CN1315974C - Complex with self heat accumulation function, its preparation and use thereof - Google Patents
Complex with self heat accumulation function, its preparation and use thereof Download PDFInfo
- Publication number
- CN1315974C CN1315974C CNB2004101015941A CN200410101594A CN1315974C CN 1315974 C CN1315974 C CN 1315974C CN B2004101015941 A CNB2004101015941 A CN B2004101015941A CN 200410101594 A CN200410101594 A CN 200410101594A CN 1315974 C CN1315974 C CN 1315974C
- Authority
- CN
- China
- Prior art keywords
- heat accumulation
- self heat
- complex
- powder
- tourmalinite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention belongs to the field of pulverulent products, which relates to a complex material with self heat accumulation functions. The complex material with self heat accumulation functions is composed of the following components of the following portion by weight (weight %): 25 to 50 % of tourmalinite submicron powders, 40 to 65% of thermogen powders, 2 to 5 % bonding agents and 1 to 5 % of embedding agents, wherein the tourmalinite submicron powders are formed by that tourmalinite raw ores are processed by a submicron technology which is that the tourmalinite raw ores are crushed, milled and heated. The heat process is carried out after the tourmalinite raw ores are milled for 36 to 70 hours after the tourmalinite raw ores are crushed; temperatures for the heat process are 300 to 900 DEG C, and the time for keeping the temperatures is one to three hours. The manufacturing method of the complex material with self heat accumulation functions comprises the following steps: preparing raw materials, mixing the materials and shaping by pressing. The pressure of shaping by pressing is 12 to 30MPa, and the complex material with self heat accumulation functions is formed after the materials are shaped by pressing. The complex powders with self heat accumulation functions prepared by the present invention are suitable for the fields of anion generating materials, coating paints, bacteriostasis and deodorization; the complex material with self heat accumulation functions is suitable for health care products for human bodies.
Description
Technical field
The invention belongs to powder product field, relate to the self heat accumulation function matrix material.
Background technology
The functional performance of self heat accumulation function matrix material is exactly can self to release energy under certain condition, excites the negative ion that improves the tourmalinite ultrasome to produce ability, thereby has multiple functional health effect.
In recent years, negative ion and generating material thereof are subjected to numerous scientific research institutions, experts and scholars and entrepreneur's great attention to Air quality, healthy influence.What of negative aeroion have become standard whether with fresh air, The World Health Organization's regulation, and the normal concentration of fresh air negative ion is to be lower than 1000 to 1500 in every cc of air.The biological significance of negative ion is approved by vast medical circle at present, negative ion promotes the blood circulation of human body micro-system, activating human body cells, raising immunity except having, reconciles the functional healths such as acid base metabolism balance of human body, also have bacteriostasis, and deodorization, dedusting, purify air and optimize the environment, improve the effect of water quality.Yet along with modern production, in city that population is relatively concentrated, indoor negative aeroion content such as office, meeting room, shopping center, hospital is seldom (generally at 100/cm
3Below), it is very muddy that air seems, and sickness rate obviously improves.Along with the raising of people's living standard and the development of modern medicine, people wish that urgently the surrounding enviroment of oneself surviving become pure and fresh as the Nature, that is to say the negative ion concentration that will improve living environment, improve self health.
The anion generator of Chu Xianing mainly is the effect that utilizes electrion in the market, when producing negative ion, supervenes objectionable impuritiess such as ozone and oxynitrides, thereby does not meet the aim of environmental protection.And natural mineral tourmaline has piezoelectricity and pyroelectricity, can make outside the characteristic of ambient air negative ionization and water molecules moment negative ionization, also has emitting far-infrared characteristic, natural is considered to a kind of natural anion generator.But under normal condition, the anion-generating capacity of tourmalinite ultrafine powder material is very little, can not satisfy the needs of human habitat far away.
Chinese patent ZL02123892.8 has announced and a kind ofly can efficiently produce composition tourmaline powder body of negative aeroion and preparation method thereof.Narrated in order to improve the tourmaline anion generating capacity and added rare earth, photocatalyst material etc., added rare earth from it, prepared composite granule exists bigger potential safety hazard, moreover can only improve the generating capacity of negative ion, does not have the effect from accumulation of heat.The patent that has is to have added argent, but its purpose is not improve the tourmaline anion material functional.Utilize thermal excitation, improve the negative ion luminous efficiency, it is also rare at home that development has from the functional composite material of accumulation of heat.
