CN1331966A - Care or make-up composition containing fiber and hydrophilic polysiloxane - Google Patents
Care or make-up composition containing fiber and hydrophilic polysiloxane Download PDFInfo
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- CN1331966A CN1331966A CN 00124271 CN00124271A CN1331966A CN 1331966 A CN1331966 A CN 1331966A CN 00124271 CN00124271 CN 00124271 CN 00124271 A CN00124271 A CN 00124271A CN 1331966 A CN1331966 A CN 1331966A
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Abstract
The present invention relates to composition used for the cutin care of skin, lip or body surface and beauty treatment. The composition contains cellulose and at least partially crosslinked solid elastic organic polysilane grains suspended in water phase and can deposit on the said cutin to produce soft and fresh feeling. It is used especially as foundation make-up in beauty treatment of face and body or as non-stick lipstick.
Description
The present invention relates to contain the compositions of fiber and polysiloxane aqueous dispersion, said composition is applicable to beauty treatment and dermatosis.More specifically, the present invention is applicable to nursing and/or the treatment and/or the cosmetic of keratose such as skin (comprising scalp), lip and body surface growth-gen (for example eyelashes, eyebrow, fingernail and human hair).Described compositions is not easy to sprawl in when coating soft feel and pure and fresh, and is sticky and mummification do not take place on skin or lip.It is particularly suitable for oily skin, and this is owing to the powder of its camber photoextinction (matt-effect).
Particularly, said composition can be product bar-shaped or dish shape form, for example lip pomade or lip face cream, cast foundation cream, covering product, deodorizer, eye shadow or the end powder of making up; The form of paste that liquidity is different or cream frost, for example can flow foundation cream or lip pomade, informer, mascara, the nursing that is used for skin, sun-proof or coloured composition, body and function make-up composition or be used for fingernail and the make-up composition of hair; Or the form of hydrogel, for example nurse shampoo.
People had understood the practical use of fiber in cosmetic product already, particularly their lengthening effects (referring to JP-A57/158 714) in mascara were known already, its " fabric " sense (referring to JP-A-7/196 440), its in lip pomade fabric effect or its wetting property (referring to US-A-5 498 407) or improve the profile (referring to EP-A-0 106 762) of lip pomade at the lip edge.Unfortunately, fiber is difficult in compositions homodisperse and does not form caking, and this is at coloured composition and particularly changing in the compositions, usually produces inhomogeneous and quite inaesthetic dressing effect, and its profile is not obvious especially.In addition, difficulties in dispersion causes the beauty treatment characteristic of compositions to tie up and earns constant and be difficult to reappears, and therefore can bring problem and make manufacturing cost increase height to suitability for industrialized production.
The cosmetic or the care product that are used for human body skin or lip, for example foundation cream and lip pomade generally contain fat mutually as wax and oily, pigment and/or filler and additive such as cosmetics or skin active substance arbitrarily.Described filler normally plays the modifying composition quality, particularly become more meticulous, and the thin film that compositions is deposited on skin and/or the lip has extinction effect, and these are for the user with Combination or oily skin and live in the user under the damp and hot climate desirable especially.On the other hand, it is painted that the effect of described pigment normally makes compositions.Unfortunately, be used to provide the filler of extinction effect not give skin pure and fresh sense, produce dry on the contrary and tighten and uncomfortable sensation.
Therefore, need a kind of above-mentioned defective that do not exist, and particularly in the process on being coated on skin or lip or the compositions of mummification did not take place in a period of time, effect and pure and fresh sense that said composition can produce uniform aesthstic nursing or make up provide photoextinction simultaneously.
Say that exactly a theme of the present invention is the nursing that is applicable to keratose and/or treatment and/or the make-up composition that overcomes above-mentioned defective.The applicant is surprised to find, in make-up composition, use the aqueous dispersion of fiber and partial cross-linked polysiloxane can give said composition with good beauty treatment character, particularly the time produced evenly in coating, the dressing effect of unanimity and clear-cut, have soft feeling and pure and fresh sense simultaneously.Whole day is coated with this cosmetic also can feel comfortable, and has extinction effect and resistance to water.
The present invention not only is suitable for the cosmetic product of human body face and body skin and lip, and is applicable to the cosmetic product of body surface growth-gen such as eyelashes, eyebrow, fingernail and hair, and is applicable to the nursing and/or the treatment product of the skin that comprises scalp.
More specifically, a theme of the present invention is nursing or the make-up composition that is used for keratose, and said composition contains water, and the granule of partial cross-linked at least solid elastic polysiloxane and fiber dispersion are at this aqueous phase.
Particularly, described organo-polysilane granules and fiber dispersion or even directly be dissolved in this water.
Another theme of the present invention is a kind of keratose that is used for, particularly human body skin or lip, the beauty method of nursing or treatment, and this method comprises that with above-mentioned composition particularly cosmetic composition is coated on these keratoses.
Another theme of the present invention be suspended in aqueous phase and the partial cross-linked at least solid elastic organo-polysilane granules that share with fiber at cosmetic composition, especially for the purposes in the make-up composition of keratose nursing or cosmetic, or in preparation local coating compositions, especially keratose with make up or care composition in purposes, be used to provide the cosmetic or the nursing efficacy of water-fast and/or even and/or pure and fresh and/or delustring.
It is that L and diameter are the object that D and L are far longer than D that term " fiber " is interpreted as length, and D is the inscribe diameter of the circumference of wherein fiber cross section.Particularly, ratio L/D (or form factor) is selected from 3.5-2500, preferably 5-500 and more preferably 5-150.
