Gas-liquid mixed phase gasification nozzle and using method
Technical field:
The present invention relates generally to structure and the using method of non-catalytic oxidation method gasification furnace with gas-liquid mixed phase gasification nozzle.
Background technology:
Because international oil price rises violently and develop the short supply that causes as the petroleum refining product deep process technology of synthetic ammonia feedstock, be faced with raw material sources anxiety, cost of material rise, the downslide of business economic benefit, the material composition predicament of off-design composition day by day as the large-scale synthetic ammonia installation that with light oil, heavy oil, residual oil is raw material, the fluctuation of device operation, energy consumption strengthen, operating cost increases thereby bring, and make Business survival, development face severe situation; On the other hand, along with the exploitation of domestic a large amount of natural gas resources, finished or carried out " oil changes gas " of device at the big-and-middle-sized synthesis ammonia plant that can utilize natural gas to implement the domestic petrochemical industry of raw material route transformation; And to some comprehensive large enterprises, how petroleum refining byproduct such as oil refinery dry gas, asphalt etc. fully rationally utilize, and rely on existing resource to carry out the transformation of raw material technical route, and the economic benefit that improves device has become problem demanding prompt solution.So Guan Jian problem is exactly gasification furnace and the gasification nozzle thereof as the synthetic ammonia installation nucleus equipment, is the patented technology and the complete system import of offshore company in the past.In service in production operation, because the gasification furnace working environment is comparatively abominable, be in the flame, burning phenomenon very easily takes place in the end of gasification nozzle, and the maintenance nozzle needs to send to abroad through the patent merchant, expends a large amount of financial resources and time.Because the gasification nozzle import price is higher, can not be equipped with spare part more, benefit and the safe operation that has had a strong impact on device changed in frequent nozzle scaling loss and blowing out.
Shell (Shell) and Texaco (Texaco) develop separately and drop into that the residual oil of industrialized non-catalytic partial oxidation method preparing synthetic gas and natural gas gasifying stove and gasification nozzle thereof is widely used in residual oil, light oil, natural gas is that raw material is produced in the device of synthetic ammonia.The industrial applications of the natural gas gasifying nozzle of Shell company is only under the vapor pressure of 3.5Mpa.At vapor pressure is not have industrialized unit under the 6.0Mpa.The industrial applications of the natural gas gasifying nozzle of Texaco company is not have industrialized unit under the 6.0Mpa at vapor pressure under the vapor pressure of 8.53Mpa.
Application number is 97235458.1, name is called the utility model patent of " five-way road load controllable type coal-water-slurry gasification nozzle ", a kind of new nozzle arrangements is disclosed, in order to make the anti-scaling loss of nozzle segment, thickeied the wall thickness of nozzle, make the inner chamber of runner that boss be arranged, gasification substance is hindered at the spout place, is unfavorable for the gasification of gasification substance.
Summary of the invention:
The objective of the invention is to avoid the deficiencies in the prior art part and a kind of gas-liquid mixed phase gasification nozzle and using method are provided.The measure of being taked is except improving structure of nozzle, adopt rational gasifying medium, oxygen material runner is provided with and different mass velocity and the hybrid modes of each runner material, farthest eliminate because the elevated temperature heat offset is big from the gasification furnace vault heat flow density that short-range missile causes, the influence strong to the vault radiation, thereby reduce the temperature of gasification furnace vault outer wall effectively, make to form best flow field and temperature field coupling in gasification nozzle and the gasification furnace, thereby guarantee gasification efficiency (effectively gas productive rate); Adopt the aqueous cold plate cast nozzle type of cooling and adopt high-temperature alloy material and thin-walled runner end construction, prolong the operation lifetime of gasification nozzle, satisfy the requirement of gasification furnace long period stable operation.
Purpose of the present invention can be by realizing by the following technical solutions: a kind of gas-liquid mixed phase gasification nozzle, the gasifying medium inlet tube (1) or the liquefaction medium inlet (11) that have ring flange are connected mutually with each inlet tube (1) or the corresponding multithread road jet pipe (2) of medium inlet (11) that liquefies, shower nozzle (3) is connected with jet pipe (2) or is one, described shower nozzle (3) is to wait wall thickness to be connected with jet pipe (2), and its transition is for seamlessly transitting; The inside and outside wall of shower nozzle is taper, and its wall thickness is trapezoidal with the even attenuate of straight line; The spout wall thickness of shower nozzle (3) end is 1~5mm, and its main feature is that the shower nozzle (3) of described gas-liquid mixed phase gasification nozzle, the water-cooled coil pipe (4) that is provided with on the outer wall of nozzle-end adopt the high-temperature alloy material.
