CN1308490C - High performance brown gas generator - Google Patents

High performance brown gas generator Download PDF

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Publication number
CN1308490C
CN1308490C CNB031496229A CN03149622A CN1308490C CN 1308490 C CN1308490 C CN 1308490C CN B031496229 A CNB031496229 A CN B031496229A CN 03149622 A CN03149622 A CN 03149622A CN 1308490 C CN1308490 C CN 1308490C
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China
Prior art keywords
electrolyte
electrolytic solution
battery lead
electrolyzer
lead plate
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Expired - Fee Related
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CNB031496229A
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Chinese (zh)
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CN1510172A (en
Inventor
金相湳
金圣坤
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KIM SANG-NAN
KIM SANG NAN
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KIM SANG-NAN
KIM SANG NAN
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A high efficiency brown gas generator is provided which is not only economical, but also obtains the maximum efficiency by reducing electrical resistance through proper setting of electrode plate area, increasing cooling efficiency to constantly maintain electrolyte temperature and adopting natural electrolyte circulation process. The high efficiency brown gas generator comprises a case(10) on a body of which casters(11) are mounted; an electrode plate projecting type electrolytic cell(20) installed inside the case and fixed by an insulation bracket(12); electrolyte tanks(41,41a) connected to the electrolytic cell through connection hose to supply electrolyte and collect brown gas; a cross flow fan(30) comprising a wind guiding box(31) for cooling the electrolytic cell; a power supply impressing unit for impressing a DC power supply; and a control unit, wherein the electrolyte tanks comprising subsidiary tanks are equipped with electrolyte level gauge, water level sensor and water injection port with being formed in a cylinder shape having height of 700 mm or more, the electrolyte tanks are connected to gas exhaust nipples formed on electrolytic cell finishing plates by connection hoses so that brown gas flows upward, and the electrolyte tanks are connected to electrolyte inflow nipples by connection hoses so that electrolyte natural circulation is smoothly performed by directly flowing in electrolyte into the electrolyte tanks through the electrolyte inflow nipples.

