing of substrate, wherein, the power density in heating steps surpasses the power density in reactions steps.
The present invention allows to increase flexibility in handling substrate, wherein can heat the one or both sides that face toward substrate to UV optical processing and UV independently.For example, activate, can protect the substrate front side to avoid direct UV irradiation if only require vapour phase.In addition, because the spuious heating of the treatment box that is associated with the IR heating is decreased to a great extent, when high throughput can be kept, can eliminate demand to complicated and expensive case cooling system with the UV heating system.
The accompanying drawing summary
The absorption spectrum of Si when Fig. 1 is illustrated in temperature and is 25 ℃ in the ultraviolet range;
Fig. 2 illustrates the schematic diagram of one embodiment of the present of invention;
Fig. 3 illustrates the schematic diagram of case in one embodiment of the invention.
Detailed Description Of The Invention
In the substrate of handling such as semiconductor chip, before handling or during handling, often need be heated to desired treatment temperature to substrate.Device of the present invention provides the UV radiation source not only to be used for heated substrate but also promote the needed photochemical double duty of substrate processing.
Another aspect of the present invention provides a kind of method of handling substrate, and described method is heated to the one or both sides of substrate temperature more than the ambient temperature by be exposed to the UV radiation with very first time average power level in one or more steps; And when the UV of second time averaging power level radiation exists, regulate substrate by the one or both sides of substrate are exposed to photochemistry (UV) compound of reaction in one or more treatment steps, the described second time average power level decreases than very first time average power level.The photochemical reaction compound comprises those compounds that become sensitization owing to the effect such as the absorption on substrate surface, or on substrate surface and owing to the existence of shining the UV radiation causes that photodissociation removes the material of absorption.
The backing material that can handle with device of the present invention generally can be any kind material that can be coupled and absorb the big energy that the UV radiation source discharged with release photon effectively.These examples of material comprise and contain silicon substrate, contain gallium arsenide substrate, other Semiconductor substrate or have the substrate of other material of suitable absorption cross section.This definition also comprises some substrates, and described substrate is transparent to the radiation that is discharged, but has deposited suitable absorbing membrane or the embedding of suitable absorbing membrane wherein in its surface.Fig. 1 is depicted in the absorption spectrum of the silicon in the ultraviolet range.Strong UV absorbs the effective coupling between the photon that exemplary source discharged of indicating silicon and describing in the present invention.Therefore, material is conspicuous for adaptability of the present invention.
The present invention is useful for carrying out various processing, these are handled such as the metal removal of the oxide etch that uses UV and halogenating reaction thing, UV excitation and handle, or any other comprise photochemistry and require substrate preheated more than the ambient temperature but less than the processing of about 400 ℃ temperature.Thermal excitation more than 400 ℃ makes based on the heating means of IR more effective because there is the more freedom carrier to exist, as viewed in the rapid thermal treatment technology.
Any kind photochemical reaction gas that the photochemical reaction compound can be the etching that becomes known for substrate surface, cleaning, peel off or regulate in a large number, but in preferred embodiment, will comprise mixing of first gas and one or more photochemical reaction gases such as nitrogen, argon gas or another inert gas.Photochemical reaction gas can be a kind of compound, and it reacts in gas phase to form the reactive material such as atomic group.The example of this photochemical reaction gas comprises (but being not limited to) ClF
3, F
2, O
2, N
2O, H
2, NF
3, Cl
2, other halo gas or these gases mixture.The photochemical reaction compound can also be any compound, no matter be gas or other, as long as can or be adsorbed on the substrate surface to form the photochemical reaction material with the compound reaction.Other photochemical reaction compound that has again comprises that the halo metal is (as CuCl
2) and other as described in No. the 08/818th, 890, the uncertain application that proposes in the above on March 17th, 1997.In this case, the photochemical reaction compound is a kind of adsorption complex, can make its photodissociation remove absorption when having irradiation UV radiation.
Fig. 2 is the schematic diagram of the main element part of system, and described system constitutes the embodiment of our device.Reaction chamber is generally with 10 expressions.The UV radiation source comprises the lampshade 14 that is installed in reaction chamber 10 outsides.The front of case 10 comprises UV transmissive window 22, and it allows UV light to be sent on the inner arrival of the case substrate from lampshade 14.The compound delivery system is shown with 26, and with 28 control system that control UV radiation is shown.Vacuum pump 30 is connected to case 10.In operation, 35 compound is discharged into case 10 by entering the mouth, and discharges by outlet 36.
