CN103275490A - Modified silica gel material, preparation method and applications thereof - Google Patents
Modified silica gel material, preparation method and applications thereof Download PDFInfo
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Abstract
The present invention discloses a modified silica gel material, a preparation method and applications thereof. The modified silica gel material comprises the following components, by weight, 60-90% of a silica gel main material, 1-5% of germanium powder, 2-10% of titanium powder, 2-10% of negative ion powder, 2-10% of bamboo carbon, and 2-10% of far infrared ray powder. The method comprises: (a) preparing raw materials: mixing the raw materials according to the weight ratio, completely and uniformly stirring, and carrying out pressure reduction bubble removing; and (2) carrying out mold pressing or mold injection: placing or injecting the prepared raw materials into a preset mold, heating to a temperature of 180-300 DEG C, and discharging from the mold to obtain the modified silica gel material, wherein a heating time is 200-600 s. The modified silica gel material is used in health care products, has a good biological effect, a good chemical effect and a good physical effect, and can provide effects of body fatigue elimination and air purification.
Description
Technical field
The present invention relates to the silica gel technical field, relate in particular to a kind of modified silica-gel material, its preparation method and application.
Background technology
Silica gel is a kind of high reactivity sorbing material, belongs to environment-friendly materials, and this is as non-crystalline material, and absorption property is good, stronger physical strength etc. is stablized, had to Heat stability is good, chemical property, and water insoluble equal solvent, and is nonpoisonous and tasteless.
Owing to have the performance of above-mentioned excellence, silica gel is widely used in building, electric, weaving, automobile, machinery, leather papermaking, chemical industry light industry, metal and fields such as paint, food, medical medical treatment and health-care product.The example that typically is applied to field of food has the silica gel that uses food grade to make nipple for baby; The example that typically is applied to the health-care product field has the silica gel of use to make the silica gel cushion, because the silica gel good elasticity is brought good bradyseism effect, makes the people can not feel very tired above being sitting in.
Though characteristics such as the mechanical property excellence of silica gel determine it can be applied to the health-care product field, its health-care effect is limited.Be because shortage can produce the material of particular biological, chemistry or physics effect, such as the material to the human body beneficial such as negative ion, infrared rays in essence.In addition, though existing silica gel product has certain adsorption effect, can play slight deodorizing effect, purify air, its effect is limited, can not satisfy the needs under the severe environment.
Human body can produce very strong sense of fatigue behind permanent work or long-time same sitting posture, especially in long-time process of driving, tired aggravation may cause the generation of traffic accident.If can improve the quality of the cushion of the quality of wheel house air and navigating mate, will alleviate the fatigue of navigating mate.
Negative ion be known as in medical circle " air VITAMIN ".Its significant feature shows: pallium function and mental activity are strengthened, and in high spirits; The effect of obvious vasodilation is arranged, can remove the arteries spasm, reach the purpose that brings high blood pressure down; Make the effect that the blood pool flow velocity is slack-off, prolong the clotting time, can make oxygen level increase in the blood, be conducive to blood oxygen and carry, absorb and utilize; The effect that improves and increase pulmonary function is arranged; Promotion body redox processes can activate enzyme system in the body, promotes to synthesize in the body with vitamin storage, promotes body metabolism, reduces lactic acid content, Ginseng Extract in the blood, increases work efficiency.
For the foregoing reasons, research has alleviating fatigue, the material of nourishing function such as purify air is significant.
Summary of the invention
One of purpose of the present invention is to provide a kind of modified silica-gel material, and described modified silica-gel is material doped to be had and can discharge negative ion and ultrared material, can regulate human-body fatigue well, and have the function of absorption stink, reaches the purpose that purifies air.
For realizing purpose of the present invention, the present invention by the following technical solutions:
A kind of modified silica-gel material is composed of the following components by weight percentage:
In described modified silica-gel material, the content of silica gel major ingredient is 60%～90% by weight percentage, for example: 61%, 62%, 63%, 65%, 67%, 69%, 71%, 73%, 76%, 79%, 81%, 83%, 85%, 87%, 88%, 89% etc.; The content of germanium powder is 1%～5% by weight percentage, for example: 1.1%, 1.2%, 1.5%, 1.9%, 2%, 2.1%, 2.5%, 2.9%, 3.1%, 3.5%, 3.9%, 4.1%, 4.4%, 4.7%, 4.9% etc.; The content of titanium valve is 2%～10% by weight percentage, for example: 2.1%, 2.3%, 2.7%, 2.9%, 3.1%, 3.5%, 3.9%, 4.1%, 4.5%, 4.8%, 5.2%, 5.6%, 5.9%, 6.1%, 6.3%, 6.7%, 7.3%, 7.5%, 7.9%, 8.1%, 8.6%, 8.8%, 9.2%, 9.5%, 9.8%, 9.9% etc.; The content of negative ion powder is 2%～10% by weight percentage, for example: 2.1%, 2.3%, 2.7%, 2.9%, 3.1%, 3.5%, 3.9%, 4.1%, 4.5%, 4.8%, 5.2%, 5.6%, 5.9%, 6.1%, 6.3%, 6.7%, 7.3%, 7.5%, 7.9%, 8.1%, 8.6%, 8.8%, 9.2%, 9.5%, 9.8%, 9.9% etc.; The content of bamboo carbon is 2%～10% by weight percentage, for example: 2.1%, 2.3%, 2.7%, 2.9%, 3.1%, 3.5%, 3.9%, 4.1%, 4.5%, 4.8%, 5.2%, 5.6%, 5.9%, 6.1%, 6.3%, 6.7%, 7.3%, 7.5%, 7.9%, 8.1%, 8.6%, 8.8%, 9.2%, 9.5%, 9.8%, 9.9% etc.; The content of far-infrared powder is 2%～10% by weight percentage, for example: 2.1%, 2.3%, 2.7%, 2.9%, 3.1%, 3.5%, 3.9%, 4.1%, 4.5%, 4.8%, 5.2%, 5.6%, 5.9%, 6.1%, 6.3%, 6.7%, 7.3%, 7.5%, 7.9%, 8.1%, 8.6%, 8.8%, 9.2%, 9.5%, 9.8%, 9.9% etc.
Preferably, described modified silica-gel material is composed of the following components by weight percentage:
Further preferred, described modified silica-gel material is composed of the following components by weight percentage:
Preferably, described far-infrared powder is selected from the combination of any a kind or at least 2 kinds in tourmaline powder, medical stone powder or the far infrared ceramic powder; Typical case but the combination of indefiniteness comprise: the combination of tourmaline powder and medical stone powder, the combination of tourmaline powder and far infrared ceramic powder, the combination of tourmaline powder, medical stone powder and far infrared ceramic powder, preferred especially far infrared ceramic powder.
Two of purpose of the present invention is to provide a kind of modified silica-gel preparation methods, said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 180～300 ℃, heat-up time 200～600s, depanning namely gets the modified silica-gel material.
In step (2), temperature is heated to 180～300 ℃, for example: 181 ℃, 185 ℃, 189 ℃, 191 ℃, 199 ℃, 201 ℃, 205 ℃, 209 ℃, 211 ℃, 220 ℃, 225 ℃, 235 ℃, 239 ℃, 241 ℃, 248 ℃, 252 ℃, 258 ℃, 262 ℃, 268 ℃, 272 ℃, 280 ℃, 285 ℃, 288 ℃, 292 ℃, 298 ℃, 299 ℃ etc.; Preferred temperature is heated to 200～260 ℃, and further preferred 210～230 ℃, preferred especially 220 ℃.
In step (2), heat-up time 200～600s, for example: 205s, 215s, 220s, 230s, 235s, 245s, 255s, 260s, 270s, 280s, 285s, 295s, 305s, 320s, 340s, 350s, 360s, 370s, 375s, 378s, 382s, 300s, 305s, 340s, 360s, 370s, 375s, 385s, 400s, 430s, 455s, 470s, 500s, 550s, 585s, 590s, 595s, 599s etc.; Preferred heat-up time 250～500s, further preferred 300～400s, preferred especially 380s.