The high-temperature alloy material that adopts is INCONEL 600, HAYNES alloy, UMCo-50, HASTELLOY, C-276 or Stellite 6 materials.
The runner inner wall of the three described shower nozzle of runner gas-liquid mixed phase gasification nozzle (3) ends and the angle of center line are α
x, the 1st runner (21) angle α
0Be 0 °~5 °, the 2nd runner (22) angle α
1Be 10 °~18 °, the 3rd runner (23) angle α
2It is 15 °~25 °.The runner inner wall of the five described shower nozzle of runner gas-liquid mixed phase gasification nozzle (3) ends and the angle of center line are α
x, also include the 1st runner (21) angle α
0Be 0 °~2 °, the 2nd runner (22) angle α
1Be 1 °~5 °, the 3rd runner (23) angle α
2Be 5 °~8 °, the 4th runner (24) angle α
3Be 15 °~18 °, the 5th runner (25) angle α
4It is 20 °~25 °.
The angle of three runner gas-liquid mixed phase gasification nozzle shower nozzle end runner outer walls and shower nozzle (3) end face is β
x, the 1st runner (21) angle β
0Be 90 °~85 °, the 2nd runner (22) angle β
1Be 85 °~70 °, the 3rd runner (23) angle β
2It is 80 °~65 °.The angle of five runner gas-liquid mixed phase gasification nozzle shower nozzle end runner outer walls and shower nozzle (3) end face is β
x, the 1st runner (21) angle β
0Be 90 °~85 °, the 2nd runner (22) angle β
1Be 85 °~80 °, the 3rd runner (23) angle β
2Be 80 °~75 °, the 4th runner (24) angle β
3Be 75 °~70 °, the 5th runner (25) angle β
4It is 60 °~40 °.
Each jet pipe medium import annulus area of described gas-liquid mixed phase gasification nozzle three runners is that the 1st runner (21) is 10.6~9.2 with the annulus area ratio of medium ejiction opening: 1, the 2 runner (22) is 6.7~4.3: 1, the 3 runner (23) is 4.9~2.5: 1.
Each jet pipe medium import annulus area of described gas-liquid mixed phase gasification nozzle five runners is 3.9~1.5: 1 with the annulus area of medium ejiction opening than also including the 1st runner (21), the 2nd runner (22) is 8.2~5.8: 1, the 3rd runner (23) is 13~10.6: 1, the 4th runner (24) is 9.8~7.4: 1, the 5 runner (25) is 13.2~10.8: 1.
The jet pipe of the first flow of nozzle of the present invention (21) is connected by support ring (5) and adjacent jet pipe wall or is that the air-flow guide pad (6) that blind hole and adjacent jet pipe wall are connected is connected; The passage (7) that air-flow guide pad (6) is provided with can be communicated with non-conterminous runner.
Described gas-liquid mixed phase gasification nozzle is provided with water-cooled coil pipe (4) on the outer wall of nozzle-end, water-cooled coil pipe (4) is 2~5 layers, and every layer is made as 2~10 circles, is provided with 2~5 water inlets and delivery port.The present invention is by adopting the aqueous cold plate cast nozzle type of cooling and adopting high-temperature alloy material and thin-walled runner end construction, guaranteed the elevated temperature strength of gasification nozzle, and the local return peroxide that effectively reduces the runner end is ablated, prolonged the operation lifetime of gasification nozzle greatly, gasification furnace has satisfied the requirement of long period stable operation.
Multithread of the present invention road jet pipe is two runners~six runner jet pipes.
The using method of gas-liquid mixed phase gasification nozzle of the present invention is that the medium of three runners the 1st runners (21) is the gas phase gasifying medium, and the medium of the 2nd runner (22) is an oxygen, and the medium of the 3rd runner (23) is the liquid-phase vaporization medium.The medium of four runner gas-liquid mixed phase gasification nozzle the 1st runners (21) is the gas phase gasifying medium, and the medium of the 2nd runner (22) is an oxygen, and the medium of the 3rd runner (23) is the liquid-phase vaporization medium, and the medium of the 4th runner (24) is oxygen (on a small quantity).Medium at three runners or four runner gas-liquid mixed phase gasification nozzle outermost runners is a protection steam, becomes four runners or five runner gas-liquid mixed phase gasification nozzles.