Though only need a UV lamp, the existence of first lampshade on the front side of case and second lampshade on rear side allows to handle simultaneously the both sides of substrate.On the other hand, can shine any side of substrate on demand respectively.In the present embodiment, the rear side of case also comprises a UV transmissive window.When using two UV lampshades, preferably the 2nd UV lampshade is turned over 90 degree for a UV lampshade, to promote even heating to the substrate both sides.For convenience's sake, we are expressed as case and substrate both and have front side and rear side.Yet the front side of substrate needn't be in the face of the front side of case.
Fig. 3 is depicted in a case and a lampshade among the embodiment that comprises front side and two kinds of light sources of rear side.Case 10 has two transmissive window 22 now, each one of front side and rear side.14, one on two lampshades are in the front side, and one at rear side, allow the both sides of irradiation substrate.Beneath lampshade revolves with respect to the front side lampshade and turn 90 degrees.
In another embodiment, can be installed in lamp in the case.In the present embodiment, just do not need the UV transmissive window.
Suitable UV lamp is the quartz flash lamp (being made by Xenon company) that 9 inches (7 millimeters internal diameters) is linear, fill xenon.In our preferred embodiment, in a lampshade, place two such lamps.In this embodiment, provide 1500 watts so that lamp is powered up to lampshade.Can also use other radiation source such as mercury vapor lamp, as long as light source produces enough power in 0.1 to 1.0 micron wave length scope, and output photon is to react with interested specific compound.Can use more powerful or lower-powered UV source.Certainly, the power of lamp is determined can carry out to such an extent that what are fast to the heating of substrate.With two 1500 watts lampshade, one front side and one at rear side, in 30 seconds, the temperature of the silicon chip of 150mm just rises to 200 ℃ from room temperature.
Flash generator comprises a power supply that can be discharged into the input power up to 1500 watts with fixing input pulse lampshade.At random, power supply can also comprise pulse forming network, and described Design of Pulse-forming Network is become to have maximum power output in the zone of desired photochemistry the best.
Though lampshade can be a device that is used to install the UV source simply, lampshade can also comprise one or more cylinder parabolas or ellipsoidal reflector.
Device of the present invention is operated with two kinds of patterns, i.e. heating mode and photochemistry pattern.In heating mode, the UV source is the operation of high power level in than photochemistry pattern, or makes gaseous environment become non-photosensitivity by for example using inert gas or discharging UV in a vacuum.In the photochemistry pattern, power output is reduced to enough carries out desired photochemical level, or introduce the photochemical reaction compound.
The UV controller can be any circuit, when sort circuit is connected to the UV source, can allow the UV source with UV heating level release time average power institute's required amount and with institute's required amount of average power photochemical reaction level release time.The method of the power that a kind of control time is average is by using variable power supply.Two kinds of Xenon 740 of Xenon company are examples of this power supply, and this power supply allows the per second pulse number that light source discharges is controlled.On the other hand, the operator can artificially control UV.
The present invention can move in the open loop without any Temperature Feedback during the heating steps.If the UV source is a photoflash lamp, then low caloic allows the pulse energy calibration, thereby allows in open cycle system substrate to be carried out repeatably temperature control.On the other hand, can provide the output of revising the UV source together with the temperature control system of programmable control system, so that obtain and randomly keep desired underlayer temperature.Can come the control cabinet temperature by the feedback mechanism that is associated with feedback loop and heat-resistor, so that behind initial UV heating steps, make case remain on desired temperature.
Be suitable for temperature control system of the present invention and can comprise that temperature sensor and feedback temperature controller are to regulate the output of UV radiation source.The feature of the output of UV radiation source represents that by pulse train the feature of pulse train is represented by the pulse number of the per second of UV radiation and the energy of each pulse.The Temperature Feedback controller is regulated the energy of per second pulse number and/or each pulse.RDS 1000 type temperature sensors from Thermionic are the noncontact optical sensors that can obtain in enormous quantities, can use this transducer in the present invention, but also can use other transducer.
The compound feed system can comprise one or more compounds source, carries out fluid communication with pipe-line system, exchanges with reaction chamber again.Can dispose the compound feed system like this, so that allow mix one or more gases and allow and be provided at compound in the gas phase by many in the art any methods of knowing.
Vacuum pump can make case be evacuated down to be lower than 10mTorr (milli torr).If require lower air pressure, then can use higher vacuum pump.