Summary of the invention
At defective on the prior art and tourmaline anion properties of materials, the object of the present invention is to provide a kind of may command heat production speed and complex with self heat accumulation function and manufacture method and application that heat production efficient is high.
At above-mentioned purpose, the technical scheme of complex with self heat accumulation function of the present invention and manufacture method thereof and application is as follows:
(1) composition of complex with self heat accumulation function of the present invention (weight %) is: tourmalinite super-fine powder 25～50%, phlogiston powder 40～65%, binding agent 2～5%, embedding medium 1～5%.
The particle diameter of tourmalinite super-fine powder＜5 micron wherein, 10～600 microns of the particle diameters of phlogiston powder.
The tourmalinite super-fine powder is that the tourmalinite raw ore is handled and got through ultramicronising, the ultramicronising treatment process is thermal treatment again behind the pulverizing of tourmalinite raw ore process, the ball milling, the tourmalinite raw ore is pulverized the back ball milling, the ball milling time is 36～70 hours, with postheat treatment, thermal treatment temp is 300～900 ℃, and soaking time is 1～3 hour.
Above-mentioned phlogiston powder is any or any two above sum in magnesium powder, iron powder, aluminium powder, the calcium oxide.
Binding agent is any or any two above sum in oleum lini, Viscotrol C, polyvinyl chloride, stearic acid, the rosin.
Embedding medium is any or any two above sum in paraffin oil, rosin, methylcellulose gum, the polyvinyl chloride.
(2). the processing step of the manufacture method of complex with self heat accumulation function of the present invention is as follows:
A. raw material is equipped with
Press the composition proportioning of complex with self heat accumulation function, promptly tourmalinite super-fine powder 25～50%, phlogiston powder 40～65%, binding agent 2～5%, embedding medium 1～5% are prepared burden.
B. batch mixing
The raw material that above-mentioned outfit is good adds in the mixer in the lump, and after mixing, promptly becomes the self heat accumulation function composite granule.
C. compression moulding
The powder raw material that mixes is placed mould with definite shape
, being placed on the pressing machine it is exerted pressure, pressure is 12～30Mpa, promptly becomes complex with self heat accumulation function after the compression moulding.
The mould of compression moulding has various shape and specification, and promptly made complex with self heat accumulation function has various shape and specification.
Above-mentioned complex with self heat accumulation function comprises self heat accumulation function composite granule and complex with self heat accumulation function.
(3). what the present invention was prepared is applicable to anion-generating material, paint of coating, bacteriostasis, and deodorization field from the accumulation of heat composite granule; Then be applicable to the body-care goods from the accumulation of heat complex body.
The complex with self heat accumulation function intensity height of making through aforesaid method, heat production efficient is controlled, lastingly, negative ion incidence height, and it is safe and reliable, without any side effects, pollution-free, complex body is without any need for external energy, in certain humidity or just can spontaneously produce heat after for some time next to the shin, utilize oneself energy of holding of phlogiston powder, excite the tourmaline anion powder, improve its negative ion incidence, has the alleviation arthralgia, environment purification, emitting far-infrared, activating human body cells, bacteriostasis, and deodorization, regulate little the following of human body system, regulate multiple efficacies such as human body acid base metabolism balance, be particularly suitable for the health body health care of human body, aspects such as environmental improvement.
Tourmalinite is nontoxic, the safe natural mineral of a kind of cyclosilicate, contain multiple trace element to the human body beneficial, tourmalinite has piezoelectricity and pyroelectricity, under certain pressure and temperature and humidity, its polarization performance improves, and the negative ion luminous efficiency obviously strengthens.The tourmalinite super-fine powder is that the self heat accumulation function composite granule reaches the main body that produces negative ion from the accumulation of heat complex body, provides human body and the useful negative ion of environment.Same thermal treatment also is based on the purpose of the polarization performance that strengthens the tourmaline anion powder.Tourmaline powder can improve its specific surface area after handling through ultramicronising, strengthens the polarization characteristic of tourmalinite, and the present invention requires the diameter of particle of ultramicronising must not surpass 5 microns, if particle diameter can be less than 1 micron then better effects if.
