CN1307276C - Environmental protection fire retardant hot-melt film adhesive in user for electric clothes - Google Patents
Environmental protection fire retardant hot-melt film adhesive in user for electric clothes Download PDFInfo
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- CN1307276C CN1307276C CNB2005100949099A CN200510094909A CN1307276C CN 1307276 C CN1307276 C CN 1307276C CN B2005100949099 A CNB2005100949099 A CN B2005100949099A CN 200510094909 A CN200510094909 A CN 200510094909A CN 1307276 C CN1307276 C CN 1307276C
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- environmental protection
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- melt adhesive
- fire retardant
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Abstract
The present invention relates to an environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth, which is characterized in that according to weight, the environmental protection combustion stopping hot-melt adhesive film is composed of 30% to 50% of hot-melt adhesive, 5% to 10% of Sb2O3, 5 to 10% of ZnB, 10 to 30% of tri (2, 3-dibromopropyl) isotripolycyanate and 10% to 30% of hexabromododecane, and the sum of the weight percentage of the components is 100%. The environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth has good combustion stopping performance, UL94V-O grade can be achieved, the environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth is compounded on the surface of the electric conduction cloth, and the requirement of stopping combustion is easily achieved. The environmental protection combustion stopping hot-melt adhesive film for electric conduction cloth has nontoxic and tasteless materials and conforms to the requirement of environmental protection.
Description
Technical field:
The present invention relates to a kind of hot melt adhesive film, be specifically related to a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric.Be compound in the conductive fabric surface, play fire retardation.
Background technology:
Conductive fabric is applied to electron trade and plays electric action, because therefore the singularity of electron trade be furnished with fire-retardant requirement to conduction.Before effect of the present invention, traditional conductive fabric flame resistant method is that conductive fabric is flooded fire retardant, as polybromodiphenyl ether, but polybromodiphenyl ether when burning syntheticly generate poisonous carcinogens and disabled, and the conductive fabric electrical and thermal conductivity is good, is difficult to realize fire-retardant than general cloth.
Summary of the invention:
The objective of the invention is to overcome above-mentioned deficiency, a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric of realizing fire-retardant requirement and meeting environmental protection again of being easy to is provided.
The object of the present invention is achieved like this: a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric is characterized in that: it is made up of the raw material of following weight part:
30～50 parts of hot melt adhesives
5～10 parts of antimonous oxides
5～10 parts of zinc borates
10～30 parts of three (2, the 3-dibromopropyl) isocyanuric acid esters
10～30 parts of hexabromo dodecanes
The present invention is used for the environmental protection fire retardant hot-melt film adhesive in user of conductive fabric, and described hot melt adhesive adopts polyester or urethane.
Hot melt adhesive plays the melted by heat bonding effect in the raw material of the present invention in fire retardant hot-melt film adhesive in user, has higher softening temperature and good cementability;
Antimonous oxide plays fire retardation in fire retardant hot-melt film adhesive in user, halogen flame is had tangible synergistic effect;
Zinc borate is a kind of inorganic combustion inhibitor, plays fire-retardant synergistic effect in fire retardant hot-melt film adhesive in user, and Heat stability is good eliminates smoke, and is nontoxic, effective with other fire retardant compositional flame-retardant;
Three (2, the 3-dibromopropyl) isocyanuric acid ester plays fire retardation in fire retardant hot-melt film adhesive in user, good flame retardation effect, and volatility is low, and consistency is good, and is durable, fast light, water-fast and nontoxic;
The hexabromo dodecane plays fire retardation in fire retardant hot-melt film adhesive in user, have enough thermostabilitys, and good free-running property is minimum to the hot melt adhesive performance impact;
Three (2, the 3-dibromopropyl) isocyanuric acid esters and hexabromo dodecane are used in combination the performance impact of hot melt adhesive less; Antimonous oxide and three (2, the 3-dibromopropyl) isocyanuric acid ester and hexabromo dodecane are used in combination and have good synergistic function, flame retardant effect obviously improves, because at high temperature decomposing, halogen compounds emits hydrogen halide, except suppressing the burning by Mulberry Extract HO terminating chain lock reactor, also, generate low melting point quantized antimony halides of energy and zirconyl oxyhalides antimony with the antimonous oxide reaction; Three (2, the 3-dibromopropyl) isocyanuric acid esters and antimonous oxide are used in combination, and obviously reduce the material combustion smoke density, reduce environmental pollution.