Owing to eliminate a result of spuious heating, the present invention allows in design and textural to have bigger simplicity one be not to be coupled in the case effectively because of the UV photon, so can not need the liquid cools of case.In addition, the present invention further allows in Semiconductor substrate is handled bigger flexibility and controlled is arranged.Device under suitably disposing allows from rear side, front side or both sides substrate to be heated.Must be to substrate heating and can not be exposed to high-energy UV photon following time to the front side, heating has special advantage to substrate from rear side.When comprising the lot of materials that can not be coupled effectively with the UV photon in the front side of substrate, this also is favourable, and described material is such as (but being not limited to) aluminium or copper.On the other hand, both sides are heated allow to make temperature to rise simultaneously than faster when rear side heats separately.Similarly, described device allows from the front side, rear side or both sides carry out optical processing to substrate.
The invention further relates to a kind of method that is used on Semiconductor substrate, carrying out the UV photochemical treatment, described method comprises at least one heating steps, in this step, the UV radiation at average power level of the very first time-heating level is provided to substrate makes the substrate heating; And at least one reactions steps, in this step, providing the UV radiation of second time averaging power level-reaction level, the heating level surpasses the reaction level.During reactions steps, UV radiation and at least one photochemical reaction compound interact, and cause chemical reaction and realize the processing of substrate.Heating steps can be when the photochemical reaction compound exists or takes place when not existing.The photochemical reaction compound may reside in substrate surface and/or in the gaseous environment that substrate is placed.Can directly offer reaction chamber to the photochemical reaction compound by the compound delivery system, or indirectly as compound in gaseous environment with substrate surface reactions to form the reaction result of photochemical reaction compound.Can in gas phase, not be exposed to the UV photon to the substrate front side and produce the photochemical reaction compound by only rear side being carried out photochemical treatment.
In one embodiment of the invention, in the both sides of substrate substrate is heated simultaneously, then, carry out optical processing in the one or both sides of substrate.This allows maximum heating.Include only among the embodiment of a lamp at another, only the one side-rear side to substrate heats, to avoid on the front side, promoting any photochemistry during the heating steps, then, carry out the rear side optical processing, so that in reaction chamber, produce atomic group, on the front side, react then and any material is not removed absorption from the front side of substrate.Comprise among the embodiment of two lamps that at another after the rear side heating, the front side that makes substrate is through direct UV optical processing.In another embodiment, before heating steps, carry out the optical processing step.In another embodiment, can use a plurality of heating and optical processing step.In another embodiment, by the UV of heat treated level being introduced a side of substrate, and simultaneously the UV of optical processing level is introduced other side of substrate and heating and optical processing are taken place simultaneously.
In another embodiment, the present invention relates to carry out on Semiconductor substrate the method for UV photochemical treatment, described substrate has front side and rear side, and described method comprises at least one heating steps, in this step, the total mark power density of from 0.1 to 1.0 micron of wavelength is at least 0.3 watt/centimetre
2Or higher UV radiation is provided at least a portion substrate; And at least one reactions steps, in this step, UV radiation and at least a photochemical reaction compound interact, and cause chemical reaction and realize the processing of substrate, and wherein, the power density in heating steps surpasses the power density in reactions steps.At random, the photochemical reaction compound may reside in during the heating steps.
In above-mentioned any one embodiment, during photochemical step, can operate the UV source and make it to be in such level, to keep or to increase substrate temperature.
Following example illustrates the abundant flexibility of bilateral UV system
Example 1
In ORION dry type gas phase substrate processing equipment, make to have and to abandon SiO
2The silicon chip of layer stands the UV heating and handles.Described equipment is provided by FSI International, INC. (Chaska, Minnesota), and is configured according to the preferred embodiment that discloses above.
Two lampshades have two 9, and " fill flashbulb (manufacturing of Xenon company) and two paraboloidal reflectors of xenon, each is by a variable power supply power supply.Use these two power-supply systems to make total electric intake maintain 400 joules of each pulses, the pulse number (pps) of regulating per second makes from 0 to 3000 watt of variation of time averaging power.In the present embodiment, 3000 watts of electric input powers are corresponding to about 1.5 watts/cm on the substrate
2Luminous power (between 100 to 1000nm).A lampshade is placed on the front of treatment box, another lampshade is placed on the back of treatment box.
