CN1317372C - Nanometer fuel oil addition agent - Google Patents
Nanometer fuel oil addition agent Download PDFInfo
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- CN1317372C CN1317372C CNB2005100292890A CN200510029289A CN1317372C CN 1317372 C CN1317372 C CN 1317372C CN B2005100292890 A CNB2005100292890 A CN B2005100292890A CN 200510029289 A CN200510029289 A CN 200510029289A CN 1317372 C CN1317372 C CN 1317372C
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Abstract
The present invention relates to a nanometer fuel oil additive which belongs to the technical field of chemical and industrial fuel oil. The fuel oil additive comprises the following components by weight percentage: 0.1 to 10% of rare earth powder, 1 to 10% of fuel oil synergistic agent, 1 to 20% of dispersing agent, 1 to 10% of oleic acid, 1 to 20% of castor oil and white oil as the rest. In the present invention, the nanometer particles in fuel oil have catalysis and combustion supporting function on combustion in a combustion process, the combusted particles have the functions of equipment attrition inhibition, lubrication improvement, self repair, three-way catalyst poisoning inhibition and catalysis cooperated with noble metals, such as platinum, rhodium, palladium, etc. The fuel oil additive is characterized in that the problem that the nanometer particles have no dispersibility in the fuel oil is solved, and proper lubrification performance of fuel is enhanced.
Description
Technical field
What the present invention relates to is a kind of additive of chemical industry fuel oil technical field, particularly a kind of nano fuel additive agent.
Background technology
In recent years, micron or nano material are used as additive and are used for fuel oil, wherein micron or nano material have employing nickel, steel, iron nano metal powder, contain the carbon alcohol material of Si nano material, 0.2-1.5 micron level etc., improved the efficiency of combustion of fuel, improved emission behavior, but the oilness of its dispersion effect and fuel oil is not improved, and nanoparticle is also unsatisfactory to the lubrication of equipment in the fuel oil.
Find through literature search prior art, Chinese patent application number: 02826782, denomination of invention: cerium oxide nanoparticles, this patent disclosure a kind of fuel or fuel dope that comprises cerium oxide particle, described cerium oxide has been a rare earth metal by divalence or trivalent metal or metalloid, the IIA of transition metal or periodictable, IIIB, VB, or group vib is metal-doped.Though adopted the oxide form of rare earth material cerium in this patent, but do not had thoroughly to solve the dispersiveness of nanoparticle in fuel oil and the unfavorable problem of lubricity of fuel itself.Further in the retrieval, do not find the report that is applied in fuel oil additive of the compound nano particle of other element of group of the lanthanides so far as yet.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of nano fuel additive agent is provided, make that nanoparticle plays the catalytic combustion-supporting function to burning in its fuel oil in combustion processes, particle after its burning has the suppression equipment wearing and tearing, improves the function of lubricated and selfreparing, has and suppresses the function that ternary catalyzing unit is poisoned and worked in coordination with precious metal catalysts such as platinum rhodium palladium.Be characterized in thoroughly solving the dispersiveness of nanoparticle in fuel oil, increased the lubricity of fuel itself.
The present invention is achieved by the following technical solutions, and components of additives of the present invention comprises and weight percent is: rare earth powder 0.1-10%, synergist for fuel oil 1-10%, dispersion agent 1-20%, oleic acid 1-10%, Viscotrol C 1-20%, surplus: white oil.
Described rare earth powder is meant one or more in the lanthanide element of granularity between the 50-150 nanometer.
Described dispersion agent is selected one or more in calcium sulfenyl phenolate, alkyl sodium salicylate, high-alkali calcium mahogany sulfonate, the polyisobutene succinimide for use.
The JM-1 type synergist for fuel oil that described synergist for fuel oil selects for use Shanghai energy collecting chemical industry company limited to produce.Its component is the metal oil dissolubility rare earth compound of about 5% calcium and cerium and the mixture that 95% white oil is formed.Calcium is different owing to its molecule two ends polarity with the metal oil dissolubility rare earth compound of cerium, therefore, booster action is played in dispersion in fuel oil to the rare earth nano powder, in addition, under the synergy of JM-1 type synergist for fuel oil, sodium, vanadium and rare earth nano powder in the burning after product easily form the rare earth sodium vanadium compound of fusing point higher (greater than the fusing point of sodium vanadium compound), thereby play the effect that reduces parts surface incrustation.