Description

Efficient Blang's gas generator
Technical field
The present invention relates to a kind of gas generation technique, a kind of especially relevant Blang's gas generator technology that improves electrolytic efficiency.Set the most suitable battery lead plate area by it,, and improve cooling efficiency, make electrolytic solution keep constant temperature with minimizing resistance.In addition, its adopts electrolytic solution natural recirculating type, with the minimizing expense and given play to top efficiency.
Background technology
With water electrolysis, can generate negative pole hydrogen and anodal oxygen, and the chemical ratios that hydrogen and oxygen occur is 2: 1 air mixture form, Here it is so-called Blang's gas.Blang's gas is complete nuisanceless fuel, and it passes through self oxygen perfect combustion, and is reduced into water vapour, is a kind of optimal fuel, and becomes alternative energy of the 21 century that favored by consumers in general.
For using this Blang's gas to make fuel, need a kind of efficient Blang's gas generator.For Blang's gas being used for boiler, process furnace or factory's automatic heating device,, can occurring any problem yet and have the combustion gas maker of high-durability even need continuous operations 24 hours.
Conventional combustion gas maker is as long as one operate slightly, and electrolyzer temperature will rise immediately, and generates water vapour internally, reduces combustion gas quality, and electrolyzer is cancelled because of overheated.Therefore, be badly in need of a kind of electrolytic solution that can make and keep the homothermic method.
Possess electrolyte circulating pump and scatterer, and adopt the forced cyclic type water-cooling method, also can reduction obtain cooling-down effect, but this mode need expend a lot of unnecessary expenses.Therefore, the efficient Blang's gas generator that is developed into according to this invention has adopted electrolytic solution natural circulation air cooling mode, reducing required expense to greatest extent, and fundamentally brings cooling-down effect, has improved electrolytic efficiency.
In the electrolyzer that adopts the air-cooled type method of cooling that relies on the electrolytic solution natural recirculating type, the most effectively the inventor proposes patent application in nineteen ninety-five, and the air-cooled type electrolyzer of detailed description in the practical new case patent of No. the 117445th, practical new case patent of the Korea S of registration in 1998 and Japan No. 3037633 " oxygen maker cell construction " (hereinafter to be referred as referenced patents), this electrolyzer has adopted and has made the outwards outstanding formation of battery lead plate, relies on the mode of fan Direct Air-Cooled.The summary book of this referenced patents thes contents are as follows:
" this invention is different from usual manner, is provided with battery lead plate, partition and O type ring, and vertical battery lead plate, is the scatterer form, can effectively cool off the electrolyzer temperature of heating, easily decomposes maintenance, is located at its inner electrolytic solution filling chamber and can also generates high-quality oxygen.
That is, the electrolyzer of this invention vertically form semicircle shape, and portion is provided with electrolytic solution filling chamber within it with turn buckle connection electrode plate and partition, and two ends configuration gas box and water tank are effectively filled electrolytic solution in electrolyzer filling chamber up and down.Wherein, the electrolyzer of filling electrolyte is heat sink format, and extraneous air passes through between the battery lead plate, with effective cool electrolysis cells.”
As described in this referenced patents, use the battery lead plate protruding-type electrolyzer of electrolytic solution natural recirculating type, its battery lead plate is established relatively, a plurality of battery lead plates vertically connect across electrolytic solution filling chamber respectively, and by being connected in the pipeline of electrolyzer two side cover plates bottom suction nozzle, from water tank supply electrolytic solution, the Blang's gas that generates in the electrolyzer, pipeline by linking to each other with the upper end exhaust nozzle rises to gas box, so that the electrolytic solution natural circulation.
In this electrolytic solution natural recirculating type electrolyzer, particularly the important point is exactly, Blang's gas electrolyzer is inner generate after, the discharge that should directly make progress, and electrolytic solution also should be filled at any time.Otherwise, will form the space of the electrolytic solution amount of capacity of discharge, this part can't form the electrolysis phenomenon, thereby reduces electrolytic efficiency, finally causes superheating phenomenon.
If electrolyzer is overheated, will generate water vapour, cause combustion gas quality to descend, damage the O type ring between the battery lead plate, and cause electrolyte leakage, cause spark, electrolyzer is cancelled, this point has proved absolutely the importance of electrolyte flow.
Summary of the invention
In order fundamentally to address these problems, ensure the smooth and easy circulation of electrolytic solution, need reduce the quantity of battery lead plate, shorten electrolyte path.But can not blindly reduce battery lead plate, so an amount of the setting is the key of dealing with problems.Reduce battery lead plate quantity, effective electrolysis area of unit electrode plate will increase thereupon, should fully take into account these mutual relationships when dealing with problems.
Wherein, the most flimsy is O type ring, so for improving its endurance quality, it is special concavo-convex that O type ring cross section should be, but not simple circle.
Therefore, the present invention has carried out improved treatment to the O type ring of electrolyzer, and for improving its weather resistance, guarantee the smooth and easy circulation of electrolytic solution of electrolyzer, reduced battery lead plate quantity, and set optimum battery lead plate useful area, to reduce resistance, formed the effective electrolysis that fundamentally reduces temperature.
In addition, use the cross flow fan that laterally is provided with the air port, the shape in its air port conforms to electrolyzer with size, improved air-cooling efficiency, made electrolytic solution keep constant temperature, and made the electrolytic solution case be higher cylindric, to guarantee the electrolytic solution natural circulation, provide whole structure outstanding Blang's gas generator.