After substrate is put into case, use first heating steps to make substrate be raised to 60 ℃ treatment temperature from room temperature (about 23 ℃), at this section time durations, nitrogen is charged in the case to 5torr (torr).Two lampshades are worked under separately the maximum luminous time ratio, i.e. 7 pulses of per second are so that the temperature rate-of-rise maximum.Under these conditions, substrate reached 60 ℃ temperature in 5 seconds.Notice that heat, the increase of temperature is related with each UV flash phase of calibrating in an independent process in open loop mode.
Turn off the rear side lampshade then, and the front side pulse rate is reduced to 2 pulses of per second.Then substrate is carried out 5 seconds, the UC/Cl of 5torr (torr)
2Any hydrocarbon is removed in the processing of photochemistry, and makes the surface of substrate become specified states preferably.
Then turn off the front side lampshade, make substrate temperature be adjusted by case, case itself is under the FEEDBACK CONTROL and maintains on 60 ℃.At this moment, utilize 40 seconds, 75 torr vapour phases, handle SiO based on HF
2Etch away, silicon face is stayed in the hydrogen termination state.
After finishing the HF etching,, and make case be opened to vacuum again with 7 pulse-on rear sides of per second lampshade.Make lampshade keep connecting 30 seconds, during during this period of time, substrate temperature reaches about 150 ℃.Use this to have only the rear side step to make under 60 ℃, to be not enough to volatilization to carry out pyrolysis and remove absorption with any oxygen carrier of removing absorption (between oxygen candle is set a date), and not on the substrate front side any photodissociation of required hydrogen end product remove absorption.
Example 2a
In second example, handle with the same way as of describing in the example 1 and to have the SiO that will abandon
2The silicon chip of layer, to the last step.Finishing the HF oxygen candle after quarter, two lampshades were connected 25 seconds, with maximum power (7 pulses of per second) so that substrate temperature rises to about 200 ℃.
Then Cl
2Charge into and arrive 5torr (torr) in the case, and turn off the back side lamp.Kept this state 30 seconds, to remove unwanted metal impurities.
Example 2b
In the modification of routine 2a, all conditions keeps identical and repeats routine 2a, and different is Cl during the photochemistry that (makes substrate be heated to 200 ℃ in this period) during the temperature up step rather than following
2Charge in the case to 5torr (torr), to allow that some photochemistry takes place during heating steps.
Modification according to the 19th of treaty
1. device that is used on substrate carrying out UV heating and optical processing step with front side and rear side, described device comprises:
Be used to hold and keep the reaction chamber of substrate, this reaction chamber comprises front side and rear side;
Be configured to direct radiation at least one UV radiation source on substrate, radiation source described here is accumulated to 1.0 microns be at least 0.3 watt/centimetre with wavelength from 0.1
2Total radiant power be discharged at least a portion of substrate; And
Control system is used to control at least one UV radiation source so that the UV output of the average energy level of at least two kinds of different times to be provided, heating level to the heating of bringing out substrate effectively and a photochemistry level effective to bringing out described optical processing.
2. device as claimed in claim 1 further comprises the compound delivery system that compound is discharged into reaction chamber.
3. device as claimed in claim 1 is characterized in that, described UV radiation source comprises at least one the front side UV lampshade on the front side that is installed in described reaction chamber or is installed at least one rear side UV lampshade on the rear side of described reaction chamber.
4. device as claimed in claim 1 is characterized in that, the UV radiation source comprises at least one the front side UV lampshade on the front side that is installed in described reaction chamber and is installed at least one rear side UV lampshade on the rear side of described reaction chamber.
5. device as claimed in claim 4 is characterized in that, described front side and rear side UV lampshade are installed in the outside of described case, and described case further comprises the UV transmissive window, and described UV radiation is transmitted in the described case by described transmissive window.
6. device as claimed in claim 4 is characterized in that, described at least one front side UV lampshade comprises at least one linear xenon flash lamp bubble, and described at least one rear side UV lampshade comprises at least one linear xenon flash lamp bubble.
7. device as claimed in claim 4 is characterized in that, described at least one front side and rear side lampshade respectively comprise at least one cylinder parabola or ellipsoidal reflector.
8. device as claimed in claim 4 is characterized in that, described at least one rear side UV lampshade rotates 90 degree for described at least one front side UV lampshade.
9. device as claimed in claim 1 is characterized in that, the feature of the output of described UV radiation source represents that by pulse train the feature of described pulse train is represented by the per second pulse number of UV radiation and the energy of each pulse.