The present invention is exactly the characteristic according to the tourmalinite ultrafine powder, mutually compound the tourmalinite ultrafine powder with the phlogiston powder, utilize the phlogiston powder come the thermal excitation tourmalinite from the energy that holds, the main effect of phlogiston powder provides energy, by the control content of phlogiston powder in the self heat accumulation function composite granule, just can regulate work-ing life of self heat accumulation function composite granule and complex with self heat accumulation function and heat production efficient etc.
Self heat accumulation function composite granule that the present invention is prepared and complex with self heat accumulation function have excellent performance, and negative ion produces number can reach 3000/centimetre
3Air.
Compared with prior art, the present invention has following advantage:
1. produce the anion number height, can reach 3000/centimetre
3Air.
2. safe and reliable, without any side effects, pollution-free.
3. without any need for external energy, and Energy Controllable, long service life.
4. have negative ion, alleviate multiple functions such as arthralgia, far infrared, bacteriostasis, and deodorization.
Embodiment
Prepare 3 batches of self heat accumulation function composite granules and 3 batches of complex with self heat accumulation function according to complex with self heat accumulation function of the present invention and manufacture method thereof, and carried out practical application respectively.
Embodiment 1
The composition of the complex with self heat accumulation function of being prepared (weight %) is: tourmalinite super-fine powder 36%, phlogiston powder 60% (wherein magnesium powder 10%, iron powder 20%, aluminium powder 30%), binding agent 1.5% (wherein stearic acid 0.5%, oleum lini 1.0.%), embedding medium 2.5% (wherein Valelinum Liquidum 1.5%, rosin 1.0%); Wherein the particle diameter of tourmalinite super-fine powder is 3.5 microns, and the particle diameter of phlogiston powder is 95 microns.
In the above-mentioned batching, the tourmalinite super-fine powder is that the tourmalinite raw ore is handled and got through ultramicronising, and promptly the tourmalinite raw ore carries out ball milling after crushed, with postheat treatment.The ball milling time is 50 hours, and thermal treatment temp is 850 ℃, and soaking time is 1.5 hours.
Above-mentioned batching adds in the mixer, and after mixing, promptly becomes the self heat accumulation function composite granule.This powder is used for anion material, and the anion number that this anion generator is produced reaches 2600/every cc of air.Standard well beyond World Health Organization's defined.
Prepared self heat accumulation function composite granule is packed in the circular die, be pressed into the disk shape on pressing machine, promptly become the disk shape from the accumulation of heat complex body, wherein pressing force is 24Mpa.
The self-heating tablet that prepared sheet is used for body-care from the accumulation of heat complex body, self-heating tablet is without any need for external energy, in certain humidity or just can spontaneously produce heat after 10 minutes next to the shin, tangible warm sensation is arranged after next to the shin, has the alleviation arthralgia, activating human body cells is regulated little the following of human body system, is particularly suitable for the health body health care of human body.
Embodiment 2
The composition proportioning (weight %) of the complex with self heat accumulation function of being prepared is: tourmalinite super-fine powder 30%, phlogiston powder 65% (wherein calcium oxide 11.8%, iron powder 35.4%, aluminium powder 17.8%), binding agent 3.0% (wherein polyvinyl chloride 2.0%, rosin 1.0%), embedding medium 2.0% (wherein methylcellulose gum Asia 1.5%, rosin 0.5%), wherein the particle diameter of tourmalinite super-fine powder is 2.1 microns, and the particle diameter of phlogiston powder is 530 microns.
In the above-mentioned batching, the tourmalinite super-fine powder is that the tourmalinite raw ore is handled and got through ultramicronising, and in the ultramicronising treating processes, the ball milling time is 38 hours, and thermal treatment temp is 600 ℃, and soaking time is 2 hours.
Above-mentioned batching adds in the mixer, and after mixing, promptly becomes the self heat accumulation function composite granule.
Prepared self heat accumulation function composite granule is packed in the circular die, be pressed into the disk shape on pressing machine, promptly become disk shape complex with self heat accumulation function, wherein pressing force is 16Mpa.
The self-heating tablet that prepared sheet complex with self heat accumulation function is used for body-care, self-heating tablet is without any need for external energy, be stained with a little moisture on the self-heating tablet surface, just can spontaneously produce heat after 15 minutes, can feel warm effect after next to the shin significantly.