Therefore, good flame resistance of the present invention can reach the UL94V-O level, it is compound in the conductive fabric surface is easy to realize fire-retardant requirement; Raw materials used in addition nontoxic, tasteless, compliance with environmental protection requirements.
Embodiment:
Embodiment 1;
Step 1, get polyester 50 weight parts and add in the stirrer, be heated to 150 ℃, add antimonous oxide 5 weight parts, zinc borate 5 weight parts, three (2, the 3-dibromopropyl) isocyanuric acid ester 30 weight parts and hexabromo dodecane 10 weight parts again, heating keeps 150 ℃, stir compound;
Step 2, step 1 got compound place granulation in the tablets press, oven dry, hot melt adhesive tablet;
Step 3, step 2 is got hot melt adhesive tablet place and be blow molded into the tubular glued membrane in the blowfilm shaping machine;
Step 4, use side cutter cuts both sides make the tubular glued membrane become biplate shape glued membrane, film thickness 0.08mm.
Embodiment 2:
Step 1, get urethane 30 weight parts and add in the stirrer, be heated to 130 ℃, add antimonous oxide 10 weight parts, zinc borate 10 weight parts, three (2 again, the 3-dibromopropyl) isocyanuric acid ester 20 weight parts and hexabromo dodecane 30 weight parts, heating and keep 130 ℃ of temperature, stir compound, all the other steps are with embodiment one.
Embodiment 3:
Step 1, get urethane 45 weight parts to going in the stirrer, be heated to 130 ℃, add antimonous oxide 8 weight parts, zinc borate 7 weight parts, three (2 again, the 3-dibromopropyl) isocyanuric acid ester 10 weight parts and hexabromo dodecane 30 weight parts, heating and keep 130 ℃ of temperature, stir compound, all the other steps are with embodiment one.
Claims (1)
1, a kind of environmental protection fire retardant hot-melt film adhesive in user that is used for conductive fabric, it is characterized in that: it is made up of the raw material of following weight part:
30～50 parts of polyester or urethane
5～10 parts of antimonous oxides
5～10 parts of zinc borates
10～30 parts of three (2, the 3-dibromopropyl) isocyanuric acid esters
10～30 parts of hexabromo dodecanes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100949099A CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100949099A CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1760297A CN1760297A (en) | 2006-04-19 |
| CN1307276C true CN1307276C (en) | 2007-03-28 |
Family
ID=36706528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100949099A Expired - Fee Related CN1307276C (en) | 2005-10-19 | 2005-10-19 | Environmental protection fire retardant hot-melt film adhesive in user for electric clothes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1307276C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101435154B (en) * | 2008-12-18 | 2011-07-27 | 浙江三元电子科技有限公司 | Halogen-free flame-retardant conductive fabric and production method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338174B (en) * | 2008-08-14 | 2011-03-09 | 江阴科隆化工材料有限公司 | Environment protection type halogen-free flame-retardant hot-melt adhesive film for conducting cloth |
| CN105469891A (en) * | 2014-08-29 | 2016-04-06 | 上海硅邦电子科技发展有限公司 | Halogen-free flame-retardant mixed liquor and preparation method thereof and flame-retardant conductive fabric and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273254A (en) * | 1999-05-11 | 2000-11-15 | 福裕化学有限公司 | Flame-retarding composition of polypropylene |
| CN1294146A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Fire-retarding mother particles and preparing process thereof |
| CN1478123A (en) * | 2000-09-29 | 2004-02-25 | ���ҵ�ۼ���ѧͶ�ʿعɹ�˾ | Flame-retardant composition |
-
2005
- 2005-10-19 CN CNB2005100949099A patent/CN1307276C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1273254A (en) * | 1999-05-11 | 2000-11-15 | 福裕化学有限公司 | Flame-retarding composition of polypropylene |
| CN1294146A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Fire-retarding mother particles and preparing process thereof |
| CN1478123A (en) * | 2000-09-29 | 2004-02-25 | ���ҵ�ۼ���ѧͶ�ʿعɹ�˾ | Flame-retardant composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101435154B (en) * | 2008-12-18 | 2011-07-27 | 浙江三元电子科技有限公司 | Halogen-free flame-retardant conductive fabric and production method thereof |
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| Publication number | Publication date |
|---|---|
| CN1760297A (en) | 2006-04-19 |
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