10. device as claimed in claim 9 is characterized in that, by the per second pulse number in the regulating impulse string and/or the energy of each pulse, control device produces described at least two time averaging power levels.
11. a method that is used for carrying out the UV photochemical treatment on the Semiconductor substrate with front side and rear side, described method comprises the following steps:
At least one heating steps in this step, is provided to substrate to the UV radiation of heating power so that the substrate heating; And
At least one reactions steps in this step, provides the UV radiation of reaction power, and described UV radiation and at least one photochemical reaction compound interact, and causes chemical reaction and realizes substrate processing.
12. method as claimed in claim 11 is characterized in that, during at least one heating steps, described UV radiation source is at least 0.3 watt/centimetre to what at least a portion of substrate surface discharged from 0.1 to 1.0 micron of wavelength
2Total radiant power density, and surpass the power at least one reactions steps, be discharged into substrate at the power that is discharged into substrate during at least one heating steps.
13. method as claimed in claim 11 is characterized in that, has at least a photochemical reaction compound on the substrate surface.
14. method as claimed in claim 11 is characterized in that, described at least a photochemical reaction compound is present in the gaseous environment.
15. method as claimed in claim 14 is characterized in that, at least a photochemical reaction compound is a halo gas.
16. method as claimed in claim 11 is characterized in that, by control the heating to substrate by desired speed generation UV pulses of radiation.
17. method as claimed in claim 11 is characterized in that, during photochemical step, the UV radiation source can be in the operation of power level so, promptly keeps or increases substrate temperature.
18. method as claimed in claim 11 is characterized in that, the UV radiation is provided to the front side and the rear side of substrate.
19. method as claimed in claim 11 is characterized in that, the UV radiation only is provided to a side of substrate.
20. method as claimed in claim 11 is characterized in that, at least one photochemical reaction compound is present in the gaseous environment or on the surface at substrate during described at least one heating steps.
21. the device of a microelectronic component parent that is used to handle have first and second corresponding main surfaces, described device comprises:
(a) the case shell of qualification treatment box, the microelectronic component parent is placed on wherein during handling;
(b) first case window, first the case window is placed by this way, and the first energy stream can be radiated on first first type surface by first case window; And
(c) second case window, second the case window is placed by this way, and the second energy stream can be radiated on second first type surface by second case window;
(d) gas access comprises that the stream of handling gas flows in the described case by this inlet;
(e) gas vent, exporting described stream by this flows out from case, wherein, operationally locating gas inlet and gas vent cause stream from the gas access to the gas vent to align and the horizontal first type surface by the microelectronic component parent with the direction from a periphery of microelectronic component parent to another periphery of microelectronic component parent.
22. case as claimed in claim 21 is characterized in that, further comprises:
(a) first energy source operationally is coupled to described case, causes to launch first energy stream and to pass through first case window irradiation to the first surface of microelectronic component parent from first energy source; And
(b) second energy source operationally is coupled to described case, causes to launch second energy stream and to pass through second case window irradiation to the second surface of microelectronic component parent from second energy source.
23. device as claimed in claim 22 is characterized in that, first and second energy sources are UV radiation sources.
24. device as claimed in claim 23 is characterized in that, first energy source comprises at least one the front side UV lampshade on the front side that is installed in described case and is installed at least one rear side UV lampshade on the rear side of described case.
25. device as claimed in claim 24 is characterized in that, described at least one front side UV lampshade comprises at least one linear xenon flash lamp bubble, and described at least one rear side UV lampshade comprises at least one linear xenon flash lamp bubble.
26. device as claimed in claim 24 is characterized in that, described at least one front side and rear side lampshade respectively comprise at least one cylinder parabola or ellipsoidal reflector.
27. device as claimed in claim 24 is characterized in that, described at least one rear side UV lampshade rotates 90 degree for described at least one front side UV lampshade.
28. device as claimed in claim 23 is characterized in that, the feature of the output of at least one UV radiation source represents that by pulse train the feature of pulse train is represented by the pulse number of the per second of UV radiation and the energy of each pulse.
29. as claim 22 or 23 described devices, it is characterized in that further comprising a control system, be used for the control energy source so that the energy output of the average energy level of at least two kinds of different times to be provided, heating level to the heating of bringing out substrate effectively and a photochemistry level effective to bringing out described optical processing.