For addressing the above problem, efficient Blang's gas generator is provided, at first should suitably set the useful area of battery lead plate, adopt the fundamentally method of cooling.
The area of suitably setting battery lead plate is the key of dealing with problems, so the present invention has only selected the electrolyzer that obtains actual authentication for use in the comparatively practical effective electrolysis of developing so far.
Therefore, the present invention calculates and has pointed out the electrical energy of input and the ratio of oxyhydrogen generating capacity, and for improving electrolyzer efficient, makes comparisons with the situation of electrolytic efficiency 100%, has adopted following method: according to Faraday's electromagnetic indution law,
1) the material total amount that is discharged in the electrode by electrolysis is directly proportional with total amount of electric charge by electrode.
2) the material total amount that electrode generated is directly proportional with the chemical equivalent of this material.(quantity of electric charge that is equivalent to Faraday's number will discharge the chemical equivalent of decomposed substance.)
3) Faraday's number=9.648670 * 10 4(C/mol)
Quantity of electric charge when as mentioned above, Faraday's electromagnetic indution law is pointed out electrolysis and the relation between the chemical equivalent.
The chemical equivalent of water equals the chemical equivalent sum of hydrogen and oxygen, is 9 (g).Therefore,, revise the electrolysis equation coefficients of water, just draw following equation according to the chemical equivalent 9 (g) of water:
(g)
×22.4(L)+×22.4(L)=16.8(L)
×2(g)+×32(g)=9(g)
From aforesaid equation as can be known, the hydrogen-oxygen tolerance that is equivalent to the chemical equivalent 9 (g) of water is 16.8 (L).
For obtaining the gas of 16.8 (L), will in 1 hour, supply 9.648670 * 10 4(C/mol) the quantity of electric charge is so calculate the required magnitude of current in the following manner.
Q(C)=I(A)×t(Sec)
I = Q t = 96486.70 3600 = 26.80 ( A )
Then, in 1 hour, continue the electric current of supply 26.80 (A),, calculate electric weight in the following manner for drawing the gas of 16.8 (L).If electrolytic solution at this moment is KOH, general 2.1 (V) that adopt of the voltage between the electrode.
P=V×I×h
=2.1×26.8×1=56.28(W)
At last, drop into the electrical energy of 56.28 (W), the oxyhydrogen total amount of generation is 16.8 (L), just means that its efficient has reached 100%.
That is, 16.8/56.28=298.5 (l/W) or 56.28/16.8=3.35 (W/l).
Therefore, if any electrolyzer newly developed, it is fixed just can to utilize voltameter and gas quantity to measure instrumentation, and makes comparisons with 298.5 (l/kW), calculates its electrolytic efficiency.
The method of calculation that describe the battery lead plate proper area in detail are as follows:
The Model B K-6000 Blang gas generating unit that No. the 0275504th, patent of applying for the registration of at first according to the inventor and Japanese Patent No. 3130014 " being provided with a large amount of generating units of Blang's gas of block form electrolyzer " are developed, drop into 23kW voltage, generate 6600 (l) Blang gas.
Therefore, its power is 6600/23=286.9 (l/kW),
And draw according to 286.9/298.5=0.96, its electrolytic efficiency is 96%.
The battery lead plate total area of BK-6000 is 94,080cm 2So, learn 94080/6600=14.25cm 2/ l.From now on, the battery lead plate area will be with 14.25cm 2The block form effective electrolysis unit surface of/l is as its standard value.
Therefore, in the efficient Blang's gas generator that is developed into according to the present invention, every combustion gas turnout (l) is suitable for 14.25cm 2The battery lead plate unit surface, and set battery lead plate quantity and unit electrode plate area with this, form electrolyzer, fundamentally improve electrolytic efficiency.
In sum, the calculation formula of battery lead plate area is as follows:
Battery lead plate area (cm 2)=14.25 * combustion gas generating capacity (l)
As mentioned above, the Blang's gas generator that is developed into according to the present invention is locked as 14.25cm with setting the required standard value of battery lead plate area 2/ l, develop the effective electrolysis that can fundamentally reduce superheating phenomenon, and by the cross flow fan identical with the length of electrolyzer is set, improve cooling efficiency, solved noise problem, make the electrolytic solution case be higher cylindric, to guarantee the smooth and easy circulation of electrolytic solution, strengthened the combustion gas formation efficiency of natural recirculating type battery lead plate protruding-type electrolyzer, and the most flimsy O type ring cross section is made into special concavo-convex, strengthened its endurance quality, even if long-time the use the electrolyte leakage phenomenon can not occur yet.From whole aspect, improved electrolytic efficiency greatly, make it under 24 hours situation of continuous operations, also any problem can not occur, and to make Blang's pneumatolytic be fuel worthy of the name.
Efficient Blang's gas generator industry of the being mainly used in automatic heating device that is developed into according to the present invention also can be widely used in greenhouse fuel supply devices such as boiler, makes that Blang's pneumatolytic is the alternative energy of 21 century of gaining great popularity.
Description of drawings
Below in conjunction with accompanying drawing in detail concrete structure of the present invention is described in detail
Fig. 1 is an one-piece construction assembling exemplary plot of the present invention
Fig. 2 is the cross-sectional view of Fig. 1
Fig. 3 is the assembling sectional view of one of composition structure of the present invention electrolyzer
Fig. 4 is one of composition structure of the present invention electrolyzer accessory decomposing schematic representation
Fig. 5 is one of composition structure of the present invention O type ring sectional view and detailed annotation figure
Fig. 6 is provided with the electrolytic solution case assembling synoptic diagram of auxiliary tank for one of composition structure of the present invention
Fig. 7 is an overall system view of the present invention
Major portion nomenclature among the figure
10 casings, 11 rollers, 12 insulator supports
20 electrolyzers, 21 battery lead plate 21a backguy screws
21b electrolyte stream through hole 21c ventilating pit 22 partitions
23 O type rings, 24 cover plates, 25 electrolyte entrances