Embodiment 3
The composition proportioning (weight %) of the complex with self heat accumulation function of being prepared is: tourmalinite super-fine powder 41%, phlogiston powder 52% (wherein calcium oxide powder 21.8%, magnesium powder 10%, iron powder 20.2%), binding agent (polyvinyl chloride) 3.0%, embedding medium 4.0% (wherein methylcellulose gum Asia 1.5%, paraffin oil 2.5%).Wherein the particle diameter of tourmalinite super-fine powder is 2.9 microns, and the particle diameter of phlogiston powder is 480 microns.
In the above-mentioned batching, the tourmalinite super-fine powder is that the tourmalinite raw ore is handled and got through ultramicronising, and in the ultramicronising treating processes, the ball milling time is 39 hours, and thermal treatment temp is 450 ℃, and soaking time is 2.8 hours.
Above-mentioned batching adds in the mixer, and after mixing, promptly becomes the self heat accumulation function composite granule.
Prepared self heat accumulation function composite granule packed into is pressed into the disk shape in the circular die on pressing machine, promptly become disk shape complex with self heat accumulation function, and wherein pressing force is 20Mpa.
The self-heating tablet that prepared sheet complex with self heat accumulation function is used for body-care, self-heating tablet is without any need for external energy, be stained with a little moisture on the self-heating tablet surface, just can spontaneously produce heat after 15 minutes, can feel warm effect after next to the shin significantly.
Claims (6)
1. a complex with self heat accumulation function is characterized in that its weight percent consists of: tourmalinite super-fine powder 25～50%, phlogiston powder 40～65%, binding agent 2～5%, embedding medium 1～5%;
The phlogiston powder is any or any two above sum in magnesium powder, iron powder, aluminium powder, the calcium oxide.
2. the preparation method of the described complex with self heat accumulation function of claim 1 is characterized in that its processing step is as follows:
(1) raw material is equipped with
Weight percent by the described complex with self heat accumulation function composition of claim 1: tourmalinite super-fine powder 25～50%, phlogiston powder 40～65%, binding agent 2～5%, embedding medium 1～5% are prepared burden;
Wherein the tourmalinite super-fine powder is the tourmalinite raw ore is handled gained through ultramicronising a super-fine powder;
(2) batch mixing
The raw material that above-mentioned outfit is good adds in the mixer in the lump, after mixing, promptly becomes the self heat accumulation function composite granule;
(3) compression moulding
The powder raw material that mixes is put into the mould that has definite shape on the pressing machine, and it is exerted pressure, pressure is 12～30Mpa, promptly becomes complex with self heat accumulation function after the compression moulding.
3. the application of the described complex with self heat accumulation function of claim 1 is characterized in that complex with self heat accumulation function is applicable to the body-care goods.
4. complex with self heat accumulation function according to claim 1 is characterized in that particle diameter＜5 micron of tourmalinite super-fine powder, and the particle diameter of phlogiston powder is 10～600 microns.
5. complex with self heat accumulation function according to claim 1 is characterized in that binding agent is any or any two above sum in oleum lini, Viscotrol C, polyvinyl chloride, stearic acid, the rosin.
6. complex with self heat accumulation function according to claim 1 is characterized in that embedding medium is any or any two above sum in paraffin oil, rosin, methylcellulose gum, the polyvinyl chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004101015941A CN1315974C (en) | 2004-12-24 | 2004-12-24 | Complex with self heat accumulation function, its preparation and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004101015941A CN1315974C (en) | 2004-12-24 | 2004-12-24 | Complex with self heat accumulation function, its preparation and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1635045A CN1635045A (en) | 2005-07-06 |
| CN1315974C true CN1315974C (en) | 2007-05-16 |
Family
ID=34848096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004101015941A Expired - Fee Related CN1315974C (en) | 2004-12-24 | 2004-12-24 | Complex with self heat accumulation function, its preparation and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1315974C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101057980B (en) * | 2006-04-17 | 2012-07-04 | 杨孟君 | High efficient functional composite material and its preparation method and application |
| CN106380175A (en) * | 2016-08-26 | 2017-02-08 | 安徽沃木采暖科技有限公司 | Preparation method of fireplace inner lining material having heat storage function |
