CN102400168A - Tin case aerosol type cleaning agent - Google Patents
Tin case aerosol type cleaning agent Download PDFInfo
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- CN102400168A CN102400168A CN2011103985459A CN201110398545A CN102400168A CN 102400168 A CN102400168 A CN 102400168A CN 2011103985459 A CN2011103985459 A CN 2011103985459A CN 201110398545 A CN201110398545 A CN 201110398545A CN 102400168 A CN102400168 A CN 102400168A
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Abstract
The invention discloses a tin case aerosol type cleaning agent, which comprises a solution consisting of nonylphenol polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, coconut oil fatty acid diethanol amide, triethanolamine, ethanol, sodium benzoate, sodium molybdate, deionized water and essence; and the solution is mixed uniformly and then put into a tin case, a specified amount of propane/butane gas reaching the rated pressure is introduced, and thus the product is obtained. The cleaning agent has good anticorrosive effect on the tin case, does not leak, has good cleaning effect and low cost, and is widely applied to cleaning of various articles in the fields of automobile maintenance, home care and the like.
Description
Technical field
The present invention relates to a kind of aerosol-type clean-out system, relate more specifically to a kind of can aerosol-type clean-out system.
Background technology
The aerosol-type clean-out system is because its convenient and swift, that reasonable price is widely used in the various article in field such as Motor Maintenance, household care cleaning.Usually the aerosol-type clean-out system all is potted in the can, however tank body be prone to be corroded, often take place to leak a jar phenomenon, become each manufacturer's common difficult problem of puzzlement for a long time.Metallic corrosion is divided into three kinds of chemical corrosion, galvanic corrosion, physics corrosion.The corrosion of tinplate tin mainly is galvanic corrosion, is divided into three processes: first process is the oxidation of anode metal and discharges electronics, and the outer field tin coating oxidation of tinplate tin comes off, and the iron of bottom begins to be oxidized to iron ion; Second process is that oxygen (neutrality or alkaline condition) the absorption electronics of negative electrode is reduced; The 3rd process be electronics in metal, ion flow to form electric current in solution.These three processes are the prerequisites that form galvanic corrosion, prevent that this corrosive from taking place is exactly through suppressing realizing of one or several process reaction.
At present, the anticorrosion main path of tinplate tin aerosol container is: select tensio-active agent for use, the purity of control water is added inhibiter.Because the character of tensio-active agent is few to the relevant report of mechanism of corrosion of tinplate tin; Cause from tens of kinds of tensio-active agents and to select several kinds of synergies good, it is very big, same that the tinplate tin aerosol container is not produced the very little work difficulty of corrosion or corrodibility; From tens of kinds of organic and inorganic inhibiter; The selection corrosion mitigating effect is good, the acceptable composite corrosion inhibitor of cost producer, and difficulty is bigger.Although the purity of water height is all known corrosion of metal property great majority, when producing specific to can aerosol-type sanitising agent, the purity requirement of water is often out in the cold, causes when corrosion takes place and does not know that also where is the problem.
Summary of the invention
Technical problem to be solved by this invention provides a kind ofly has good anticorrosion ability and the good can aerosol-type clean-out system of cleaning effect to can itself.
For solving the problems of the technologies described above, can aerosol-type clean-out system of the present invention by weight, comprises following material:
Polyoxyethylene nonylphenol: 0.5%～3%,
AEO: 1%～3%,
The fatty acid distribution of coconut oil diglycollic amide: 1%～2%,
Trolamine: 1%～3%,
Ethanol: 1%～5%,
Sodium Benzoate: 0.5%～2%,
Sodium orthomolybdate: 0.1%～0.8%,
Essence: 0.1%～0.6%,
Deionized water: 80.6%～94.8%.
Preferred proportioning is:
Polyoxyethylene nonylphenol: 2%,
AEO: 3%,
The fatty acid distribution of coconut oil diglycollic amide: 1%,
Trolamine: 3%,
Ethanol: 5%,
Sodium Benzoate: 1%,
Sodium orthomolybdate: 0.8%,
Essence: 0.2%
Deionized water: 84.0%.