Described water is suitable to be contained water and optional one or more be the chemical compound of liquid to the miscible room temperature of small part and water, for example polyhydric alcohol, rudimentary C
2-C
5Monohydric alcohol and C
3-C
4Ketone compounds.
It is that temperature is 25 ℃ under normal pressure (760mmHg) that term " room temperature " is interpreted as.
Term " polyol " is interpreted as any organic molecule that contains at least two free hydroxyl groups.Particularly, the IOB that polyhydric alcohol of the present invention has (inorganic/organic balanced) value is greater than 0.5, preferred 1-7 and more preferably 1.5-5.5.These polyhydric alcohol are particularly as the fiber wetting agent.
One skilled in the art can understand the IOB parameter from some publication, described publication is A.Fujita for example, at " pharmacy communication " (Pharm.Bull) 2, the J09/175 925 of the article among the 163-173 (1954) and the J09/151 109 of Shiseido and J08/217 639 or Kose.
Satisfy above-mentioned standard and can be in compositions of the present invention separately or the examples of polyhydric alcohols of using as mixture can be:
Title IOB value-propylene glycol 3.333-butanediol 2.500-isoamyl glycol 2.222-pentanediol 2.000-hexanediol 1.818-PEG-4 (
*) 2.656-PEG-6,2.396-PEG-8,2.266-glycerol, 5.000-pantothenylol 3.125
(
*) usually, be meant the Polyethylene Glycol (PEG) that contains 4-8 ethylene glycol unit.
Described water can be 1%-98% (weight) and preferred 10%-95% (weight), the more preferably 30%-95% (weight) of said composition gross weight.
The mixable chemical compound of described water can be the 0%-30% (weight) of said composition gross weight, preferably 0.1%-30% (weight) and more preferably 1%-15% (weight).
Particularly, said composition is sticking in when coating, non-greasy and soft and sprawl well, has uniform outward appearance simultaneously.
The fiber that can be used for the present composition can be a fiber synthetic or natural, inorganic or organic origin.They can be lacked or be long, and single or many root tissues (for example braiding) and can be hollow or solid together.They can be the cross sections of Any shape, especially circle or polygon (square, hexagon or octagonal), and this depends on specific purposes.Especially, their end is flush end and/or is polished in case major structure becomes damage.
Particularly, the length of described fiber is at 1nm-20mm, preferred 0.1mm-5mm and more preferably in the scope of 0.2mm-1.6mm.Its cross section can be that diameter is 2nm-100 μ m, preferably 20nm-50 μ m and the more preferably circle of 500nm-5 μ m.The fibre weight or the count of yarn (yam count) usually are represented as Denier (denier) or dtex, and represent the gram of 9km yarn to count weight.Fiber of the present invention preferably has the count of yarn of 0.15 Denier-30 Denier and preferred 0.18 Denier-18 Denier.
In order to obtain glossiness cosmetic, this is optimal for fingernail and lip cosmetic, and suitable employing short fiber, particularly length are the short fiber of 1nm-200 μ m.On the other hand, make up for delustring, this makes up especially desirable for facial (particularly powder or foundation cream), preferably adopt long fibre, the particularly length long fibre greater than 200 μ m.
Described fiber fibers that can be those adopt in fabric is produced, and particularly silk fiber, cotton fiber, wool fiber, flax fiber, by the cellulose fibre that extracts in timber, plant or the algae, polyamide (nylon ) fiber, staple fibre, viscose rayon; Acetate fiber, especially silk, cellulose or artificial acetate fiber; Poly-(right-the phenylene terephthalamide) fiber, especially Kevlar ); Acrylic fiber, especially polymethyl methacrylate fiber or poly-(methacrylic acid 2-hydroxyethyl ester) fiber; Polyolefine fiber, especially polyethylene fiber peacekeeping polypropylene fibre; Glass fibre, silicon dioxide fibre, fragrant amide (aramide) fiber; Carbon fiber, the especially carbon fiber of graphite form; Politef (polytetrafluoroethylene ) fiber, insoluble collagen fiber, polyester fiber, polyvinyl chloride fibre or Saran, vinal, polyacrylonitrile fibre, chitosan (chitosan) fiber, polyurethane fiber, polyethylene glycol phthalate fiber, the fiber that forms with mixture by polymer (for example above-mentioned polymer) is as the polyamide/polyester fiber.
Also can adopt the surgery fiber, for example the absorbed synthetic fibers (Johnson﹠amp that makes by hydroxyacetic acid and 6-caprolactone; The Monocryl that Johnson sells); The absorbed synthetic fibers (Johnson﹠amp of lactic acid and co-glycolic acid type; The Vicryl that Johnson sells); Polyester terephthalate fiber (Johnson﹠amp; The Fthibond that Johnson sells) and stainless steel wire (Johnson﹠amp; The Acier that Johnson sells), in the fingernail varnish.
In addition, the surface of described fiber can be treated or unprocessed, coating or coating not, as the coated fiber that can be used as among the present invention, what can mention is with the Fypro (for example R-STAT of Rhodia sale) of copper sulfide coating to have antistatic property, or make the Fypro of the polymer coating of fiber particular organizationization (special surface treatment) with another kind, or through surface treatment painted to produce/Fypro of holographic effect (the Lurex fiber of selling as Sildorex)
The preferred fiber that uses synthesis material, and more preferably organic fiber are as those surgery fibers.