The invention has the beneficial effects as follows, elevated temperature heat offset in the gasification furnace shortens from short and flame, almost do not have the black area and cause that gasification furnace vault heat flow density strengthens, the vault radiation is strengthened, gasification furnace vault metal outer wall temperature does not only raise, descend 10~15 ℃ on the contrary, guaranteed the normal running of gasification furnace.The reasonable Arrangement of gasification nozzle and gasification furnace vault and fire door structure has obtained best flow field and temperature field coupling and has reached best gasification result, guarantees that the available gas composition greater than 95.5%, reaches as high as 96.3%.Prolonged the operation lifetime of gasification nozzle, solve since the damage of gasification nozzle to cause that gasification furnace fire door brick damages the fire door brick that causes short service life, frequent parking problem satisfies the long period of gasification installation, the oepration at full load requirement, the economic benefit of raising device.
Description of drawings:
Fig. 1 is the front view of the embodiment of the invention 1 three runners;
Fig. 2 is the embodiment of the invention 1 three runner nozzle-end enlarged drawings;
Fig. 3 is the front view of the embodiment of the invention 2 five runners;
Fig. 4 is the embodiment of the invention 2 five runner nozzle-end enlarged drawings.
The specific embodiment:
Be described in further detail below in conjunction with the most preferred embodiment shown in the accompanying drawing:
Below by embodiment the present invention is described in further detail, but the present invention is not limited to embodiment:
See Fig. 1, Fig. 2, the embodiment of the invention 1 gas-liquid mixed is three runner gasification nozzles mutually, have the gasifying medium inlet tube 1 or liquefaction medium inlet 11 and the inlet tube 1 of ring flange or the medium inlet 11 corresponding multithread road jet pipes 2 that liquefy are connected mutually, shower nozzle 3 is an one with jet pipe 2, shower nozzle 3 is connected for waiting wall thickness with jet pipe 2, and its transition is for seamlessly transitting; The inside and outside wall of shower nozzle is taper, and its wall thickness is trapezoidal with the even attenuate of straight line; The spout wall thickness of shower nozzle 3 ends is 1~5mm.It is INCONEL 600 that shower nozzle 3 adopts the high-temperature alloy material.It is HASTELLOY that the water-cooled coil pipe 4 that is provided with on the outer wall of nozzle-end adopts the high-temperature alloy material.The runner inner wall of three runner gas-liquid mixed phase gasification nozzle shower nozzles, 3 ends and the angle of center line are α
x, the 1st runner 21 angle α
0Be 0 °~5 °, the 2nd runner 22 angle α
1Be 10 °~18 °, the 3rd runner 23 angle α
2It is 15 °~25 °.The angle of its shower nozzle end runner outer wall and shower nozzle 3 end faces is β
x, the 1st runner 21 angle β
0Be 90 °~85 °, the 2nd runner 22 angle β
1Be 85 °~70 °, the 3rd runner 23 angle β
2It is 80 °~65 °.Each jet pipe medium import annulus area is that the 1st runner 21 is 10.6~9.2 with the annulus area ratio of medium ejiction opening: 1, the 2 runner 22 is 6.7~4.3: 1, the 3 runner 23 is 4.9~2.5: 1.The jet pipe of the first flow 21 of nozzle is that the air-flow guide pad 6 that blind hole and adjacent jet pipe wall are connected is connected; The passage 7 that air-flow guide pad 6 is provided with can be communicated with non-conterminous runner.
Described gas-liquid mixed phase gasification nozzle is provided with water-cooled coil pipe 4 on the outer wall of nozzle-end, water-cooled coil pipe 4 is 2~5 layers, and every layer is made as 10 circles, is provided with 2 water inlets and 2 delivery ports.
The using method of gas-liquid mixed phase gasification nozzle, the medium that is the 1st runner is the gas phase gasifying medium, and the medium of the 2nd runner is an oxygen, and the medium of the 3rd runner is the liquid-phase vaporization medium.