Said de-ionized electrical conductivity of water is not more than 15 μ S/cm.
Because technique scheme has adopted three kinds of nonionogenic tensides such as polyoxyethylene nonylphenol, AEO, fatty acid distribution of coconut oil diglycollic amide; Under the prerequisite of the clean effect that guarantees clean-out system, avoided the destruction of anionic group such as sulfonate radical, the cl ions etc. of tensio-active agent effectively to the passive film of metallic surface.Adopt trolamine, Sodium Benzoate, Sodium orthomolybdate is organic and the compound prescription of inorganic multiple inhibition material, corrosion mitigating effect has satisfied requirement of products.Adopting deionized water, is the important step that effectively prevents the tinplate tin galvanic corrosion.Therefore, the present invention has good anticorrosion ability to can itself, can not take place to leak a jar phenomenon, and cleaning effect is good, and cost is low, can be widely used in the cleaning of the various article in field such as Motor Maintenance, household care.
Embodiment
Embodiment 1
Polyoxyethylene nonylphenol (TX-10) 2 grams
AEO (AEO-9) 2 grams
Fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 1 gram
Ethanol 2 grams
Trolamine 1 gram
Sodium Benzoate 1 gram
Sodium orthomolybdate 0.4 gram
Deionized water 90.5 grams
Essence 0.1 gram.
Embodiment 2
Polyoxyethylene nonylphenol (TX-10) 0.5 gram
AEO (AEO-9) 1 gram
Fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 2 grams
Trolamine 2 grams
Ethanol 5 grams
Sodium Benzoate 2 grams
Sodium orthomolybdate 0.8 gram
Deionized water 86.6 grams
Essence 0.1 gram.
Embodiment 3
Polyoxyethylene nonylphenol (TX-10) 3 grams
AEO (AEO-9) 3 grams
Fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 2 grams
Trolamine 3 grams
Ethanol 5 grams
Sodium Benzoate 2 grams
Sodium orthomolybdate 0.8 gram
Deionized water 81.1 grams
Essence 0.1 gram.
Embodiment 4
Polyoxyethylene nonylphenol (TX-10) 0.5 gram
AEO (AEO-9) 1 gram
Fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 1 gram
Trolamine 1 gram
Ethanol 1 gram
Sodium Benzoate 0.5 gram
Sodium orthomolybdate 0.1 gram
Deionized water 94.8 grams
Essence 0.1 gram.
Embodiment 5
Polyoxyethylene nonylphenol (TX-10) 2 grams
AEO (AEO-9) 3 grams
Fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 1 gram
Trolamine 3 grams
Ethanol 5 grams
Sodium Benzoate 1 gram
Sodium orthomolybdate 0.8 gram
Deionized water 83.8 grams
Essence 0.4 gram.
Put into can after the feed liquid of above-mentioned each embodiment mixes, on the production line inflator, charge into specified amount like 10 grams and reach third butane gas of rated pressure, can aerosol-type clean-out system of the present invention.
Can aerosol-type clean-out system of the present invention shakes up these article before using, and is directly injected into article surface to be cleaned, treat 20-30 seconds after, erase to get final product with soft cloth.For the serious part of spot, spray these article after 20-30 seconds, use the wiping on spot of soft brush, erase with clean rag again.