Claims (20)
1. device that is used on substrate carrying out UV heating and optical processing step with front side and rear side, described device comprises:
Be used to hold and keep the reaction chamber of substrate, this reaction chamber comprises front side and rear side;
Be configured to direct radiation at the UV at substrate place radiation source, radiation source described here is at least 0.3 watt/centimetre with from 0.1 to 1.0 micron of wavelength
2Total radiant power be discharged at least a portion of described substrate; And
Control system is used to control the UV radiation source so that the UV output of the average energy level of at least two kinds of different times to be provided, heating level to the heating of bringing out substrate effectively and a photochemistry level effective to bringing out described optical processing.
2. device as claimed in claim 1 further comprises the compound delivery system that compound is discharged into reaction chamber.
3. device as claimed in claim 1 is characterized in that, described UV radiation source comprises at least one the front side UV lampshade on the front side that is installed in described reaction chamber or is installed at least one rear side UV lampshade on the rear side of described reaction chamber.
4. device as claimed in claim 1 is characterized in that, the UV radiation source comprises at least one the front side UV lampshade on the front side that is installed in described reaction chamber and is installed at least one rear side UV lampshade on the rear side of described reaction chamber.
5. device as claimed in claim 4 is characterized in that, described front side and rear side UV lampshade are installed in the outside of described case, and described case further comprises the UV transmissive window, and described UV radiation is transmitted in the described case by described transmissive window.
6. device as claimed in claim 4 is characterized in that, described at least one front side UV lampshade comprises at least one linear xenon flash lamp bubble, and described at least one rear side UV lampshade comprises at least one linear xenon flash lamp bubble.
7. device as claimed in claim 4 is characterized in that, described at least one front side and rear side lampshade respectively comprise at least one cylinder parabola or ellipsoidal reflector.
8. device as claimed in claim 4 is characterized in that, described at least one rear side UV lampshade rotates 90 degree for described at least one front side UV lampshade.
9. device as claimed in claim 1 is characterized in that, the feature of the output of described UV radiation source represents that by pulse train the feature of described pulse train is represented by the per second pulse number of UV radiation and the energy of each pulse.
10. device as claimed in claim 9 is characterized in that, by the per second pulse number in the regulating impulse string and/or the energy of each pulse, control device produces described at least two time averaging power levels.
11. a method that is used for carrying out the UV photochemical treatment on the Semiconductor substrate with front side and rear side, described method comprises the following steps:
At least one heating steps in this step, is provided to substrate to the UV radiation of heating power so that the substrate heating; And
At least one reactions steps in this step, provides the UV radiation of reaction power, and described UV radiation and at least one photochemical reaction compound interact, and causes chemical reaction and realizes substrate processing.
12. method as claimed in claim 11 is characterized in that, during at least one heating steps, described UV radiation source is at least 0.3 watt/centimetre to what at least a portion of substrate surface discharged from 0.1 to 1.0 micron of wavelength
2Total radiant power density, and surpass the power at least one reactions steps, be discharged into substrate at the power that is discharged into substrate during at least one heating steps.
13. method as claimed in claim 11 is characterized in that, has at least a photochemical reaction compound on the substrate surface.
14. method as claimed in claim 11 is characterized in that, described at least a photochemical reaction compound is present in the gaseous environment.
15. method as claimed in claim 14 is characterized in that, at least a photochemical reaction compound is a halo gas.
16. method as claimed in claim 11 is characterized in that, by control the heating to substrate by desired speed generation UV pulses of radiation.
17. method as claimed in claim 11 is characterized in that, during photochemical step, the UV radiation source can be in the operation of power level so, promptly keeps or increases substrate temperature.
18. method as claimed in claim 11 is characterized in that, the UV radiation is provided to the front side and the rear side of substrate.
19. method as claimed in claim 11 is characterized in that, the UV radiation only is provided to a side of substrate.