Fuel oil in the described nano fuel additive agent can be gasoline, diesel oil, heavy oil, residual oil and ethanol petrol.
Additive of the present invention is brown thick liquid, can dissolve each other with gasoline, diesel oil, heavy oil, residual oil and ethanol petrol.Adding proportion in fuel oil is 1 according to fuel oil type difference: 500-1: between 2000.
Preparation method of the present invention is: 1) white oil is poured in the heating container, heating is also poured dispersion agent and JM-1 type synergist for fuel oil in the white oil into, stirs until evenly by the toothed gear pump circulation; 2) stop heating, the rare earth powder is evenly poured in the white oil, powder is carried out the oil bath thinning processing by the engagement of pump; 3) add oleic acid, Viscotrol C, reheat, continue powder to be carried out the oil bath thinning processing by the engagement of pump; 4) stop heating, 2000RPM centrifugal treating 1 hour, the precipitation that removes slag is qualified finished product between the granularity Detection 50-150 nanometer.
Lanthanide rare and JM-1 type synergist for fuel oil have the suppression equipment wearing and tearing in the additive of the present invention, improvement is lubricated and the function of selfreparing, have and suppress the function that ternary catalyzing unit is poisoned and worked in coordination with precious metal catalysts such as platinum rhodium palladium.The nanoparticle that contains rare earth element after combustion processes finishes can be used as between solid lubricant existence and the friction means, reduce the friction and wear between the parts, because its particle diameter is little, be present in easily between parts surface microcosmic ditch hole or the crackle simultaneously, play dynamic self-repair function.Rare earth element has the ability that generates high melting compound with compound reactions such as containing vanadium, phosphorus, sodium, calcium in combustion processes, therefore, can not produce incrustation at the component surface of equipment exhaust system, significantly reduced the phenomenon that precious metal catalysts such as platinum rhodium palladium are poisoned, the nanoparticle that contains simultaneously rare earth element is on a small quantity handled waste gas with noble metal catalysts such as can assisting platinum rhodium palladium in the waste gas discharge process, plays synergistic function.Oleic acid and Viscotrol C can significantly improve the lubricated and abrasion resistance of fuel oil in the additive of the present invention under the effect of dispersion agent.
Embodiment
Provide following examples in conjunction with content of the present invention:
Example 1
Prescription: lanthanum 5, neodymium 5 grams of size-grade distribution between the 50-150 nanometer, JM-1 synergist for fuel oil 100 grams, high-alkali calcium mahogany sulfonate 100 grams, oleic acid 100 grams, Viscotrol C 100 grams are from oil 9590 grams.Its preparation method is: 1) 9590 gram white oils are poured in the heating container, heating is also poured 100 high-alkali calcium mahogany sulfonates of gram and 100 gram .JM-1 synergist for fuel oil in the white oil into, stirs until evenly by the toothed gear pump circulation; 2) stop heating, 5 gram lanthanums, 5 gram neodymium mixed powders are evenly poured in the white oil, powder is carried out the oil bath thinning processing by the engagement of pump; 3) add 100 gram oleic acid, 100 gram Viscotrol C, reheat, continue powder to be carried out the oil bath thinning processing by the engagement of pump; 4) stop heating, 2000RPM centrifugal treating 1 hour, the precipitation that removes slag is qualified finished product between the granularity Detection 50-150 nanometer.