The fiber that can be used for the present composition is Fypro or poly-(to the phenylene terephthalamide) fiber preferably.Its length L can be at 0.1mm-5mm, and in the scope of preferred 0.25mm-1.6mm, and its average diameter D can be in the scope of 5 μ m-50 μ m.Particularly, the Fypro that can adopt Etablissements P.Bonte to sell with trade name Polyamide0.9Dtex0.3mm, its average diameter is 6 μ m, 12.2 μ m or 20 μ m, weight about (0.9dtex) and length are 0.3mm-1mm.Also can adopt average diameter is poly-(right-the phenylene terephthalamide) fiber that 12 μ m and length are about 1.5mm, for example Du Pont Fibres company sell with trade name Kevlar Floc those.
The concentration of fiber depends on concrete purposes and product type.For face cosmetic product such as foundation cream, or lip cosmetic product (for example lip pomade), the concentration of fiber can be the 0.1%-20% (weight) of said composition gross weight, preferred 0.5%-10% (weight).For special role, to the cosmetic effect of body (fingernail or hair), the consumption of described fiber can reach 30% (weight) of said composition gross weight especially.
Even the cream frost that compositions of the present invention can be paste, solid, liquidity is different is the liquor form.Said composition can be moisture or hydrophilic gel, fluid, hard or soft oil-in-water or Water-In-Oil dispersion or emulsified body, is bar-shaped or the dish shape by casting randomly.
Term " elasticity " but polysiloxane is meant the polysiloxane of the softness deformation with viscous-elastic behaviour and particularly sponge or soft spheroid sample denseness.Its elastic modelling quantity is meant that this material can tolerate deformation and elongation and contraction are had limited capacity.This material can recover its original shape after stretching.This elastomer is to have the high molecular weight polymers chain to constitute, uniformly its flowability of crosslinking points network limits.
Elasticity polysiloxane in the present composition has the water-bearing media structural property, and can improve the viscosity of this water-bearing media, except good beauty treatment characteristic, also has softness, pure and fresh sense and extinction effect especially.They do not make xerosis cutis.These new elastomers make compositions comfortable when coating, are easy to sprawl and soft feel and not sticking.Above-mentioned beauty treatment characteristic part is owing to the quality of polysiloxane, and part has the microsponge of being equivalent to owing to it and catch water-bearing media, the character of especially compositions and the water-bearing media skin perspiration.When uniting use with fiber, they are thickener composition to some extent, retains moisture thus well and has good stable.
Elasticity polysiloxane of the present invention is the part or all of crosslinked hydrophilic compounds with three dimensional structure.With these elastomer thickening waters can be wholly or in part.Very surprisingly, the hydrophilic polymer of uniting use with fiber has the moisture retention characteristic.
Elastomer in the present composition is powder or the emulsifying gel form that is dispersed in the elasticity polysiloxane with three dimensional structure in the water.Particulate dispersion (or suspension) is even.
Elasticity polysiloxane of the present invention can be selected from the cross linked polymer described in the patent application JP-A-10/175 816.According to this application, they can by in the presence of the catalyst especially platinum class catalyst by at least :-(a) contain the polysiloxane (i) of at least two vinyls in a kind of α-ω position at the per molecule polysiloxane chain; With-(b) a kind of organosiloxane that contains at least one hydrogen atom that links to each other with silicon atom in per molecule is (ii); Addition and crosslinked the acquisition.
Particularly, described polysiloxane (i) is selected from the polydimethylsiloxane compounds, α especially, ω-dimethyl vinyldimethicone.
Elasticity polysiloxane in the present composition is suitably the form of water slurry or dispersion.Described suspension especially can make according to following method :-(a) polysiloxane (i) and organosiloxane are (ii) mixed;-(b) in the mixture of step (a), add the water contain emulsifying agent;-(c) emulsifying water and this mixture;-(d) in the emulsified body of step (c), add hot water; With-(e) in the presence of platinum catalyst, make intravital polysiloxane of emulsifying (i) and (ii) polymerization of organosiloxane.
The temperature of hot water is suitably 40-60 ℃.After the step (e), all or part of moisture that the gained particle drying can be contained to evaporate wherein.
But described polysiloxane is the form with hydrophilic deformation solid particle of certain degree of hardness, and its hardness can be utilized under Xiao A hardness meter (according to the ASTM standard D2240) room temperature and to measure or adopt Japanese JIS-A method to measure.Can measure this hardness on an elastomer that for this reason prepares, method is as follows: polysiloxane (i) and organosiloxane are (ii) mixed; Remove the air in the mixture; In 100 ℃ baking oven molded and the sclerosis 30 minutes; Be cooled to room temperature, measure hardness subsequently.Also can be with this piece elastomer density measurement.
Particularly, Shore hardness can be in the scope of 1-100, is less than or equal to 80 favourablely, is more preferably less than 65, for example (comprises bound) between 5-50.
Polysiloxane in the present composition for example is the product that those Dow-Coming Toray companies sell with trade name BY 29-122 and BY 29-119.Also can adopt the mixture of these commercially available prod.
The hardness of the elastomer block of product B Y29-119 is 30, and the hardness of the elastomer block of product B Y 29-122 is 7.Density is 097-0.98.
The content of elasticity polysiloxane powder in compositions is suitably 0.1%-70% (weight), preferred 4%-70% and more preferably 4%-50%, this is equivalent to the content of active material in polymer is 0.5%-65% (weight) and more preferably 3%-45% (weight).In fact it constitutes the dispersible filler of water.
The granularity of the granule of elasticity polysiloxane (as active material) is preferably 0.1 μ m-500 μ m, preferred 3 μ m-200 μ m and more preferably 10 μ m-20 μ m.These granules can be spherical, flat or amorphous, are preferably sphere.Particulate granularity is 4.5 μ m among product B Y29-119 and the product B Y29-122.