| CN109160768A (en) * | 2018-07-10 | 2019-01-08 | 中瑞绿源科技有限公司 | A kind of health ornaments and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02260A (en) * | 1987-11-12 | 1990-01-05 | Canon Inc | Liquid crystal compound, liquid crystal composition containing the same compound and liquid crystal element using the same composition |
| JPH11206801A (en) * | 1998-01-19 | 1999-08-03 | Genchi Kenkyusho:Kk | Packaging material for heating element and heating element using the same |
| EP1439213A1 (en) * | 2001-10-25 | 2004-07-21 | Mycoal Warmers Co., Ltd | Exothermic composition and exothermic article using the composition, and method for producing the exothermic article |
| CN1554809A (en) * | 2003-12-19 | 2004-12-15 | 苗晓光 | Method for preparing protein fiber synthesizing spinning emulsion and fibrous product |
-
2004
- 2004-12-24 CN CNB2004101015941A patent/CN1315974C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02260A (en) * | 1987-11-12 | 1990-01-05 | Canon Inc | Liquid crystal compound, liquid crystal composition containing the same compound and liquid crystal element using the same composition |
| JPH11206801A (en) * | 1998-01-19 | 1999-08-03 | Genchi Kenkyusho:Kk | Packaging material for heating element and heating element using the same |
| EP1439213A1 (en) * | 2001-10-25 | 2004-07-21 | Mycoal Warmers Co., Ltd | Exothermic composition and exothermic article using the composition, and method for producing the exothermic article |
| CN1554809A (en) * | 2003-12-19 | 2004-12-15 | 苗晓光 | Method for preparing protein fiber synthesizing spinning emulsion and fibrous product |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1635045A (en) | 2005-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103275490A (en) | Modified silica gel material, preparation method and applications thereof | |
| CN107048546A (en) | A kind of preparation method with spontaneous hot and interior both effectiveness waistband and waistband heat generating components | |
| CN107089827A (en) | Without machine width ripple far infrared composite environmental-friendly material | |
| CN101774672B (en) | Functional material for preparing multifunctional healthy running water and preparation method thereof | |
| CN105645938A (en) | Far-infrared negative-ion ceramic and preparation method thereof | |
| CN109046193A (en) | A kind of preparation method and anion nanometer composite material of anion nanometer composite material | |
| CN101982205A (en) | Method for manufacturing tourmaline health-care products and applications thereof | |
| CN102418021B (en) | Broadband infrared ceramic material with anti-aging function at normal temperature and preparation method thereof | |
| CN110003660A (en) | A kind of Terahertz material silica gel composite and preparation method thereof | |
| CN106904979A (en) | Additive of releasable negative oxygen ion and preparation method thereof | |
| CN1315974C (en) | Complex with self heat accumulation function, its preparation and use thereof | |
| CN109680486B (en) | Preparation method of negative ion generation fabric and negative ion generation fabric | |
| CN105732011A (en) | A preparing method of novel multifunctional diatomite ceramsite | |
| CN1961989A (en) | Far infrared magnetic patch for physical therapy and production method thereof | |
| CN107586040B (en) | Preparation method of magnetic bioactive glass ceramic with high heat ratio | |
| KR20140011811A (en) | Sauna floor structure and sauna structure comprising the same | |
| CN108774877A (en) | A kind of biolipid slurry and its preparation method and application | |
| CN112646438A (en) | Negative ion antibacterial coating and preparation method thereof | |
| CN109207124B (en) | Preparation method of C3N4 excited natural ore negative ion emission nanocomposite and product thereof | |
| CN106511400A (en) | Cell wall breaking method used for preparing medicinal material wall breaking powder | |
| CN105862162A (en) | Method for preparing Ge-containing composite health fiber | |
| CN110505722A (en) | A kind of graphene oxygen release Electric radiant Heating Film and preparation method thereof | |
| KR101069933B1 (en) | Shoes spread pad with antibiotic deodorantand and manufacturing method thereof | |
| CN109225081A (en) | A kind of preparation method and its nanocomposite of the nanocomposite with anion emission function | |
| KR101933854B1 (en) | Far infrared ray clothes having function of character display |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: ANTAI SCIENCE AND TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: ANTAI SCIENCE AND TECHNOLOGY CO., LTD.; IRON AND STEEL RESEARCH GEUERAL INST. Effective date: 20071012 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20071012 Address after: 100081 No. 76 South College Road, Beijing, Haidian District Patentee after: Antai Science and Technology Co., Ltd. Address before: 100081 No. 76 South College Road, Beijing, Haidian District Co-patentee before: Central Iron & Steel Research Institute Patentee before: Antai Science and Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070516 Termination date: 20171224 |