See Fig. 3, Fig. 4, gas-liquid mixed phase gasification nozzle is five runner aqueous cold plate casts, and outermost layer has the steam protection runner, and no fire pot covers, and is complementary with the transformation of gasification furnace vault fire door, has to imitate gas componant height and the long common advantage of operation lifetime.Except for the following differences, all the other structures and above-mentioned Fig. 1,2 identical.The runner inner wall of five runner gas-liquid mixed phase gasification nozzle shower nozzles, 3 ends and the angle of center line are α
x, the 1st runner 21 angle α
0Be 0 °~2 °, the 2nd runner 22 angle α
1Be 1 °~5 °, the 3rd runner 23 angle α
2Be 5 °~8 °, the 4th runner 24 angle α
3Be 15 °~18 °, the 5th runner 25 angle α
4It is 20 °~25 °.The angle of shower nozzle 3 end runner outer walls and shower nozzle 3 end faces is β
x, the 1st runner 21 angle β
0Be 90 °~85 °, the 2nd runner 22 angle β
1Be 85 °~80 °, the 3rd runner 23 angle β
2Be 80 °~75 °, the 4th runner 24 angle β
3Be 75 °~70 °, the 5th runner 25 angle β
4It is 60 °~40 °.Each jet pipe medium import annulus area is that the 1st runner 21 is 3.9~1.5: 1 with the annulus area ratio of medium ejiction opening, the 2nd runner 22 is 8.2~5.8: 1, the 3rd runner 23 is 13~10.6: 1, the 4 runner 24 is 9.8~7.4: 1, the 5 runner 25 is 13.2~10.8: 1.The jet pipe of the first flow 21 of nozzle is connected by support ring 5 and adjacent jet pipe wall, and there is the air-flow guide pad 6 that is connected with adjacent jet pipe wall the end of nozzle; The passage 7 that air-flow guide pad 6 is provided with can be communicated with non-conterminous two, four runners.
The hybrid mode that each runner material is different, the hybrid mode of oxygen and natural gas is cut impacting type for flat (tiltedly), be that vertical (90 °) straight snips of center small amounts of natural gas and oxygen enters, a large amount of natural gases are tiltedly cut the bump incision with 78.5 ° of angles (is 0 ° with nozzle spout plane).Protection steam enters with 16.6 °/21.2 ° angles; Taked the mass velocity that each runner material is different and be complementary, promptly the mass velocity of center small amounts of natural gas is 25.6m/s; Oxygen is 31.5m/s with the mass velocity difference of a large amount of natural gases; The protection steam flow rate is 21.8m/s.Like this, effectively solve gasification furnace vault overtemperature problem, guaranteed acquisition higher effective gas componant, also make gasification nozzle and gasification furnace rationally mate and in gasification furnace, form the flow field and the temperature field of the best simultaneously.By gasification nozzle top flange mouth, can install and dismantle the nozzle that goes into operation easily, guarantee that gasification nozzle installs the go into operation normal running of nozzle of the normal intensification of the nozzle that goes into operation and dismounting; By spacer flanger, can open nozzle easily and overhaul or change nozzle spout end; Even lower cooling water pressure has guaranteed to take place cooling water cavity or coil pipe damages and be unlikely to make water to leak into gasification furnace interior (operating pressure 6.0Mpa in the stove) and damage corundum brick refractory liner, prolonged the service life of refractory liner.
Comparative Examples is an aqueous cold plate cast gasification nozzle.The maximum difference of this nozzle and embodiment is that this gasification nozzle general structure is two runner settings, and the unprotect steam flow channel is provided with.It comes with some shortcomings technically: the firstth, and the available gas composition of this nozzle is lower, is between 91%~93%, and the consumption of raw materials of gasification furnace is higher; The secondth, in order to reduce the gasification furnace dome temperature, taked the method for thickening gasification furnace vault insulated lining thickness, but behind the thickening vault insulated lining thickness, in order to keep the stability of vault, straight tube place tangent line moves down, and vault weight is increased, and investment increases; The 3rd to be that the waterway cross section structure of such nozzle is shaped as square, although convenient processing and manufacture is stressed not good, thermal stress is higher, its weld seam takes place easily damage cracking, the operation lifetime that influences nozzle is short, thereby has influenced the long period oepration at full load of gasification furnace.
The major technique of Comparative Examples and embodiment is compared as follows:
The technology item compared |
Comparative Examples |
Embodiment |
Material runner quantity |
2 runners |
4 runners |
The material runner is provided with (therefrom mind-set is outer) |
Oxygen-natural gas |
Natural gas-oxygen-natural gas-protection steam |
The mixing of materials mode |
Impacting type |
Flat (tiltedly) cuts impacting type |
Spout end cooling water cavity cross sectional shape |
Rectangle (square) |
Semi-circular |
Spout protection steam |
Do not have |
Have |
Available gas composition (CO+H2) |
Hang down 91%~93% |
Higher 〉=95.5% |
Hermetically-sealed construction between natural gas tube and the oxygen hose |
Welding |
The sliding sealing structure |
Coupling gasification furnace vault refractory heat-insulating liner thickness |
Thicker |
Thinner |
Operation lifetime |
Can reach 3 months |
Longer |
The long-term economic benefit |
Relatively poor |
Better |