For stable dispersion in water, above-mentioned organo-polysilane granules can be united use with nonionic, cation or the anion surfactant of one or more HLB 〉=8.Particularly, step (c) obtains in the presence of nonionic emulsifier.
In the elasticity polysiloxane of 100 weight portions, the ratio of surfactant is preferably the 0.1-20 weight portion, more preferably 0.5-10 weight portion (referring to the description of JP-A-10/175 816).
The dispersion of elasticity polysiloxane powder and fiber can (be also referred to as oil for the fatty material of liquid with containing under one or more room temperatures, for example be in JP-A-10/175 816, to disclose those), one or more waxes or one or more at room temperature are solid natural gum, the paste fat thing in one or more animals, plant, mineral or synthetic source, the use fatty linked together of their mixture and inorganic powder or filler (as disclosed herein those).
This additional fat can be any natural fatty phase mutually, particularly can contain under room temperature and atmospheric pressure and to be fluidic product (being also referred to as oil), for example silicone oil, fluorocarbon oil (fluoro oils), fluorosilicone oil and randomly part contain the alkyl oil (hydrocarbon-based oils) of polysiloxane.These oily substances can be the oil in animal, plant, mineral or synthetic source.These oil at room temperature with can be evaporable under the atmospheric pressure.Term " volatile oil " specifically is meant can evaporable oil in the time less than 1 hour when contacting with skin or lip.
Term " fatty phase " is interpreted as being meant the non-water that contains one or more fatty materials, not miscible with water medium, described fatty material is selected from chemical compound, polysiloxane compound and the fluorine compounds that contain at least 10 carbon atoms and preferred 16 carbon atoms, and their mixture.Organic solvent commonly used in the nial polish is not considered to fatty material.
Term " alkyl oil " is meant and mainly contains for example oil of alkane or alkene of carbon atom and hydrogen atom and especially alkyl or alkenyl chain, but also comprises and contain the alkyl that has one or more ethers, ester or hydroxy-acid group or the oil of alkenyl chain.
As the oil that can use in the present composition, what can mention especially is: the alkyl oil of-animal origin, for example perhydro Squalene;-alkyl vegetable oil, the triglyceride of the fatty acid of liquid 4-10 carbon atom for example is as enanthic acid or Trivent OCG; Or other oil, as Oleum helianthi, Semen Maydis oil, Oleum Glycines, bone marrow oil (marrow oil), Oleum Vitis viniferae, Oleum sesami, hazelnut oil, Fructus Pruni oil, macadimia nut oil (macadamia oil), arara oil, Oleum Ricini, American Avocado Tree oil; Caprylic/capric triglyceride, the product of selling as those Stearineries Dubois companies or those Dynamit Nobel are with trade name Miglyol 810,812 and 818 products of selling; Simmondsia oil or shea oil;-Acrawax and ether, for example formula R
1COOR
2Oil, R wherein
1Expression contains the higher fatty acids residue and the R of 7-29 carbon atom
2Expression has the side chain or the non-branched hydrocarbyl chain of 3-30 carbon atom, for example purcellin oil, isononyl isononanoate, isopropyl myristate, Palmic acid 2-Octyl Nitrite, stearic acid 2-octyl group dodecane ester, erucic acid 2-octyl group dodecane ester or isostearic acid iso stearyl ester; The hydroxylating ester type compound, for example lactic acid iso stearyl ester, octyl hydroxystearate, hydroxy stearic acid octyl group dodecane ester, malic acid two iso stearyl esters, citric acid three different cetyl and enanthic acid fat Arrcostab, sad fatty alkyl ester and capric acid fat Arrcostab; Polyol ester is as propylene glycol dicaprylate, dimethyltrimethylene glycol two heptanoates or diethylene glycol two different pelargonates; And pentaerythritol ester, for example pentaerythritol tetraoctyl stearate; The straight or branched hydrocarbon compound in-mineral or synthetic source for example volatilizees or non-volatile liquid paraffin and their derivant petroleum jelly, poly decene or Parleam such as parleam;-synthetic ester and ether, for example isopropyl myristate and alkyl or poly-alkyl caprylate, decanoin or ricinoleate ester;-contain the aliphatic alcohol of 12-26 carbon atom, for example octyldodecanol, 2-butyl capryl alcohol, 2-hexyldecanol, 2-undecyl pentadecanol or oleyl alcohol;-part for example is disclosed among the JP-A-2 295 912 those based on hydrocarbon and/or polysiloxanes fluorocarbon oil;-silicone oil for example contains the volatilization or non-volatile polydimethylsiloxane (PDMS) compounds of straight chain or cyclic polysiloxanes chain, and they at room temperature are liquid or pasty state; The side chain of polysiloxanes and the terminal polydimethylsiloxane that contains alkyl, alkoxyl or phenyl, these groups contain 2-24 carbon atom; Phenyl polysiloxane, for example phenyl gathers trimethicone (phenyl trimethicones), phenyl polydimethylsiloxane (phenyldimethicones), phenyl trimethylsiloxy diphenyl siloxane, the diphenyl polydimethylsiloxane, diphenyl methyl diphenyl trisiloxanes, 2-phenylethyl trimethylsiloxy esters of silicon acis and PSI;-their mixture.
Above-mentioned oil can be the 0%-98.80% of said composition gross weight, preferably 0.5%-80% and more preferably 1%-70% (weight).
Compositions of the present invention is useful on the reagent of forming the liquid fat phase, for example wax, natural gum and filler suitable containing.Described wax can be hydro carbons (only containing carbon atom and hydrogen atom), fluoridize wax and/or silicone waxes or their mixture that they at room temperature can be solid or semisolid (pasty state form), and contain ester group, hydroxyl or mercapto functional group arbitrarily.Particularly, the fusing point of these waxes is higher than 45 ℃.
Described silicone waxes can be to comprise polysiloxane structure and polysiloxane structure side group and/or the terminal unitary wax that has one or more alkyl or oxyalkyl chain, and these chains are straight or brancheds and contain 10-45 carbon atom.Known these waxes are respectively alkyl polydimethylsiloxane and alkoxyl polydimethylsiloxane.These alkyl chains can also contain one or more ester functional group.
Can be used for wax of the present invention as other, what can mention is: the wax of animal origin, as lanoline or Cera Flava; The wax of plant origin is as Brazil wax and candelilla wax; The wax in mineral source, for example paraffin, montan wax or microwax, ceresin or ceresine; Synthetic wax, for example Tissuemat E and Fischer-Tropsch wax; With their mixture.
In order to prepare the compositions with expection characteristic such as denseness or quality, one of ordinary skill in the art can select above-mentioned fatty material in several ways.
Particularly, the existence of wax can be guaranteed excellent mechanical intensity, especially when said composition is bar-shaped form.
Described compositions can contain the wax of 0%-50% and preferred 5%-30% usually, in composition total weight.
Compositions of the present invention can also contain normal other additives that adopt in any this field, for example: and dyestuff, as pigment, Concha Margaritifera, water solublity or lipid-soluble dye; Antioxidant, quintessence oil, antiseptic; Beauty treatment or skin active substance, for example emollient, wetting agent (glycerol), vitamin, essential fatty acid, liquid lanolin, lipotropy or hydrophilic sunscreen; Lipophilic polymer is particularly based on the polymer of hydrocarbon, as polyene; Nertralizer, liquid aliphatic mutually in the reagent and the spice of gelling or thickening, and their mixture.
The consumption of above-mentioned additive in compositions for example is 0%-20% usually, and more preferably 0.1%-10% is in composition total weight.
Compositions of the present invention is suitable to contain one or more water phase thickener or gellant as additional additives, in can be used for water gellant of the present invention, what can mention is: water-soluble cellulose class gellant such as hydroxyethyl-cellulose, methylcellulose, hydroxypropyl cellulose or carboxymethyl cellulose; Guar gum; Quaternized guar gum; Contain C
1-C
6The nonionic guar gum of hydroxyalkyl; Xanthan gum, tragon, lac glucosan glue (scleroglucangum), gellan gum, Fructus rhamni (Rhamnus davurica Pall.) glue (rhamsan gum) or POLY-karaya; Alginate, maltodextrin, starch and derivant thereof and hyaluronic acid and salt thereof; Clay, particularly Montmorillonitum, hectorite or bentonite, and LAPONITE; The polymer that contains carboxyl, for example crosslinked, to the neutral polyacrylic acid of small part, for example " Carbopol " of Goodrich company or " Carbomer " product (Carbomer980 for example uses triethanolamine (TEA) neutralization); Polyglyceryl (methyl) acrylate copolymer; Polyvinylpyrrolidone; Polyvinyl alcohol; Crosslink propylene amide polymer and copolymer; Crosslinked methacrylic acyloxy ethyl-trimethyl salmiac homopolymer; Associative polyurethane and their mixture.These gellant can be 0%-60% (weight), particularly 0.1%-50% (weight) of said composition gross weight.
According to the present invention, described water gellant is preferably from xanthan gum, clay (bentonite or LAPONITE), associative polyurethane; Cellulose thickener, particularly hydroxyethyl-cellulose; With crosslinked, to the neutral polyacrylic acid of small part.
Certainly, those of ordinary skill in the field can careful select optional additional additives and/or its consumption, thus make above-mentioned reinforced not to or the good characteristic of the present composition is not had a negative impact substantially.Particularly, these additives must not produce illeffects to uniformity, stability, comfortableness, extinction effect, pure and fresh sense or the resistance to water of compositions.
Compositions of the present invention can be the form of color-tinted product, cosmetic product in particular for dye, particularly apply some make up as the lipstick and the lip pomade that adds lustre to as foundation cream, kermes, wiping face powder, eye shadow, mascara, informer, bar-shaped covering product, nial polish or lip, can randomly have nursing or curative properties, or body and function is tatooed.They also can be the non-staining forms, wherein randomly contain beauty treatment or skin activating agent.In this case, they can be as the nursing substrate (being used to protect the lip face cream of lip to cold resistance and/or Exposure to Sunlight and/or wind) or the used fixedly substrate of conventional lip pomade of lip.
Compositions of the present invention can also be to be used for skin (comprising scalp), cutin fiber (hair, eyelashes, eyebrow), fingernail or the Dermatology of lip or the form of cosmetic treatments or care composition, or the form of sunscreen composition or artificial tanned compositions, or form, deodorising product or the aromatic props of the cleaning product of skin or cutin fiber or makeup removing agent.In this case, it can be a colorless form, at random contains beauty treatment or skin activating agent.So, nursing substrate (being used to protect the lip face cream of lip) or daily or ight nursing cream frost that it can be used as skin or lip to cold resistance and/or Exposure to Sunlight and/or wind.Also can be treatment or non-treatment, painted or the shampoo of non-staining or the form of hair conditioner.
Obviously, compositions of the present invention should be that cosmetic or skin are acceptable, promptly should contain the medium of nontoxic, the physiologically acceptable human face's of being applicable to skin (drawing together the eyelid inward flange) or lip and body surface growth-gen.
Compositions of the present invention preferably contains coloring agent, particularly contains the coloring agent of granule phase, and described coloring agent is the 0%-60% of said composition gross weight in the ratio of said composition usually, preferred 5%-35%; Can contain pigment and/or Concha Margaritifera and/or filler commonly used in the cosmetic composition with described compositions.Described coloring agent can also be made up of the dyestuff that dissolves in described medium, the red or brown of lipotropy or hydrophilic dye such as Sudan particularly, methylene blue, beta-carotene or beet root juice; They can account for the 0%-6% (weight) of said composition gross weight.
Term " pigment " is interpreted as being meant white or coloured, inorganic or organic granule, and they are insoluble to the medium of compositions and are used for painted and/or make said composition opaque.That term " filler " is interpreted as being meant is colourless or white, inorganic or synthetic, stratiform or non-laminate granular.Term " Concha Margaritifera " is interpreted as being meant the granule that flash of light (iridescent) granule, particularly some Mollusca generate in its shell, or other synthetic granules.These fillers and Concha Margaritifera play compositions quality and/or the delustring/luminous effect of improving.
The ratio of described pigment in compositions is the 0%-60% (weight) of final composition gross weight, preferably 0.05%-25% (weight) and more preferably 4%-20% (weight).As can be used for inorganic pigment of the present invention, can mention titanium dioxide, zirconium oxide or ceria, and zinc oxide, ferrum oxide or chromium oxide and barba hispanica.In can be used for organic pigment of the present invention, what can mention is white carbon black and barium, strontium, calcium and aluminum color lake and their mixture.
The ratio of Concha Margaritifera in compositions is the 0%-20% (weight) of said composition gross weight, preferably about 1%-15% (weight).In can be used for Concha Margaritifera of the present invention, what can mention is the Muscovitum of using titanium dioxide, ferrum oxide, natural pigment or bismuth oxychloride coating, for example coloured odenite.
The ratio of described filler in compositions is the 0%-35% (weight) of said composition gross weight, preferred 0.5-15% (weight).What can mention especially is Talcum, Muscovitum, Silicon stone, nylon (especially Atochem company provide Orgasol ) powder, polyethylene powders, polytetrafluoroethylene , starch, boron nitride, microsphere copolymer such as Expancel (Nobel Industrie), Polytrap (Dow Coming) and polyorganosiloxane resin microballon (for example Tospearl of Toshiba company) and their mixture.
Compositions of the present invention can or not heat one or more elasticity polysiloxane that are dispersed in the powder type in the water by heating and prepares, wherein add one or more pigment, one or more fillers and/or one or more other additives, the optional fatty phase (particularly rising to the wax of peak melting point) that adds liquid form, and if need subsequent emulsifying.
Also can be according to patent application EP-A-667 146 described extrusion molding preparations.This method is included in the cooling procedure pastel (wax+oil+additive+pigment) mixed and generates band, wherein extrudes mixer by means of roll mill or screw rod above-mentioned pastel is crushed.This product is the compositions of soft paste form.
The present invention illustrates in the following example in more detail.Described percentage ratio is based on weight.
Embodiment 1: foundation cream
Oil phase-ring penta siloxanes (cyclopentasiloxane) 10%-KSG-21 20.4%-pigment 10%
Water-Trefil BY 29-119 5%-xanthan gum 0.3%-Fypro 2.5%-propylene glycol 4%-antiseptic is an amount of-water an amount of 100
Preparation: under room temperature (25 ℃), fiber added in the propylene glycol and and under 1000rpm, stirred 30 minutes with the Rayneri turbine-type mixer.Individually, pigment is added in oil/KSG 21 mixture, stir with the three-roller type turbine-type mixer.Propylene glycol/fibre blend is added in KSG 21/ oil/pigment composition.
The foundation cream that obtains the time feels pure and fresh in coating, and is soft and be easy to sprawl, and forms the dressing effect of homogeneous and aesthetic feeling.
Embodiment 2: tingle body with gel-Trefil BY 29-119 32%-Carbomer, 980 0.6%-triethanolamines (nertralizer) 0.6%-Fypro (long 0.3mm long) 1%-propane diols, 1.8%-pigment, 5%-anticorrisive agent an amount of-water an amount of 100 prepares
Being somebody's turn to do color frost gel (cream-gel) prepares by following method: at room temperature add polysiloxane in water, in adding subsequently and gellant, after this add pigment and antiseptic.In addition, at room temperature fiber is introduced propylene glycol, and the gained mixture was stirred 30 minutes under 1000rpm with the Rayneri turbine-type mixer.At last, fiber/propylene glycol mixture is introduced the polysiloxane gel, and then in 10-15 minute, stir with the Rayneri turbine-type mixer.This gel is particularly suitable for the health cosmetic or is used to tatoo.It can be coated on the health of small size, it has profile clearly.Film deposition ground is very even.Through appraising through discussion of 6 experts, this gel produces even, attractive in appearance, soft, no sticky dressing effect.This gel has extremely strong extinction effect when coating, pure and fresh sense keeps good fixing and resistance to water in long-time, and these are different from prior art.
Claims (33)
1. the nursing or the make-up composition that are used for keratose, said composition contain the granule of water, fiber and partial cross-linked at least solid elastic polysiloxane, and described fiber and described Dispersion of Particles are at aqueous phase, and the length of described fiber is much bigger than its diameter.
2. compositions according to claim 1, it is characterized in that described elasticity polysiloxane be in the presence of catalyst by at least: the polysiloxane (i) that contains at least two vinyls in-a kind of α-ω position at the per molecule polysiloxane chain; With-a kind of organosiloxane that contains at least one hydrogen atom that links to each other with silicon atom in per molecule is (ii); Addition and crosslinked the acquisition.