26 exhaust nozzles, 27 turn buckles, 28 power ports
Electrolytic solution filling chambers 29 30 cross flow fans
31 air inducing casees, 41 electrolytic solution casees, 42 auxiliary tanks
43 electrolytic solution water level gauges, 50 water filling ports, 60 water level sensors
70 pressure switches, 80 electric supply installations, 90 control device
Embodiment
As Fig. 1~shown in Figure 7, the efficient Blang's gas generator that is developed into according to the present invention has following constructional feature: promptly, the Blang's gas generator that has roller 11 is provided with corresponding casing 10; Casing 10 inside fixedly install battery lead plate protruding-type electrolyzer 20 with insulator support 12; Be connected in the electrolytic solution case 41 that electrolyzer 20 is supplied electrolytic solution and compiled Blang's gas; Cool off the cross flow fan 30 of this electrolyzer 20; The electric supply installation 80 of supplying DC power source and control device 90.
As Fig. 3~shown in Figure 5, four jiaos of battery lead plate protruding-type electrolyzer 20 are provided with backguy screw 21a; Be provided with the battery lead plate 21 of electrolyte stream through hole 21b and ventilating pit 21c; For making quadrangle become the backguy screw 22a partition 22 of insulating material injection moulding; Be anti-electrolyte leakage O type ring 23 that the alkali resistance elastomeric material makes and cover plate 24,24a.Between battery lead plate and battery lead plate 21, cross connection partition 22 and O type ring 23, to form electrolytic solution filling chamber 29, quantitative arrangement battery lead plate 21 is provided with one-piece type electrolyzer cover plate 24,24a in its both sides, and connects with turn buckle 27 assemblings.
Electrolyzer 20 among the present invention has following constructional feature: promptly, be suitable for the formula of " battery lead plate area=14.25 * combustion gas turnout ", and calculate the battery lead plate area according to the combustion gas turnout of Blang's gas generator, set the useful area of an amount of battery lead plate 21 and unit electrode plate 21, calculate O type ring 23 internal diameters of the actual loading level of electrolytic solution, set the size of partition 22 and battery lead plate 21 with this.
Utilize air inducing case 31 to cover the gabarit of electrolyzer, bring maximum cooling performance by cross flow fan 30.
As shown in Figure 5, O type ring 23 cross sections are not the circle that is simple, but form depression 23b and protruding 23a state, and be compressed and be fixed between battery lead plate 21 and the battery lead plate 21, strengthened its weather resistance with this, even if long-time the use the electrolyte leakage phenomenon can not occur yet.
As shown in Figure 6 and Figure 7, electrolytic solution case 41 of the present invention, 41a have following constructional feature: promptly, be cylindric, highly reach more than the 700mm, be provided with electrolytic solution water level gauge 43, water level sensor 60 and water filling port 50, and, improve cooling efficiency for the enough electrolytic solution of storage, also be provided with auxiliary tank 42,42a.The exhaust nozzle 26, the 26a that are located on top stem bar 44,44a and electrolyzer cover plate 24, the 24a on electrolytic solution case 41, the 41a link to each other with pipe connecting 46,46a; Bottom stem bar 45,45a are by pipe connecting 47, and 47a is connected with electrolyte entrance 25,25a; The Blang's gas that generates in the electrolyzer 20 will move on pipe connecting 46,46a, finally come together in electrolytic solution case 41,41a top, and along fuel gas line 49, through adverse current preventer (not shown), be supplied to burner.
As shown in Figure 7, total system of the present invention has following constructional feature: promptly, the left and right sides is respectively equipped with same electrolytic solution case 41,41a, and electrolytic solution case 41,41a all have electrolyzer 20 and auxiliary tank 42,42a, and clearly distinguish positive source and power cathode, in case leaky appears.
Supply power supply from DC power supply apparatus 80 to the cathode power supply port 28 and the negative power supply port 28a that are located on electrolyzer cover plate 24, the 24a, will generate Blang's gas immediately, and along pipe connecting 46,46a, upwards enter electrolytic solution case 41,41a, electrolytic solution can directly be replenished along pipe connecting 47,47a, forms natural circulation phenomenon smoothly.
The Blang's gas generator that is developed into according to the present invention also has following characteristics: promptly, increase along with gas consumption, by " ON ", " OFF " running of pressure switch 70, can generate combustion gas automatically and generate combustion gas with stopping, just operate repeatedly by maneuvering system.For example, close switch-valve 75, will stop generating combustion gas.In addition, overvoltage alarm unit and be able to automatic control by control device 90 by the water shortage alarm unit that water level sensor 60 is formed.
Compare as follows with the new model BN-600 that develops according to invention the conventional Model B S-600 (combustion gas growing amount 600l/h) of the existing actual production of present inventor:
The battery lead plate area of the BN-600 type Blang gas generator that is developed into according to the present invention is 14.25cm 2/ l * 600l/h=8550cm 2If its battery lead plate quantity is 80EA, the useful area of unit electrode plate is exactly 8550cm 2/ 80EA=106.8cm 2, the internal diameter of O type ring is 116 .
Consider key elements such as the size of O type ring and partition and area of dissipation, the actual size of battery lead plate is decided to be W155 * H180.
Its electrolyzer two ends apply the electric power of 160V * 13A, generate the combustion gas of 600l/h, and current consumption is 3.7W/l, and electrolytic efficiency is 96%.
This and conventional BS-600 (current consumption is that 4.2W/l, battery lead plate quantity are 105EA) type Blang's gas generator are compared, and electrolytic efficiency has increased by 12%.
Because of the quantity of battery lead plate reduces 25, thereby reduced manufacturing cost, and the center of circle shape aerofoil fan of routine has been replaced to cross flow fan, improved cooling efficiency, air quantity has been reduced to 1/3rd.The aerofoil fan of conventional model needs very high blast and air quantity for playing radiating effect, can cause very big noise, and the present invention has then successfully solved this problem.

Claims (3)

1, a kind of efficient Blang's gas generator is characterized in that: the Blang's gas generator that has roller (11) is provided with corresponding casing (10); Casing (10) is inner to be fixed with battery lead plate protruding-type electrolyzer (20) with insulator support (12); Be connected in electrolyzer (20) supply electrolytic solution and compile Blang's gas the electrolytic solution case (41,41a); Cool off this electrolyzer (20) and be provided with the cross flow fan (30) of air inducing case (31); Electric supply installation of supplying DC power source (80) and control device (90), and between the battery lead plate (21) of battery lead plate protruding-type electrolyzer (20), answer cross connection partition (22) and O type ring (23), be arranged in electrolytic solution filling chamber (29), utilize turn buckle (27) to connect one-piece type electrolyzer cover plate (24), and calculate the size and the quantity of battery lead plate (21) with the formula of " battery lead plate area=14.25 * combustion gas growing amount " in its two ends assembling.
2, efficient Blang's gas generator as claimed in claim 1, it is characterized in that: O type ring (23) cross section that forms electrolytic solution filling chamber (29) is not the circle that is simple, and should form depression 23b and protruding 23a state, and be compressed and be fixed between the battery lead plate (21).
3, efficient Blang's gas generator as claimed in claim 1, it is characterized in that: the electrolytic solution case (41,41a) that has auxiliary tank (42,42a) is cylindric, height and is provided with electrolytic solution water level gauge (43), water level sensor (60) and water filling port (50) more than 700mm; Be located at exhaust nozzle on the electrolyzer cover plate (24,24a) (26,26a) and pipe connecting (46,46a) and link to each other, and electrolyte entrance (25,25a) and pipe connecting (47,47a) are linked to each other.
CNB031496229A 2002-12-21 2003-08-01 High performance brown gas generator Expired - Fee Related CN1308490C (en)

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KR20020082075 2002-12-21
KR10-2002-0082075A KR100503886B1 (en) 2002-12-21 2002-12-21 High Efficiency Brown Gas Generator

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KR100620801B1 (en) * 2005-02-14 2006-09-13 (주)국제에너지 A hydrogen and oxygen generator with high electrolytic efficiency and its using method
JP4796373B2 (en) * 2005-10-25 2011-10-19 株式会社 セロテクノロジー Fuel gas generator
JP4074322B2 (en) * 2006-07-06 2008-04-09 炳霖 ▲楊▼ Combustion gas generator using electrolysis and in-vehicle combustion gas generator
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KR100780515B1 (en) * 2006-12-20 2007-11-30 김상남 Brown gas auto supply apparatus using an air cooling electrolyzer
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JP2011058015A (en) * 2009-09-07 2011-03-24 Toyo Tanso Kk Electrolytic device
WO2012056751A1 (en) * 2010-10-29 2012-05-03 有限会社T&K Water electrolysis device and fuel supply apparatus provided with water electrolysis device
KR101360353B1 (en) * 2011-07-04 2014-02-07 서용석 Brown gas generator
JP6100386B2 (en) * 2013-09-27 2017-03-22 フレンド株式会社 Hydrogen gas generator
CN105297071A (en) * 2015-10-29 2016-02-03 鹤山市嘉德环保科技有限公司 High-energy gas
ES2785775B2 (en) * 2019-04-03 2021-03-26 H Inven Grup Xxi S L DEVICE FOR SUBMERGED ELECTROLYTIC WATER ELECTROLYSIS

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CN1510172A (en) 2004-07-07

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