Example 2
Prescription: lanthanum 400 grams, neodymium 600 grams of size-grade distribution between the 50-150 nanometer, JM-1 synergist for fuel oil 1000 grams, calcium sulfenyl phenolate 2000 grams, oleic acid 1000 grams, Viscotrol C 2000 grams, white oil 3000 grams.Its preparation method is: 1) 3000 gram white oils are poured in the heating container, heating is also poured 2000 gram calcium sulfenyl phenolates and 1000 gram JM-1 synergist for fuel oil in the white oil into, stirs until evenly by the toothed gear pump circulation; 2) stop heating, 400 gram lanthanums, 600 gram neodymium mixed powders are evenly poured in the white oil, powder is carried out the oil bath thinning processing by the engagement of pump; 3) add 1000 gram oleic acid, 2000 gram Viscotrol C, reheat, continue powder to be carried out the oil bath thinning processing by the engagement of pump; 4) stop heating, 2000RPM centrifugal treating 1 hour, the precipitation that removes slag is qualified finished product between the granularity Detection 50-150 nanometer.
Example 3
Prescription: cerium 50 grams, neodymium 100 grams of size-grade distribution between the 50-150 nanometer, JM-1 synergist for fuel oil 500 grams, alkyl sodium salicylate 500 grams, oleic acid 500 grams, Viscotrol C 500 grams, white oil 7900 grams.Its preparation method is: 1) 7900 gram white oils are poured in the heating container, heating is also poured 500 gram alkyl sodium salicylates and 500 gram JM-1 synergist for fuel oil in the white oil into, stirs until evenly by the toothed gear pump circulation; 2) stop heating, 50 gram ceriums, 100 gram neodymium mixed powders are evenly poured in the white oil, powder is carried out the oil bath thinning processing by the engagement of pump; 3) add 500 gram oleic acid, 500 gram Viscotrol C, reheat, continue powder to be carried out the oil bath thinning processing by the engagement of pump; 4) stop heating, 2000RPM centrifugal treating 1 hour, the precipitation that removes slag is qualified finished product between the granularity Detection 50-150 nanometer.
Example 4
Prescription: lanthanum 100 grams, cerium 100 grams, praseodymium 100 grams, neodymium 200 grams of size-grade distribution between the 50-150 nanometer, JM-1 synergist for fuel oil 400 grams, polyisobutene succinimide 1500 grams, oleic acid 500 grams, Viscotrol C 1500 grams, white oil 5600 grams.Its preparation method is: 1) 5600 gram white oils are poured in the heating container, heating is also poured 1500 gram polyisobutene succinimides and 400 gram JM-1 synergist for fuel oil in the white oil into, stirs until evenly by the toothed gear pump circulation; 2) stop heating, 100 gram lanthanums, 100 gram ceriums, 100 gram praseodymiums, 200 gram neodymium mixed powders are evenly poured in the white oil, powder is carried out the oil bath thinning processing by the engagement of pump; 3) add 500 gram oleic acid, 1500 gram Viscotrol C, reheat, continue powder to be carried out the oil bath thinning processing by the engagement of pump; 4) stop heating, 2000RPM centrifugal treating 1 hour, the precipitation that removes slag is qualified finished product between the granularity Detection 50-150 nanometer.
The effect that embodiment is useful
(1) the dispersed evaluation
Example 1 ~ 4 prescription makes an addition in the 93# gasoline and 0# diesel oil of China Petrochemical Industry service station sale in 1 to 500,1 to 1000 and 1 to 2000 ratio respectively, carries out centrifugal treating by 1 hour 2000rpm rotating speed, and all appearance precipitates, and demonstrates good dispersing property.
Example 1 ~ 4 prescription makes an addition in the 93# gasoline and 0# diesel oil of China Petrochemical Industry service station sale in 1 to 500,1 to 1000 and 1 to 2000 ratio respectively, by 6 monthly precipitate and separate phenomenons that do not take place of room temperature placement.Illustrate that it has solved the scattering problem of nano material in fuel oil up hill and dale, shelf characteric is good.
(2) oilness evaluation
Example 1 ~ 4 prescription is made an addition in the petrochemical industry 0# diesel oil of Shanghai in 1 to 500,1 to 1000 and 1 to 2000 ratio respectively, carry out HFRR method (ISO12156-1) and test its grinding defect diameter WSD
1.4/ μ mAs shown in table 1.Its result shows that this patent has good lubricated improved action.As: the evaluation of table 1 oilness
| Sample | Oilness WSD 1.4/μm | ||
| 1∶500 | 1∶1000 | 1∶2000 | |
| Example 1+0# diesel oil | 380 | 280 | 320 |
| Example 2+0# diesel oil | 355 | 310 | 380 |
| Example 3+0# diesel oil | 250 | 280 | 280 |
| Example 4+0# diesel oil | 280 | 350 | 350 |
| 0# diesel oil | 580 | ||
Combustionproperty is estimated
Example 1 made an addition in the heavy oil by 1: 2000, carried out 72 hours contrast combustion experiments, and its result is as shown in table 2.The result shows this patent owing to have the catalyticcombustion function, and fuel combustion is abundant, and oil-saving effect is obvious.
72 hours blank contrast results of combustion tests of table 2 embodiment 3 Industrial Boilers
| Blank test | Add the agent test | |
| Oil tank liquid level starting altitude (m) | 4.25 | 4.23 |
| Oil tank liquid level (m) during off-test | 2.10 | 2.37 |
| Oil fuel reduces number (ton) | 38.24 | 33.38 |
| Quantity of steam (ton) takes place | 529.13 | 495.48 |
| The quantity of steam S that the unit residual oil combustion obtains | 13.84 | 14.84 |
| Funnel temperature (℃) | 344.4 | 333.1 |
| The rate of economizing gasoline of oil fuel | (13.84/13.84-1)*100％＝7.2％ | |
Claims (5)
1, a kind of nano fuel additive agent is characterized in that, component and weight percent are: rare earth powder 0.1-10%, synergist for fuel oil 1-10%, dispersion agent 1-20%, oleic acid 1-10%, Viscotrol C 1-20%, surplus: white oil; Described rare earth powder is meant one or more in the lanthanide element of granularity between the 50-150 nanometer; The JM-1 type synergist for fuel oil that described synergist for fuel oil selects for use Shanghai energy collecting chemical industry company limited to produce.
2, nano fuel additive agent according to claim 1 is characterized in that, described dispersion agent is selected in calcium sulfenyl phenolate, alkyl sodium salicylate, high-alkali calcium mahogany sulfonate, the polyisobutene imide one or several for use.
3, nano fuel additive agent according to claim 1 is characterized in that, is brown thick liquid, dissolves each other with fuel oil, and the adding proportion in fuel oil is 1: 500-1: between 2000.
4, nano fuel additive agent according to claim 3 is characterized in that, described fuel oil is gasoline, diesel oil, heavy oil, residual oil or ethanol petrol.
5, nano fuel additive agent according to claim 1 is characterized in that, described nano fuel additive agent, and its granularity is uniform distribution in the 50-150 nanometer range.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100292890A CN1317372C (en) | 2005-09-01 | 2005-09-01 | Nanometer fuel oil addition agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100292890A CN1317372C (en) | 2005-09-01 | 2005-09-01 | Nanometer fuel oil addition agent |
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| CN1737090A CN1737090A (en) | 2006-02-22 |
| CN1317372C true CN1317372C (en) | 2007-05-23 |
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| CNB2005100292890A Active CN1317372C (en) | 2005-09-01 | 2005-09-01 | Nanometer fuel oil addition agent |
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| CN101955807B (en) * | 2009-07-17 | 2013-12-18 | 东莞市智造生物科技有限公司 | Biomass nanometer gasoline liquid fuel |
| CN102071074B (en) * | 2010-11-25 | 2013-06-05 | 鹤壁宝发能源科技股份有限公司 | Nano rare earth additive, preparation method of nano rare earth additive and application of nano rare earth additive in gas fuel |