The anticorrosion scheme of can: the one, improve the purity of water, effect is well-known to ortho-water to corrosion of metal.Therefore, guarantee that the purity of water is the important step that effectively prevents the tinplate tin galvanic corrosion, the present invention requires electrical conductivity of water to be not more than 15 μ S/cm.The 2nd, add inhibiter; Inhibiter is divided into inorganic and organic two big types; The mineral compound inhibiter; Like metasilicate, phosphoric acid salt, tungstate, borate, nitrite, molybdate, benzoate etc., they can make the metallic surface form the fine and close passive film of one deck, can block or prevent oozing hydrogen and oozing the acid effect of metal.The organic cpds inhibiter, like trolamine, benzotriazole, mercaptobenzothiazole, organophosphate etc., corrosion inhibition is better.The corrosion mitigating effect that improves inhibiter is a key of the present invention, and the present invention adopts the compound prescription of inorganic and organic multiple inhibition material, and corrosion mitigating effect reaches requirement of products, and cost is attend enterprise and also can be accepted.The 3rd, select surfactant types; Through experiment repeatedly; The anionic group of our table of discovery surface-active agent such as sulfonate radical, cl ions etc. have destruction to the passive film of metallic surface; The present invention has screened three kinds of nonionogenic tensides, under the prerequisite of the clean effect that guarantees clean-out system, has avoided the generation of this type of anionic group destruction effectively.
Proof test of the present invention is following:
Comparative example A: sulfonic acid 2 grams, polyoxyethylenated alcohol sodium sulfate (AES) 2 grams, AEO (AEO-9) 1.5 grams, ethanol 5 grams, trolamine 3.5 grams, Sodium Benzoate 1 gram, tripoly phosphate sodium STPP 1 gram, deionized water 83.6 grams, essence 0.4 gram.
Comparative Examples B: polyoxyethylene nonylphenol (TX-10) 2 grams, AEO (AEO-9) 3 grams, fatty acid distribution of coconut oil diglycollic amide (6501, model 1: 1.5) 1 gram, ethanol 5 grams, trolamine 3 grams, Sodium Benzoate 1 gram, Sodium orthomolybdate 0.8 gram, soft water 83.8 grams, essence 0.4 gram.
The feed liquid of comparative example A, Comparative Examples B and embodiment 5 is put into jar respectively, add third butagas after, put into 55 ℃ ± 1 ℃ water-soluble pot, take out 2 week backs (336 hours), opens the aerosol jar and observe the inner wall corrosion situation.
Experimental result:
The comparative example A: the can seam burnt hair has many places scale spot, moderate corrosion.
Comparative Examples B: the can seam burnt hair has the little rust staining in a place, mild corrosion.
Embodiment 5: tank body light, no rust staining, no corrosion phenomenon.
Conclusion:
The corrosion mitigating effect of the purity of the character of tensio-active agent, water, inhibiter has direct relation to the corrosion of tank body in the material; Select suitable tensio-active agent for use; The purity of control water, the compound interpolation of organic and inorganic inhibiter can well solve the etching problem of can aerosol-type tank body.
Claims (3)
1. can aerosol-type clean-out system by weight, comprises following material:
Polyoxyethylene nonylphenol: 0.5%～3%,
AEO: 1%～3%,
The fatty acid distribution of coconut oil diglycollic amide: 1%～2%,
Trolamine: 1%～3%,
Ethanol: 1%～5%,
Sodium Benzoate: 0.5%～2%,
Sodium orthomolybdate: 0.1%～0.8%,
Essence: 0.1%～0.6%,
Deionized water: 80.6%～94.8%.
2. can aerosol-type clean-out system according to claim 1 is characterized in that:
Polyoxyethylene nonylphenol: 2%,
AEO: 3%,
The fatty acid distribution of coconut oil diglycollic amide: 1%,
Trolamine: 3%,
Ethanol: 5%,
Sodium Benzoate: 1%,
Sodium orthomolybdate: 0.8%,
Essence: 0.2%,
Deionized water: 84%.