20. method as claimed in claim 11 is characterized in that, at least one photochemical reaction compound is present in the gaseous environment or on the surface at substrate during described at least one heating steps.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1998/024491 WO2000030157A1 (en) | 1998-11-16 | 1998-11-16 | Equipment for uv wafer heating and photochemical processing |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1337062A true CN1337062A (en) | 2002-02-20 |
CN1155990C CN1155990C (en) | 2004-06-30 |
Family
ID=22268309
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB988143151A Expired - Fee Related CN1155990C (en) | 1998-11-16 | 1998-11-16 | Equipment for UV wafer heating and photochemical processing |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1131845A1 (en) |
JP (1) | JP2002530859A (en) |
KR (1) | KR20010107966A (en) |
CN (1) | CN1155990C (en) |
WO (1) | WO2000030157A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2815395B1 (en) * | 2000-10-13 | 2004-06-18 | Joint Industrial Processors For Electronics | DEVICE FOR QUICK AND UNIFORM HEATING OF A SUBSTRATE BY INFRARED RADIATION |
DE10051125A1 (en) * | 2000-10-16 | 2002-05-02 | Steag Rtp Systems Gmbh | Device for the thermal treatment of substrates |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3682716D1 (en) * | 1985-07-17 | 1992-01-16 | Nec Corp | OPTICAL METHOD FOR PRODUCING LAYERS FROM THE GAS PHASE WITH A STRONG OPTICAL INTENSITY DURING THE BEGINNING PHASE, AND DEVICE THEREFOR. |
NL8602356A (en) * | 1985-10-07 | 1987-05-04 | Epsilon Ltd Partnership | APPARATUS AND METHOD FOR AN AXIAL SYMMETRICAL REACTOR FOR THE CHEMICAL VAPORIZATION. |
JPH0228322A (en) * | 1988-04-28 | 1990-01-30 | Mitsubishi Electric Corp | Preliminary treatment of semiconductor substrate |
EP0441905B1 (en) * | 1989-05-04 | 1995-09-06 | The Regents Of The University Of California | Method and apparatus for processing materials |
US5580421A (en) * | 1994-06-14 | 1996-12-03 | Fsi International | Apparatus for surface conditioning |
-
1998
- 1998-11-16 EP EP98960239A patent/EP1131845A1/en not_active Withdrawn
- 1998-11-16 KR KR1020017006177A patent/KR20010107966A/en not_active Application Discontinuation
- 1998-11-16 JP JP2000583072A patent/JP2002530859A/en active Pending
- 1998-11-16 WO PCT/US1998/024491 patent/WO2000030157A1/en not_active Application Discontinuation
- 1998-11-16 CN CNB988143151A patent/CN1155990C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1131845A1 (en) | 2001-09-12 |
KR20010107966A (en) | 2001-12-07 |
CN1155990C (en) | 2004-06-30 |
WO2000030157A1 (en) | 2000-05-25 |
JP2002530859A (en) | 2002-09-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8338809B2 (en) | Ultraviolet reflector with coolant gas holes and method | |
US8951348B1 (en) | Single-chamber sequential curing of semiconductor wafers | |
US6663792B2 (en) | Equipment for UV wafer heating and photochemistry | |
JP3361112B2 (en) | Semiconductor wafer processing equipment | |
US20060249175A1 (en) | High efficiency UV curing system | |
US8911553B2 (en) | Quartz showerhead for nanocure UV chamber | |
US20060249078A1 (en) | High efficiency uv curing system | |
US8702870B2 (en) | Superimposition of rapid periodic and extensive post multiple substrate UV-ozone clean sequences for high throughput and stable substrate to substrate performance | |
US20100096569A1 (en) | Ultraviolet-transmitting microwave reflector comprising a micromesh screen | |
US10373823B2 (en) | Deployment of light energy within specific spectral bands in specific sequences for deposition, treatment and removal of materials | |
TW202205020A (en) | Pre-exposure photoresist curing to enhance euv lithographic performance | |
CN1155990C (en) | Equipment for UV wafer heating and photochemical processing | |
EP0227839B1 (en) | Method of forming a thin film | |
KR101631586B1 (en) | Superimposition of rapid periodic and extensive post multiple substrate uv-ozone clean sequences for high throughput and stable substrate to substrate performance | |
US20140262037A1 (en) | Transparent yttria coated quartz showerhead | |
WO2006015620A1 (en) | Method for the thermal treatment of disk-shaped substrates | |
JPS6064426A (en) | Method and device for forming vapor-phase reaction thin- film | |
CN117795433A (en) | Dry development apparatus and method for volatilization of dry development byproducts in wafers | |
JPS6246515A (en) | Thin film forming method | |
JPS61196528A (en) | Thin film forming apparatus | |
JPS6118125A (en) | Thin film forming apparatus | |
JPS61131418A (en) | Semiconductor manufacturing equipment | |
JPS61131430A (en) | Semiconductor manufacturing equipment | |
JPS61131427A (en) | Semiconductor manufacturing equipment | |
JPS61131421A (en) | Semiconductor manufacturing equipment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |