CN1323879A - Efficient metal scavenger - Google Patents
Efficient metal scavenger Download PDFInfo
- Publication number
- CN1323879A CN1323879A CN 01115064 CN01115064A CN1323879A CN 1323879 A CN1323879 A CN 1323879A CN 01115064 CN01115064 CN 01115064 CN 01115064 A CN01115064 A CN 01115064A CN 1323879 A CN1323879 A CN 1323879A
- Authority
- CN
- China
- Prior art keywords
- percent
- triethanolamine
- weight
- peregal
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 239000002516 radical scavenger Substances 0.000 title abstract 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229960004418 trolamine Drugs 0.000 claims abstract description 7
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims abstract description 6
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 8
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 5
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 239000012459 cleaning agent Substances 0.000 claims description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 7
- 239000006260 foam Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 abstract 1
- 229940049964 oleate Drugs 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- -1 Oleic acid triethanolamine Sodium nitrite Triethanolamine Sodium carbonate Chemical compound 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Detergent Compositions (AREA)
Abstract
A high efficiency metal scavenger is composed of (wt.%): peregal 0.5-2%, 6501 1-10%, triethanol amin oleate 1-5%, sodium nitrite 1-10%, triethanol amine 1-10%, the rest is water. Advantages include: low foam, high efficiency (cleaning rate higher than 90%), no corrosion to metal surface, stable, no pollution (no phosphosus and aluminium) etc.
Description
The invention relates to a detergent, in particular to a detergent for cleaning a metal surface.
The metal cleaning agent produced and used in China at present mostly contains chemical components such as strong acid, strong base, phosphate, aluminum salt and the like, and the products are toxic to human bodies, have poor microbial degradation performance, seriously damage animals and plants, have more foams, pollute river water and underground water resources and can damage the metal surface to be cleaned to different degrees.
Aiming at the problems, the invention provides a high-efficiency, low-foam, antirust and pollution-free metal cleaning agent.
The invention relates to a composition, which consists of the following components in percentage by weight:
0.5 to 2 percent of peregal
6501 1～10％
1-5% of triethanolamine oleate
1 to 10 percent of sodium nitrite
1 to 10 percent of triethanolamine
The balance of water.
The preferred formula (weight percentage) of the invention is as follows:
0.5 to 1 percent of peregal
6501 1～5％
1-3% of triethanolamine oleate
1 to 6 percent of sodium nitrite
4 to 10 percent of triethanolamine
The balance of water.
The formulation of the present invention may further comprise 0.5 to 5% by weight of sodium carbonate, preferably 0.5 to 2% by weight.
In order to achieve the purpose of corrosion prevention, 1-10% (weight percentage) of sodium benzoate can be added into the formula.
The composition of the invention is prepared by mixing and uniformly stirring all the components in the formula.
The invention has the advantages of low foam, high efficiency (the cleaning rate is more than 90%), no corrosion to the metal surface (the rust resistance reaches 0 level), good stability and no pollution (no phosphorus and aluminum).
The present invention is further illustrated by the following examples.
Examples 1 to 3:
the metal cleaner was obtained by mixing the components in different proportions (in weight percent) as shown in Table 1, and the cleaning rate, pH value and rust inhibitive performance were measured respectively. Wherein,
cleaning rate: cleaning rate = oil stain weight cleaned/original oil stain weight.
pH value: the pH of the mixed composition was measured using pH paper.
Antirust property: rating standard: the grade 0 surface is free of rust and has no obvious change.
Grade 1 surfaces are rust free, slightly discolored or dull.
Grade 2 surface rust or uneven discoloration.
Large-area corrosion on the surface of the level 3.
TABLE 1
| Pingpijia | 6501 | Oleic acid triethanolamine | Sodium nitrite | Triethanolamine | Sodium carbonate | pH value | Rust resistance | Cleaning rate | |
| Example 1 | 0.5 | 1.5 | 3.0 | 1.5 | 4.0 | 1.5 | 9.3 | Level 0 | 95.9 |
| Example 2 | 0.5 | 2.0 | 2.0 | 2.0 | 5.0 | 1.0 | 9.0 | Level 0 | 91.0 |
| Example 3 | 0.5 | 3.0 | 1.5 | 2.5 | 5.0 | 0.5 | 9.3 | Level 0 | 91.2 |
| Example 4 | 0.5 | 4.0 | 1.0 | 3.0 | 7.0 | 0 | 9.0 | Level 0 | 92.1 |
| Example 5 | 0.5 | 5.0 | 1.0 | 4.0 | 7.0 | 0 | 9.3 | Level 0 | 95.0 |
| Example 6 | 1.0 | 5.0 | 1.0 | 4.0 | 9.0 | 0 | 9.3 | Level 0 | 93.2 |
| Example 7 | 1.0 | 5.0 | 1.0 | 6.0 | 8.0 | 0.5 | 9.0 | Level 0 | 90.1 |
The components of the manufacturers and the main components are as follows:
adding in a plain mode: fatty alcohol polyoxyethylene (15) ether Tianjin reagent factory;
6501: dodecyl diethanol amide Shanghai auxiliary agent II;
triethanolamine oleate: a near-to chemical plant;
triethanolamine: a near-to-the-chemical plant.
Claims (5)
1. The efficient metal cleaning agent is characterized by comprising the following components in percentage by weight:
0.5 to 2 percent of peregal
6501 1～10％
1-5% of triethanolamine oleate
1 to 10 percent of sodium nitrite
1 to 10 percent of triethanolamine
The balance of water.
2. The metal cleaner as claimed in claim 1, wherein the formulation (weight percent) is:
0.5 to 1 percent of peregal
6501 1～5％
1-3% of triethanolamine oleate
1 to 6 percent of sodium nitrite
4 to 10 percent of triethanolamine
The balance of water.
3. The metal cleaner as claimed in claim 1, wherein the formulation (weight percent) is:
0.5 percent of peregal
6501 1.5％
Oleic acid triethanolamine 1.5%
Sodium nitrite 3%
4 percent of triethanolamine
The balance of water.
4. The metal cleaner as claimed in claim 1, 2 or 3, wherein the formulation further comprises 0.5-5% (by weight) sodium carbonate.
5. The metal cleaner as claimed in claim 1, 2 or 3, wherein the formulation further comprises 1-10% (by weight) of sodium benzoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01115064 CN1117142C (en) | 2001-06-18 | 2001-06-18 | Efficient metal scavenger |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01115064 CN1117142C (en) | 2001-06-18 | 2001-06-18 | Efficient metal scavenger |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1323879A true CN1323879A (en) | 2001-11-28 |
| CN1117142C CN1117142C (en) | 2003-08-06 |
Family
ID=4661655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01115064 Expired - Fee Related CN1117142C (en) | 2001-06-18 | 2001-06-18 | Efficient metal scavenger |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1117142C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460493C (en) * | 2006-06-16 | 2009-02-11 | 大连绿洲化工有限公司 | Environmental protection high concentration low foam rust proof metal cleaning agent and its technology |
| CN100526513C (en) * | 2007-04-11 | 2009-08-12 | 江苏德美科技有限公司 | Wax removing water for cleaning automobile aluminum wheel hub and preparation method thereof |
| CN101914410A (en) * | 2010-08-25 | 2010-12-15 | 成都龙邦科技有限公司 | Metal cutting fluid and preparation method thereof |
| CN102400168A (en) * | 2011-12-06 | 2012-04-04 | 安徽省泰隆投资股份有限公司 | Tin case aerosol type cleaning agent |
| CN104830548A (en) * | 2015-05-13 | 2015-08-12 | 吴江市震宇缝制设备有限公司 | Oil stain detergent for sewing machine overhauling |
| CN112708497A (en) * | 2020-07-09 | 2021-04-27 | 科之杰新材料集团有限公司 | Concrete release agent and preparation method thereof |
-
2001
- 2001-06-18 CN CN 01115064 patent/CN1117142C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100460493C (en) * | 2006-06-16 | 2009-02-11 | 大连绿洲化工有限公司 | Environmental protection high concentration low foam rust proof metal cleaning agent and its technology |
| CN100526513C (en) * | 2007-04-11 | 2009-08-12 | 江苏德美科技有限公司 | Wax removing water for cleaning automobile aluminum wheel hub and preparation method thereof |
| CN101914410A (en) * | 2010-08-25 | 2010-12-15 | 成都龙邦科技有限公司 | Metal cutting fluid and preparation method thereof |
| CN101914410B (en) * | 2010-08-25 | 2012-10-24 | 成都龙邦科技有限公司 | Metal cutting fluid and preparation method thereof |
| CN102400168A (en) * | 2011-12-06 | 2012-04-04 | 安徽省泰隆投资股份有限公司 | Tin case aerosol type cleaning agent |
| CN104830548A (en) * | 2015-05-13 | 2015-08-12 | 吴江市震宇缝制设备有限公司 | Oil stain detergent for sewing machine overhauling |
| CN112708497A (en) * | 2020-07-09 | 2021-04-27 | 科之杰新材料集团有限公司 | Concrete release agent and preparation method thereof |
| CN112708497B (en) * | 2020-07-09 | 2021-11-19 | 科之杰新材料集团有限公司 | Concrete release agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1117142C (en) | 2003-08-06 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |