CN1312061C - Waste water purifying method and its magnetic puddler integrated device - Google Patents
Waste water purifying method and its magnetic puddler integrated device Download PDFInfo
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- CN1312061C CN1312061C CNB2003101176544A CN200310117654A CN1312061C CN 1312061 C CN1312061 C CN 1312061C CN B2003101176544 A CNB2003101176544 A CN B2003101176544A CN 200310117654 A CN200310117654 A CN 200310117654A CN 1312061 C CN1312061 C CN 1312061C
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- waste water
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- 239000002351 wastewater Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 108
- 230000005415 magnetization Effects 0.000 claims abstract description 32
- 238000000746 purification Methods 0.000 claims abstract description 27
- 239000003054 catalyst Substances 0.000 claims abstract description 22
- 238000001914 filtration Methods 0.000 claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 230000003197 catalytic effect Effects 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 16
- 238000011001 backwashing Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 239000004927 clay Substances 0.000 claims description 8
- 239000011941 photocatalyst Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- 239000003610 charcoal Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000012544 monitoring process Methods 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000000701 coagulant Substances 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000033558 biomineral tissue development Effects 0.000 abstract 1
- 230000005404 monopole Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- -1 hydroxyl radical free radical Chemical class 0.000 description 13
- 239000012535 impurity Substances 0.000 description 11
- 230000008859 change Effects 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000010865 sewage Substances 0.000 description 6
- 230000001954 sterilising effect Effects 0.000 description 6
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- 241000195493 Cryptophyta Species 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 230000010718 Oxidation Activity Effects 0.000 description 4
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003621 irrigation water Substances 0.000 description 2
- 238000000016 photochemical curing Methods 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011118 depth filtration Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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- 238000001556 precipitation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
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- Water Treatment By Sorption (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
Abstract
The present invention relates to a water treatment method for purifying waste water and integrated equipment of magnetization puddler thereof. Waste water passes through a magnetic-inductive water pipe whose inner wall is attached with catalyst thin film, and produces an electron hole pair with strong activity through the catalytic oxidation reaction of a catalyst for promoting the mineralization of organic substances in the waste water; then, the waste water is purified through a filtration treatment; in the magnetization puddler, a magnetic field is produced by a monopole magnetic loop made of SRO6Fe2O3 and arranged at the outer covering of the magnetic-inductive water pipe; the catalyst is prepared from titanium dioxide and iron powder; in a filter, the waste water purification is completed through a primary filtration of active carbon and a fine filtration by adopting filter bag interception, the amount of sundries intercepted by the filter bag can be monitored with a pressure difference between the inside and the outside of the filter bag, and the sundries in the filter bag are cleaned when the pressure difference between the inside and the outside of the filter bag reaches a certain extent. The present invention provides an energy-saving type water quality purifying method with no need of adding coagulant and no power consumption and equipment thereof, and has the advantages of low cost, high purification efficiency and strong practicability.
Description
Technical field
The present invention relates to water treatment, relate in particular to the purification of water quality of urban industry waste water, municipal sanitary wastewater processing and landscape water, agricultural irrigation water sterilization algae removal, be used for the purification method for effluent and the magnetization coagulator integrated equipment thereof of environmental protection.
Background technology
Along with socioeconomic high development, the industrialization and the urbanization of human society increasingly sharpen, and water pollutes serious day by day.Over nearly 10 years, China's city domestic sewage quantity discharged every year surpassed the industrial sewage quantity discharged first with 5% speed increase in 1999.Calendar year 2001, the city domestic sewage quantity discharged was 22,100,000,000 tons, accounted for 53.2% of national total amount of sewage discharge.Whole nation industry in 2002 and urban life wastewater emission amount are 439.5 hundred million tons, and wherein the urban life wastewater emission amount is 232.3 hundred million tons, increases by 0.9% than the last year.Because huge blowdown pressure like this, make the long-term excess load running of various places sewage work, even the sewage of unprocessed mistake directly is discharged into rivers and lakes, make rivers and lakes slowly lose self-purification capacity, the first-generation water that formation is representative with black smelly anoxic pollutes, or formation is the s-generation water pollution of representative with heavy metal, noxious chemical pollution, even or form that to pollute with the nutritive element excess be that the third generation water of representative pollutes, more very be that the three generations pollutes simultaneously in a lot of rivers and lakes, it is serious day by day that rivers and lakes water is polluted.At existing water-treatment technology field, the most traditional method is directly to add coagulated agent to carry out coagulation-settlement process, water outlet after the processing reaches requirement substantially, but it is big to exist floor space, the investment cost height, the problem with high costs that working cost is high needs a large amount of coagulated agents and the electricity charge in actual applications, cause the economic benefit of technology not high, cause the wasting of resources.
Summary of the invention
The object of the present invention is to provide a kind of purification method for effluent and magnetization coagulator integrated equipment thereof,, provide a kind of method and apparatus of adding coagulating agent and not having power consumption of exempting to solve defective with high costs in the prior art.
Purification method for effluent of the present invention is:
A. waste water with the magnetic conduction water pipe of catalyst film, by the catalytic oxidation of catalyzer, produces that strong active electronics--the hole is right through inwall in the magnetization coagulator, promotes organic mineralising in the waste water;
B. handle purification of waste water after filtration then.
In the described steps A, in the described magnetization coagulator, produce magnetic field by the outer sheathed one pole magnet ring of magnetic conduction water pipe;
Described one pole magnet ring adopts SRO
6Fe
2O
3Make;
Flow rate of water flow in the described magnetic conduction water pipe is between 1 meter per second-3 meter per second;
In the described steps A, catalyzer adopts titanium dioxide and iron powder composition;
Among the described step B, by strainer to purification of waste water;
Among the described step B, pass through the gac primary filter in the described strainer successively, and the fine filtering that the employing filter bag is held back is to purification of waste water;
Among the described step B, in the described strainer, by monitoring to filter bag external and internal pressure difference, reflection filter bag object-catching degree, when filter bag external and internal pressure difference to a certain degree the time, the foreign material of filter bag inner face are cleaned;
Described filter bag is a needling fiber felt filter bag;
Described filter bag adopts moment sintering method making.
The magnetization coagulator integrated equipment of this realization aforesaid method comprises magnetization coagulator and settling tank, and described magnetization coagulator comprises the magnetic conduction water pipe, it is characterized in that: described magnetic conduction pipe inner wall is with catalyst film.
The another kind of magnetization coagulator integrated equipment of realizing aforesaid method comprises the magnetization coagulator with strainer and link to each other successively, and described magnetization coagulator comprises the magnetic conduction water pipe, it is characterized in that: described magnetic conduction pipe inner wall has catalyst film.
In the described magnetization coagulator, the outer sheathed one pole magnet ring of magnetic conduction water pipe;
Described strainer comprises the primary filter layer of bottom and the fine filtering layer on top, described primary filter layer comprises water intaking valve, gac and wash water valve, and link to each other with the magnetic conduction water pipe by water intaking valve, described fine filtering layer comprises filter bag, outlet valve and backwashing intake valve;
Described gac is the compound charcoal of photocatalyst potter's clay;
Described strainer also is equiped with the control device of monitoring filter bag external and internal pressure difference, and described control device is according to the unlatching of filter bag external and internal pressure difference control backwashing intake valve or wash water valve;
Described control device comprises Mgs, differential pressure pickup and recoil counter, differential pressure pickup detects filter bag external and internal pressure difference and sends corresponding signal to Mgs and recoil counter, described Mgs is directly carried out the opening and closing operations of backwashing intake valve and wash water valve according to differential pressure pickup and the recoil signal that sends of counter or instruction, and the operating time of described recoil counter controls Mgs at interval;
Described control device also comprises the alarm follower, and described alarm follower carries out corresponding prompting, warning according to differential pressure pickup or the signal that sends of recoil counter.
Beneficial effect of the present invention is: in the present invention, when waste water when flowing to the magnetic conduction water pipe, because the magnetic conduction pipe inner wall is with catalyst film, catalyst film carries out the magnetic line of force catalytic oxidation, electron absorption hertzian wave in catalyst film forbidden band under the magnetic line of force effect (valence associating) and being excited on the conduction band (conduction), promptly on conduction band, produce and have very strong electronegative high reactivity electronics, on the forbidden band, produce the hole (h+) of positively charged simultaneously, very strong active electronics--the hole is right thereby generation has, form redox system, by these electronics--the hole is to after moving to the catalyst film surface, with dissolved oxygen and H
2O has an effect, final hydroxyl radical free radical (.OH) and the super-oxide ion (superoxide ion) that produce with highly chemical oxidation activity, and hydroxyl radical free radical (.OH) is a strong oxidizer, can be CO with the organism permineralization
2And H
2O, to reach sterilization, algae removal and to remove the chemical consumption of part (COD), biological oxygen demand (BOD), suspended substance (SS), effect with the magnetization coagulation, more effectively finish purification of waste water at low cost and handle, the present invention avoids adopting pharmaceutical chemicals to remove the impurity in the waste water and do not have power consumption in the course of the work, thereby reduces the cost of wastewater treatment.Particularly the outer sheathed one pole magnet ring of magnetic conduction water pipe produces magnetic field, the permanent magnet ring of this one pole can produce powerful magnetic field, reach 4000 to 20000 Gausses, water passes through magnetic field with certain flow velocity under external force, magnetic line of force and current perpendicular quadrature are made cutting magnetic line movement, can produce electric charge and the electromotive force that makes charge movement in the water, so water has just produced physical changes such as electric current, potential difference, so produced into electric energy.At this moment electric charge, current potential have been arranged in the water, the state and the character that will change water itself and be included in other material in the water, this magnetized water has just had tube wall contacted with it, wall of container to produce the energy of physical change and electrochemical change.Be dissolved with the impurity of compositions such as salt, alkali, acid in the waste water, make water that certain potential of hydrogen be arranged, undissolved solid impurity and micro-metal, non-metallic element are to some extent also suspending simultaneously, these impurity and other element impel has the nonisulated material of certain conductivity to be magnetized, and foreign material such as calcium in the water and iron also can produce the ion of positively charged and negative electricity simultaneously.Ion condenses and the volume increase suspending sundries owing to plus-minus electric relation attracts each other, and to reach the purpose of coagulation, further improves decontamination effect improving of the present invention.
In the present invention, by adopting control device monitoring filter bag external and internal pressure poor, unlatching according to filter bag external and internal pressure difference control backwashing intake valve or wash water valve, can realize automatic self-stip, discharging, need not to dismantle filter bag manually cleans, improve practicality of the present invention and working efficiency, attached in the control device with the alarm follower, make use of the present invention, control process more directly perceived.
The gac of primary filter layer adopts the compound charcoal of photocatalyst potter's clay in the strainer, its photoelectrochemistry adsorptive power is very high, most of suspending sundries in the waste water tentatively can be filtered, hold back by the fine filtering layer again, filter bag adopts needling fiber felt filter bag, because this filter pocket material mainly is a polyester felt, polyethylene felt and polypropylene mat, its characteristics are that fibrous tissue is loose, high voidage, increased the appearance amount of cutting to foreign material, and this kind filter bag belongs to the Depth Filtration type, and a promptly big material is trapped in fiber on the surface, and small-particle absorbs between deep layer, has high filtration efficiency, in addition, owing to adopt the moment sintering method, thereby fiber is subjected to fluid high-speed to dash band and scatters and disappears can prevent to filter effectively the time, no fibre shedding phenomenon, its filtering accuracy can reach 1-100um, and granularity I to the 1 μ m of the pollutent of holding back improves decontamination effect improving of the present invention.
In a word, the water purifying plant floor space that the invention solves existing waste water is big, investment cost and the high problem of working cost, provide a kind of can be in order to avoid add coagulating agent and do not have the energy-saving water quality purifying method and the equipment of power consumption, cost of the present invention is low, purification efficiency height, practical can be widely applicable for:
1, urban industry waste water, municipal sanitary wastewater, and the purification of water quality of agricultural irrigation water.
2, be used for heat exchanger, cold and hot water supply system, power station towards ash water system oil-field flooding sterilization.
3, industrial cooling circulating water system.
4, central air-conditioning cooling system, condenser, cooling tower, cooling water tank, recycle pump pipeline etc.
5, hot water boiler, steam oven, fuel oil gas-fired stove, drinking water boiler etc.
6, biotope water system, high-floor feedwater.
7, the purification of water bodys such as river, lake, plant, hydrophilic park, view fishpond and sterilization, algae removal.
Description of drawings
Fig. 1 is the embodiment of the invention 1 a main assembly synoptic diagram;
Fig. 2 is the embodiment of the invention 2 main assembly synoptic diagram;
Fig. 3 is that the embodiment of the invention 2 structure units indicate synoptic diagram;
Fig. 4 is the control texture synoptic diagram of control device in the embodiment of the invention 2.
Embodiment
With embodiment the present invention is described in further detail with reference to the accompanying drawings below:
Embodiment 1:
According to Fig. 1, the present invention includes magnetization coagulator 1 and settling tank 3, magnetization coagulator 1 comprises magnetic conduction water pipe 11, magnetic conduction water pipe 11 inwalls are with catalyst film, catalyzer adopts nano titanium oxide and nanometer iron powder composition, this titanium dioxide and iron powder composition can adopt the method for low temperature photocuring that it is attached in the magnetic conduction water pipe 11, magnetic conduction water pipe 11 outer sheathed one pole magnet rings 12, and one pole magnet ring 12 adopts SRO
6Fe
2O
3Make, settling tank 3 is provided with wash water valve 213 and outlet valve 222.
As shown in Figure 1, when waste water with suitable flow velocity, as 1 meter per second-3 meter per second, enter outer three the one pole magnet rings 12 that are with, inwall is coated with the nano-catalytic agent film, when two ends have the hollow metal magnetic conduction water pipe 11 of flange 13, can produce 4000 to 20000 Gausses' strong magnetic field in the water pipe, the catalyst film that is coated with in the magnetic line of force that takes place by strong magnetic area and the pipe carries out the magnetoelectricity chemical reaction, the catalyzer major ingredient is nano titanium oxide and nanometer iron powder composition, electron absorption hertzian wave in catalyst film forbidden band under the magnetic line of force effect (valence associating) and being excited on the conduction band (conduction), promptly on conduction band, produce and have very strong electronegative high reactivity electronics, on the forbidden band, produce the hole (h+) of positively charged simultaneously, very strong active electronics--the hole is right thereby generation has, in magnetic conduction water pipe 11, form redox system, these electronics--hole is to after moving to the catalyst film surface, with dissolved oxygen and H
2O has an effect, final hydroxyl radical free radical (.OH) and the super-oxide ion (superoxide ion) that produce with highly chemical oxidation activity, and hydroxyl radical free radical (.OH) is a strong oxidizer, can be CO with the organism permineralization usually
2And H
2O, the effect of playing sterilization, algae removal and removing portion C OD, BOD, SS.Water passes through magnetic field with certain flow velocity under external force, makes cutting magnetic line movement, can produce electric charge and the electromotive force that makes charge movement in the water, so water has just produced physical changes such as electric current, potential difference, so produced into electric energy.At this moment electric charge, current potential have been arranged in the water, the state and the character that will change water itself and be included in other material in the water, this magnetized water has just had tube wall contacted with it, wall of container to produce the energy of physical change and electrochemical change.Be dissolved with the impurity of compositions such as salt, alkali, acid in the water, make water that certain potential of hydrogen be arranged, undissolved solid impurity and micro-metal, non-metallic element are to some extent also suspending simultaneously, these impurity and other element impel has the nonisulated material of certain conductivity to be magnetized, and foreign material such as calcium in the water and iron also can produce the ion of positively charged and negative electricity simultaneously.Ion is owing to plus-minus electric relation attracts each other, make the suspending sundries cohesion and the volume increase, after forming coagulation effect, waste water flows into settling tank 3 then, after the filtration treatment through precipitation, discharging in settling tank 3, waste water is purified, and filtered impurity is discharged by wash water valve 213, and the water after the purification flows out through outlet valve 222.
Embodiment 2:
According to Fig. 2, Fig. 3 and Fig. 4, the present invention includes magnetization coagulator 1 with strainer 2 and link to each other successively, as shown in Figures 2 and 3, magnetization coagulator 1 comprises magnetic conduction water pipe 11, magnetic conduction water pipe 11 inwalls are with catalyst film, and catalyzer adopts nano titanium oxide and nanometer iron powder composition, and this nano titanium oxide and nanometer iron powder composition can adopt the method for low temperature photocuring that it is attached in the magnetic conduction water pipe 11, magnetic conduction water pipe 11 outer sheathed one pole magnet rings 12, one pole magnet ring 12 adopts SRO
6Fe
2O
3Make.
As shown in Figure 2, strainer 2 comprises the primary filter layer 21 of bottom and the fine filtering layer 22 on top, as shown in Figures 2 and 3, primary filter layer 21 comprises water intaking valve 211, gac 212 and wash water valve 213, and link to each other with magnetic conduction water pipe 11 by water intaking valve 211, wherein, gac 212 is the compound charcoal of photocatalyst potter's clay, the compound charcoal of photocatalyst potter's clay by carbon granule, potter's clay, and the photocatalyst agent mix to burn and form through the high temperature satin, have carbon granule, potter's clay, and the microvoid structure difference of photocatalyst three-decker and each layer; Fine filtering layer 22 comprises filter bag 221, outlet valve 222 and backwashing intake valve 223, filter bag 221 is a needling fiber felt filter bag, adopt moment sintering method making, filter bag cover 224 is housed on the filter bag 221, installing perforate dividing plate 225 between primary filter layer 21 and the fine filtering layer 22.
As shown in Figures 2 and 3, also be equiped with control device 23 in the strainer 2, the external and internal pressure of these control device 23 monitoring filter bags 221 is poor, and according to the unlatching of filter bag 221 external and internal pressure differences control backwashing intake valve 223 or wash water valve 213, as shown in Figure 4, this control device 23 comprises Mgs 231, differential pressure pickup 232, recoil counter 233 and alarm follower 234,232 pairs of filter bags of differential pressure pickup, 221 external and internal pressure differences detect and send corresponding signal to Mgs 231 and recoil counter 233, the opening and closing operations that backwashing intake valve 223 and wash water valve 213 are directly carried out in signal that Mgs 231 is sent according to differential pressure pickup 232 and recoil counter 233 or instruction, the operating time of recoil counter 233 control Mgs 231 at interval, alarm follower 234 carries out corresponding prompting according to differential pressure pickup 232 or the signal that sends of recoil counter 233, report to the police, as shown in Figure 4, relevant prompting, warning can be passed through loud speaker as required, multiple medium such as luminotron or indicating meter are embodied.
As shown in Figure 2, waste water has the magnetic conduction water pipe 2 of catalyst film through inwall in magnetization coagulator 1, catalytic oxidation by catalyzer, generation has the hydroxyl radical free radical (.OH) and the super-oxide ion (superoxide ion) of highly chemical oxidation activity, promote organic mineralising in the waste water, purify by 2 pairs of waste water filterings of strainer then.
As shown in Figures 2 and 3, when waste water with suitable flow velocity, as 1 meter per second-3 meter per second, enter outer be with three or three above one pole magnet rings 12, inwall is coated with the nano-catalytic agent film, when two ends have the hollow metal magnetic conduction water pipe 11 of flange 13, can produce 4000 to 20000 Gausses' strong magnetic field in the water pipe, the catalyst film that is coated with in the magnetic line of force that takes place by strong magnetic area and the pipe carries out the magnetic line of force electrochemical reaction, the catalyzer major ingredient is nano titanium oxide and nanometer iron powder composition, electron absorption hertzian wave in catalyst film forbidden band under the magnetic line of force effect (valence associating) and being excited on the conduction band (conduction), promptly on conduction band, produce and have very strong electronegative high reactivity electronics, on the forbidden band, produce the hole (h+) of positively charged simultaneously, very strong active electronics--the hole is right thereby generation has, in magnetic conduction water pipe 11, form redox system, these electronics--hole is to after moving to the catalyst film surface, with dissolved oxygen and H
2O has an effect, final hydroxyl radical free radical (.OH) and the super-oxide ion (superoxide ion) that produce with highly chemical oxidation activity, and hydroxyl radical free radical (.OH) is a strong oxidizer, can be CO with the organism permineralization usually
2And H
2O, the effect of playing sterilization, algae removal and removing portion C OD, BOD, SS.When water passes through magnetic field with certain flow velocity under external force, make cutting magnetic line movement, can produce electric charge and the electromotive force that makes charge movement in the water, so water has just produced physical changes such as electric current, potential difference, so produced into electric energy.At this moment electric charge, current potential have been arranged in the water, the state and the character that will change water itself and be included in other material in the water, this magnetized water has just had tube wall contacted with it, wall of container to produce the energy of physical change and electrochemical change.Be dissolved with the impurity of compositions such as salt, alkali, acid in the water, make water that certain potential of hydrogen be arranged, undissolved solid impurity and micro-metal, non-metallic element are to some extent also suspending simultaneously, these impurity and other element impel has the nonisulated material of certain conductivity to be magnetized, and foreign material such as calcium in the water and iron also can produce the ion of positively charged and negative electricity simultaneously.Ion is owing to plus-minus electric relation attracts each other, make the suspending sundries cohesion and the volume increase, after forming coagulation effect, flow through the then primary filter layer 21 of strainer 2, gac 212 adopts the compound charcoal of photocatalyst potter's clay efficiently in the primary filter layer 21, the photoelectrochemistry adsorptive power is very high, most of suspending sundries tentatively can be filtered, finer foreign material are with living current again toward the upper reaches, hold back through the filter bag 221 of fine filtering layer 22 again, dirt accumulates in the fine filtering bag 221, when reaching a certain amount of, make filter bag 221 internal pressures and bag external pressure form pressure difference, as shown in Figure 3 and Figure 4, when pressure reduction reaches a certain preset value (as 0.5kg/cm2), differential pressure pickup 232 in the control device 23 reaches Mgs 231 with signal, make it open backwashing intake valve 223 and wash water valve 213, via the water feeding pressure of backwashing intake valve 223 from top to bottom, the dirt that filter bag 221 inner faces are produced cleans up, discharge by wash water valve 213, simultaneously, differential pressure pickup 232 triggers and starts recoil counter 233, when 233 timing of recoil counter reach preset value, promptly after filter bag 221 is rinsed totally, recoil counter 233 sends shutdown signal to Mgs 231, Mgs 231 is closed backwashing intake valve 223 and wash water valve 213, equipment among the present invention automatically restores to full filter state again, like this, just by monitoring to filter bag 221 external and internal pressure differences, reflection filter bag 221 object-catching degree, when filter bag 221 external and internal pressure differences to a certain degree the time, foreign material to filter bag 221 inner faces clean automatically, discharging, by constantly so moving in circles, realize automatic self-cleaning filter 2, in this automatic control process, alarm follower 234 carries out corresponding prompting according to differential pressure pickup 232 or the signal that sends of recoil counter 233, report to the police, as shown in Figure 4, make use of the present invention, control process is more directly perceived, if system produces flase operation, can in time solve fault by manual intervention by reporting to the police.In the present invention, Mgs 231 also can be controlled water intaking valve 211 and outlet valve 222 simultaneously, and its control process is similar substantially to the above, need not give unnecessary details herein.
In the present invention, fine filtering layer 22 in the strainer 2 can adopt many group filter bags 221, can dispose corresponding backwashing intake valve 223 and control device 23 as required, its structure, principle and working process repeat no more to basic identical or similar described in the embodiment 2 herein.
Claims (15)
1. purification method for effluent, it is characterized in that: it adopts following steps:
A. waste water with the magnetic conduction water pipe of catalyst film, outside sheathed one pole magnet ring, by the catalytic oxidation of catalyzer, produces that strong active electronics--the hole is right through inwall in the magnetization coagulator, promotes organic mineralising in the waste water; Wherein said catalyzer adopts titanium dioxide and iron powder composition;
B. handle purification of waste water after filtration then.
2. purification method for effluent according to claim 1 is characterized in that: described one pole magnet ring adopts SRO
6Fe
2O
3Make.
3. purification method for effluent according to claim 1 is characterized in that: the flow rate of water flow in the described magnetic conduction water pipe is between 1 meter per second-3 meter per second.
4. purification method for effluent according to claim 1 is characterized in that: among the described step B, by strainer to purification of waste water.
5. purification method for effluent according to claim 4 is characterized in that: among the described step B, pass through the gac primary filter in the described strainer successively, and the fine filtering that the employing filter bag is held back is to purification of waste water.
6. purification method for effluent according to claim 5 is characterized in that: among the described step B, in the described strainer, by detection to filter bag external and internal pressure difference, reflection filter bag object-catching degree, when filter bag external and internal pressure difference to a certain degree the time, the foreign material of filter bag inner face are cleaned.
7. according to claim 5 or 6 described purification method for effluent, it is characterized in that: described filter bag is a needling fiber felt filter bag.
8. purification method for effluent according to claim 7 is characterized in that: described filter bag adopts moment sintering method making.
9. magnetization coagulator integrated equipment of realizing the described method of claim 1, comprise magnetization coagulator (1) and settling tank (3), described magnetization coagulator (1) comprises magnetic conduction water pipe (11), it is characterized in that: described magnetic conduction water pipe (11) inwall is with the catalyst film, the outside sheathed one pole magnet ring (12) that are made of titanium dioxide and iron powder composition.
10. magnetization coagulator integrated equipment of realizing the described method of claim 1, comprise that magnetization coagulator (1) is with strainer (2) and link to each other successively, described magnetization coagulator (1) comprises magnetic conduction water pipe (11), it is characterized in that: described magnetic conduction water pipe (11) inwall is with the catalyst film, the outside sheathed one pole magnet ring (12) that are made of titanium dioxide and iron powder composition.
11. magnetization coagulator integrated equipment according to claim 10, it is characterized in that: described strainer (2) comprises the primary filter layer (21) of bottom and the fine filtering layer (22) on top, described primary filter layer (21) comprises water intaking valve (211), gac (212) and wash water valve (213), and link to each other with magnetic conduction water pipe (11) by water intaking valve (211), described fine filtering layer (22) comprises filter bag (221), outlet valve (222) and backwashing intake valve (223).
12. magnetization coagulator integrated equipment according to claim 11 is characterized in that: described gac (212) is the compound charcoal of photocatalyst potter's clay.
13. magnetization coagulator integrated equipment according to claim 11 is characterized in that: described strainer (2) also is equiped with the control device (23) of monitoring filter bag (221) external and internal pressure difference,
Described control device (23) is according to the unlatching of filter bag (221) external and internal pressure difference control backwashing intake valve (223) or the dirty valve of draining (213).
14. magnetization coagulator integrated equipment according to claim 13, it is characterized in that: described control device (23) comprises Mgs (231), differential pressure pickup (232) and recoil counter (233), differential pressure pickup (232) detects filter bag (221) external and internal pressure difference and sends corresponding signal to Mgs (231) and recoil counter (233), described Mgs (231) is directly carried out the opening and closing operations of backwashing intake valve (223) and wash water valve (213), the operating time interval of described recoil counter (233) control Mgs (231) according to differential pressure pickup (232) and the signal that sends of recoil counter (233) or instruction.
15. magnetization coagulator integrated equipment according to claim 14, it is characterized in that: described control device (23) also comprises alarm follower (234), and described alarm follower (234) is pointed out, reported to the police according to differential pressure pickup (232) or the signal that sends of recoil counter (233).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2003101176544A CN1312061C (en) | 2003-12-31 | 2003-12-31 | Waste water purifying method and its magnetic puddler integrated device |
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| Application Number | Priority Date | Filing Date | Title |
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| CNB2003101176544A CN1312061C (en) | 2003-12-31 | 2003-12-31 | Waste water purifying method and its magnetic puddler integrated device |
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| CN1634777A CN1634777A (en) | 2005-07-06 |
| CN1312061C true CN1312061C (en) | 2007-04-25 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101817613B (en) * | 2010-03-16 | 2011-09-28 | 王甫华 | Purifier and method for performing advanced treatment on secondarily-polluted drinking water |
| CN108249684B (en) * | 2018-01-31 | 2021-04-13 | 许玉蕊 | Electromagnetic sewage filtering device |
| CN110386726A (en) * | 2019-07-22 | 2019-10-29 | 中国建筑东北设计研究院有限公司 | A kind of Heisui River buck joint processing system and method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1111599A (en) * | 1994-12-13 | 1995-11-15 | 孙同福 | Magnetic filtering sewage purifying method and equipment |
| CN1223967A (en) * | 1998-01-21 | 1999-07-28 | 广东工业大学 | Method for purification of waste water |
| CN1269330A (en) * | 1999-04-02 | 2000-10-11 | 株式会社日立制作所 | Water purifying apparatus and method thereof |
| CN1288779A (en) * | 2000-09-21 | 2001-03-28 | 上海交通大学 | Composite nanometer titanium dioxide/iron powder catalyst and its preparation |
| CN1350477A (en) * | 1999-04-13 | 2002-05-22 | 尤尼瑟奇有限公司 | A photocatalyst |
| CN1460542A (en) * | 2003-05-31 | 2003-12-10 | 福州大学 | Photo-magnetic concerted catalysis technology and application thereof in degrading organic pollutants |
-
2003
- 2003-12-31 CN CNB2003101176544A patent/CN1312061C/en not_active Expired - Lifetime
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1111599A (en) * | 1994-12-13 | 1995-11-15 | 孙同福 | Magnetic filtering sewage purifying method and equipment |
| CN1223967A (en) * | 1998-01-21 | 1999-07-28 | 广东工业大学 | Method for purification of waste water |
| CN1269330A (en) * | 1999-04-02 | 2000-10-11 | 株式会社日立制作所 | Water purifying apparatus and method thereof |
| CN1350477A (en) * | 1999-04-13 | 2002-05-22 | 尤尼瑟奇有限公司 | A photocatalyst |
| CN1288779A (en) * | 2000-09-21 | 2001-03-28 | 上海交通大学 | Composite nanometer titanium dioxide/iron powder catalyst and its preparation |
| CN1460542A (en) * | 2003-05-31 | 2003-12-10 | 福州大学 | Photo-magnetic concerted catalysis technology and application thereof in degrading organic pollutants |
Non-Patent Citations (5)
| Title |
|---|
| 二氧化钛催化剂其在废水有机污染物处理中的应用展望 武荣国，楚雄师专学报，第16卷第3期 2001 * |
| 磁化技术在水处理方面的应用 王克宁等，北方环境，第1期 2000 * |
| 磁化技术在水处理方面的应用 王克宁等，北方环境，第1期 2000;磁化用于有机废水处理的试验研究 雒文生等，武汉水利电力大学学报，第33卷第5期 2000;二氧化钛催化剂其在废水有机污染物处理中的应用展望 武荣国，楚雄师专学报，第16卷第3期 2001;纳米二氧化钛在环保领域中的应用 常红等，矿冶，第11卷第4期 2002 * |
| 磁化用于有机废水处理的试验研究 雒文生等，武汉水利电力大学学报，第33卷第5期 2000 * |
| 纳米二氧化钛在环保领域中的应用 常红等，矿冶，第11卷第4期 2002 * |
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