3. can aerosol-type clean-out system according to claim 1 and 2 is characterized in that: said de-ionized electrical conductivity of water is not more than 15 μ S/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110398545 CN102400168B (en) | 2011-12-06 | 2011-12-06 | Tin case aerosol type cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110398545 CN102400168B (en) | 2011-12-06 | 2011-12-06 | Tin case aerosol type cleaning agent |
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| CN102400168A true CN102400168A (en) | 2012-04-04 |
| CN102400168B CN102400168B (en) | 2013-04-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110398545 Active CN102400168B (en) | 2011-12-06 | 2011-12-06 | Tin case aerosol type cleaning agent |
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| CN (1) | CN102400168B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104141135A (en) * | 2014-07-28 | 2014-11-12 | 宁国市大泉机械有限公司 | Antirust water for casting |
| CN104404498A (en) * | 2014-11-12 | 2015-03-11 | 无锡伊佩克科技有限公司 | Chromate-free passivator for galvanized steel sheets and preparation method thereof |
| CN109776402A (en) * | 2019-01-30 | 2019-05-21 | 深圳市兆新能源股份有限公司 | Isopropylamine yl pyridines quaternary ammonium salt and preparation method thereof and aqueous cleaning aerosol |
| CN111321419A (en) * | 2020-04-13 | 2020-06-23 | 宿迁盾嘉生物科技有限公司 | Degreasing agent used in tinplate process and using method |
| CN112745992A (en) * | 2020-12-31 | 2021-05-04 | 广东好顺欧迪斯科技股份有限公司 | Water-based cleaning agent, and preparation method and application thereof |
| CN113082570A (en) * | 2021-03-30 | 2021-07-09 | 浙江钱锦气雾剂制品有限公司 | Water-based foam type aerosol fire extinguisher and manufacturing method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323879A (en) * | 2001-06-18 | 2001-11-28 | 青岛海洋大学 | Efficient metal scavenger |
| CN101503804A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Cleaning liquid composition and use thereof |
| CN101705496A (en) * | 2009-11-16 | 2010-05-12 | 南通飞拓生物科技有限公司 | Environment-friendly metal cleaner |
-
2011
- 2011-12-06 CN CN 201110398545 patent/CN102400168B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323879A (en) * | 2001-06-18 | 2001-11-28 | 青岛海洋大学 | Efficient metal scavenger |
| CN101503804A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Cleaning liquid composition and use thereof |
| CN101705496A (en) * | 2009-11-16 | 2010-05-12 | 南通飞拓生物科技有限公司 | Environment-friendly metal cleaner |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104141135A (en) * | 2014-07-28 | 2014-11-12 | 宁国市大泉机械有限公司 | Antirust water for casting |
| CN104404498A (en) * | 2014-11-12 | 2015-03-11 | 无锡伊佩克科技有限公司 | Chromate-free passivator for galvanized steel sheets and preparation method thereof |
| CN109776402A (en) * | 2019-01-30 | 2019-05-21 | 深圳市兆新能源股份有限公司 | Isopropylamine yl pyridines quaternary ammonium salt and preparation method thereof and aqueous cleaning aerosol |
| CN111321419A (en) * | 2020-04-13 | 2020-06-23 | 宿迁盾嘉生物科技有限公司 | Degreasing agent used in tinplate process and using method |
| CN112745992A (en) * | 2020-12-31 | 2021-05-04 | 广东好顺欧迪斯科技股份有限公司 | Water-based cleaning agent, and preparation method and application thereof |
| CN112745992B (en) * | 2020-12-31 | 2022-04-22 | 广东好顺欧迪斯科技股份有限公司 | Water-based cleaning agent, and preparation method and application thereof |
| CN113082570A (en) * | 2021-03-30 | 2021-07-09 | 浙江钱锦气雾剂制品有限公司 | Water-based foam type aerosol fire extinguisher and manufacturing method thereof |
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| CN102400168B (en) | 2013-04-17 |
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Address after: 246005 No. 3.9 Industrial Park, two West Road, Anqing Development Zone, Anhui, 6-03 Patentee after: ANHUI TAILONG CHENGYA GROUP CO., LTD. Address before: 246005 No. 3.9 Industrial Park, two West Road, Anqing Development Zone, Anhui, 6-03 Patentee before: Anhui Tailong Investement Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Tin case aerosol type cleaning agent Effective date of registration: 20171226 Granted publication date: 20130417 Pledgee: Merchants Bank Anqing branch of Limited by Share Ltd birthday celebration Pledgor: ANHUI TAILONG CHENGYA GROUP CO., LTD. Registration number: 2017340000466 |
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