Preferably, described far-infrared powder is far infrared ceramic powder.
Three of purpose of the present invention is to provide a kind of application of modified silica-gel material, and described modified silica-gel material is used for health-care product.
Preferably, described health-care product is health-care cushion.
Compared with prior art, beneficial effect of the present invention is:
(1) contain germanium in the raw material of modified silica-gel material of the present invention, have characteristic of semiconductor, when the close contact human body, regulate human body potential difference, stimulate circulation, clear up symptom such as sore muscle, and then relieving fatigue;
(2) contain titanium in the raw material of modified silica-gel material of the present invention, have the ability of regulating the natural electric current of health by cell ionization, help to stablize physical condition, strengthen flowing of body inner blood;
(3) contain negative ion powder in the raw material of modified silica-gel material of the present invention, produce negative ion, purify air, eliminate foreign flavor indoors and various obnoxious flavour, killing pathogenic bacteria, make oxygen level increase in the blood, be conducive to blood oxygen and carry, absorb and utilize, have the metabolism of the human body of promotion, improve the human immunological competence, strengthen human body flesh energy, regulate the effect of human body function balance;
(4) contain bamboo carbon in the raw material of modified silica-gel material of the present invention, the effect that discharges negative ion is arranged, unique effect of purifying air is arranged, remove residual various obnoxious flavoures, play effects such as deodorizing, anticorrosion and protection against the tide;
(5) contain far-infrared powder in the raw material of modified silica-gel material of the present invention, releasing far infrared, activated the activity of biomacromolecule, thereby brought into play biomacromolecule and regulated movable function such as organism metabolism, immunity, the restore peace weighing apparatus that is conducive to function, reach the purpose of preventing and curing diseases, promote and improve blood circulation.
In sum, modified silica-gel material of the present invention has good biology, chemistry and physics effect, can be used as the material of good health care articles for use.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, below by the typical case but the embodiment of indefiniteness illustrates the present invention.
Embodiment 1
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 220 ℃, heat-up time 380s, depanning namely gets the modified silica-gel material.
Embodiment 2
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 210 ℃, heat-up time 580s, depanning namely gets the modified silica-gel material.
Embodiment 3
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 230 ℃, heat-up time 400s, depanning namely gets the modified silica-gel material.
Embodiment 4
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 200 ℃, heat-up time 600s, depanning namely gets the modified silica-gel material.
Embodiment 5
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 260 ℃, heat-up time 300s, depanning namely gets the modified silica-gel material.
Embodiment 6
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 260 ℃, heat-up time 250s, depanning namely gets the modified silica-gel material.
Embodiment 7
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 180 ℃, heat-up time 600s, depanning namely gets the modified silica-gel material.
Embodiment 8
A kind of modified silica-gel material is composed of the following components by weight percentage:
Said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 300 ℃, heat-up time 200s, depanning namely gets the modified silica-gel material.
Modified silica-gel material of the present invention has good biology, chemistry and physics effect, is the material that good health-care product is used, typical case but the application example of indefiniteness comprises the material as health-care cushion.Those skilled in the art can understand: described modified silica-gel material can also be applied in the health-care products such as health promoting shoe.
Technical scheme of the present invention has below been described in conjunction with specific embodiments.These are described just in order to explain the solution of the present invention, and can not be interpreted as limiting the scope of the invention by any way.Based on explanation herein; those skilled in the art does not need to pay performing creative labour can associate other specific embodiment of the present invention; namely to the equivalence replacement of each raw material of product of the present invention and the suitable adjustment of content, these embodiment will fall within protection scope of the present invention.
Claims (10)
1. a modified silica-gel material is characterized in that, described modified silica-gel material is composed of the following components by weight percentage:
2. modified silica-gel material according to claim 1 is characterized in that, described modified silica-gel material is composed of the following components by weight percentage:
3. modified silica-gel material according to claim 2 is characterized in that, described modified silica-gel material is composed of the following components by weight percentage:
4. according to each described modified silica-gel material of claim 1 to 3, it is characterized in that described far-infrared powder is selected from the combination of any a kind or at least 2 kinds in tourmaline powder, medical stone powder and the far infrared ceramic powder.
5. one kind according to each described modified silica-gel preparation methods of claim 1 to 4, it is characterized in that, said method comprising the steps of:
(1) preparation of raw material: according to described weight percent raw material is mixed, stir, bubble is got rid of in decompression;
(2) mold pressing or injection moulding: the raw material for preparing is put into or injected the mould that presets, temperature is heated to 180～300 ℃, heat-up time 200～600s, depanning namely gets the modified silica-gel material.
6. modified silica-gel preparation methods according to claim 5 is characterized in that, described temperature is heated to 210～230 ℃.
7. modified silica-gel preparation methods according to claim 5 is characterized in that, described heat-up time 380s.
8. according to each described modified silica-gel preparation methods of claim 5 to 7, it is characterized in that described far-infrared powder is far infrared ceramic powder.
9. the application according to each described modified silica-gel material of claim 1 to 4 is characterized in that, described modified silica-gel material is used for health-care product.
10. the application of modified silica-gel material according to claim 9 is characterized in that, described health-care product is health-care cushion.
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104622715A (en) * | 2015-01-07 | 2015-05-20 | 杨小毛 | Silica gel mask |
| CN104693804A (en) * | 2014-12-24 | 2015-06-10 | 东莞市希贝实业有限公司 | Negative ion silicon rubber material and preparation method thereof |
| CN105032345A (en) * | 2015-06-24 | 2015-11-11 | 何相华 | Negative-ion activated carbon and preparation method thereof |
| CN105385161A (en) * | 2015-08-28 | 2016-03-09 | 龙门多泰工业有限公司 | Far infrared silica gel material |
| CN105879240A (en) * | 2015-06-05 | 2016-08-24 | 娄敬涛 | Far-infrared negative ion health care pad |
| CN105901777A (en) * | 2016-04-08 | 2016-08-31 | 厦门天绅生物科技有限公司 | Formula and preparation method for health care underpants |
| CN105919169A (en) * | 2016-04-21 | 2016-09-07 | 厦门天绅生物科技有限公司 | Steel-ring-free health bra with functions of enlarging and beautifying breasts and preventing breast diseases |
| CN106243724A (en) * | 2016-08-12 | 2016-12-21 | 海宁久久塑胶有限公司 | Bamboo charcoal silica gel and production technology thereof and application |
| CN106317728A (en) * | 2015-07-03 | 2017-01-11 | 上海伟星新型建材有限公司 | High-efficiency and high-strength composite material with far infrared radiation heating and preparation method thereof |
| CN107286665A (en) * | 2017-07-28 | 2017-10-24 | 玉荆泉 | A kind of multifunctional material health mat and preparation method thereof |
| CN107430937A (en) * | 2015-01-22 | 2017-12-01 | 株式会社理光 | element and generator |
| CN109251002A (en) * | 2018-09-20 | 2019-01-22 | 东莞市米乐真科技有限公司 | Far-infrared negative-ion composite colloid material, preparation method and its utilization based on Tourmaline |
| CN110003660A (en) * | 2019-04-28 | 2019-07-12 | 张慧 | A kind of Terahertz material silica gel composite and preparation method thereof |
| CN110041704A (en) * | 2019-04-23 | 2019-07-23 | 深圳市蜀音音频技术有限公司 | A kind of anion formula of earphone silica gel earplugs ear-hang |
| CN111233429A (en) * | 2020-03-16 | 2020-06-05 | 深圳市瑞吉思科技有限公司 | Health-care antibacterial soft rubber and production process thereof |
| CN112852166A (en) * | 2021-01-11 | 2021-05-28 | 意得凯(深圳)科技有限责任公司 | Silica gel composite material capable of continuously releasing far infrared rays |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104693804A (en) * | 2014-12-24 | 2015-06-10 | 东莞市希贝实业有限公司 | Negative ion silicon rubber material and preparation method thereof |
| CN104622715A (en) * | 2015-01-07 | 2015-05-20 | 杨小毛 | Silica gel mask |
| CN107430937B (en) * | 2015-01-22 | 2019-03-08 | 株式会社理光 | Element and generator |
| CN107430937A (en) * | 2015-01-22 | 2017-12-01 | 株式会社理光 | element and generator |
| CN105879240A (en) * | 2015-06-05 | 2016-08-24 | 娄敬涛 | Far-infrared negative ion health care pad |
| CN105879240B (en) * | 2015-06-05 | 2018-06-29 | 娄敬涛 | A kind of far-infrared negative-ion health mat |
| CN105032345A (en) * | 2015-06-24 | 2015-11-11 | 何相华 | Negative-ion activated carbon and preparation method thereof |
| CN106317728A (en) * | 2015-07-03 | 2017-01-11 | 上海伟星新型建材有限公司 | High-efficiency and high-strength composite material with far infrared radiation heating and preparation method thereof |
| CN105385161A (en) * | 2015-08-28 | 2016-03-09 | 龙门多泰工业有限公司 | Far infrared silica gel material |
| CN105901777A (en) * | 2016-04-08 | 2016-08-31 | 厦门天绅生物科技有限公司 | Formula and preparation method for health care underpants |
| CN105919169A (en) * | 2016-04-21 | 2016-09-07 | 厦门天绅生物科技有限公司 | Steel-ring-free health bra with functions of enlarging and beautifying breasts and preventing breast diseases |
| CN106243724A (en) * | 2016-08-12 | 2016-12-21 | 海宁久久塑胶有限公司 | Bamboo charcoal silica gel and production technology thereof and application |
| CN107286665A (en) * | 2017-07-28 | 2017-10-24 | 玉荆泉 | A kind of multifunctional material health mat and preparation method thereof |
| CN109251002A (en) * | 2018-09-20 | 2019-01-22 | 东莞市米乐真科技有限公司 | Far-infrared negative-ion composite colloid material, preparation method and its utilization based on Tourmaline |
| CN110041704A (en) * | 2019-04-23 | 2019-07-23 | 深圳市蜀音音频技术有限公司 | A kind of anion formula of earphone silica gel earplugs ear-hang |
| CN110003660A (en) * | 2019-04-28 | 2019-07-12 | 张慧 | A kind of Terahertz material silica gel composite and preparation method thereof |
| CN111233429A (en) * | 2020-03-16 | 2020-06-05 | 深圳市瑞吉思科技有限公司 | Health-care antibacterial soft rubber and production process thereof |
| CN112852166A (en) * | 2021-01-11 | 2021-05-28 | 意得凯(深圳)科技有限责任公司 | Silica gel composite material capable of continuously releasing far infrared rays |
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Effective date of registration: 20160826 Address after: 518000, -3 building, No. 2, industrial road, step Yong Community Industrial Street, Baoan District, Guangdong, Shenzhen 201, China, 101 Patentee after: SHENZHEN HENGBINLI TECHNOLOGY CO., LTD. Address before: 518104, Shenzhen, Guangdong, Baoan District manhole town, manhole street, step village, step Yong Industrial Road, No. 3, building 2, 3 floor Patentee before: Cai Lubing |
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| TR01 | Transfer of patent right |
Effective date of registration: 20210827 Address after: 518000 Room 101, building 2, zone a, Yuhe Road, Gonghe community, Shajing street, Bao'an District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Yikang Medical Technology Co.,Ltd. Address before: 518000 101 and 201, building 3, No. 2, industrial road, Buyong community, Shajing street, Bao'an District, Shenzhen, Guangdong Patentee before: SHENZHEN HENGBINLI TECHNOLOGY Co.,Ltd. |