3. require each compositions according to aforesaid right, it is characterized in that described polysiloxane is selected from polydimethylsiloxane.
4. require each described compositions according to aforesaid right, it is characterized in that described elasticity polysiloxane is α, ω-dimethyl vinyldimethicone.
5. aforesaid right requires each described compositions, it is characterized in that the dispersion of described organo-polysilane granules derives from following step :-(a) polysiloxane (i) and organosiloxane are (ii) mixed;-(b) in the mixture of step (a), add the water contain emulsifying agent;-(c) emulsifying water and this mixture;-(d) in the emulsified body of step (c), add hot water; With-(e) in the presence of platinum catalyst, make intravital polysiloxane of emulsifying (i) and (ii) polymerization of organosiloxane.
6. compositions according to claim 5 is characterized in that step (c) is to obtain in the presence of nonionic emulsifier.
7. require each described compositions according to aforesaid right, the particulate particle size range that it is characterized in that described elasticity polysiloxane is 0.1 μ m-500 μ m and preferred 3 μ m-200 μ m.
8. require each described compositions according to aforesaid right, the hardness that it is characterized in that described organo-polysilane granules is less than or equal to 80 and preferably less than 65.
9. require each described compositions according to aforesaid right, it is characterized in that described elasticity polysiloxane is the 0.1%-70% of said composition gross weight (weight), and more preferably 4%-50% (weight).
10. require each described compositions according to aforesaid right, it is characterized in that described fiber is selected from: silk fiber, cotton fiber, wool fiber, flax fiber; Extraction is from the cellulose fibre of timber, plant or algae; Fypro, staple fibre, viscose rayon; Acetate fiber, especially silk, cellulose or artificial acetate fiber; Poly-(right-the phenylene terephthalamide) fiber; Acrylic fiber, especially polymethyl methacrylate fiber or poly-(methacrylic acid 2-hydroxyethyl ester) fiber; Polyolefine fiber, especially polyethylene fiber peacekeeping polypropylene fibre; Glass fibre, silicon dioxide fibre, aramid fiber; Carbon fiber, the especially carbon fiber of graphite form; Polytetrafluoroethylene fiber, insoluble collagen fiber, polyester fiber, polyvinyl chloride fibre or Saran, vinal, polyacrylonitrile fibre, chitin fiber, polyurethane fiber, polyethylene glycol phthalate fiber, the fiber and the surgical operation fiber that form by mixture of polymers.
11. require each described compositions according to aforesaid right, it is characterized in that described fiber is the fiber in synthetic source.
12. require each described compositions according to aforesaid right, it is characterized in that described fiber is Fypro or poly-(right-the phenylene terephthalamide) fiber.
13. require each described compositions according to aforesaid right, it is characterized in that described fiber has the count of yarn of 0.15 Denier-30 Denier and preferred 0.18 Denier-18 Denier.
14. require each described compositions according to aforesaid right, it is characterized in that described fiber has length L and diameter D, L/D is selected from 3.5-2500, preferably 5-500 and more preferably 5-150.
15. require each described compositions according to aforesaid right, the length that it is characterized in that described fiber is 0.1mm-5mm, preferred 0.2mm-1.6mm.
16. require each described compositions according to aforesaid right, the average diameter that it is characterized in that described fiber is 2nm-100 μ m.
17. require each described compositions according to aforesaid right, it is characterized in that described fiber is the 0.1%-20% (weight) of said composition gross weight and more preferably 0.5%-10% (weight).
18. require each described compositions according to aforesaid right, it is characterized in that said composition also contains fatty phase.
19. require each described compositions according to aforesaid right, it is characterized in that described fat contains at least a fatty material mutually, this fatty material is selected from and is the volatilization of liquid or fixed oil, wax, natural gum and animal, plant, mineral or synthetic paste fat thing of originating under the room temperature, and their mixture.
20. require each described compositions according to aforesaid right, it is characterized in that it contains at least a oil, described grease separation is from perhydro Squalene, enanthic acid or Trivent OCG; Perhaps, Oleum helianthi, Semen Maydis oil, Oleum Glycines, bone marrow oil, Oleum Vitis viniferae, Oleum sesami, hazelnut oil, Fructus Pruni oil, macadimia nut oil, arara oil, Oleum Ricini, American Avocado Tree oil; Suffering/sour tricaprin; Simmondsia oil or shea oil; Liquid paraffin and derivant thereof, petroleum jelly, poly decene or Parleam such as parleam; Purcellin oil, isopropyl myristate, isononyl isononanoate, Palmic acid 2-Octyl Nitrite, stearic acid 2-octyl group dodecane ester, erucic acid 2-octyl group dodecane ester or isostearic acid iso stearyl ester; Lactic acid iso stearyl ester, octyl hydroxystearate, hydroxy stearic acid octyl group dodecane ester, malic acid two iso stearyl esters, citric acid three different cetyl or enanthic acid fat Arrcostab, sad fatty alkyl ester and capric acid fat Arrcostab; Propylene glycol dicaprylate, neopentyl glycol two heptanoates or diethylene glycol two different pelargonates; And pentaerythritol ester; Octyldodecanol, 2-butyl capryl alcohol, 2-hexyldecanol, 2-undecyl pentadecanol or oleyl alcohol; Under the room temperature volatilization or non-volatile, the straight chain or the cyclic polydimethylsiloxane (PDMS) of liquid; Phenyl gathers trimethicone, phenyl trimethylsiloxy diphenyl siloxane, diphenyl polydimethylsiloxane, diphenyl methyl diphenyl trisiloxanes and trimethylsiloxy silicic acid 2-phenylethylester; With their mixture.