| CN102504886A (en) * | 2011-11-02 | 2012-06-20 | 杨戈坪 | Low-carbon methanol diesel oil and preparation method thereof |
| CN102703140B (en) * | 2012-05-18 | 2014-08-20 | 上海保能环保节能材料科技有限公司 | Fuel oil storage stabilizer with good compatibility and preparation method thereof |
| CN103320183B (en) * | 2013-07-05 | 2015-12-09 | 西北民族大学 | Bio-based methanol gasoline detergent-dispersant additive and preparation method thereof |
| CN103387857B (en) * | 2013-08-16 | 2015-07-15 | 重庆车伴侣科技有限公司 | Nanometer fuel oil catalytic additive |
| CN103952194B (en) * | 2014-04-29 | 2016-05-11 | 成都天丰清洁能源发展有限公司 | As the automobile-used dimethoxymethane composition of mixing fuel burning |
| CN103952191B (en) * | 2014-04-29 | 2017-01-18 | 成都天丰清洁能源发展有限公司 | Dimethoxymethane gasoline based on national standard gasoline component |
| CN103952190B (en) * | 2014-04-29 | 2016-03-16 | 成都天丰清洁能源发展有限公司 | A kind of Dimethoxymethane gasoline based on multiple non-GB gasoline component |
| CN105505490B (en) * | 2015-12-08 | 2017-03-15 | 谢传林 | Oxidoreduction pressor |
| CN105462637A (en) * | 2016-01-06 | 2016-04-06 | 山东泰德新能源有限公司 | Efficient ethanol gasoline cleanser |
| CN107641531A (en) * | 2017-11-07 | 2018-01-30 | 廖卫星 | A kind of biological nano environment-friendly and high-energy fires liquid |
| CN108130145A (en) * | 2017-12-23 | 2018-06-08 | 洛阳名力科技开发有限公司 | A kind of fuel oil additive |
| CN110205171A (en) * | 2019-06-10 | 2019-09-06 | 罗振林 | A kind of fuel oil additive of energy-saving and emission-reduction |
| CN112480989B (en) * | 2020-12-08 | 2023-03-17 | 佛山市豪纳科技有限公司 | Efficient energy-saving environment-friendly diesel catalytic combustion agent, and preparation method and application thereof |
| CN112625750B (en) * | 2020-12-17 | 2022-12-27 | 上海集能化工有限公司 | Nano rare earth composite polymerization inhibitor, preparation method and application thereof |
| CN115029166A (en) * | 2021-03-04 | 2022-09-09 | 吴勇 | Efficient energy-saving environment-friendly combustion improver |
| CN115717089A (en) * | 2022-11-14 | 2023-02-28 | 上海锱碳节能环保技术有限公司 | Method and system for improving fuel energy efficiency and fuel thereof |
| CN115895757A (en) * | 2022-12-09 | 2023-04-04 | 上海集能化工有限公司 | Microporous composite additive |
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| US4372862A (en) * | 1980-10-10 | 1983-02-08 | Exxon Research & Engineering Co. | Oil-soluble metal containing sulfonated polymers useful as oil additives |
| CN1320682A (en) * | 2001-04-16 | 2001-11-07 | 徐清华 | Oil additive |
| CN1363648A (en) * | 2002-02-04 | 2002-08-14 | 中国科学院兰州化学物理研究所 | Machine oil additive with friction-reducing and repairing function |
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2005
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4372862A (en) * | 1980-10-10 | 1983-02-08 | Exxon Research & Engineering Co. | Oil-soluble metal containing sulfonated polymers useful as oil additives |
| CN1320682A (en) * | 2001-04-16 | 2001-11-07 | 徐清华 | Oil additive |
| CN1363648A (en) * | 2002-02-04 | 2002-08-14 | 中国科学院兰州化学物理研究所 | Machine oil additive with friction-reducing and repairing function |
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| CN1737090A (en) | 2006-02-22 |
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Owner name: SHANGHAI JINENG CHEMICAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI NATIONAL ENGINEERING RESEARCH CENTER FOR NANOTECHNOLOGY CO., LTD. Effective date: 20080118 |
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Effective date of registration: 20080118 Address after: Shanghai City, Jinshan District Jinyi road 2308 room Patentee after: Shanghai energy gathering Chemical Co., Ltd. Address before: Shanghai City Jia Chuan Road No. 245, building 3, room 706 Patentee before: Shanghai National Engineering Research Center for Nanotechnology Co., Ltd. |