21. require each described compositions according to aforesaid right, it is characterized in that also containing the water gellant in said composition.
22. require each described compositions according to aforesaid right, it is characterized in that described water gellant be selected from xanthan gum, clay, associative polyurethane, cellulose thickener and crosslinked, to the neutral polyacrylic acid of small part.
23. require each described compositions according to aforesaid right, it is characterized in that it also contains coloring agent.
24. require each described compositions according to aforesaid right, it is characterized in that also containing the granule phase, this granule is the 0%-60% (weight) of said composition gross weight mutually, preferred 5%-35% (weight).
25. require each described compositions according to aforesaid right, it is characterized in that also containing at least a cosmetics or skin active agent.
26. require each described compositions according to aforesaid right, it is characterized in that said composition is the form of hydrophilic gel or rigidity or softish oil-in-water or invert emulsion body, is configured as bar-shaped arbitrarily or the dish shape.
27. require each described compositions according to aforesaid right, it is characterized in that said composition also contains at least a component that is selected from antioxidant, quintessence oil, antiseptic, spice, lipophilic polymer, liquid aliphatic phase gellant, wax, natural gum, filler, dispersion liquid and miscible type chemical compound of water and their mixture.
28. require each described compositions according to aforesaid right, it is characterized in that said composition be foundation cream, wipe face powder or eye shadow compositions form, hide product, body and function cosmetic product, lip pomade, informer, mascara, nial polish, lip nursing with substrate or fixedly substrate, dermatosis with product or skin or cutin fiber with care product, sunscreen composition or artificial tanned compositions, or skin or cutin fiber Cleasing compositions.
29. be used for the method for human keratinous material aesthetic nursing or treatment, this method comprises above-mentioned each described cosmetic composition is coated on these keratoses.
30. be used to obtain the evenly beauty method of cosmetic, this method comprise in cosmetic composition introduce be dispersed in aqueous phase as each described fiber among each described partial cross-linked at least solid elastic organo-polysilane granules and the claim 10-17 among the claim 2-9.
31. the granule of partial cross-linked at least solid elastic polysiloxane and fiber are at the cosmetic use that is used for keratose nursing or make-up composition, described granule and described fiber dispersion are at aqueous phase, and said composition is water-fast and/or provide even and/or delustring and/or pure and fresh cosmetic or nursing efficacy.
32. purposes according to claim 31 is characterized in that described organo-polysilane granules is described granule among the claim 2-9.
33., it is characterized in that described fiber is described fiber among the claim 10-17 according to claim 31 or 32 described purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00124271 CN1236755C (en) | 2000-07-12 | 2000-07-12 | Care or make-up composition containing fiber and hydrophilic polysiloxane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00124271 CN1236755C (en) | 2000-07-12 | 2000-07-12 | Care or make-up composition containing fiber and hydrophilic polysiloxane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1331966A true CN1331966A (en) | 2002-01-23 |
| CN1236755C CN1236755C (en) | 2006-01-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00124271 Expired - Fee Related CN1236755C (en) | 2000-07-12 | 2000-07-12 | Care or make-up composition containing fiber and hydrophilic polysiloxane |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100361697C (en) * | 2004-06-02 | 2008-01-16 | 严跃华 | Medicine for replenishing liver and detoxicating |
| CN101080213B (en) * | 2005-01-21 | 2010-09-29 | 株式会社资生堂 | Cosmetics for eyelash |
| CN104955440A (en) * | 2012-12-04 | 2015-09-30 | 日产化学工业株式会社 | Cosmetic additive and cosmetic containing same |
| CN105828790A (en) * | 2013-12-23 | 2016-08-03 | 莱雅公司 | Aqueous cosmetic composition comprising alkylcellulose, non-volatile oils, a hydrophilic gelling polymer and a polyol |
| CN105963148A (en) * | 2016-07-08 | 2016-09-28 | 广州卡迪莲化妆品有限公司 | Lip make-up product |
| CN107320395A (en) * | 2017-08-14 | 2017-11-07 | 上海欧润化妆品有限公司 | A kind of eye shadow and preparation method thereof |
-
2000
- 2000-07-12 CN CN 00124271 patent/CN1236755C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100361697C (en) * | 2004-06-02 | 2008-01-16 | 严跃华 | Medicine for replenishing liver and detoxicating |
| CN101080213B (en) * | 2005-01-21 | 2010-09-29 | 株式会社资生堂 | Cosmetics for eyelash |
| CN104955440A (en) * | 2012-12-04 | 2015-09-30 | 日产化学工业株式会社 | Cosmetic additive and cosmetic containing same |
| US10010490B2 (en) | 2012-12-04 | 2018-07-03 | Nissan Chemical Industries, Ltd. | Cosmetic composition comprising cellulose fibers with small fiber diameter and comparatively small aspect ratio |
| CN105828790A (en) * | 2013-12-23 | 2016-08-03 | 莱雅公司 | Aqueous cosmetic composition comprising alkylcellulose, non-volatile oils, a hydrophilic gelling polymer and a polyol |
| CN105963148A (en) * | 2016-07-08 | 2016-09-28 | 广州卡迪莲化妆品有限公司 | Lip make-up product |
| CN107320395A (en) * | 2017-08-14 | 2017-11-07 | 上海欧润化妆品有限公司 | A kind of eye shadow and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1236755C (en) | 2006-01-18 |
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